CN102925297A - Foam oil and smoke cleaning agent and preparation method thereof - Google Patents
Foam oil and smoke cleaning agent and preparation method thereof Download PDFInfo
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- CN102925297A CN102925297A CN201210383770XA CN201210383770A CN102925297A CN 102925297 A CN102925297 A CN 102925297A CN 201210383770X A CN201210383770X A CN 201210383770XA CN 201210383770 A CN201210383770 A CN 201210383770A CN 102925297 A CN102925297 A CN 102925297A
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Abstract
The invention discloses a foam oil and smoke cleaning agent and a preparation method thereof. The foam oil and smoke cleaning agent comprises the following components in percentage by mass: 0.03 to 14.5% of surfactant, 0.2 to 15% of alkaline aid, 0.1 to 15.5% of solvent, 0.1 to 2% of corrosion inhibitor, 5 to 40% of propellant, 0.5 to 2% of humectant, and the balance of water, wherein the surfactant is one or two of sodium sec-alkane sulfonate, fatty acid methyl ester sulfonate and fatty acid methyl ester ethoxylates; and the propellant is one or two of liquefied petroleum gas and dimethyl ether. The foam oil and smoke cleaning agent is sprayed in form of foam so as not to be absorbed into body through nose holes and irritate body like common oil and smoke cleaning agent; therefore, the agent is good for the environment and body health of users. In addition, the agent can effectively attach onto vertical surfaces or bottom surface of a hood, so material liquid waste is avoided and the cleaning is more completely.
Description
Technical field
The invention belongs to the clean-out system field, be specifically related to a kind of foam type fumes from cleaning agent and preparation method thereof.
Background technology
Along with China's expanding economy, the raising of living standards of the people, smoke exhaust ventilator has been installed by increasing family.Traditional sino type cooking methods is as sauting, can producing a large amount of oil smoke in the stir-fry, the process such as quick-fried, fried, and the formation of oil smoke mainly is grease, organic matter and thermal degradation thereof or the split product of volatilization.Traditional fumes from cleaning agent uses spray form mostly, and tiny atomizing droplet is easy in the person's of being operated suction body, intense stimulus and harmful; The small droplets that sprays is difficult to stop the long period on the oil smoke surface, causes emulsification times inadequate, and clean effect is relatively poor.
Summary of the invention
In order to solve the problems of the technologies described above, the invention provides a kind of foam type fumes from cleaning agent, adopt green material, good penetrability, foam is abundant, and long with the oil smoke binding time, emulsification is good, strong dirt-removing; Because form of foam has the advantages such as free from extraneous odour, low stimulation, performance gentleness, protection of the environment.
Foam type fumes from cleaning agent of the present invention, contain the mass percent that following component and each component account for described fumes from cleaning agent and be:
Tensio-active agent 0.03 ~ 14.5%;
Alkaline assistant 0.2 ~ 15%;
Solvent 0.1 ~ 15.5%;
Inhibiter 0.1 ~ 2%;
Propelling agent 5 ~ 40%;
Wetting Agent for Printing Inks 0.5 ~ 2%;
Water surplus;
Wherein, described tensio-active agent is a kind of or its two or more arbitrary combination in Seconary Alkane Sulphonate Sodium, fatty acid methyl ester sulfonate or the fatty acid methyl ester ethoxylate;
Described propelling agent is a kind of of liquified petroleum gas or dme or its combination.
Preferably, above-mentioned foam type fumes from cleaning agent, contain the mass percent that following component and each component account for described fumes from cleaning agent and be:
Tensio-active agent 5 ~ 9%;
Alkaline assistant 3 ~ 15%;
Solvent 5 ~ 13.2%;
Inhibiter 0.4 ~ 1.1%;
Propelling agent 18 ~ 27%;
Wetting Agent for Printing Inks 0.5 ~ 2%;
Water surplus;
Wherein, described tensio-active agent is a kind of or its two or more arbitrary combination in Seconary Alkane Sulphonate Sodium, fatty acid methyl ester sulfonate or the fatty acid methyl ester ethoxylate;
Described propelling agent is a kind of of liquified petroleum gas or dme or its combination.
