CN102925796A - Non-alloyed ultra-low carbon structure cold-rolled sheet and production method thereof - Google Patents
Non-alloyed ultra-low carbon structure cold-rolled sheet and production method thereof Download PDFInfo
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Abstract
The invention relates to the rolling field of automobile steel plates, and in particular relates to a production method of a non-alloyed ultra-low carbon structure cold-rolled sheet. The production method is characterized in that the steel comprises the chemical components by weight percent: 0.0020-0.0060% of C, less than or equal to 0.10% of Si, 0.30-0.80% of Mn, 0.030-0.080% of P, 0.010-0.025% of S, 0.020-0.060% of ALS, 0.0003-0.0005% of Bs and the balance of Fe and unavoidable impurities. Compared with the prior art, the production method has the advantages that 1) niobium-titanium alloy is omitted, and solution strengthening function of C, P and the like is applied, so that the cost is greatly lowered; and 2) the yield strength and the yield strength of ultra-low carbon steel are improved, the ultra-low carbon steel is guaranteed to have good deep drawing performance, and the produced cold-rolled sheet has high strength and good shaping property so as to meet the using aim of the automobile industry.
Description
Technical field
The present invention relates to the rolling field of automotive sheet, particularly a kind of no-alloyed Ultra-low carbon structure cold-reduced sheet and production method thereof.
Background technology
In the Ultra-low carbon product of Hyundai Motor steel plate, generally all add an amount of niobium or titanium alloy and come C, N in the sublimate steel, improve the formed product performance.The IF steel is gapless atomic steel, have low-yield, low yield strength ratio, yield strength≤190MPa, the characteristics of traditional ultra low-carbon steel be carbon content extremely low≤0.004%, has very strong deformability, prevent the ram-type cracking, require to have simultaneously good r value and n value, with smooth surface after the assurance moulding.21st century, world energy sources was supplied with growing tension, and for alleviating the consumption to the energy of automobile, the while does not affect the security requirement of automobile, and the automobile of high-strength light becomes main flow.
European standard EN10268-2006 proposes a series of Secretaries to the production technology of autobody sheet, wherein HC220Y trade mark steel requires steel plate when having good super deep drawability, structural part and reinforcing member as automobile will have high-strength impact-resistant, both " high strength and ductility ", require ultra low-carbon steel to have high yield strength (σ s=220~270MPa), high-tensile (Rm=350~420MPa), deep drawability (r=1.6~2.2, n=0.18~0.25), good ductility (A80 〉=34%, A50 〉=40%).
Generally adopt to add phosphorus and silicon or manganese in the IF steel, require it to have good mechanical property, and have good anti-secondary processing brittleness, chemical treatment properties and the zinc-plated adaptability of alloying, yield range is very little simultaneously, requires product to have very high stability.General high-strength steel adds niobium titanium alloy when adopting phosphorus as main strengthening element, though close technique is at home and abroad arranged, implementation has obvious difference, and the unit elongation of the method can't satisfy user's demand.
Summary of the invention
The purpose of this invention is to provide a kind of no-alloyed Ultra-low carbon structure cold-reduced sheet and production method thereof, strengthening effect with niobium and titanium in the alternative ultra low-carbon steel of P, make steel plate when having good super deep drawability, have high-strength impact-resistant, satisfy as the structural part of automobile and the performance requriements of reinforcing member.
For achieving the above object, the present invention realizes by the following technical solutions:
The thin brilliant Ultra-low carbon structure cold-reduced sheet of a kind of no-alloyed, the chemical composition of steel is by weight percentage: C 0.0020%~0.0060%, Si≤0.10%, Mn 0.30%~0.80%, P 0.030%~0.080%, S 0.010%~0.025%, AL
S0.020%~0.060%, Bs 0.0003%~0.0005%, and surplus is Fe and inevitable impurity.
The thin brilliant Ultra-low carbon structure of above-mentioned a kind of no-alloyed comprises smelting, continuous casting, hot rolling, cold-rolling pickling, continuous annealing, smooth with the production method of cold-reduced sheet, and the concrete technology parameter is:
1) hot rolling:
Billet heating temperature: 1200~1300 ℃;
Roughing temperature out: 1050~1150 ℃;
Finish rolling start rolling temperature: 1050~1150 ℃;
Hot rolling finishing temperature: 850~930 ℃;
Coiler plate temperature: 580~620 ℃;
2) cold rolling: cold rolling draft: 73~87%;
3) continuous annealing: connect and move back 3~4 ℃/s of temperature rise rate;
Annealing temperature: 820~840 ℃;
Soaking time: 90~130s;
Slow cooling section temperature: 600~550 ℃;
Slow cooling speed: 35~50 ℃/s;
Fast cold section temperature: 400~300 ℃;
Fast cooling rate rate: 35~50 ℃/s;
4) smooth unit elongation: 0.4%~2.0%.
On steel ultra low-carbon steel C≤0.010% basis, increase P content, improve surrender and the tensile strength of ultra low-carbon steel, guarantee that simultaneously it has good deep draw performance, by optimizing the carbon content in the steel, the intensity of the raising steel such as alloying element Mn, Si that interpolation can be strengthened is avoided the secondary processing brittleness of steel, and the simultaneously adding of boron suppresses the secondary processing brittleness of P.
Utilize hot rolling low temperature coiling technique to avoid the formation of FePTi, prevent that it is to the destruction of stampability and high-elongation, avoided because of the two-phase particle inhibition of crystal boundary being improved unit elongation by pure carbon element no-alloyed simultaneously, adjust the cold-rolling process soaking temperature up to making product have { the 111} texture of higher strong punching press more than 820 degree, utilize simultaneously high polishing draft to obtain high tensile strength and yield strength, to guarantee plasticity and the shock resistance of steel.
