CN102883611B - Pest control material - Google Patents
Pest control material Download PDFInfo
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- CN102883611B CN102883611B CN201180024655.7A CN201180024655A CN102883611B CN 102883611 B CN102883611 B CN 102883611B CN 201180024655 A CN201180024655 A CN 201180024655A CN 102883611 B CN102883611 B CN 102883611B
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
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- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
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Abstract
Disclosed is a pest control material having a pyrethroid compound and an insect growth regulator held on a carrier.
Description
Technical field
The present invention relates to the pest control material for control of insect.
Background technology
In patent document 1, give pest control material, it has the control of insect component remained on carrier such as thermoplastic resin etc.Give the pest control material of mesh-shaped in patent document 2, it is prepared with the resin combination containing control of insect component.
Patent document 1:JP-A-H11-21206
Patent document 2:JP-A-2008-13508.
Summary of the invention
(the technical problem to be solved in the present invention)
A target of the present invention is to provide the pest control material showing excellent pest controling effect.
(mode of dealing with problems)
The present invention is pest control material, has and remains on pyrethroid compound on carrier and insect growth regulator, IGR.
That is, the present invention includes following invention.
[1] pest control material, it has and remains on pyrethroid compound on carrier and insect growth regulator, IGR.
[2] according to the pest control material of [1], wherein said carrier is resin.
[3] according to the pest control material of [1] or [2], be net structure.
[4] according to the pest control material of any one of [1]-[3], be mosquito net structure.
[5] according to the pest control material of any one of [1]-[4], wherein said pyrethroid compound and/or described insect growth regulator, IGR are blended in described carrier.
[6] according to the pest control material of any one of [1]-[5], wherein said pyrethroid compound and/or described insect growth regulator, IGR are coated on the surface of described carrier.
[7] according to the pest control material of any one of [1]-[6], wherein said pyrethroid compound is permethrin.
[8] according to the pest control material of any one of [1]-[7], wherein said insect growth regulator, IGR is Nylar.
[9] according to the pest control material of any one of [1]-[7], wherein said insect growth regulator, IGR is methoprene.
[10] according to the pest control material of any one of [1]-[9], wherein pyrethroid compound is 1:20-20:1 with the compounding ratio of insect growth regulator, IGR.
[11] according to the pest control material of any one of [1]-[9], wherein pyrethroid compound is 1:5-5:1 with the compounding ratio of insect growth regulator, IGR.
[12] according to the pest control material of any one of [1]-[9], wherein pyrethroid compound is 1:2-2:1 with the compounding ratio of insect growth regulator, IGR.
[13] according to the pest control material of any one of [1]-[12], also synergist is comprised.
(effect of the present invention)
The present invention can show excellent pest controling effect.
Accompanying drawing explanation
Fig. 1 is the partial view of the pest control material of the present invention with knitted net structure.
Fig. 2 is the partial view of the pest control material of the present invention with woven net structure.
Description of reference numerals
1: silk thread
3: mesh.
Embodiment
Pest control material of the present invention has and remains on pyrethroid compound on carrier and insect growth regulator, IGR.
(1) one or more carriers
Preferred use resin.Fibrous material can also be used, such as native fiber, glass fibre etc.The example of native fiber comprises paper pulp (pulp), cellulose, cotton, wool etc.
As described resin, thermoplastic resin is preferred.Vistanex, polyvinyl alcohol, polyvinyl acetate, Merlon, polyester, polyamide, polystyrene, polymethyl methacrylate, acrylonitrile-butadiene-styrene copolymer, polyvinyl chloride etc. can be used as described thermoplastic resin.
As described thermoplastic resin, vistanex is preferred.As described vistanex, preferred following material (compounds).
The homopolymers of (i) alpha-olefin: such as polyethylene, polypropylene etc.
(ii) ethene-alpha-olefin copolymer: such as ethylene-propylene copolymer, Ethylene/Butylene-1 copolymer, ethene-4 methyl 1 pentene copolymer, ethylene-hexene co-polymers etc.
(iii) ethene and the copolymer of organic carboxyl acid derivative with ethylenic unsaturated bond: such as ethylene methyl methacrylate copolymer, ethylene-vinyl acetate copolymer, ethylene-acrylic acid copolymer, ethylene-vinyl acetate-methylmethacrylate copolymer etc.
(2) pyrethroid compound (one or more) and insect growth regulator, IGR (one or more)
(2-1) pyrethroid compound
The example of described pyrethroid compound comprises acrinathrin (acrinathrin), allethrin (allethrin), d-allethrin (d-allethrin), dd-allethrin (dd-allethrin), β-cyfloxylate (beta-cyfluthrin), Biphenthrin (bifenthrin), cycloprothrin (cycloprothrin), cyfloxylate (cyfluthrin), Cyhalothrin (cyhalothrin), cypermethrin (cypermethrin), dimefluthrin (dimefluthrin), Prallethrin (empenthrin), decis (deltamethrin), terarethrin, tefluthrin (tefluthrin), cis fenvalerate (esfenvalerate), ether chrysanthemum ester (ethofenprox), fenpropathrin (fenpropathrin), sumicidin (fenvalerate), flucythrinate (flucythrinate), flufenoprox, flumethrin (flumethrin), taufluvalinate (fluvalinate), third Flumethrin (profluthrin), bromine fluorine ether chrysanthemum ester (halfenprox), Imiprothrin (imiprothrin), permethrin (permethrin), transfluthrin (benfluthrin), Prallethrin (prallethrin), pyrethrins, resmethrin (resmethrin), d-resmethrin (d-resmethrin), sigma-cypermethrin (sigma-cypermethrin), silafluofene (silafluofen), tefluthrin (tefluthrin), tralomethrin (tralomethrin), transfluthrin (transfluthrin), tetramethrin (tetramethrin), d-tetramethrin (d-tetramethrin), phenothrin (phenothrin), d-phenothrin (d-phenothrin), cyphenothrin (cyphenothrin), α-cypermethrin (alpha-cypermethrin), sialpha-cypermethrin (sialpha-cypermethrin), zeta-cypermethrin (zeta-cypermethrin), lambda-Cyhalothrin (lambda-cyhalothrin), gamma-Cyhalothrin (gamma-cyhalothrin), PH (furamethrin), tau-taufluvalinate (tau-fluvalinate), metofluthrin (metofluthrin), natural pyrethrin etc.
As described pyrethroid compound, permethrin, decis or α-cypermethrin are preferred.
These pyrethroid compounds can be used alone or two or more combinationally use.In some above-claimed cpds, there is optical isomer, stereoisomer, geometric isomer etc., pyrethroid compound of the present invention comprises their active isomer and mixture.