Preferably, described alkaline assistant is a kind of of sodium hydroxide or soda ash or its combination.
Preferably, described inhibiter is a kind of of Sodium Benzoate or Sodium Nitrite or its combination.
Preferably, described solvent is a kind of of propandiol butyl ether, Diethylene Glycol butyl ether or D-limonene or its two or more arbitrary combination.
Preferably, described wetting Agent for Printing Inks is glycerine.
Preferably, above-mentioned foam type fumes from cleaning agent contains the mass percent that following component and each component account for described fumes from cleaning agent and is:
Tensio-active agent:
Seconary Alkane Sulphonate Sodium 0.5-8%,
Fatty acid methyl ester sulfonate 0.03-1.5%,
Fatty acid methyl ester ethoxylate 0.1-5%;
Alkaline assistant:
Sodium hydroxide 0.2-2%,
Soda ash 1-15%;
Solvent:
Propandiol butyl ether 1-5%,
Diethylene Glycol butyl ether 5-10%,
D-limonene 0.1-0.5%;
Inhibiter:
Sodium Benzoate 0.1-1%,
Sodium Nitrite 0.1-1%;
Propelling agent:
Liquefied petroleum gas (LPG) 5-20%,
Dme 5-20%;
Wetting Agent for Printing Inks:
Glycerine 0.5-2%;
Water surplus.
Further preferably, above-mentioned foam type fumes from cleaning agent contains the mass percent that following component and each component account for described fumes from cleaning agent:
Tensio-active agent:
Seconary Alkane Sulphonate Sodium 2-6%,
Fatty acid methyl ester sulfonate 0.15-0.6%,
Fatty acid methyl ester ethoxylate 1-3%;
Alkaline assistant:
Sodium hydroxide 0.2-1%,
Soda ash 5-10%;
Solvent:
Propandiol butyl ether 1-3%,
Diethylene Glycol butyl ether 6-8%,
D-limonene 0.1-0.3%;
Inhibiter:
Sodium Benzoate 0.1-0.5%,
Sodium Nitrite 0.1-0.5%;
Propelling agent:
Liquefied petroleum gas (LPG) 10-20%,
Dme 10-15%;
Wetting Agent for Printing Inks:
Glycerine 0.5-1%;
Water surplus.
The preparation method of above-mentioned foam type fumes from cleaning agent comprises the steps:
1) in container A, adds solvent, wetting Agent for Printing Inks and tensio-active agent first, make it dissolving;
2) in container B, add entry, add again alkaline assistant and inhibiter, make it dissolving.
3) material in the container A is poured in the container B, mixed, filter;
4) feed liquid that step 3) is obtained is carried out can, sealing, and the filling propelling agent is finished product.
The present invention can reach following technique effect:
1) foam type fumes from cleaning agent provided by the present invention, spray pattern is foam type, has avoided common fumes from cleaning agent atomizing type because easily sucking the nostril to the stimulation that human body produces, and is conducive to protection of the environment and the user is healthy.
2) foam type fumes from cleaning agent provided by the present invention, owing to use formulation to be foam type, can effectively be attached on vertical surface and the lower surface lampblack dirty, reduced the waste of feed liquid, improved utilization ratio, increased the action time of feed liquid and lampblack dirty, so that emulsifying effectiveness is more thorough, cleaned cleaner.
3) foam type fumes from cleaning agent provided by the present invention, the tensio-active agent Seconary Alkane Sulphonate Sodium SAS that adopts has anti-hard water and foaming power is good, in the presence of highly basic, high temperature, oxygenant, still has superior infiltration, emulsification, degreasing, washing ability;
Fatty acid methyl ester sulfonate MES has good soil release characteristics, anti-hard water, calcium soap dispersiveness, whipability, low irritant;
Nonionogenic tenside fatty acid methyl ester ethoxylate FMEE, water-soluble speed is fast, and strong to the grease solubilising, skin irritation is little, and eco-toxicity is low.
Three kinds of tensio-active agents all have the characteristics such as safe, efficient, that biological degradability is good, are green surfactant; Three kinds of raw materials carry out ratio optimization, have the advantages such as high bubble, strong osmotic, anti-highly basic, low stimulation, and obstinate oil smoke is had the strong dirt-removing effect.