Compared with prior art, the invention has the beneficial effects as follows:
1) solution strengthening effects such as C, P are used in the adding of cancellation niobium titanium alloy, and the ultra low-carbon steel that adopts high Mn is as main component, P and Mn element are distributed with the effect of crystal grain thinning at grain boundaries, adjusting process makes refined crystalline strengthening, greatly reduces cost and effect stability.
2) improve surrender and the tensile strength of ultra low-carbon steel, guaranteed that simultaneously it has good deep draw performance, produced and namely have high intensity and have again good forming property, satisfied the application target of automotive industry.
Description of drawings
Fig. 1 is continuous annealing process figure of the present invention;
Fig. 2 is cold-rolled products metallograph of the present invention.
Embodiment
The present invention is further described below in conjunction with embodiment:
The thin brilliant Ultra-low carbon structure cold-reduced sheet of a kind of no-alloyed of the present invention, the chemical composition of steel is by weight percentage: C 0.0020%~0.0060%, Si≤0.10%, Mn 0.30%~0.80%, P 0.030%~0.080%, S 0.010%~0.025%, AL
S0.020%~0.060%, Bs 0.0003%~0.0005%, and surplus is Fe and inevitable impurity.Wherein Bs is sour molten boron.
The thin brilliant Ultra-low carbon structure of a kind of no-alloyed comprises smelting, continuous casting, hot rolling, cold-rolling pickling, continuous annealing, smooth with the production method of cold-reduced sheet, and its concrete technology parameter is:
1) hot rolling:
Billet heating temperature: 1200~1300 ℃;
Roughing temperature out: 1050~1150 ℃;
Finish rolling start rolling temperature: 1050~1150 ℃;
Hot rolling finishing temperature: 850~930 ℃;
Coiler plate temperature: 580~620 ℃;
2) cold rolling: cold rolling draft: 73~87%;
3) see Fig. 1, continuous annealing process figure of the present invention: connect and move back 3~4 ℃/s of temperature rise rate;
Annealing temperature: 820~840 ℃;
Soaking time: 90~130s;
Slow cooling section temperature: 600~550 ℃;
Slow cooling speed: 35~50 ℃/s;
Fast cold section temperature: 400~300 ℃;
Fast cooling rate rate: 35~50 ℃/s;
4) smooth unit elongation: 0.4%~2.0%.
Seeing Fig. 2, is cold-rolled products metallograph of the present invention, and cold-rolled products performance test effect of the present invention sees Table 1:
Table 1
Unit elongation A 50 | Yield strength | Tensile strength | R is average | N is average |
40~45 | 222~260 | 350~370 | 1.89~2.1 | 0.19~0.22 |
The present invention has satisfied high yield strength (σ s=220~270MPa), the tensile strength (350~420MPa) of the ultra low-carbon steel that is used for automobile structure and reinforcing member of European EN10268-2006 standard fully, deep drawability (r=1.6~2.2, n=0.18~0.25), the requirement of good ductility (δ 〉=34%).
Owing in steel, not adding the alloys such as Nb or Ti, there is not precipitation strength, the C of Main Basis, Mn, P, N exist in steel with the form of solid solution, so that product has very high intensity, produce and namely have high intensity and have again good forming property, can satisfy the thin brilliant Ultra-low carbon structural steel of no-alloyed of the super deep-draw needs of automotive industry.
Claims (2)
1. thin brilliant Ultra-low carbon structure cold-reduced sheet of no-alloyed, it is characterized in that, the chemical composition of steel is by weight percentage: C 0.0020%~0.0060%, Si≤0.10%, Mn 0.30%~0.80%, P 0.030%~0.080%, S 0.010%~0.025%, AL
S0.020%~0.060%, Bs 0.0003%~0.0005%, and surplus is Fe and inevitable impurity.
2. the production method of the thin brilliant Ultra-low carbon structure usefulness cold-reduced sheet of no-alloyed comprises smelting, continuous casting, hot rolling, cold-rolling pickling, continuous annealing, smooth, it is characterized in that, the concrete technology parameter is:
1) hot rolling:
Billet heating temperature: 1200~1300 ℃;
Roughing temperature out: 1050~1150 ℃;
Finish rolling start rolling temperature: 1050~1150 ℃;
Hot rolling finishing temperature: 850~930 ℃;
Coiler plate temperature: 580~620 ℃;
2) cold rolling: cold rolling draft: 73~87%;
3) continuous annealing: connect and move back 3~4 ℃/s of temperature rise rate;
Annealing temperature: 820~840 ℃;
Soaking time: 90~130s;
Slow cooling section temperature: 600~550 ℃;
Slow cooling speed: 35~50 ℃/s;
Fast cold section temperature: 400~300 ℃;
Fast cooling rate rate: 35~50 ℃/s;
4) smooth unit elongation: 0.4%~2.0%.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103789608A (en) * | 2014-02-11 | 2014-05-14 | 河北钢铁股份有限公司邯郸分公司 | Cold-based ultra-high strength galvanized sheet for structures and production method thereof |
CN109440005A (en) * | 2018-11-14 | 2019-03-08 | 河钢股份有限公司承德分公司 | A kind of SAPH440 crystal grain refinement steel and its production method |
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CN103789608A (en) * | 2014-02-11 | 2014-05-14 | 河北钢铁股份有限公司邯郸分公司 | Cold-based ultra-high strength galvanized sheet for structures and production method thereof |
CN109440005A (en) * | 2018-11-14 | 2019-03-08 | 河钢股份有限公司承德分公司 | A kind of SAPH440 crystal grain refinement steel and its production method |
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