CN102894001A - Antiseptic and mildew inhibitor composition for wet tissues and production method thereof - Google Patents
Antiseptic and mildew inhibitor composition for wet tissues and production method thereof Download PDFInfo
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Abstract
The invention relates to an antiseptic and mildew inhibitor composition for wet tissues and a production method thereof. The composition consists of an aqueous solvent of an antiseptic, a mildew inhibitor, a quick fungicide, a solvent and an auxiliary. The production method comprises the steps of dissolving the antiseptic and deionized water to prepare the aqueous solvent of the antiseptic, dissolving the mildew inhibitor in the solvent and adding the quick fungicide, adding the auxiliary after stirring for dissolution, finally adding the aqueous solvent of the antiseptic during the stirring and obtaining the antiseptic and mildew inhibitor composition for wet tissues after stirring and filtering. The antiseptic and mildew inhibitor composition for wet tissues is reasonable in formula, advanced in process, simple to operate and easy in mass production; and the product has good antiseptic effect and mildew inhibition effect when being applied to the wet tissues.
Description
Technical field
The invention belongs to the preparing technical field of chemical preservation mould inhibitor, relate to a kind of wet tissue Antisepticize and mildew preventive composition and production method thereof.
Background technology
Along with improving constantly of people's living standard, also in continuous increase, the kind of wet tissue is also more and more to the consumption figure of wet tissue for people.From the wet towel in hotel, wipe the car wet tissue, makeup-removing wet tissue, the facial mask wet tissue arrives child's hygiene care wet tissue etc., and the making scale of wet tissue also expands automatic assembly line to by handicraft workshop.With regard to many occasions and function that wet tissue is used, without not requiring wet tissue manufacturer in the wet tissue manufacture process, should carry out strict sterilization to wet tissue, goodish anticorrosive mildewproof effect also will be arranged in storage process simultaneously.
Distinguish by existing material, the type of wet tissue is divided into four kinds usually: a kind of is nonwoven fabric of synthetic fibre, and the second is pure cotton cloth, and the third is exactly chemical fibre/cotton blended cloth, and the 4th kind is the whole wood pulp paper cloth.Nonwoven fabric of synthetic fibre class wet tissue is easy breed bacteria and be difficult for the mildew bacterium comparatively speaking, and textile dry goods wet tissue ratio is easier to breed bacteria and mould, and the long bacterium situation of the wet tissue of chemical fibre/cotton blending or all wood paper is basically identical with the situation that cotton textiles occur.
According to country's " disposable use amenities sanitary standard " (GB15979-2002) in to the requirement of wet tissue series products sanitary index, the outward appearance of disposable use wet tissue (wet towel) should be clean and tidy, product must not have unusual odor and foreign matter, must not produce pessimal stimulation and allergy and other infringements to skin and mucous membrane; Its microbiology index is: the total number of bacterial colonies≤200cfu/g of disposable use wet towel, coliform and pathogenic suppuration bacterium must not detect fungus colony sum≤100cfu/g; Total number of bacterial colonies≤the 20cfu/g of disposable use wet sanitary napkins, coliform, pathogenic suppuration bacterium and fungi must not detect.
This standard-required is very high, and it is very inaccessible not having good production environment and good anticorrosive mildewproof system.Though wet tissue is sterile products, do not comprise sterilization in its technique, in case contaminated in the process of producing, store, transporting, can subsidiary many harmful microorganisms on the wet tissue.After the consumer has used contaminated wet towel, gently then cause diarrhoea, skin disease, heavy then may cause other diseases.
Existing wet tissue production process is divided into five steps substantially, that is, 1) preparation: preservative, essence and water, skin conditioner etc. are proportionally prepared, if the health wet towel also need add disinfectant; 2) stir: with the liquid mixing and stirring for preparing; 3) soak: dried towel or dry towel are continued to be immersed in certain hour in the liquid; 4) drain: wet tissue is drained to predetermined weight; 5) packing: the folding wet tissue packaging bag enclosing of packing into.If serialization is produced then the spray liquid that will prepare on the towel body, packed subsequently.
