CN102910870A - Nano-silicon aerogel/vitrified microball composite thermal-insulation mortar - Google Patents
Nano-silicon aerogel/vitrified microball composite thermal-insulation mortar Download PDFInfo
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- CN102910870A CN102910870A CN201210373076XA CN201210373076A CN102910870A CN 102910870 A CN102910870 A CN 102910870A CN 201210373076X A CN201210373076X A CN 201210373076XA CN 201210373076 A CN201210373076 A CN 201210373076A CN 102910870 A CN102910870 A CN 102910870A
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Abstract
The invention discloses nano-silicon aerogel/vitrified microball composite thermal-insulation mortar, which consists of the following raw materials by weight parts: 70-80 parts of silicate cement, 15-20 parts of modified fly ash, 10-20 parts of modified diatomaceous earth, 10-15 parts of coarse whiting, 10-20 parts of nano-silicon aerogel, 10-20 parts of vitrified microballs, 0.5-1 part of redispersible latex powder, 0.5-1 part of cellulose ether, 0.2-0.3 parts of wood fibers and 0.1-0.2 parts of polyimide fibers. The thermal-insulation mortar prepared in the invention has the advantages that the thermal-insulation property, the fire resistance and the construction performance are excellent, the intensity is high, the weather resistance is good, the mortar is environmentally friendly, etc. The mortar is especially suitable for the composite thermal insulation of inner and outer wall bodies in various brick-concrete structures, frame structures and shear wall structures and for the fire proofing and the thermal insulation of public facilities such as basements, garages, fire fighting accesses and has great market space and development prospect in the construction energy-saving application field.
Description
Technical field
The present invention relates to a kind of material of construction, particularly a kind of thermal insulation mortar that utilizes nano-silicon aerogel and glass bead to replace traditional heat preserving aggregates such as pearlstone.
Background technology
At present, the inorganic heat insulation mortar that uses in the construction work has following several: swelling perlite heat-insulating mortar, closed perlite thermal insulation mortar, swelling perlite heat-insulating mortar pottery sand thermal insulation mortar etc., above-mentioned inorganic heat insulation mortar is for exterior wall internal insulation or outer insulation all exists unit weight large, thermal conductivity is large, the common faults such as hollowing easy to crack affect overall appearance and heat insulation effect, have in addition finish coat come off, cause personnel casualty accidents, social influence is very poor.The reason that these problems occur mainly is because the easily suction and easily broken in the process that stirs of traditional thermal insulation mortar so that cement dilation occurs in the hydration reaction process, causes the hollowing crack.For addressing this problem, many enterprises adopt the consumption that reduces light skeletal, increase the method for other aggregates (such as medium sand, quartz sand etc.) and gel material content, have improved the unit weight (〉=600Kg/m of thermal insulation mortar
3) and intensity (ultimate compression strength 〉=1.OMPa), but also increased this thermal insulation mortar thermal conductivity (〉=0.85W/mk).If building will reach energy-conservation 50%, just must increase the thickness of this thermal insulation mortar.It is dangerous that thickness increases by one, especially to Highrise buildings; The 2nd, increased the cost of building, affected inorganic heat insulation mortar promoting the use of on market.And for organic insulation material, although its thermal conductivity is very low, their intensity is not high, and all has problems at aspects such as weathering resistance, fire line, green environmental protections.Therefore how to develop and have green environmental protection, heat insulation property, high-intensity weather-proof high, but the thermal insulation mortar of the good contour performance of application property is particularly important.
Summary of the invention
The objective of the invention is for the deficiencies in the prior art, but the nano-silicon aerogel that a kind of intensity is high, thermal conductivity is low, heat insulation property good, the good application property of bonding tensile property is good/glass bead composite thermal insulation mortar is provided.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of nano-silicon aerogel/glass bead composite thermal insulation mortar is comprised of the raw material of following weight part: silicate cement 70-80, modified coal ash 15-20, modification infusorial earth 10-20, coarse whiting 10-15, nano-silicon aerogel 10-20, glass bead 10-20, redispersable latex powder 0.5-1, ether of cellulose 0.5-1, wood fibre 0.2-0.3, polyimide fiber 0.1-0.2.
Described modification infusorial earth is made by following method: first with diatomite calcining 2-3h under 600-800 ℃, after grind to form 200-300 order powder, the titanate coupling agent TMC-TTS that admixes the quartz sand nanometer powder, 5-10% plant straw powder and the 2-3% that are equivalent to powder weight 5-10% stirs, high speed dispersion 10-20min, oven dry is ground into powder and gets final product.