(2-2) insect growth regulator, IGR
Described insect growth regulator, IGR comprises juvenoid (juvenile hormone analogs) and chitin synthesis Inhibitors (chitin synthesis inhibitors) especially.
The example of described juvenoid comprises Nylar, methoprene, hydroprene (hydroprene), fenoxycarb (fenoxycarb) etc.
The example of described chitin synthetic inhibitor comprises Jia oxazole (ethoxazole), chlorfluazuron (chlorfluazuron), fluazuron (fluazuron), azoles prestige (triazuron), Rimon (novaluron), HEXAFLUMURON (hexaflumuron), diflubenzuron (diflubenzuron), cyromazine (cyromazine), flufenoxuron (flufenoxuron), fluorobenzene urea (teflubenzuron), triflumuron (triflumuron), flucycloxuron (flucycloxuron), hydroprene (hydroprene), fluorine third oxygen urea (lufenuron), noviflumuron (noviflumuron), bistrifluron (bistrifluron) etc.
(3) form
Such as, following form is mentioned especially.
(3-1) pyrethroid compound and insect growth regulator, IGR mixing are in the carrier.
(3-2) pyrethroid compound and insect growth regulator, IGR are coated on carrier surface.
(3-3) pyrethroid compound mixing in the carrier, and insect growth regulator, IGR is coated on carrier surface.
(3-4) pyrethroid compound is coated on carrier surface, and insect growth regulator, IGR mixing in the carrier.
The compounding ratio of pyrethroid compound to insect growth regulator, IGR is 1:10000-1000:1, preferred 1:1000-100:1.In addition, specific components is compounding than being as follows.
Permethrin is to Nylar=1:100-100:1
Decis is to Nylar=1:1000-20:1
α-cypermethrin is to Nylar=1:1000-20:1
Permethrin is to methoprene=1:100-100:1
Decis is to methoprene=1:1000-20:1
α-cypermethrin is to methoprene=1:1000-20:1
More preferably, the compounding ratio of pyrethroid compound to insect growth regulator, IGR is 1:20-20:1, further preferably 1:10-10:1, further more preferably 1:5-5:1, particularly preferably 1:2-2:1.
(4) preparation method
Pest control material of the present invention can such as be prepared as described in following methods (i), (ii) or (iii).In (i)-(iii), describe the situation using thermoplastic resin as carrier.
I thermoplastic resin, pyrethroid compound, insect growth regulator, IGR and any compounding dose (compounding agent) are uniformly mixed by (), by the mixture melt kneading that obtains to obtain resin combination, and by using this resin combination to obtain the resinite with given structure.
(ii) thermoplastic resin, one of pyrethroid compound and insect growth regulator, IGR and any compounding dose are uniformly mixed, by the mixture melt kneading that obtains to obtain resin combination, and by using this resin combination to obtain the resinite with given structure.Then, the another one of pyrethroid compound and insect growth regulator, IGR is coated on the surface of described resinite.Thus obtain pest control material.
(iii) thermoplastic resin and any compounding dose are uniformly mixed, by the mixture melt kneading that obtains to obtain resin combination, and by using this resin combination to obtain the resinite with given structure.Then, pyrethroid compound and insect growth regulator, IGR are coated on the surface of described resinite.Thus obtain pest control material.
In said method (i)-(iii), resinite can be formed by such as melt molding resin combination, but described resinite also can be formed by other molding methods.As described molding methods, can use the method be generally used in resin moulded processing, its example comprises extrusion molding, injection-molded, blowing, compression molding, powder molding, compacting molding etc.
The method that carrier surface applies pyrethroid compound and/or insect growth regulator, IGR comprise such as method that wherein these component former states use or wherein these components dissolved in solvent such as alcohol etc. and the solution obtained for the method for the impregnation process of resinite, spraying process or coating processing.
It is also feasible that at least one load of pyrethroid compound and insect growth regulator, IGR is on assistant carrier, then itself and thermoplastic resin melt kneading obtain resin combination, and the resinite by using this resin combination to obtain given structure.Above-mentioned assistant carrier comprises silica-type compound, zeolite, clay mineral, metal oxide, mica group, hydrotalcite, organic carrier etc.Described silica-type compound comprises amorphous silica and crystalline silica, and its example comprises powdered silicate, fine powder silicic acid, acid clay, diatomite, quartz, white carbon etc.Described zeolite comprises type A zeolite, modenite etc., described clay mineral comprises imvite (montmorillonite), saponite (saponite), beidellite (beidellite), bentonite (bentonite), kaolin (kaolinite), galapectite (halloysite), nacrite (nacrite), dickite (dickite), anauxite, illite (illite), sericite (sericite) etc., described metal oxide comprises zinc oxide, magnesia, aluminium oxide, iron oxide, copper oxide, titanium oxide etc., described mica group comprises mica, vermiculite etc., described hydrotalcite comprises hydrotalcite, montmorillonite etc., coal (charcoal is comprised with described organic carrier, peat, peat composed of rotten mosses etc.), polymeric beads (microcrystalline cellulose, polystyrene bead, acrylate pearl, methacrylate pearl, polyvinyl alcohol pearl etc.) and their crosslinked polymeric beads, etc..In addition, perlite can be used, gypsum, pottery, volcanic rock etc.As above-mentioned assistant carrier, preferred amorphous inorganic carrier, further preferred amorphous silica.
Pest control material of the present invention can contain following compounding dose of listing: synergist; Insecticide is anabasine such as, carbamates, Organophosphonate class, phenyl pyrazoles etc.; Pest repellant; Antioxidant; Fungicide; Antibacterial agent; Pigment; Aromatic substance; Antiperspirant; Spreading agent; Ultraviolet absorber; Light stabilizer; Lubricant; Anti-blocking agent; Antistatic additive; Surfactant; Filler; Fire retardant; Plasticizer; Antirustic agent etc.
When using synergist as above-mentioned compounding dose, pest control material of the present invention can such as be prepared as described in following methods (i), (ii) or (iii).In (i)-(iii), describe the situation using thermoplastic resin as carrier.
I thermoplastic resin, pyrethroid compound, insect growth regulator, IGR, synergist and any compounding dose are uniformly mixed by (), by the mixture melt kneading that obtains to obtain resin combination, and by using this resin combination to obtain the resinite with given structure.Thus obtain pest control material.
(ii) by thermoplastic resin, be selected from least one component in the group be made up of pyrethroid compound, insect growth regulator, IGR and synergist, and any compounding dose is uniformly mixed, by the mixture melt kneading that obtains to obtain resin combination, and by using this resin combination to obtain the resinite with given structure.Then, other component in nonoptional above-mentioned group is coated on the surface of described resinite.Thus obtain pest control material.
