CN102877561A - Fireproof phenolic foam plate for outer heat-insulation system of exterior wall and process for manufacturing fireproof phenolic foam plate - Google Patents

Fireproof phenolic foam plate for outer heat-insulation system of exterior wall and process for manufacturing fireproof phenolic foam plate Download PDF

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Publication number
CN102877561A
CN102877561A CN2012104053371A CN201210405337A CN102877561A CN 102877561 A CN102877561 A CN 102877561A CN 2012104053371 A CN2012104053371 A CN 2012104053371A CN 201210405337 A CN201210405337 A CN 201210405337A CN 102877561 A CN102877561 A CN 102877561A
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China
Prior art keywords
phenolic foam
heat
insulation
fire prevention
foam board
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CN2012104053371A
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Chinese (zh)
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CN102877561B (en
Inventor
宿新泰
武荣兰
张培升
曹旭东
王守江
张麓
徐世美
李少松
张锦蓉
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XINJIANG UYGUR AUTONOMOUS REGION FIRE FIGHTING PRODUCT QUALITY SUPERVISION INSPECTION STATION
CHANGJI KANGMAN CHEMICAL BUILDING MATERIAL Co Ltd
Xinjiang University
Original Assignee
XINJIANG UYGUR AUTONOMOUS REGION FIRE FIGHTING PRODUCT QUALITY SUPERVISION INSPECTION STATION
CHANGJI KANGMAN CHEMICAL BUILDING MATERIAL Co Ltd
Xinjiang University
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Priority to CN201210405337.1A priority Critical patent/CN102877561B/en
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Abstract

The invention provides an outer heat-insulation system of an exterior wall, a fireproof phenolic foam heat-insulation plate for the system and a process for manufacturing the heat-insulation plate. The outer heat-insulation system of the exterior wall comprises an adhesion layer, a heat-insulation layer and a decorative finish layer. The heat-insulation layer comprises the fireproof phenolic foam plate. The fireproof phenolic foam plate can be continuously manufactured from phenolic resin, foaming agents, surfactants, curing agents and a reinforcement protective layer via foaming, curing and cladding. The outer heat-insulation system, the fireproof phenolic foam heat-insulation plate and the process have the advantages that the process for manufacturing the fireproof phenolic foam heat-insulation plate is simple in operation and is environment-friendly, and continuous and batch production can be realized; the manufactured heat-insulation plate overcomes shortcomings that the traditional phenolic plate is easy to break and powder of the traditional phenolic plate is easy to drop; the manufactured heat-insulation plate is high in strength and convenient to use, and is fireproof and heat-insulation; and the outer heat-insulation system of the exterior wall comprises the heat-insulation plate, accordingly, not only can sufficiently realize heat-insulation and fireproof effects, but also is energy-saving and attractive, meets the national requirement on environmental protection, and has a good social benefit.