4) foam type fumes from cleaning agent provided by the present invention owing to added wetting Agent for Printing Inks in the feed liquid, so that the foam that feed liquid forms keeps good wettability, has increased the action time to lampblack dirty, permeates more abundant.
5) foam type fumes from cleaning agent provided by the present invention, used propelling agent dme has the advantages such as inertia, non-corrosiveness, non-carcinogenesis.Also have good compatibility, can be miscible with most of polarity and non-polar organic solvent, also lampblack dirty there are hydrotropy, loosening effect among the present invention.
Embodiment
The invention will be further described for following specific embodiment, can be implemented so that those skilled in the art can better understand the present invention also, but illustrated embodiment is not as a limitation of the invention.
As shown in table 1, the prescription of the foam type fumes from cleaning agent of embodiment 1 ~ 11
Table 1
| Embodiment | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 |
| Seconary Alkane Sulphonate Sodium % | 8 | 0.5 | 5 | 2 | 6 | 8 | — | 5 | 7 | — | 14.5 |
| Fatty acid methyl ester sulfonate % | 0.03 | 1.5 | 0.3 | 0.6 | 0.15 | — | — | — | 1 | 0.03 | — |
| Fatty acid methyl ester ethoxylate % | 0.1 | 5 | 2 | 3 | 1 | — | 5 | 4 | — | — | — |
| Sodium hydroxide % | 2 | 0.2 | 0.5 | 0.2 | 1 | — | 1.5 | 0.2 | 0.8 | 0.2 | — |
| Soda ash % | 1 | 14 | 7 | 10 | 5 | 15 | — | 12 | 12 | — | 15 |
| Propandiol butyl ether % | 5 | 1 | 5 | 3 | 2 | — | 3 | 5 | 2 | — | — |
| Diethylene Glycol butyl ether % | 5 | 10 | 8 | 7 | 6 | 10 | 8 | — | 7 | 15.5 | — |
| D-limonene % | 0.1 | 0.5 | 0.2 | 0.1 | 0.3 | — | — | — | — | — | 0.1 |
| Sodium Benzoate % | 1 | 0.1 | 0.2 | 0.1 | 0.5 | 0.6 | — | 0.1 | 0.5 | — | 0.1 |
| Sodium Nitrite % | 0.1 | 1 | 0.2 | 0.5 | 0.1 | — | 0.6 | — | 0.3 | 2 | 0.1 |
| Liquified petroleum gas % | 20 | 5 | 12 | 10 | 15 | — | 20 | 15 | 10 | 40 | — |
| Dme % | 5 | 20 | 8 | 15 | 12 | 18 | — | 5 | 10 | — | 5 |
| Glycerine % | 0.5 | 2 | 0.8 | 1 | 0.7 | 2 | 0.5 | 1 | 1 | 2 | 0.5 |
| Deionized water % | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus | Surplus |
The preparation method of the foam type fumes from cleaning agent of embodiment 1 ~ 11:
1) in container A, adds first solvent (a kind of or its combination of propandiol butyl ether, Diethylene Glycol butyl ether or D-limonene), wetting Agent for Printing Inks (glycerine), tensio-active agent (a kind of or its two or more arbitrary combination in Seconary Alkane Sulphonate Sodium, fatty acid methyl ester sulfonate or the fatty acid methyl ester ethoxylate), stir, make it dissolving;
2) in container B, add entry, add alkaline assistant (a kind of or its combination of sodium hydroxide or soda ash), inhibiter (a kind of or its combination of Sodium Benzoate or Sodium Nitrite), stir and make it dissolving.
3) material in the container A is poured in the container B, stirred, make it fully to mix, filter with 300 mesh filter screens;
4) feed liquid that step 3) is obtained is carried out can, sealing, and filling propelling agent (a kind of or its combination of liquified petroleum gas or dme), under (25 scholar 1) ℃ condition, the internal pressure of product is finished product less than 0.8 M Pa.