If wet tissue is placed in humidity, sultry, the nonventilated warehouse for a long time, especially plum rain season, suitable temp. and humidity can make the fungi amount reproduction, open the package and to see that the wet tissue in white has black or bottle green, purple or yellow mildew, can also smell musty beastly simultaneously.
Because the anticorrosive mildewproof difficulty of wet tissue is large, domestic many wet tissue manufacturing enterprise all once occured owing to wet tissue microorganism severe overweight, smelly going mouldy are caused the situation of a large amount of losses in the past.In order to prevent the breeding of microorganism on the wet tissue, many enterprises all adopt the mode of adding preservative in preparation liquid to meet state health standards to guarantee product within the shelf-life.But; because the preservative that China adds wet tissue is not at present made the regulation of kind and the amount of limiting the use of; some enterprises meet the requirements in order to guarantee the wet tissue microbiological indicator; often use arbitrarily various preservatives or strengthen concentration of preservatives; although microbiological indicator is under control like this; but the health that the harm that is hidden in the depths is greatly threatening the consumer, especially some toxicity are large, often can cause user's facial skin irritated or other is uncomfortable to the strong preservative of skin irritatin.Such as the employed preservative glutaraldehyde of many enterprises, as a kind of high effect disinfectants, 2% glutaraldehyde concentration just can reach sterilization effect, but glutaraldehyde has a stronger excitant to mucocutaneous, and it can be absorbed by the body through skin, and Long Term Contact can be carcinogenic.In cosmetics and skin and mucous membrane disinfection agent, the concentration of country's clear glutaraldehyde must not surpass 0.1%, and when glutaraldehyde concentration surpasses 0.05% in cosmetics, must contain glutaraldehyde at the label mark, but investigation finds that the glutaraldehyde that many wet tissue manufacturing enterprises add runs far deeper than 0.1% in product.In daily behavior, common people mostly can not wash one's hands after having used wet tissue again, so the chemical compositions such as preservative can remain on the face, on hand.Contain the more wet tissue wiping face of glutaraldehyde if use, gently then cause allergic and contact dermatitis, if directly touch eyes, even can cause cornea and visually impaired serious consequence.
Removed glutaraldehyde, the employed protective system of wet tissue manufacturer also has Kathon CG (Kathon CG, Kathon) at present, the sterilization wide spectrum of this preservative, bacterium, mould all had bactericidal effect, but shortcoming is that this product is helpless to bacterial spore, and is poor to the killing effect of pseudomonad, and stability is also bad, strong to skin irritation, use separately and be easy to cause anticorrosion failure.
In addition, domestic some wet tissue manufacturer has used biguanides, quaternary ammonium salts preservative.Say on the stricti jurise that cation belongs to bactericide with sterilization fast but do not have lasting anti-corrosion function, but be used in separately chemical fibre class wet tissue still the short time preserve, and for cotton or contain cotton wet tissue and do not have due antisepsis.