Description

A kind of fire prevention phenolic foam board and production technology thereof for external thermal insulation system
Technical field
The invention belongs to the energy-saving building materials field, relate in particular to a kind of external thermal insulation system and be used for fire prevention phenolic foam board and the production technology thereof of this system, be applicable to the energy-saving heat preserving of skin.
Background technology
Building energy conservation heat insulation is conducive to the saving of the energy and the improvement of dwelling environment, is the target that will make great efforts to reach both at home and abroad at present.External Thermal Insulation Technology for External is not only applicable to new building, and is applicable to the reducing energy consumption of existing building, is a kind of energy-saving building technology of wideling popularize at present.But, the heat insulating materials such as normal operation polystyrene foam, polyurethane foam in present External Thermal Insulation Technology for External.These materials are heat-resisting poor, loss of properties on aging not only, but also exists easy firing, when burning to discharge the shortcoming of a large amount of poison gas, and this has just buried potential safety hazard, serious threat people's the security of the lives and property for building.
Phenol formaldehyde foam has caused people's attention owing to having unique flame resistant performance.It not only has difficult combustion, low toxicity, low cigarette, prevents the character of flame spread, but also has good effect of heat insulation, becomes the at first material of present building energy conservation heat insulation.
But there are the shortcomings such as fragility is large, surface strength is low, use is inconvenient in traditional phenolic foam material, and usually adopts environmentally harmful chloro-fluoro-carbon kind blowing agent in the production of phenol formaldehyde foam, and usually adopts the lower intermittent operation mode of production capacity.These have just limited being widely used of phenolic aldehyde foam thermal insulation material.
Summary of the invention
Purpose of the present invention is exactly that exist during the problems such as the intensity that exists for existing phenolic aldehyde foam thermal insulation material is low, frangible and phenol formaldehyde foam are produced environment is produced such as pollutes, production efficiency is low at the problem, a kind of exterior wall heat-preserving system is provided and has been used for fire prevention phenolic foam board and the production technology thereof of this system.External thermal insulation system of the present invention can make building realize energy-conservation, fire prevention and purpose attractive in appearance with comparalive ease.Fire prevention phenolic foam board of the present invention has advantages of that intensity is high, is difficult for efflorescence, and its production technology environmental protection, simple to operate, and the serialization of the phenolic foam board of can realizing preventing fires prepares in batches.
The present invention realizes with following technical scheme.
A kind of external thermal insulation system, it is comprised of tack coat (2), insulation layer (3) and finish coat (4).Lay tack coat (2) on exterior wall (1) surface, lay insulation layer (3) at tack coat (2), lay finish coat (4) at insulation layer (3) again.Wherein employed tack coat (2) is one or more in mortar, cement, gypsum, the adhesive, and employed finish coat (4) is exterior wall putty and emulsion paint.The thickness of tack coat (2) is 0.5~2mm, and the thickness of finish coat (4) is 0.5~1mm.
A kind of fire prevention phenolic foam board for external thermal insulation system, it has formed the insulation layer (3) of this exterior wall outer heat preservation system, and its thickness is 10~80mm.
A kind of production technology of the fire prevention phenolic foam board for external thermal insulation system, this technique makes the fire prevention phenolic foam board for phenolic resins, blowing agent, surfactant, curing compound and enhancing overcoat are carried out serialization production through foaming, curing and clad can.Wherein, the quality of material proportioning of production fire prevention phenolic foam board is 100 parts of phenolic resins: 1~20 part of blowing agent: 0.5~8 part of surfactant: 1~15 part of curing compound: 20~50 parts strengthen overcoats.Employed phenolic resins is high ortho position phenol-formaldehyde resin modified, employed blowing agent is one or more in chloromethanes, chloroethanes, the benzinum, employed surfactant is one or more in silicone oil, tween, the neopelex, employed curing compound is one or more in sulfuric acid, phosphoric acid, benzene sulfonic acid, the xylene monosulfonic acid, and employed enhancing overcoat is glass fiber reticular cloth or aluminum foil plate.
The production technology of the described fire prevention phenolic foam board of the application of the invention is carried out the production of phenolic-aldehyde heat-insulation board, and the phenolic board of gained is used for external thermal insulation system, can make building realize energy-conservation, fire prevention and purpose attractive in appearance, and employed fire prevention phenolic foam board has advantages of that intensity is high, is difficult for efflorescence, and the production technology environmental protection of phenolic foam board, simple to operate is easy to realize batch production.
Description of drawings
Fig. 1 is external thermal insulation system schematic diagram of the present invention.
Fig. 2 is the production technology schematic diagram of fire prevention phenolic foam board of the present invention.
Among the figure: 1. exterior wall, 2. tack coat, 3. insulation layer, 4. finish coat.
The specific embodiment
The present invention is further elaborated below in conjunction with specific embodiment.These embodiment are interpreted as only being used for explanation the present invention and are not used in restriction protection scope of the present invention.After the content of having read the present invention's record, based on principle of the present invention various changes or the modification that the present invention makes fallen into claims limited range of the present invention equally.
At first, phenolic resins, blowing agent, surfactant, curing compound and enhancing overcoat are carried out raw material mass mixture ratio, adopt 100 parts of high ortho position phenol-formaldehyde resin modifieds, 10 parts of chloroethanes are as blowing agent, 5 parts of silicone oil are as surfactant, 15 parts of benzene sulfonic acids are as curing compound, and 20 parts of glass fiber reticular cloths are as strengthening overcoat.
Secondly, will strengthen overcoat and be placed on the laminating conveyor, will remain join raw material and join in the mobile casting machine and with it and be sprayed on the enhancing overcoat, to raw material foam, curing and clad can, produce the fire prevention phenolic foam board.
At last, the fire prevention phenolic foam board that makes is used as the insulation layer (3) of external thermal insulation system.Lay the mortar bonding layer (2) of 1mm on exterior wall (1) surface, lay the insulation layer (3) of 30mm on tack coat (2) surface, lay again the emulsion paint finish coat (4) of 0.5mm on insulation layer (3) surface.
Statement by above-described embodiment also can find out by reference to the accompanying drawings, the invention provides external thermal insulation system and can make building realize energy-conservation, fire prevention and purpose attractive in appearance.Employed fire prevention phenolic foam board has advantages of that intensity is high, is difficult for efflorescence, and its production technology environmental protection, simple to operate, the continuous batch production of the phenolic foam board of can realizing preventing fires.