The effect experimental technique:
Select 6 experimenters, the 1# experimenter cleans the 1# lampblack absorber with 16 kinds of samples respectively, and the 2# experimenter cleans the 2# lampblack absorber with 16 kinds of samples respectively ..., by that analogy.The experimenter carries out actual cleaning operation to smoke exhaust ventilator, during sprinkling smell (nasil), pungency (to the pungency of eyes, skin), sticking power is passed judgment on, and after 15 minutes detersive power is passed judgment on.To 16 kinds of samples, respectively detersive power, pungency, smell, sticking power are given a mark at last, marking standard such as following table add up to the high person's whole structure of score best.
Table 2 marking standard
| Sequence number | Effect is described | Detersive power | Pungency | Smell | Sticking power |
| 1 | Good | 1 | 1 | 1 | 1 |
| 2 | In | 0 | 0 | 0 | 0 |
| 3 | Poor | -1 | -1 | -1 | -1 |
Annotate: the marking of detersive power is defined as: spray the sample of identical grammes per square metre, reacted 15 minutes, then use the rag wiping, and observing effect, the marking regulation:
Good (gently wiping, any surface finish is without oil stain) 1, in (firmly wiping, a small amount of oil stain of remained on surface) 0, poor (wiping of exerting oneself, nearly unavailable)-1.
Irritating marking is defined as: good (non-stimulated) 1, in (general stimulate) 0, poor (intense stimulus)-1.
The marking of smell regulation: good (non-stimulated, savory) 1, in (minimal irritation) 0, poor (intense stimulus, British plain spirits)-1.
The sticking power experimental technique: with each sample respectively spray attachment observe and adhere to the time in vertical surface and the lower surface of lampblack absorber, the marking regulation: good (adhering to more than 3 minutes) 1, in (adhering to 1-3 minute) 0, poor (adhering to below 1 minute)-1.
Table 3 detersive power marking situation
Table 4 pungency marking situation
Table 5 smell marking situation
Table 6 sticking power marking situation
The comprehensive marking situation of table 7
| Sample | Detersive power | Pungency | Smell | Sticking power | Add up to |
| Commercially available prod 1 | 3 | -6 | -6 | -6 | -15 |
| Commercially available prod 2 | 2 | -6 | -6 | -6 | -16 |
| Commercially available prod 3 | 4 | -6 | -6 | -6 | -14 |
| Commercially available prod 4 | 2 | 2 | 4 | -6 | 2 |
| Commercially available prod 5 | 4 | -6 | -6 | -6 | -14 |
| Embodiment 1 | 5 | 6 | 3 | 5 | 19 |
| Embodiment 2 | 5 | 6 | 3 | 3 | 17 |
| Embodiment 3 | 6 | 6 | 6 | 6 | 24 |
| Embodiment 4 | 5 | 6 | 6 | 4 | 21 |
| Embodiment 5 | 5 | 6 | 6 | 3 | 20 |
| Embodiment 6 | 5 | 4 | 4 | 3 | 16 |
| Embodiment 7 | 4 | 3 | 3 | 5 | 15 |
| Embodiment 8 | 4 | 3 | 4 | 4 | 15 |
| Embodiment 9 | 4 | 3 | 3 | 4 | 14 |
| Embodiment 10 | 4 | 3 | 4 | 1 | 12 |
| Embodiment 11 | 4 | 3 | 4 | 2 | 13 |
In table 2 ~ 7, commercially available prod 1 ~ 5 refers to the common spray-type fumes from cleaning agent of commercially available different brands.
Can find out from the above results:
1, product of the present invention is starkly lower than other commercially available prod to the pungency of eyes, skin, illustrated foam type fumes from cleaning agent of the present invention in use should not descend slowly and lightly other positions of human body, should not be sucked by human body, the operator's is healthy thereby protected.
2, detersive power of the present invention and sticking power are apparently higher than other commercially available prod, formulation was foam type when foam type fumes from cleaning agent operation of the present invention had been described, had prolonged the action time of material and oil smoke, made it abundant reaction, both reduce the material waste, reached again the strong dirt-removing effect.
3, foam type fumes from cleaning agent net effect of the present invention is better than commercially available common spray-type fumes from cleaning agent.