(iii) thermoplastic resin and any compounding dose are uniformly mixed, by the mixture melt kneading that obtains to obtain resin combination, and by using this resin combination to obtain the resinite with given structure.Then, pyrethroid compound, insect growth regulator, IGR and synergist are coated on the surface of described resinite.Thus obtain pest control material.
The example of described synergist comprises following compound.
α-[2-(2-Butoxyethoxy) ethyoxyl]-4,5-methylenedioxy-2-propyltoluenes [piperonyl butoxide (piperonyl butoxide) (PBO)]
Pungent-5-alkene-2, the 3-dicarboximide [Synepirin 500] of N-(2-ethylhexyl)-1-isopropyl-4-methyl dicyclo (2,2,2)
Butyl stearate
Two-(2,3,3,3-tetra-chloropropyl) ether [S-421]
N-(2-ethylhexyl) dicyclo [2.2.1]-5-in heptan alkene-2,3-dicarboximide [MGK264]
In pest control material of the present invention, the compounding amount of component comprises, preferably, 30-99 wt% thermoplastic resin, 0.01-50 wt% pyrethroid compound and 0.001-50 wt% insect growth regulator, IGR, more preferably, 50-99 wt% thermoplastic resin, 0.1-25 wt% pyrethroid compound, and 0.01-25 wt% insect growth regulator, IGR.
In addition, when containing synergist, in pest control material of the present invention, the compounding amount of component comprises, preferably, 30-99 wt% thermoplastic resin, 0.01-50 wt% pyrethroid compound, 0.001-50 wt% insect growth regulator, IGR, with 0.01-50 wt% synergist, more preferably, 50-99 wt% thermoplastic resin, 0.1-25 wt% pyrethroid compound, 0.01-25 wt% insect growth regulator, IGR, and 0.1-25 wt% synergist.
(5) construct
Pest control material of the present invention preferably has net structure.This net can be formed by knitting or woven silk thread, thus forms many meshes, and this silk thread is by obtaining the resin combination spinning in said method (i)-(iii).Above-mentioned net when by during knitting formation, there is knitted structure, when by during woven formation, there is machine-knitted structure.Fig. 1 shows by knitting silk 1 thus forms an example of the knitted structure net that many meshes 3 are formed, and Fig. 2 shows by woven silk thread 1 thus forms an example of the machine-knitted structure net that many meshes 3 are formed.
The size of mesh 3 depends on body length as the insect of controlling object and suitable setting, and preferred described size is adjusted to and makes when insect attempts to be come in contact by insect during described net and described net.Usually, the size (hole dimension) of described mesh 3 is 1-5mm, preferred 2-4mm.
Preferred described silk thread 1 is the monofilament with given thickness.Like this, knitting work or woven work become easy.In this case, " given thickness " refers to the thickness that can keep intensity as pest control material.Usually, when described silk thread 1 is monofilament, preferably use the monofilament of 50-350 Denier.
Described silk thread 1 can also be the multifilament with given thickness.
In above-mentioned net, when arrive insect attempt by during mesh 3 and silk thread 1 come in contact.Therefore, insect is prevented and treated and failure can not be occurred.
Those the example with net structure comprises mosquito net, screen window (net window), fly net (insect screen) etc., and especially, mosquito net structure is preferred.
In addition, the structure of pest control material of the present invention comprises dispensing materials (distribution materials) such as film, sheet material, paper, wallpaper, cloth, heavy curtain, flooring material, packaging material, flexible pipe, band, pipe, pipeline, bag, tent (tent turf), store curtain, electric wire, hawser, sheath, silk thread (string), synthetic fibres, rope, filter, footwear, bag, clothing, electronic device, electric device, household electrical appliance, sports goods (sport good), office equipment, vehicle arrangement, transportation machines, container, case, etc., those and the house parts that use in household articles, pet supplies are kennel such as, pad, sheet material, necklace, label etc., etc., and be used as those of following protection against insect product: people, pet is dog such as, cat, bird etc., domestic animal is ox such as, pig, sheep, bird etc., etc..Film and sheet material can be processed into the moulding bodies of intended shape further by vacuum mo(u)lding etc.
(6) effect
Adopt pest control material of the present invention, can pest control, such as harmful insect, harmful acarid etc.The example of these insects is particularly including following biology.
The mosquito of Anopheles (genus Anopheles): anopheles costalis (An. Gambiae), Anopheles arabiensis (An. Arabiensis), anopheles funestus (An. Funestus), complete black anopheles (An. Melas), anopheles minius (An. Minimus), Anopheles dirus (An. Dirus), anopheles stephensi (An. Stephensi), Anopheles sinensis (An. Sinensis), Anopheles arthropophagus (An. Anthropophagus) etc.
The mosquito of Culex (genus Culex): northern house (Cx. pipiens pipiens), Culex quinquefasciatus (Cx. Quinquefasciatus), Culex pipiens pallens (Cx. pipiens pallens), Culex molestus (Cx. pipiens f. molestus), Cx. restuans, culex tarsalis (Cx. Tarsalis), fierce little culex (Cx. Modestus), Culex tritaeniorhynchus (Cx. Tritaeniorhynchus) etc.
The mosquito of Aedes (genus Aedes): Aedes aegypti (Aedes aegypti), aedes albopictus (Ae. Albopictus), Aedes japonicus (Ae. Japonicus), Aedes vexans (Ae. Vexans) etc.
Horse botfly (Tabanidae), fly (Muscidae), black fly (black-flies) (Simuliidae), sand fly (sand-flies) (Phlebotominae), midge (biting midges) (Ceratopogonidae), tsetse fly (tsetse-flies) (Glossinidae), midge (chironomids) (Chironomidae), flea (fleas) (Siphonaptera), sucking louse (sucking-lice) (Anoplura), bedbug (bedbugs) (Cimicidae), triatomine bugs (Triatominae), ant (Formicidae), termite (Termitidae), cockroach (Blattaria), mite, tick (ticks) etc.
When insect contacts with pest control material of the present invention, demonstrate following pest controling effect especially.
(1) can prevent insect from sucking blood.
(2) insect can be killed.
(3) insect can be suppressed to hatch.
(4) insect second time can be suppressed or again suck blood.
(5) life-span of insect can be shortened.
(6) population density of insect can be reduced by above-mentioned effect.
(7) pathogene can be prevented to the propagation of humans and animals by above-mentioned inhibition of sucking blood.
(8) when insect disseminates infection, the infectious disease transmission ability of insect can significantly be reduced by above-mentioned effect.Therefore, when pest control material of the present invention is used to the whole region of given region, the infectious disease in this region can be eliminated.
(9) be excellent equally for the above-mentioned effect of the insect with kdr and/or metabolic quasi elementary convergence groups.
(10) not only can prevent and treat people's infectious disease, and can communicable disease of animals be prevented and treated.
(embodiment)
The embodiment of pest control material of the present invention will be described below.The invention is not restricted to these embodiments.