Claims (7)

1. fire prevention phenolic foam board and production technology thereof that is used for external thermal insulation system, it is characterized in that: this exterior wall outer heat preservation system is comprised of tack coat (2), insulation layer (3) and finish coat (4), lay tack coat (2) on exterior wall (1) surface, lay insulation layer (3) at tack coat (2), lay finish coat (4) at insulation layer (3) again.
2. fire prevention phenolic foam board and production technology thereof that is used for external thermal insulation system, it is characterized in that: the insulation layer of this exterior wall outer heat preservation system (3) is made of the fire prevention phenolic foam board.
3. fire prevention phenolic foam board and production technology thereof that is used for external thermal insulation system, it is characterized in that: the fire prevention phenolic foam board that is used for this external thermal insulation system carries out serialization production by phenolic resins, blowing agent, surfactant, curing compound and enhancing overcoat through foaming, curing and clad can and makes.
4. fire prevention phenolic foam board and production technology thereof for external thermal insulation system according to claim 1, it is characterized in that employed tack coat (2) is one or more in mortar, cement, gypsum, the adhesive, employed finish coat (4) is exterior wall putty and emulsion paint.
5. the fire prevention phenolic foam board and the production technology thereof that are used for external thermal insulation system described in any one according to claim 1-2, the thickness that it is characterized in that tack coat (2) is 0.5~2mm, the thickness of insulation layer (3) is 10~80mm, and the thickness of finish coat (4) is 0.5~1mm.
6. fire prevention phenolic foam board and production technology thereof for external thermal insulation system according to claim 3, the quality of material proportioning that it is characterized in that producing the fire prevention phenolic foam board is 100 parts of phenolic resins: 1~20 part of blowing agent: 0.5~8 part of surfactant: 1~15 part of curing compound: 20~50 parts strengthen overcoats.
7. fire prevention phenolic foam board and production technology thereof for external thermal insulation system according to claim 3, it is characterized in that employed phenolic resins is high ortho position phenol-formaldehyde resin modified, employed blowing agent is one or more in pentane, chloromethanes, chloroethanes, the benzinum, employed surfactant is one or more in silicone oil, tween, the neopelex, employed curing compound is one or more in sulfuric acid, phosphoric acid, benzene sulfonic acid, the xylene monosulfonic acid, and employed enhancing overcoat is glass fiber reticular cloth or aluminum foil plate.
CN201210405337.1A 2012-10-23 2012-10-23 Fireproof phenolic foam plate for outer heat-insulation system of exterior wall and process for manufacturing fireproof phenolic foam plate Expired - Fee Related CN102877561B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112937019A (en) * 2021-01-26 2021-06-11 杭州威晓科技有限公司 Heat-insulating wall of environment-friendly building and preparation method thereof
CN113321842A (en) * 2021-06-28 2021-08-31 湖北汽车工业学院 Phenolic resin foam composite material and preparation method thereof
CN112937019B (en) * 2021-01-26 2024-06-07 杭加(湖北)建筑节能新材料有限公司 Environment-friendly building heat-insulating wall and preparation method thereof