Once disclosed a kind of preparation method of smoke and dust proof wet towel in publication number is the Chinese patent text of CN101416843A, its making step comprises: choose propane diols, two imidazolidinyl urea and iodo propinyl butyl methylamine acid esters, poly hexamethylene biguanide, distilled water and menthe mixing wiring solution-forming 1.; 2. with selected towel high-temperature sterilization; 3. the towel after will sterilizing is placed in the good solvent of proportioning and soaks, and takes out; 4. the towel that takes out is put into the aluminizer packaging bag and carry out sterile sealing.Adopt two imidazolidinyl ureas as one of antiseptic ingredient in this patent, Diazolidinyl Urea, simultaneously several preservatives need to add respectively, it is very inconvenient to use, even it is also very difficult that iodo propinyl butyl methylamine acid esters dissolves in propane diols, need the very long stirring and dissolving time, simultaneously towel pre-treatment needs high-temperature sterilization, power consumption and increase production routine.In publication number is the Chinese patent text of CN102613935A a kind of aroma type pasteurization towelette and preparation method thereof was disclosed once again, its step is that quantitative 2-bromo-2-nitro propane diols, benzethonium chloride, four hydrations, eight Boratexes, essence are made the sterilization mixed liquor, then described sterilization mixing drop is wet on the carrier paper handkerchief, the amount of splashing into is by 1.5 milliliters of every gram paper handkerchiefs, the moistening aroma type pasteurization towelette that namely gets of paper handkerchief; The method uses four hydrations, eight Boratexes as antiseptic ingredient, this is a kind of wood preservative commonly used, but can not be for the wet tissue product that contacts with human body, in 56 kinds of preservatives of " 2007 cosmetics technical specification " regulation, there are not four hydrations, eight Boratexes, and various anti-corrosion compositions add respectively, very inconvenience.Be a kind of sterilization antiseptic composition and purposes that contains benzethonium chloride of once announcing in the Chinese patent text of CN102177901A at publication number in addition, it is by the benzethonium chloride that accounts for total composition 1～50%, 0.5～10% antifungal agent, 5～30% synergetic effect additives, and 10～80% solvent composition contain the high Phenoxyethanol of a large amount of prices in the said composition, Sensiva SC50 etc., viable economically property is poor, and the cation limitation is large, and meeting and anion are had an effect and lost sterilizing function.
Summary of the invention
The object of the invention is to the problem that prior art exists is solved, a kind of wet tissue reasonable, that technique is advanced, anticorrosive mildewproof is effective Antisepticize and mildew preventive composition and production method thereof of filling a prescription is provided.
For achieving the above object, the present invention is on a large amount of formula test bases, Synergistic research and for a long time production application practice in conjunction with widely Microbial Challenge test and anticorrosive mildewproof component, filter out a kind of innovative wet towel Antisepticize and mildew preventive composition, this wet tissue is prepared from the active ingredient of the Antisepticize and mildew preventive composition raw material of substance by following weight percentage:
Wherein, said preservative is 2-methylisothiazolinone (MIT) and/or 5-chloro-2-methyl isothiazolinone (CMIT) and/or bronopol (Bronopol), itself and deionized water are in 10%～50%: the fused aqueous solvent that consists of preservative of 50%～90% ratio, said mould inhibitor is 3-iodo-2 propargyl butyl carbamates (IPBC) and/or nipagin esters, said quick sterilization agent is to Chlorodimethyl phenol (PCMX) and/or 2,4-two chloro-3,5-xylenol (DCMX), said solvent is 1,2 propane diols and/or glycerine and/or ethylene glycol and/or dipropylene glycol, said auxiliary agent is rilanit special and/or polyoxyethylene nonylphenol ether (TX-10) and/or fatty alcohol-polyoxyethylene ether (AEO-9) and/or sodium lauryl tri(oxyethyl) sulfate and/or alkyl glycoside (APG), and said stabilizing agent is sodium nitrate and/or lithium nitrate and/or potassium nitrate and/or benzoyl peroxide.
Making wet tissue of the present invention with the preferred weight percentage ranges of the raw material of substance of Antisepticize and mildew preventive composition is:
Technical solution of the present invention also is: said preservative is 2-methylisothiazolinone (MIT) and/or 5-chloro-2-methyl isothiazolinone (CMIT), itself and deionized water are in 10%～50%: the fused aqueous solvent that consists of preservative of 50%～90% ratio, said mould inhibitor is 3-iodo-2 propargyl butyl carbamates (IPBC), said quick sterilization agent is to Chlorodimethyl phenol (PCMX), said solvent is dipropylene glycol, said auxiliary agent is fatty alcohol-polyoxyethylene ether (AEO-9) and/or alkyl glycoside (APG), preferred auxiliary agent is alkyl glycoside (APG), and said stabilizing agent is sodium nitrate and benzoyl peroxide.