(embodiment 1)
By 10.0 weight portion amorphous silicas, 10.0 weight portion permethrins, 7.0 weight portion zinc stearates and 0.4 weight portion BHT are uniformly mixed by high-speed mixer (super mixer) and obtain powders A 1.To adding this powders A 1 in the polyethylene of 150 DEG C of meltings thus the amount of powders A 1 is 27.4 weight portions relative to 62 weight account polyethylenes in single screw extrusion machine; mixture is mediated; the material of melt kneading is extruded as material strip by die head; then it use water cooling; then with comminutor cutting, the masterbatch pellet of cylindrical shape is obtained.
Next, the gained masterbatch pellet of 20.0 weight portions and the polyethylene of 80.0 weight portions are uniformly mixed.Then, monofilament are spinned from gained mixture 240 DEG C of processing temperatures.Then, knitting gained resin silk thread is to form many meshes, and A1 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
Then, net A1 to be immersed in 0.1% w/v alcoholic solution of Nylar 1 hour, to take out, air oxygen detrition 24 hours.
(embodiment 2)
By 10.0 weight portion amorphous silicas, 10.0 weight portion permethrins, 7.0 weight portion zinc stearates and 0.4 weight portion BHT are uniformly mixed by high-speed mixer and obtain powders A 1.To adding this powders A 1 in the polyethylene of 150 DEG C of meltings thus the amount of powders A 1 is 27.4 weight portions relative to 62 weight account polyethylenes in single screw extrusion machine; mixture is mediated; further; add by the Nylar at 55 DEG C of heating and meltings with the amount of 5.0 weight portions by using charge pump; kneaded mixture, extruded as material strip by die head by the material of melt kneading, then it use water cooling; then with comminutor cutting, the masterbatch pellet of cylindrical shape is obtained.
Next, the gained masterbatch pellet of 20.0 weight portions and the polyethylene of 80.0 weight portions are uniformly mixed.Then, monofilament are spinned from gained mixture 240 DEG C of processing temperatures.Then, knitting gained resin silk thread is to form many meshes, and B1 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
(embodiment 3)
Monofilament is spinned from polyethylene the processing temperature of 240 DEG C.Then, knitting gained resin silk thread is to form many meshes, and C1 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
Individually, by 5.0 weight portion permethrins, 5.0 weight portion Nylars and 3.0 parts by weight of propylene glycol are dissolved in 87.0 weight portion alcohol, obtain spraying liquid A1.
Then, spraying liquid A1 is sprayed onto on described net C1, and by its air oxygen detrition 24 hours.
(embodiment 4)
Monofilament is spinned from polyester the processing temperature of 260 DEG C.Then, knitting gained resin silk thread is to form many meshes, and D1 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
Individually, by 5.0 weight portion permethrins, 5.0 weight portion Nylars and 3.0 parts by weight of propylene glycol are dissolved in 87.0 weight portion alcohol, obtain spraying liquid A1.
Then, spraying liquid A1 is sprayed onto on described net D1, and by its air oxygen detrition 24 hours.
(embodiment 5)
By 10.0 weight portion amorphous silicas, 7.0 weight portion zinc stearates and 0.4 weight portion BHT are uniformly mixed by high-speed mixer and obtain powder H1.To adding this powder H1 in the polyethylene of 150 DEG C of meltings thus the amount of powder H1 is 17.4 weight portions relative to 72 weight account polyethylenes in single screw extrusion machine; mixture is mediated; further; add by the Nylar at 55 DEG C of heating and meltings with the amount of 5.0 weight portions by using charge pump; kneaded mixture, extruded as material strip by die head by the material of melt kneading, then it use water cooling; then with comminutor cutting, the masterbatch pellet of cylindrical shape is obtained.
Next, the gained masterbatch pellet of 20.0 weight portions and the polyethylene of 80.0 weight portions are uniformly mixed.Then, monofilament are spinned from gained mixture 240 DEG C of processing temperatures.Then, knitting gained resin silk thread is to form many meshes, and H1 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
Then, net H1 to be immersed in 0.1% w/v aqueous isopropanol of permethrin 1 hour, to take out, air oxygen detrition 24 hours.
(embodiment 6)
By 10.0 weight portion amorphous silicas, 10.0 weight portions are selected from the pyrethroid compound of permethrin, decis and α-cypermethrin, and 7.0 weight portion zinc stearates and 0.4 weight portion BHT are uniformly mixed by high-speed mixer and obtain powders A 2.To adding this powders A 2 in the polyethylene of 150 DEG C of meltings thus the amount of powders A 2 is 27.4 weight portions relative to 62 weight account polyethylenes in single screw extrusion machine; mixture is mediated; the material of melt kneading is extruded as material strip by die head; then it use water cooling; then with comminutor cutting, the masterbatch pellet of cylindrical shape is obtained.
Next, the gained masterbatch pellet of 20.0 weight portions and the polyethylene of 80.0 weight portions are uniformly mixed.Then, monofilament are spinned from gained mixture 240 DEG C of processing temperatures.Then, knitting gained resin silk thread is to form many meshes, and A2 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
Then, net A2 is immersed in 0.1% w/v alcoholic solution of methoprene, takes out, air oxygen detrition 24 hours.
(embodiment 7)
By 10.0 weight portion amorphous silicas, 10.0 weight portions are selected from the pyrethroid compound of permethrin, decis and α-cypermethrin, and 7.0 weight portion zinc stearates and 0.4 weight portion BHT are uniformly mixed by high-speed mixer and obtain powders A 2.To adding this powders A 2 in the polyethylene of 150 DEG C of meltings thus the amount of powders A 2 is 27.4 weight portions relative to 62 weight account polyethylenes in single screw extrusion machine; mixture is mediated; further; add by the methoprene at 55 DEG C of heating and meltings with the amount of 5.0 weight portions by using charge pump; kneaded mixture, extruded as material strip by die head by the material of melt kneading, then it use water cooling; then with comminutor cutting, the masterbatch pellet of cylindrical shape is obtained.
Next, the gained masterbatch pellet of 20.0 weight portions and the polyethylene of 80.0 weight portions are uniformly mixed.Then, monofilament are spinned from gained mixture 240 DEG C of processing temperatures.Then, knitting gained resin silk thread is to form many meshes, and B2 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
(embodiment 8)
Monofilament is spinned from polyethylene the processing temperature of 240 DEG C.Then, knitting gained resin silk thread is to form many meshes, and C2 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
Individually, 5.0 weight portions are selected from the pyrethroid compound of permethrin, decis and α-cypermethrin, 5.0 weight portion methoprenes and 3.0 parts by weight of propylene glycol are dissolved in 87.0 weight portion alcohol, obtain spraying liquid A2.