The above embodiment is the preferred embodiment that proves absolutely that the present invention lifts, and protection scope of the present invention is not limited to this.Being equal to that those skilled in the art do on basis of the present invention substitutes or conversion, all within protection scope of the present invention.Protection scope of the present invention is as the criterion with claims.
Claims (9)
1. a foam type fumes from cleaning agent is characterized in that, contains the mass percent that following component and each component account for described foam type fumes from cleaning agent to be:
Tensio-active agent 0.03 ~ 14.5%;
Alkaline assistant 0.2 ~ 15%;
Solvent 0.1 ~ 15.5%;
Inhibiter 0.1 ~ 2%;
Propelling agent 5 ~ 40%;
Wetting Agent for Printing Inks 0.5 ~ 2%;
Water surplus;
Wherein, described tensio-active agent is a kind of or its two or more arbitrary combination in Seconary Alkane Sulphonate Sodium, fatty acid methyl ester sulfonate or the fatty acid methyl ester ethoxylate;
Described propelling agent is a kind of of liquified petroleum gas or dme or its combination.
2. foam type fumes from cleaning agent according to claim 1 is characterized in that, contains the mass percent that following component and each component account for described foam type fumes from cleaning agent to be:
Tensio-active agent 5 ~ 9%;
Alkaline assistant 3 ~ 15%;
Solvent 5 ~ 13.2%;
Inhibiter 0.4 ~ 1.1%;
Propelling agent 18 ~ 27%;
Wetting Agent for Printing Inks 0.5 ~ 2%;
Water surplus;
Wherein, described tensio-active agent is a kind of or its two or more arbitrary combination in Seconary Alkane Sulphonate Sodium, fatty acid methyl ester sulfonate or the fatty acid methyl ester ethoxylate;
Described propelling agent is a kind of of liquified petroleum gas or dme or its combination.
3. foam type fumes from cleaning agent according to claim 1 and 2 is characterized in that, described alkaline assistant is a kind of of sodium hydroxide or soda ash or its combination.
4. foam type fumes from cleaning agent according to claim 1 and 2 is characterized in that, described inhibiter is a kind of of Sodium Benzoate or Sodium Nitrite or its combination.
5. foam type fumes from cleaning agent according to claim 1 and 2 is characterized in that, described solvent is a kind of of propandiol butyl ether, Diethylene Glycol butyl ether or D-limonene or its two or more arbitrary combination.
6. foam type fumes from cleaning agent according to claim 1 and 2 is characterized in that, described wetting Agent for Printing Inks is glycerine.
7. foam type fumes from cleaning agent according to claim 1 and 2 is characterized in that, contains the mass percent that following component and each component account for described foam type fumes from cleaning agent to be:
Tensio-active agent:
Seconary Alkane Sulphonate Sodium 0.5-8%,
Fatty acid methyl ester sulfonate 0.03-1.5%,
Fatty acid methyl ester ethoxylate 0.1-5%;
Alkaline assistant:
Sodium hydroxide 0.2-2%,
Soda ash 1-15%;
Solvent:
Propandiol butyl ether 1-5%,
Diethylene Glycol butyl ether 5-10%,
D-limonene 0.1-0.5%;
Inhibiter:
Sodium Benzoate 0.1-1%,
Sodium Nitrite 0.1-1%;
Propelling agent:
Liquefied petroleum gas (LPG) 5-20%,
Dme 5-20%;
Wetting Agent for Printing Inks:
Glycerine 0.5-2%;
Water surplus.
8. foam type fumes from cleaning agent according to claim 7 is characterized in that, contains the mass percent that following component and each component account for described foam type fumes from cleaning agent to be:
Tensio-active agent:
Seconary Alkane Sulphonate Sodium 2-6%,
Fatty acid methyl ester sulfonate 0.15-0.6%,
Fatty acid methyl ester ethoxylate 1-3%;
Alkaline assistant:
Sodium hydroxide 0.2-1%,
Soda ash 5-10%;
Solvent:
Propandiol butyl ether 1-3%,
Diethylene Glycol butyl ether 6-8%,
D-limonene 0.1-0.3%;
Inhibiter:
Sodium Benzoate 0.1-0.5%,
Sodium Nitrite 0.1-0.5%;
Propelling agent:
Liquefied petroleum gas (LPG) 10-20%,
Dme 10-15%;
Wetting Agent for Printing Inks:
Glycerine 0.5-1%;
Water surplus.