Comprise following processing step for the preparation of this wet tissue with the method for Antisepticize and mildew preventive composition:
1, preservative being dissolved in the deionized water, is 2～4 with the alkali pH that neutralizes rapidly, and adjusting the weight content of preservative in aqueous solvent is 10%～50%, gets the aqueous solvent of preservative, adds stabilizing agent and stirs, and filters stand-by;
2, mould inhibitor is dissolved in the solvent, then adds quick sterilization agent stirring and dissolving, add again auxiliary agent and stir evenly, obtain antimycotic antiseptic solution;
In the aqueous solvent of the preservative that 3, adding step 1 obtains under the condition that the antimycotic antiseptic solution after the step 2 is stirred, mix, filtration gets final product.
The technical solution of production method of the present invention also is: said preservative is 2-methylisothiazolinone (MIT) and 5-chloro-2-methyl isothiazolinone (CMIT), and the weight mixing ratio of the two is 1: 2～4.
The technical solution of production method of the present invention also is: said stabilizing agent is sodium nitrate and benzoyl peroxide, said mould inhibitor is 3-iodo-2 propargyl butyl carbamates, said solvent is dipropylene glycol, said quick sterilization agent is to Chlorodimethyl phenol, and said auxiliary agent is alkyl glycoside.
The beneficial effect that the present invention has is as described below.
One; it is large to the present invention is directed in the prior art preservative toxicity; use cost is high; add the defective of complex operation; select the spendable Antisepticize and mildew preventive component of regulation in country's " 2007 cosmetics technical specification "; form broad spectrum preservation mildew-resistant composition; the utilization cost performance is high; the efficient 5-chloro-2-methyl of sterilization and anticorrosion-4 isothiazolines-3-ketone; 2-methyl-4 isothiazolines-3-ketone; bronopols etc. are done antiseptic ingredient; simultaneously compound with the classic high-effective antimold IPBC of present daily use chemicals industry (3-iodo-2 propargyl butyl carbamates); nipagin esters etc.; and auxiliary can kill fast production raw material harmful microbe to Chlorodimethyl phenol (PCMX); by above-mentioned compatibility scientifically with sterilization; anticorrosion and mildew-resistant effectiveness combines; add separately and just can protect not microbial contamination of wet tissue; so just make product have more powerful anticorrosive mildewproof effect; form the best group compound of antimicrobial harm; can bring into play classic anticorrosive mildewproof and protect the protecting skin effect, use also for simultaneously wet tissue manufacturing enterprise and bring great convenience.
Two, protective system of the present invention contains the moisturizing composition, has improved the use effect of wet tissue.
Three, the used anticorrosive mildewproof component of the present invention toxicity is low, and is all in the listed scope of Preservative Technology for Personal Care, safe, once adds separately, can prevent effectively that microorganism is to the pesticide resistance of preservative.
Four, the wet tissue of the present invention good stability of Antisepticize and mildew preventive composition, the normal temperature storage phase was greater than 12 months.
Five, the present invention adopts composite anti-corrosive mildew-resistant component according to the antimicrobial spectrum of relevant preservative, the synergistic effect of having complementary advantages between various components has been taken into account quick sterilization and long-time Antifungal activity, simultaneously relatively reduce the consumption of preservative in wet tissue, reduced toxicity and excitant.
Six, wet tissue of the present invention the simple to operate of Antisepticize and mildew preventive composition production method is easy to realize large-scale production.
Wet tissue of the present invention was once carried out the anticorrosive mildewproof test effect test for wet tissue with the good stability of Antisepticize and mildew preventive composition, product normal temperature storage after 1 year, situation is as follows.