Then, spraying liquid A2 is sprayed onto on described net C2, and by its air oxygen detrition 24 hours.
(embodiment 9)
Monofilament is spinned from polyester the processing temperature of 260 DEG C.Then, knitting gained resin silk thread is to form many meshes, and D2 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
Individually, 5.0 weight portions are selected from the pyrethroid compound of permethrin, decis and α-cypermethrin, 5.0 weight portion methoprenes and 3.0 parts by weight of propylene glycol are dissolved in 87.0 weight portion alcohol, obtain spraying liquid A2.
Then, spraying liquid A2 is sprayed onto on described net D2, and by its air oxygen detrition 24 hours.
(embodiment 10)
By 10.0 weight portion amorphous silicas, 7.0 weight portion zinc stearates and 0.4 weight portion BHT are uniformly mixed by high-speed mixer and obtain powder H2.To adding this powder H2 in the polyethylene of 150 DEG C of meltings thus the amount of this powder is 17.4 weight portions relative to 72 weight account polyethylenes in single screw extrusion machine; mixture is mediated; further; add by the Nylar at 55 DEG C of heating and meltings with the amount of 5.0 weight portions by using charge pump; kneaded mixture, extruded as material strip by die head by the material of melt kneading, then it use water cooling; then with comminutor cutting, the masterbatch pellet of cylindrical shape is obtained.
Next, the gained masterbatch pellet of 20.0 weight portions and the polyethylene of 80.0 weight portions are uniformly mixed.Then, monofilament are spinned from gained mixture 240 DEG C of processing temperatures.Then, knitting gained resin silk thread is to form many meshes, and H2 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
Then, net H2 to be immersed in 0.1% w/v alcoholic solution of the pyrethroid compound being selected from permethrin, decis and α-cypermethrin 1 hour, to take out, air oxygen detrition 24 hours.
(embodiment 11)
By 10.0 weight portion amorphous silicas, 10.0 weight portion decises or α-cypermethrin, 7.0 weight portion zinc stearates and 0.4 weight portion BHT are uniformly mixed by high-speed mixer and obtain powders A 3.To adding this powders A 3 in the polyethylene of 150 DEG C of meltings thus the amount of powders A 3 is 27.4 weight portions relative to 62 weight account polyethylenes in single screw extrusion machine; mixture is mediated; the material of melt kneading is extruded as material strip by die head; then it use water cooling; then with comminutor cutting, the masterbatch pellet of cylindrical shape is obtained.
Next, the gained masterbatch pellet of 20.0 weight portions and the polyethylene of 80.0 weight portions are uniformly mixed.Then, monofilament are spinned from gained mixture 240 DEG C of processing temperatures.Then, knitting gained resin silk thread is to form many meshes, and A3 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
Then, net A3 to be immersed in 0.1% w/v alcoholic solution of Nylar 1 hour, to take out, air oxygen detrition 24 hours.
(embodiment 12)
By 10.0 weight portion amorphous silicas, 10.0 weight portion decises or α-cypermethrin, 7.0 weight portion zinc stearates and 0.4 weight portion BHT are uniformly mixed by high-speed mixer and obtain powders A 3.To adding this powders A 3 in the polyethylene of 150 DEG C of meltings thus the amount of powders A 3 is 27.4 weight portions relative to 62 weight account polyethylenes in single screw extrusion machine; mixture is mediated; further; add by the Nylar at 55 DEG C of heating and meltings with the amount of 5.0 weight portions by using charge pump; kneaded mixture, extruded as material strip by die head by the material of melt kneading, then it use water cooling; then with comminutor cutting, the masterbatch pellet of cylindrical shape is obtained.
Next, the gained masterbatch pellet of 20.0 weight portions and the polyethylene of 80.0 weight portions are uniformly mixed.Then, monofilament are spinned from gained mixture 240 DEG C of processing temperatures.Then, knitting gained resin silk thread is to form many meshes, and B3 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
(embodiment 13)
Monofilament is spinned from polyethylene the processing temperature of 240 DEG C.Then, knitting gained resin silk thread is to form many meshes, and C3 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
Individually, by 5.0 weight portion decises or α-cypermethrin, 5.0 weight portion Nylars and 3.0 parts by weight of propylene glycol are dissolved in 87.0 weight portion alcohol, obtain spraying liquid A3.
Then, spraying liquid A3 is sprayed onto on described net C3, and by its air oxygen detrition 24 hours.
(embodiment 14)
Monofilament is spinned from polyester the processing temperature of 260 DEG C.Then, knitting gained resin silk thread is to form many meshes, and D3 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
Individually, by 5.0 weight portion decises or α-cypermethrin, 5.0 weight portion Nylars and 3.0 parts by weight of propylene glycol are dissolved in 87.0 weight portion alcohol, obtain spraying liquid A3.
Then, spraying liquid A3 is sprayed onto on described net D3, and by its air oxygen detrition 24 hours.
(embodiment 15)
By 10.0 weight portion amorphous silicas, 7.0 weight portion zinc stearates and 0.4 weight portion BHT are uniformly mixed by high-speed mixer and obtain powder H3.To adding this powder H3 in the polyethylene of 150 DEG C of meltings thus the amount of powder H3 is 17.4 weight portions relative to 72 weight account polyethylenes in single screw extrusion machine; mixture is mediated; further; add by the Nylar at 55 DEG C of heating and meltings with the amount of 5.0 weight portions by using charge pump; kneaded mixture, extruded as material strip by die head by the material of melt kneading, then it use water cooling; then with comminutor cutting, the masterbatch pellet of cylindrical shape is obtained.
Next, the gained masterbatch pellet of 20.0 weight portions and the polyethylene of 80.0 weight portions are uniformly mixed.Then, monofilament are spinned from gained mixture 240 DEG C of processing temperatures.Then, knitting gained resin silk thread is to form many meshes, and H3 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
Then, net H3 to be immersed in 0.1% w/v alcoholic solution of decis or α-cypermethrin 1 hour, to take out, air oxygen detrition 24 hours.
(embodiment 16)
By 7.0 weight portion permethrins, 5.0 weight portion zinc stearates and 0.3 weight portion BHT are uniformly mixed by high-speed mixer and obtain powders A 4.To adding this powders A 4 in the polyethylene of the 3:2 of 150 DEG C of meltings and ethylene methyl methacrylate copolymer mixture thus the amount of powders A 4 is 12.3 weight portions relative to the polyethylene of 87.7 weight portion 3:2 and ethylene methyl methacrylate copolymer mixture in single screw extrusion machine; mixture is mediated; the material of melt kneading is extruded as material strip by die head; then it use water cooling; then with comminutor cutting, the masterbatch pellet of cylindrical shape is obtained.