The granularity of described glass bead is 0.5-1mm, and the particle diameter of described nano-silicon aerogel is 2-4nm.
Described redispersable latex powder is vinyl acetate and acrylate and higher fatty acid vinyl acetate terpolymer rubber powder.
Described ether of cellulose is hydroxypropyl methyl cellulose ether.
The preparation method of nano-silicon aerogel/glass bead composite thermal insulation mortar; concrete steps are as follows: press the various materials of the accurate weighing of formulation ratio; at first the powders such as silicate cement, modified coal ash, modification infusorial earth, coarse whiting are put into mortar mixer; under dry state, stir 1-2min; then add glass bead and nano-silicon aerogel; restir 2-3min; add again redispersable latex powder, ether of cellulose, wood fibre, polyimide fiber; after stirring 2-3min; the warehouse storage is put in pack.
Than being the ratio of 100:30-40, can construct after stirring by blunge according to mortar and quality for described mortar.
The nano-silicon aerogel is the novel light nanoporous amorphous solid-state material that occurs in recent years, it has lightweight, porous, the nano structure of super insulating material, its nanoporous network structure can limit solid state heat conduction and the special convection current of air-flow effectively, has excellent heat-insulating property.It has a good application prospect in energy saving building as a kind of efficient and light weight thermal insulation material.
Glass bead is a kind of unorganic glass matter mineral material; process through the special producing Technology; be irregular spherical particle; inner many cavity structures; surface vitreous sealing, gloss is level and smooth, and physicochemical property is stable; have lightweight, thermal insulation, fire prevention, high-low temperature resistant, anti-aging, excellent specific property, the application of many traditional lightweight aggregates in different goods such as alternative fly ash float, glass microballon, pearlstone, granular polystyrene such as water-intake rate is little.
The present invention utilizes nano-silicon aerogel and glass bead to substitute traditional heat preserving aggregates such as pearlstone; remedied with pearlstone and made many defectives and deficiency in other traditional thermal insulation mortars of aglite; overcome large, the easily efflorescence of pearlstone water-absorbent; volume receipts mistake rate is large in slip stirs; easily cause product later stage heat-insulating property to reduce and the phenomenon such as hollowing cracking, remedied again that granular polystyrene organic materials fire resistance is poor, insulation produces obnoxious flavour and anti-aging weathering resistance is low simultaneously, the defectives such as bounce-back property is large in the construction.Smear the thick anticracking grout with water proof anti-seepage, resistance to cleavage of one deck 2mm on vitrified micro-bead heat preserving layer surface; the thermal insulation mortar that the present invention produces has good heat insulation property, fire prevention and workability; intensity is high; good weatherability; the advantages such as environmental protection; be particularly suitable for the communal facility fireproof heat insulatings such as the external and internal wall complex heat-preservation of various brick mix structures, skeleton construction and shear wall structure and vault, garage, stair corridor, fire passage, the building energy conservation Application Areas has the great market space and development prospect in China.
Embodiment
The present invention is further illustrated below in conjunction with embodiment.
Embodiment
A kind of nano-silicon aerogel/glass bead composite thermal insulation mortar is comprised of the raw material of following weight part: 80 parts of silicate cements, 15 parts of modified coal ashs, 15 parts of modification infusorial earths, 12 parts of coarse whitings, 20 parts of nano-silicon aerogels, 2 part 0 of glass bead, 1 part of redispersable latex powder, 1 part of ether of cellulose, 0.3 part of wood fibre, 0.2 part of polyimide fiber.
Described modification infusorial earth is made by following method: first with diatomite calcining 3h under 700 ℃, after grind to form 200 order powder, the titanate coupling agent TMC-TTS that admixes the quartz sand nanometer powder that is equivalent to powder weight 10%, 10% plant straw powder and 3% stirs, high speed dispersion 20min, oven dry is ground into powder and gets final product.
The granularity of described glass bead is 0.5mm, and the particle diameter of described nano-silicon aerogel is 3nm.
Described redispersable latex powder is vinyl acetate and acrylate and higher fatty acid vinyl acetate terpolymer rubber powder.
Described ether of cellulose is hydroxypropyl methyl cellulose ether.
The preparation method of nano-silicon aerogel/glass bead composite thermal insulation mortar; concrete steps are as follows: press the various materials of the accurate weighing of formulation ratio; at first the powders such as silicate cement, modified coal ash, modification infusorial earth, coarse whiting are put into mortar mixer; under dry state, stir 2min, then add glass bead and nano-silicon aerogel, restir 3min; add again redispersable latex powder, ether of cellulose, wood fibre, polyimide fiber; after stirring 3min, the warehouse storage is put in pack.