Wet tissue of the present invention is applied to wet tissue with the Antisepticize and mildew preventive composition and has good anticorrosive mildewproof effect.In the actual tests, wet tissue of the present invention is mixed with 99.2 parts of 0.2 part of Antisepticize and mildew preventive composition, 0.5 part of extract solution from aloe, 0.1 part in essence and deionized waters, drain to predetermined weight after dry towel continued to be immersed in certain hour in the liquid (15～30 minutes), the folding wet towel packaging bag enclosing of packing into, then kept 28 days with 28 ℃ of constant temperature, regularly detect during this time the clump count of wet tissue, testing result such as table 1.The result shows: wet tissue of the present invention Antisepticize and mildew preventive composition anticorrosive mildewproof excellent, and peculiar smell has just appearred in blank wet towel afterwards at 3 days, mildew occurs on the wet towel surface subsequently.
Table 1 wet tissue of the present invention Antisepticize and mildew preventive composition anticorrosive mildewproof effect
Wet tissue of the present invention also once was applied to test by Microbial Challenge in the eutrophic wet paper immersion with the Antisepticize and mildew preventive composition.Dip formula (mass fraction) is as follows: extract solution from aloe 1.0, proline 1.2, hyaluronic acid 0.2, deionized water 97.5; Wet tissue of the present invention Antisepticize and mildew preventive composition 0.1.Above-mentioned material is mixed, add mixed cell and mixed fungus (staphylococcus aureus, pseudomonas aeruginosa, Escherichia coli, black-koji mould, Candida albicans), with 37 ℃ of constant temperature culture 28 days, routine test is content of microorganisms wherein, result such as table 2.
Table 2 eutrophy wet paper immersion Microbiology challenge test result
Embodiment
Embodiment 1
Take by weighing 20 kilograms of the 5-chloro-2-methyl that (cooking cyclizing agent with halogen or chlorosulfuric acid) obtains after the thiopropionamide cyclisation-4 isothiazolines-3-ketone/2-methyl-4 isothiazolines-3-ketone (CMIT/MIT) hydrochloride, the weight ratio of CMIT/MIT is 3/1, be dissolved in 70 kilograms of deionized waters, be 2～4 with sodium bicarbonate with the solution pH that neutralizes, mending total amount with deionized water is double centner, obtain the aqueous solvent of the 5-chloro-2-methyl-4 isothiazolines-3-ketone/2-methyl-4 isothiazolines-3-ketone preservative without divalent ion protection, adding is stirred by the stabilizing agent 4 kilograms (sodium nitrate and benzoyl peroxide are respectively 3.5 kilograms and 0.5 kilogram) that sodium nitrate and benzoyl peroxide form, and is for subsequent use; Get 75 kilograms of dipropylene glycol, add the dissolving of IPBC5 kilogram; Add again 3 kilograms of dissolvings of PCMX, add at last 2 kilograms of non-ionic surfactant APG and stir evenly; 15 kilograms of the aqueous solvents of the 5-chloro-2-methyl that adding is protected without divalent ion under stirring-4 isothiazolines-3-ketone/2-methyl-4 isothiazolines-3-ketone preservative disperse to stir 30 minutes, obtain the invention product with the filtration of 100 order stainless (steel) wires.
Embodiment 2
Take by weighing 20 kilograms of CMIT/MIT hydrochlorides, the weight ratio of CMIT/MIT is 4/1, be dissolved in 70 kilograms of deionized waters, be 2～4 with sodium bicarbonate with the solution pH that neutralizes, mending total amount with deionized water is double centner, obtain the aqueous solvent of the 5-chloro-2-methyl-4 isothiazolines-3-ketone/2-methyl-4 isothiazolines-3-ketone preservative without divalent ion protection, add 3 kilograms of stabilizing agents (sodium nitrate and benzoyl peroxide are respectively 2.5 kilograms and 0.5 kilogram), for subsequent use; Get 75 kilograms of dipropylene glycol, add 4 kilograms of IPBC dissolvings; Add again 4 kilograms of PCMX dissolvings, add at last 2 kilograms of non-ionic surfactant APG and stir evenly; 15 kilograms of the aqueous solvents of the 5-chloro-2-methyl that adding is protected without divalent ion under stirring-4 isothiazolines-3-ketone/2-methyl-4 isothiazolines-3-ketone preservative disperse to stir 30 minutes, obtain the invention product with the filtration of 100 order stainless (steel) wires.