Next, the gained masterbatch pellet of 30.0 weight portions and the polyethylene of 70.0 weight portions are uniformly mixed.Then, monofilament are spinned from gained mixture 240 DEG C of processing temperatures.Then, knitting gained resin silk thread is to form many meshes, and E1 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
Then, net E1 to be immersed in 0.1% w/v alcoholic solution of Nylar 1 hour, to take out, air oxygen detrition 24 hours.
(embodiment 17)
By 7.0 weight portion permethrins, 5.0 weight portion zinc stearates and 0.3 weight portion BHT are uniformly mixed by high-speed mixer and obtain powders A 4.To adding this powders A 4 in the polyethylene of the 3:2 of 150 DEG C of meltings and ethylene methyl methacrylate copolymer mixture thus the amount of powders A 4 is 12.3 weight portions relative to the polyethylene of 84.2 weight portion 3:2 and ethylene methyl methacrylate copolymer mixture in single screw extrusion machine, mixture is mediated, further, add by the Nylar at 55 DEG C of heating and meltings with the amount of 3.5 weight portions by using charge pump, mixture is mediated, the material of melt kneading is extruded as material strip by die head, then it use water cooling, then cut with comminutor, obtain the masterbatch pellet of cylindrical shape.
Next, the gained masterbatch pellet of 30.0 weight portions and the polyethylene of 70.0 weight portions are uniformly mixed.Then, monofilament are spinned from gained mixture 240 DEG C of processing temperatures.Then, knitting gained resin silk thread is to form many meshes, and F1 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
(embodiment 18)
5.0 weight portion zinc stearates and 0.3 weight portion BHT are uniformly mixed by high-speed mixer and obtain powder H4.To adding this powder H4 in the polyethylene of the 3:2 of 150 DEG C of meltings and ethylene methyl methacrylate copolymer mixture thus the amount of powder H4 is 5.3 weight portions relative to the polyethylene of 91.2 weight portion 3:2 and ethylene methyl methacrylate copolymer mixture in single screw extrusion machine, mixture is mediated, further, add by the Nylar at 55 DEG C of heating and meltings with the amount of 3.5 weight portions by using charge pump, mixture is mediated, the material of melt kneading is extruded as material strip by die head, then it use water cooling, then cut with comminutor, obtain the masterbatch pellet of cylindrical shape.
Next, the gained masterbatch pellet of 30.0 weight portions and the polyethylene of 70.0 weight portions are uniformly mixed.Then, monofilament are spinned from gained mixture 240 DEG C of processing temperatures.Then, knitting gained resin silk thread is to form many meshes, and H4 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
Then, net H4 to be immersed in 0.1% w/v aqueous isopropanol of permethrin 1 hour, to take out, air oxygen detrition 24 hours.
(embodiment 19)
5.0 weight portion zinc stearates and 0.3 weight portion BHT are uniformly mixed by high-speed mixer and obtain powders A 5.To adding this powders A 5 in the polyethylene of the 3:2 of 150 DEG C of meltings and ethylene methyl methacrylate copolymer mixture thus the amount of powders A 5 is 5.3 weight portions relative to the polyethylene of 84.2 weight portion 3:2 and ethylene methyl methacrylate copolymer mixture in single screw extrusion machine, mixture is mediated, further, by using charge pump by by adding with the amount of 10.5 weight portions at the permethrin of 55 DEG C of heating and meltings and the 2:1 mixture of Nylar, mixture is mediated, the material of melt kneading is extruded as material strip by die head, then it use water cooling, then cut with comminutor, obtain the masterbatch pellet of cylindrical shape.
Next, the gained masterbatch pellet of 30.0 weight portions and the polyethylene of 70.0 weight portions are uniformly mixed.Then, monofilament are spinned from gained mixture 240 DEG C of processing temperatures.Then, knitting gained resin silk thread is to form many meshes, and F2 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
(embodiment 20)
5.0 weight portion zinc stearates and 0.3 weight portion BHT are uniformly mixed by high-speed mixer and obtain powders A 5.To adding this powders A 5 in the polyethylene of the 3:2 of 150 DEG C of meltings and ethylene methyl methacrylate copolymer mixture thus the amount of powders A 5 is 5.3 weight portions relative to the polyethylene of 87.7 weight portion 3:2 and ethylene methyl methacrylate copolymer mixture in single screw extrusion machine, mixture is mediated, further, by using charge pump by by adding with the amount of 7.0 weight portions at the permethrin of 55 DEG C of heating and meltings and the 1:1 mixture of Nylar, mixture is mediated, the material of melt kneading is extruded as material strip by die head, then it use water cooling, then cut with comminutor, obtain the masterbatch pellet of cylindrical shape.
Next, the gained masterbatch pellet of 30.0 weight portions and the polyethylene of 70.0 weight portions are uniformly mixed.Then, monofilament are spinned from gained mixture 240 DEG C of processing temperatures.Then, knitting gained resin silk thread is to form many meshes, and F3 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
(embodiment 21)
5.0 weight portion zinc stearates and 0.3 weight portion BHT are uniformly mixed by high-speed mixer and obtain powders A 5.To adding this powders A 5 in the polyethylene of the 3:2 of 150 DEG C of meltings and ethylene methyl methacrylate copolymer mixture thus the amount of powders A 5 is 5.3 weight portions relative to the polyethylene of 84.2 weight portion 3:2 and ethylene methyl methacrylate copolymer mixture in single screw extrusion machine, mixture is mediated, further, by using charge pump by by adding with the amount of 10.5 weight portions at the permethrin of 55 DEG C of heating and meltings and the 1:1 mixture of Nylar, mixture is mediated, the material of melt kneading is extruded as material strip by die head, then it use water cooling, then cut with comminutor, obtain the masterbatch pellet of cylindrical shape.
Next, the gained masterbatch pellet of 30.0 weight portions and the polyethylene of 70.0 weight portions are uniformly mixed.Then, monofilament are spinned from gained mixture 240 DEG C of processing temperatures.Then, knitting gained resin silk thread is to form many meshes, and F4 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
(embodiment 22)
5.0 weight portion zinc stearates and 0.3 weight portion BHT are uniformly mixed by high-speed mixer and obtain powders A 5.To adding this powders A 5 in the polyethylene of the 3:2 of 150 DEG C of meltings and ethylene methyl methacrylate copolymer mixture thus the amount of powders A 5 is 5.3 weight portions relative to the polyethylene of 84.2 weight portion 3:2 and ethylene methyl methacrylate copolymer mixture in single screw extrusion machine, mixture is mediated, further, by using charge pump by by adding with the amount of 10.5 weight portions at the permethrin of 55 DEG C of heating and meltings and the 1:2 mixture of Nylar, mixture is mediated, the material of melt kneading is extruded as material strip by die head, then it use water cooling, then cut with comminutor, obtain the masterbatch pellet of cylindrical shape.