Than being the ratio of 100:40, can construct after stirring by blunge according to mortar and quality for described mortar.
Rice silica aerogel/glass bead composite thermal insulation mortar that present embodiment is produced and the Performance Ratio of other thermal insulation mortars see the following form.
Claims (7)
1. nano-silicon aerogel/glass bead composite thermal insulation mortar; it is characterized in that, formed by the raw material of following weight part: silicate cement 70-80, flyash 15-20, modification infusorial earth 10-20, coarse whiting 10-15, nano-silicon aerogel 10-20, glass bead 10-20, redispersable latex powder 0.5-1, ether of cellulose 0.5-1, wood fibre 0.2-0.3, polyimide fiber 0.1-0.2.
2. nano-silicon aerogel according to claim 1/glass bead composite thermal insulation mortar; it is characterized in that; described modification infusorial earth is made by following method: first with diatomite calcining 2-3h under 600-800 ℃; after grind to form 200-300 order powder; the titanate coupling agent TMC-TTS that admixes the quartz sand nanometer powder, 5-10% plant straw powder and the 2-3% that are equivalent to powder weight 5-10% stirs; high speed dispersion 10-20min, oven dry is ground into powder and gets final product.
3. nano-silicon aerogel according to claim 1/glass bead composite thermal insulation mortar is characterized in that, the granularity of described glass bead is 0.5-1mm, and the particle diameter of described nano-silicon aerogel is 2-4nm.
4. nano-silicon aerogel according to claim 1/glass bead composite thermal insulation mortar is characterized in that, described redispersable latex powder is vinyl acetate and acrylate and higher fatty acid vinyl acetate terpolymer rubber powder.
5. nano-silicon aerogel according to claim 1/glass bead composite thermal insulation mortar is characterized in that, described ether of cellulose is hydroxypropyl methyl cellulose ether.
6. the preparation method of nano-silicon aerogel as claimed in claim 1/glass bead composite thermal insulation mortar; it is characterized in that; concrete steps are as follows: press the various materials of the accurate weighing of formulation ratio; at first the powders such as silicate cement, modified coal ash, modification infusorial earth, coarse whiting are put into mortar mixer; under dry state, stir 1-2min; then add glass bead and nano-silicon aerogel; restir 2-3min; add again redispersable latex powder, ether of cellulose, wood fibre, polyimide fiber; after stirring 2-3min; the warehouse storage is put in pack.
7. nano-silicon aerogel according to claim 7/glass bead composite thermal insulation mortar is characterized in that, than being the ratio of 100:30-40, can construct after stirring by blunge according to mortar and quality for described mortar.
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| CN103641386A (en) * | 2013-11-08 | 2014-03-19 | 许炜 | Inorganic insulation mortar for building lightweight insulation brick |
| CN103693934A (en) * | 2013-12-07 | 2014-04-02 | 马鞍山市金韩防水保温工程有限责任公司 | Thermal mortar for building field |
| CN103708788A (en) * | 2013-09-16 | 2014-04-09 | 池州市崇源节能建筑材料有限公司 | Composite thermal insulation mortar |
| CN103708797A (en) * | 2013-12-26 | 2014-04-09 | 青岛友铭辰生物技术有限公司 | Crack-resistant thermal insulation mortar |
| CN103819903A (en) * | 2014-03-18 | 2014-05-28 | 上海利物盛企业集团有限公司 | Nanometer silicon composite heat conduction material and preparation method thereof |
| CN104163603A (en) * | 2014-07-14 | 2014-11-26 | 池州市崇源节能建筑材料有限公司 | Fireproof insulation mortar and preparation method thereof |
| CN104163602A (en) * | 2014-07-14 | 2014-11-26 | 池州市崇源节能建筑材料有限公司 | Composite inorganic insulation mortar and preparation method thereof |
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| CN104163590A (en) * | 2014-07-14 | 2014-11-26 | 池州市崇源节能建筑材料有限公司 | Vitrified small balls insulation mortar and preparation method thereof |
| CN104163599A (en) * | 2014-07-14 | 2014-11-26 | 池州市崇源节能建筑材料有限公司 | Energy-saving insulation mortar and preparation method thereof |
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| CN104163591A (en) * | 2014-07-14 | 2014-11-26 | 池州市崇源节能建筑材料有限公司 | Sound-absorption inorganic insulation mortar and preparation method thereof |
| CN104261759A (en) * | 2014-09-18 | 2015-01-07 | 常熟市康信节能材料工程有限公司 | Heat-preservation mortar |
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