9. the preparation method of each described foam type fumes from cleaning agent of claim 1 ~ 8 is characterized in that, comprises the steps:
1) in container A, adds solvent, wetting Agent for Printing Inks and tensio-active agent first, make it dissolving;
2) in container B, add entry, add again alkaline assistant and inhibiter, make it dissolving;
3) material in the container A is poured in the container B, mixed, filter;
4) feed liquid that step 3) is obtained is carried out can, sealing, and the filling propelling agent is finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210383770 CN102925297B (en) | 2012-10-11 | 2012-10-11 | Foam oil and smoke cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210383770 CN102925297B (en) | 2012-10-11 | 2012-10-11 | Foam oil and smoke cleaning agent and preparation method thereof |
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| CN102925297B CN102925297B (en) | 2013-12-25 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104152286A (en) * | 2014-08-27 | 2014-11-19 | 江西瑞思博化工有限公司 | Air conditioner cleaning agent and preparation method thereof |
| CN106978263A (en) * | 2017-05-27 | 2017-07-25 | 侯淑璐 | A kind of lampblack absorber cleaning agent and preparation method thereof |
| CN107254369A (en) * | 2017-07-26 | 2017-10-17 | 徐州益康环保科技有限公司 | A kind of lampblack absorber cleaning agent |
| CN110819476A (en) * | 2019-11-15 | 2020-02-21 | 广东信鹏化工实业有限公司 | Environment-friendly flame-retardant kitchen oil stain cleaning aerosol and preparation method thereof |
| CN112322398A (en) * | 2020-09-15 | 2021-02-05 | 英德市东顺精细化工实业有限公司 | Foam type air intake system disassembly-free cleaning agent |
| CN112457925A (en) * | 2020-11-10 | 2021-03-09 | 苏州市天福环保科技有限公司 | Oil fume cleaning agent and application thereof |
| CN112899084A (en) * | 2021-01-21 | 2021-06-04 | 湖北煜韩环境科技有限公司 | Special cleaning agent for black scale on pot bottom and preparation method thereof |
| CN113030115A (en) * | 2021-02-07 | 2021-06-25 | 广东莱雅新化工科技有限公司 | Metal flaw detection agent and preparation method and application thereof |
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| CN102296004A (en) * | 2011-07-26 | 2011-12-28 | 山东丽波日化股份有限公司 | Paste washing agent for cleaning hard surfaces in kitchen and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104152286A (en) * | 2014-08-27 | 2014-11-19 | 江西瑞思博化工有限公司 | Air conditioner cleaning agent and preparation method thereof |
| CN106978263A (en) * | 2017-05-27 | 2017-07-25 | 侯淑璐 | A kind of lampblack absorber cleaning agent and preparation method thereof |
| CN107254369A (en) * | 2017-07-26 | 2017-10-17 | 徐州益康环保科技有限公司 | A kind of lampblack absorber cleaning agent |
| CN110819476A (en) * | 2019-11-15 | 2020-02-21 | 广东信鹏化工实业有限公司 | Environment-friendly flame-retardant kitchen oil stain cleaning aerosol and preparation method thereof |
| CN112322398A (en) * | 2020-09-15 | 2021-02-05 | 英德市东顺精细化工实业有限公司 | Foam type air intake system disassembly-free cleaning agent |
| CN112457925A (en) * | 2020-11-10 | 2021-03-09 | 苏州市天福环保科技有限公司 | Oil fume cleaning agent and application thereof |
| CN112899084A (en) * | 2021-01-21 | 2021-06-04 | 湖北煜韩环境科技有限公司 | Special cleaning agent for black scale on pot bottom and preparation method thereof |
| CN113030115A (en) * | 2021-02-07 | 2021-06-25 | 广东莱雅新化工科技有限公司 | Metal flaw detection agent and preparation method and application thereof |
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|---|---|
| CN102925297B (en) | 2013-12-25 |
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