Next, the gained masterbatch pellet of 30.0 weight portions and the polyethylene of 70.0 weight portions are uniformly mixed.Then, monofilament are spinned from gained mixture 240 DEG C of processing temperatures.Then, knitting gained resin silk thread is to form many meshes, and F5 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
(embodiment 23)
5.0 weight portion zinc stearates and 0.3 weight portion BHT are uniformly mixed by high-speed mixer and obtain powders A 5.To adding this powders A 5 in the polyethylene of the 3:2 of 150 DEG C of meltings and ethylene methyl methacrylate copolymer mixture thus the amount of powders A 5 is 5.3 weight portions relative to the polyethylene of 87.2 weight portion 3:2 and ethylene methyl methacrylate copolymer mixture in single screw extrusion machine, mixture is mediated, further, by using charge pump by by adding with the amount of 7.5 weight portions at the permethrin of 55 DEG C of heating and meltings and the 2:1 mixture of Nylar, mixture is mediated, the material of melt kneading is extruded as material strip by die head, then it use water cooling, then cut with comminutor, obtain the masterbatch pellet of cylindrical shape.
Next, the gained masterbatch pellet of 30.0 weight portions and the polyethylene of 70.0 weight portions are uniformly mixed.Then, monofilament are spinned from gained mixture 240 DEG C of processing temperatures.Then, knitting gained resin silk thread is to form many meshes, and F6 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
(comparative example 1)
5.0 weight portion zinc stearates and 0.3 weight portion BHT are uniformly mixed by high-speed mixer and obtain powders A 5.To adding this powders A 5 in the polyethylene of the 3:2 of 150 DEG C of meltings and ethylene methyl methacrylate copolymer mixture thus the amount of powders A 5 is 5.3 weight portions relative to the polyethylene of 87.7 weight portion 3:2 and ethylene methyl methacrylate copolymer mixture in single screw extrusion machine, mixture is mediated, further, add by the permethrin at 55 DEG C of heating and meltings with the amount of 7.0 weight portions by using charge pump, mixture is mediated, the material of melt kneading is extruded as material strip by die head, then it use water cooling, then cut with comminutor, obtain the masterbatch pellet of cylindrical shape.
Next, the gained masterbatch pellet of 30.0 weight portions and the polyethylene of 70.0 weight portions are uniformly mixed.Then, monofilament are spinned from gained mixture 240 DEG C of processing temperatures.Then, knitting gained resin silk thread is to form many meshes, and G1 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
(comparative example 2)
5.0 weight portion zinc stearates and 0.3 weight portion BHT are uniformly mixed by high-speed mixer and obtain powder H4.To adding this powder H4 in the polyethylene of the 3:2 of 150 DEG C of meltings and ethylene methyl methacrylate copolymer mixture thus the amount of powder H4 is 5.3 weight portions relative to the polyethylene of 84.2 weight portion 3:2 and ethylene methyl methacrylate copolymer mixture in single screw extrusion machine, mixture is mediated, further, add by the Nylar at 55 DEG C of heating and meltings with the amount of 10.5 weight portions by using charge pump, mixture is mediated, the material of melt kneading is extruded as material strip by die head, then it use water cooling, then cut with comminutor, obtain the masterbatch pellet of cylindrical shape.
Next, the gained masterbatch pellet of 30.0 weight portions and the polyethylene of 70.0 weight portions are uniformly mixed.Then, monofilament are spinned from gained mixture 240 DEG C of processing temperatures.Then, knitting gained resin silk thread is to form many meshes, and G2 is netted in preparation.The size of described mesh is set as making every 6.45 cm
2hole count be 100.
(testing example 1)
The sheet of 25 cm × 25 cm is cut as test sample from the pest control material with net structure of embodiment 19,21 and 22 and comparative example 1 and 2.Each put into 900ml vial and with 500ml acetone, the active component on its surface washed off.Then, each is remained on 30 DEG C one day and be exposed to female white end anopheles (Anopheles albimanus) 3 minutes, bore method (cone method) according to being disclosed in below with reference to the standard WHO in document.After exposure, anopheles will be held in vain to put into 200ml and to observe plastic cup, and measure and knock down individual number after 60 minutes.The mosquito that can not stand is judged as " knocking down ".Result is shown in Table 1.
(bibliography)
WHOPES?(2005),?Guidelines?for?laboratory?and?field?testing?of?long-lasting?insecticidal?mosquito?nets,?WHO/CDS/WHOPES/GCDPP/2005.11?Geneva,?WHO.
(table 1)
| ? | The female number of test | (%) knock down |
| Embodiment 19 | 39 | 100 |
| Embodiment 21 | 39 | 77 |
| Embodiment 22 | 40 | 95 |
| Comparative example 1 | 38 | 26 |
| Comparative example 2 | 39 | 0 |
As described above, pest control material of the present invention demonstrates excellent pest controling effect.
Industrial applicibility
Pest control material of the present invention has excellent pest controling effect, and therefore it has great industrial application value.
Claims (6)
1. pest control material, it has and remains on pyrethroid compound on carrier and insect growth regulator, IGR,
(1) wherein said pest control material is mosquito net structure,
(2) wherein pyrethroid compound is 1:2-2:1 with the compounding ratio of insect growth regulator, IGR,
(3) wherein carrier is thermoplastic resin,
(4) its intermediate pore size is 1-5mm,
(5) wherein netting gear has knitted structure,
(6) wherein said pyrethroid compound is permethrin,
(7) wherein said insect growth regulator, IGR is Nylar.
2. pest control material according to claim 1, wherein said pyrethroid compound and/or described insect growth regulator, IGR are blended in described carrier.
3., according to the pest control material of any one of claim 1-2, wherein said pyrethroid compound and/or described insect growth regulator, IGR are coated on the surface of described carrier.
4., according to the pest control material of claim 1 or 2, also comprise synergist.
5. pest control material according to claim 3, also comprises synergist.