Embodiment 3
Taking by weighing 6 kilograms of 2-methyl-4 isothiazolines-3-ketone (MIT) hydrochloride preservative and be dissolved in 5 kilograms of deionized waters, is 2～4 with sodium bicarbonate with the solution pH that neutralizes, with deionized water mend total amount be 12 kilograms for subsequent use; Get 75 kilograms of 1,2 propane diols, add 5 kilograms of IPBC dissolvings; Add again 5 kilograms of PCMX dissolvings, add at last 3 kilograms of non-ionic surfactant APG and stir evenly.12 kilograms of the aqueous solvents of the above-mentioned preservative for subsequent use of the lower adding of stirring disperse to stir 30 minutes, obtain the invention product with the filtration of 100 order stainless (steel) wires.
Embodiment 4
Taking by weighing 7 kilograms of MIT hydrochloride preservatives and be dissolved in 4 kilograms of deionized waters, is 2～4 with sodium bicarbonate with the solution pH that neutralizes, and mending total amount with deionized water is 12 kilograms, adds 3 kilograms of bronopols again, dissolves to get 15 kilograms of the aqueous solvents of preservative, for subsequent use; Get 75 kilograms of 1,2 propane diols, add 5 kilograms of IPBC dissolvings; Add again 3 kilograms of PCMX dissolvings, add at last 2 kilograms of non-ionic surfactant APG and stir evenly.15 kilograms of the aqueous solvents of the preservative for subsequent use that the lower adding of stirring is above-mentioned disperse to stir 30 minutes, obtain the invention product with the filtration of 100 order stainless (steel) wires.
Claims (7)
1. wet tissue Antisepticize and mildew preventive composition, the active ingredient that it is characterized in that said composition is prepared from by the raw material of substance of following weight percentage:
Said preservative is 2-methylisothiazolinone and/or 5-chloro-2-methyl isothiazolinone and/or bronopol, itself and deionized water are in 10%～50%: the fused aqueous solvent that consists of preservative of 50%～90% ratio, said mould inhibitor is 3-iodo-2 propargyl butyl carbamates and/or nipagin esters, said quick sterilization agent is to Chlorodimethyl phenol and/or 2,4-two chloro-3, the 5-xylenol, said solvent is 1,2 propane diols and/or glycerine and/or ethylene glycol and/or dipropylene glycol, said auxiliary agent is rilanit special and/or polyoxyethylene nonylphenol ether and/or fatty alcohol-polyoxyethylene ether and/or sodium lauryl tri(oxyethyl) sulfate and/or alkyl glycoside, and said stabilizing agent is sodium nitrate and/or lithium nitrate and/or potassium nitrate and/or benzoyl peroxide.
2. wet tissue according to claim 1 Antisepticize and mildew preventive composition, the active ingredient that it is characterized in that said composition is prepared from by the raw material of substance of following weight percentage:
3. wet tissue according to claim 1 Antisepticize and mildew preventive composition, it is characterized in that said preservative is 2-methylisothiazolinone and/or 5-chloro-2-methyl isothiazolinone, itself and deionized water are in 10%～50%: the fused aqueous solvent that consists of preservative of 50%～90% ratio, said mould inhibitor is 3-iodo-2 propargyl butyl carbamates, said quick sterilization agent is to Chlorodimethyl phenol, said solvent is dipropylene glycol, said auxiliary agent is fatty alcohol-polyoxyethylene ether and/or alkyl glycoside, and said stabilizing agent is sodium nitrate and benzoyl peroxide.