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JPH01162042A (en) * 1987-12-18 1989-06-26 Nec Corp Telephone set
JPH02178444A (en) * 1988-12-29 1990-07-11 Achilles Corp Airtight heat insulating wall structure
JPH1162042A (en) * 1997-08-26 1999-03-05 Ig Tech Res Inc Structure of heat insulation panel
CN1613638A (en) * 2003-11-05 2005-05-11 厦门新风机实业有限公司 Flame retardant phenolic resin foamed sandwiching material and its preparation
CN101191371A (en) * 2007-12-07 2008-06-04 厦门高特高新材料有限公司 Composite phenolic aldehyde building energy-saving heat-insulating board and its manufacturing method and application
CN201137263Y (en) * 2007-12-15 2008-10-22 林少林 Outer wall external thermal-insulating decorative board
CN201809875U (en) * 2010-09-10 2011-04-27 湖南省中政建材有限公司 Fireproof phenolic aldehyde insulation board outer wall outer decorative integrated system
CN102061749A (en) * 2010-11-22 2011-05-18 富思特制漆(北京)有限公司 External wall heat insulation system with fireproofing function and manufacturing method thereof
CN102071754A (en) * 2009-11-24 2011-05-25 江苏康斯维信建筑节能技术有限公司 Heat-insulating decorative fireproof partition board for exterior wall of building and construction method thereof
CN201981726U (en) * 2011-03-04 2011-09-21 沈石山 External insulation board of thin-plastered outer wall for phenolic aldehyde plate

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01162042A (en) * 1987-12-18 1989-06-26 Nec Corp Telephone set
JPH02178444A (en) * 1988-12-29 1990-07-11 Achilles Corp Airtight heat insulating wall structure
JPH1162042A (en) * 1997-08-26 1999-03-05 Ig Tech Res Inc Structure of heat insulation panel
CN1613638A (en) * 2003-11-05 2005-05-11 厦门新风机实业有限公司 Flame retardant phenolic resin foamed sandwiching material and its preparation
CN101191371A (en) * 2007-12-07 2008-06-04 厦门高特高新材料有限公司 Composite phenolic aldehyde building energy-saving heat-insulating board and its manufacturing method and application
CN201137263Y (en) * 2007-12-15 2008-10-22 林少林 Outer wall external thermal-insulating decorative board
CN102071754A (en) * 2009-11-24 2011-05-25 江苏康斯维信建筑节能技术有限公司 Heat-insulating decorative fireproof partition board for exterior wall of building and construction method thereof
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CN102061749A (en) * 2010-11-22 2011-05-18 富思特制漆(北京)有限公司 External wall heat insulation system with fireproofing function and manufacturing method thereof
CN201981726U (en) * 2011-03-04 2011-09-21 沈石山 External insulation board of thin-plastered outer wall for phenolic aldehyde plate

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112937019A (en) * 2021-01-26 2021-06-11 杭州威晓科技有限公司 Heat-insulating wall of environment-friendly building and preparation method thereof
CN112937019B (en) * 2021-01-26 2024-06-07 杭加(湖北)建筑节能新材料有限公司 Environment-friendly building heat-insulating wall and preparation method thereof
CN113321842A (en) * 2021-06-28 2021-08-31 湖北汽车工业学院 Phenolic resin foam composite material and preparation method thereof

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