6. according to the pest control material of any one of claim 1-5 for preventing pathogene to the purposes of the propagation of humans and animals.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010-115308 | 2010-05-19 | ||
| JP2010115308 | 2010-05-19 | ||
| PCT/JP2011/061467 WO2011145667A1 (en) | 2010-05-19 | 2011-05-12 | Pest control material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102883611A CN102883611A (en) | 2013-01-16 |
| CN102883611B true CN102883611B (en) | 2015-01-21 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201180024655.7A Expired - Fee Related CN102883611B (en) | 2010-05-19 | 2011-05-12 | Pest control material |
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| Country | Link |
|---|---|
| JP (2) | JP2012001533A (en) |
| CN (1) | CN102883611B (en) |
| AP (1) | AP3632A (en) |
| SG (1) | SG185109A1 (en) |
| WO (1) | WO2011145667A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2013159023A1 (en) * | 2012-04-19 | 2013-10-24 | University Of Florida Research Foundation, Inc. | Dual action lethal containers and compositions for killing adult mosquitos and larvae |
| CN104838060B (en) * | 2012-12-04 | 2017-08-25 | 拜尔农作物科学股份公司 | The method for preparing the fabric comprising insecticide |
| JP5571265B1 (en) * | 2013-02-28 | 2014-08-13 | 大日本除蟲菊株式会社 | Scented insect repellent, scented insect repellent, and method for producing scented insect repellent |
| WO2014164783A1 (en) | 2013-03-12 | 2014-10-09 | University Of Florida Research Foundation, Inc. | Mosquito control devices using durable coating-embedded pesticides |
| US9775335B2 (en) | 2013-03-12 | 2017-10-03 | University Of Florida Research Foundation, Inc. | Durable coating-embedded pesticides with peel and stick mosquito treatment of containers |
| JP6119009B2 (en) * | 2013-05-17 | 2017-04-26 | 平岡織染株式会社 | Industrial material sheet |
| CN103444691A (en) * | 2013-07-30 | 2013-12-18 | 山东鲁普科技有限公司 | Mosquito and insect repellent rope net and production method thereof |
| JP6578745B2 (en) * | 2015-05-29 | 2019-09-25 | 住友化学株式会社 | Resin formulation for pest control that lives in water |
| CN104969997A (en) * | 2015-06-05 | 2015-10-14 | 陈东霖 | Disinfestation mat and applications thereof |
| JP6698449B2 (en) * | 2015-09-25 | 2020-05-27 | イノベイティブ・ベクター・コントロール・コンソーティアムＩｎｎｏｖａｔｉｖｅ Ｖｅｃｔｏｒ Ｃｏｎｔｒｏｌ Ｃｏｎｓｏｒｔｉｕｍ | Multifilaments and textile products containing insecticidal ingredients |
| US10375960B2 (en) * | 2015-09-25 | 2019-08-13 | Innovative Vector Control Consortium | Resin composition including insecticidal component |
| BR112018005689B1 (en) * | 2015-09-25 | 2022-05-10 | Innovative Vector Control Consortium | Insect pest control material and method for controlling pests |
| CN105532714A (en) * | 2015-11-30 | 2016-05-04 | 浙江新安化工集团股份有限公司 | Safe, environment-friendly and efficient insecticidal composition and use thereof |
| CN105532715A (en) * | 2015-12-11 | 2016-05-04 | 济南舜昊生物科技有限公司 | Composition containing methoprene and application thereof |
| CN105325449A (en) * | 2015-12-11 | 2016-02-17 | 济南舜昊生物科技有限公司 | Ultra-low volume spray containing methoprene and transfluthrin and application |
| WO2017205636A1 (en) * | 2016-05-25 | 2017-11-30 | University Of Florida Research Foundation, Inc. | Texturized insecticidal formulation |
| IL254439A0 (en) * | 2017-09-07 | 2017-11-30 | Rivulis Plastro Ltd | Pest repelling drip irrigation pipe |
| US20200048801A1 (en) * | 2018-03-28 | 2020-02-13 | North Carolina State University | Insect barrier textile liner system |
| JPWO2021070642A1 (en) * | 2019-10-07 | 2021-04-15 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2615729B2 (en) * | 1987-12-25 | 1997-06-04 | 住友化学工業株式会社 | Insecticidal composition |
| JP3016155B2 (en) * | 1990-09-10 | 2000-03-06 | アース製薬株式会社 | Pest control method in septic tank |
| BR9406243A (en) * | 1993-03-31 | 1996-01-09 | Zeneca Ltd | Solid insecticidal composition and processes for the preparation of a granulated composition and to combat the larvae and adult stages of dipterous insect pests |
| US5632999A (en) * | 1993-08-18 | 1997-05-27 | Virbac, Inc. | Sustained release pyriproxifen compositions for parasite control |
| AU715843B2 (en) * | 1994-11-28 | 2000-02-10 | Laboratoires Virbac | Residual control of parasites by long-acting shampoo formulations |
| JP3735953B2 (en) * | 1995-07-10 | 2006-01-18 | 住友化学株式会社 | Pest control method |
| AU700100B2 (en) * | 1995-07-10 | 1998-12-24 | Sumitomo Chemical Company, Limited | Resin composition and molded product thereof |
| US5705175A (en) * | 1996-02-29 | 1998-01-06 | Pennzoil Products Company | Non-aqueous controlled release insect repellent and insecticide gels |
| JP4448595B2 (en) * | 2000-03-31 | 2010-04-14 | 住友化学株式会社 | Resin composition and molded body |
| CN1863457A (en) * | 2003-08-08 | 2006-11-15 | 哈茨山公司 | High concentration topical insecticides containing pyrethroids |
| US20050132500A1 (en) * | 2003-12-22 | 2005-06-23 | Basf Aktiengesellschaft | Composition for impregnation of fibers, fabrics and nettings imparting a protective activity against pests |
| BRPI0711059B1 (en) * | 2006-04-28 | 2017-10-31 | Ceva Animal Health Llc | INSECTICIDE |
| CN101680160B (en) * | 2007-06-12 | 2013-07-10 | 巴斯夫欧洲公司 | Aqueous formulation and process for the impregnation of non-living-materials imparting a protective activity against pests |
| JP2010057476A (en) * | 2008-08-06 | 2010-03-18 | Sumitomo Chemical Co Ltd | Insect pest controlling net |
| JP5258115B2 (en) * | 2009-12-24 | 2013-08-07 | 住化ライフテク株式会社 | Insect repellent resin composition and sustained-release insect repellent molded article obtained therefrom |
-
2011
- 2011-05-12 AP AP2012006605A patent/AP3632A/en active
- 2011-05-12 CN CN201180024655.7A patent/CN102883611B/en not_active Expired - Fee Related
- 2011-05-12 SG SG2012080438A patent/SG185109A1/en unknown
- 2011-05-12 WO PCT/JP2011/061467 patent/WO2011145667A1/en active Application Filing
- 2011-05-13 JP JP2011107963A patent/JP2012001533A/en active Pending
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Also Published As
| Publication number | Publication date |
|---|---|
| WO2011145667A1 (en) | 2011-11-24 |
| JP2016025862A (en) | 2016-02-12 |
| JP2012001533A (en) | 2012-01-05 |
| CN102883611A (en) | 2013-01-16 |
| AP3632A (en) | 2016-03-08 |
| SG185109A1 (en) | 2012-12-28 |
| JP6028078B2 (en) | 2016-11-16 |
| AP2012006605A0 (en) | 2012-12-31 |
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