4. according to claim 1 or 3 described wet tissue Antisepticize and mildew preventive compositions, it is characterized in that said auxiliary agent is alkyl glycoside.
One kind for the production of claim 1 or 2 described wet tissues with the method for Antisepticize and mildew preventive compositions, it is characterized in that comprising following processing step:
5.1 preservative is dissolved in the deionized water, be 2～4 with the alkali pH that neutralizes rapidly, adjusting preservative weight content in aqueous solvent is 10%～50%, gets the aqueous solvent of preservative, adds stabilizing agent and stirs, and filters stand-by;
5.2 mould inhibitor is dissolved in the solvent, then add quick sterilization agent stirring and dissolving, add again auxiliary agent and stir evenly, obtain antimycotic antiseptic solution;
5.3 in the aqueous solvent of the preservative that adding step 5.1 obtains under the condition that the antimycotic antiseptic solution after the step 5.2 is stirred, mix, filtration gets final product.
6. production method according to claim 5 is characterized in that said preservative is 2-methylisothiazolinone and 5-chloro-2-methyl isothiazolinone, and the weight mixing ratio of the two is 1: 2～4.
7. production method according to claim 5, it is characterized in that said stabilizing agent is sodium nitrate and benzoyl peroxide, said mould inhibitor is 3-iodo-2 propargyl butyl carbamates, said solvent is dipropylene glycol, said quick sterilization agent is to Chlorodimethyl phenol, and said auxiliary agent is alkyl glycoside.
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| CN103583515A (en) * | 2013-11-07 | 2014-02-19 | 上海大学 | Novel disinfection liquid for wet tissue and preparation method for disinfection cotton wet tissue |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1628507A (en) * | 2004-04-21 | 2005-06-22 | 单文修 | Method for cultivating plant tissue under non-aseptic condition |
| CN1843123A (en) * | 2006-05-13 | 2006-10-11 | 林贤荣 | Antiseptic and mite-proof agent for mattress(sofa) |
| CN101624241A (en) * | 2008-07-10 | 2010-01-13 | 吴彩莲 | Detergent component and manufacturing method thereof |
| WO2010009033A2 (en) * | 2008-07-15 | 2010-01-21 | Dow Global Technologies Inc. | Biocidal composition and method |
| CN102573495A (en) * | 2009-10-02 | 2012-07-11 | 乔治洛德方法研究和开发液化空气有限公司 | Storage-stable, synergistic microbicidal concentrates containing an isothiazolone, an amine and an oxidizing agent |
| CN102702839A (en) * | 2012-06-29 | 2012-10-03 | 陕西省石油化工研究设计院 | In-tank antiseptic antimildew agent composition integrated with dry film for paint |
-
2012
- 2012-10-19 CN CN2012104006385A patent/CN102894001A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1628507A (en) * | 2004-04-21 | 2005-06-22 | 单文修 | Method for cultivating plant tissue under non-aseptic condition |
| CN1843123A (en) * | 2006-05-13 | 2006-10-11 | 林贤荣 | Antiseptic and mite-proof agent for mattress(sofa) |
| CN101624241A (en) * | 2008-07-10 | 2010-01-13 | 吴彩莲 | Detergent component and manufacturing method thereof |
| WO2010009033A2 (en) * | 2008-07-15 | 2010-01-21 | Dow Global Technologies Inc. | Biocidal composition and method |
| CN102573495A (en) * | 2009-10-02 | 2012-07-11 | 乔治洛德方法研究和开发液化空气有限公司 | Storage-stable, synergistic microbicidal concentrates containing an isothiazolone, an amine and an oxidizing agent |
| CN102702839A (en) * | 2012-06-29 | 2012-10-03 | 陕西省石油化工研究设计院 | In-tank antiseptic antimildew agent composition integrated with dry film for paint |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103583515A (en) * | 2013-11-07 | 2014-02-19 | 上海大学 | Novel disinfection liquid for wet tissue and preparation method for disinfection cotton wet tissue |
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