CN102863151A - High-strength heat-resistant glassware - Google Patents
High-strength heat-resistant glassware Download PDFInfo
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- CN102863151A CN102863151A CN2012103513560A CN201210351356A CN102863151A CN 102863151 A CN102863151 A CN 102863151A CN 2012103513560 A CN2012103513560 A CN 2012103513560A CN 201210351356 A CN201210351356 A CN 201210351356A CN 102863151 A CN102863151 A CN 102863151A
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Abstract
The invention discloses high-strength heat-resistant glassware. The high-strength heat-resistant glassware is manufactured by mixing and melting an A material and a B material in equal proportion. Raw materials employed in the invention are easy to melt and form; and the manufactured glassware has the advantages of stable color, high heat resistance, high heat stability, high strength, no easy to break, high comprehensive performance, and can be widely applied to daily life.
Description
Technical field
The present invention relates to a kind of high strength heat resistant glassware, belong to the glassware manufacture technology field.
Background technology
Glassware is exactly the vessel made from glass, and glassware is widely used in daily life, and it has the advantages such as transparent, pollution-free, the reusable and life cycle of quality is long.But the thermotolerance of most glassware is relatively poor, intensity is low, and is easily broken, limited its work-ing life.
Summary of the invention
The present invention is directed to the deficiencies in the prior art, a kind of high strength heat resistant glassware is provided, improve its over-all properties, thereby increase the service life.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of high strength heat resistant glassware is founded by A material and the mixing of B material equal proportion and to be formed, and the weight part of its two portions constitutive material is:
The A material:
Quartz sand 50-60, Wingdale 10-15, nano titanium oxide 5-10, soda ash 15-20, salt of wormwood 5-10, aluminium hydroxide 5-10, borax 2-5, cerium oxide 0.5-1, Neodymium trioxide 0.5-1, nano ceramic powder 10-20,
Described nano ceramic powder by calcite, lazurite, white jade stone by weight 1-2:1-2:1 at 600-700 ℃ of lower discharge plasma sintering 4-5 hour, become the 5-10nm nanometer powder by high-energy mechanical ball milling, admix tetra isopropyl two (dioctyl phosphorous acid acyloxy) the titanic acid ester agitating that is equivalent to powder weight 2-4% even, oven dry gets final product;
The B material:
Quartz sand 40-50, potassium felspar sand 20-30, Calcium of intensifiens 10-15, silicon carbide micro-powder 5-10, soda ash 15-20, saltpetre 5-10, electric melting magnesium aluminum spinel 5-10, nano aluminium oxide 5-10, yttrium oxide 0.5-1, Samarium trioxide 0.5-1, modified kaolin 5-10,
Described modified kaolin is that the polyvinylpyrrolidone that adds 0.4-0.6% in the kaolin raw material carries out wet ball grinding, and discharging was ground the 100-120 mesh sieve afterwards 100-110 ℃ of drying in oven after ball milling 80-90 minute, namely got the modified kaolin powder.
The preparation method of described high strength heat resistant glassware may further comprise the steps:
(1) preparation of glass metal A
Take by weighing each raw material in A material formula ratio, first with block raw material such as the pulverizing such as Wingdale, soda ash, and abundant dried feed, iron-bearing material will carry out deironing to be processed, and after pre-treatment of raw material is complete the admixtion that mixes is dropped into tank furnace and carries out heat, and temperature is 1550-1600 ℃, time is 3-4h, make it to form evenly, without calculus, without striped, without bubble, namely get glass metal A, heat preservation for standby use;
(2) preparation of glass metal B
Take by weighing each raw material in B material formula ratio, first with pulverizing such as block raw material such as potassium felspar sand, Calcium of intensifiens, soda ash, and abundant dried feed, iron-bearing material will carry out deironing to be processed, and after pre-treatment of raw material is complete the admixtion that mixes is dropped into tank furnace and carries out heat, and temperature is 1550-1600 ℃, time is 3-4h, make it to form evenly, without calculus, without striped, without bubble, namely get glass metal B, heat preservation for standby use;
(3) preparation of hybrid glass liquid
The glass metal that the glass metal A that step (1) is made and step (2) make drops in the 1000-1200 ℃ of tank furnace, stirs, and namely gets hybrid glass liquid;
(4) moulding
First with mould and die preheating to 800-900 ℃, then pour hybrid glass liquid in mould compression moulding, the demoulding after the cooled and solidified typing;
(5) thermal treatment
Glassware after the demoulding is sent in the annealing furnace, annealed according to the annealing temperature curve of formulating, the unrelieved stress of glass is controlled in the claimed range.
(6) aftertreatment
After the annealing, glassware is polished, ponders the processing such as texturing, decoration, color spray, last loading packing, the stacking finished product is sent into stockyard and is got final product.
The fineness of described nano titanium oxide is 2-5nm; The fineness of described silicon carbide micro-powder is 2-4 μ m; The fineness of described nano aluminium oxide is 4-6nm.
Raw material used in the present invention is easy to found, be easy to moulding, the glassware colour stable, the good heat resistance that prepare, and the product Heat stability is good, intensity is high, can be not broken easily, over-all properties is good, can be widely used in the daily life.
Embodiment
The present invention is further illustrated below in conjunction with specific embodiment.
Embodiment
(1) preparation of glass metal A
Take off the raw material of row weight part: 60 parts of quartz sands, 15 parts of Wingdales, 8 parts of nano titanium oxides, 20 parts of soda ash, 8 parts of salt of wormwood, 10 parts of aluminium hydroxides, 4 parts of boraxs, 0.6 part cerium oxide, 0.6 part Neodymium trioxide, 15 parts of nano ceramic powders, described nano ceramic powder is by calcite, lazurite, white jade stone by weight 2:2:1 700 ℃ of lower discharge plasma sinterings 5 hours, become 6 nm nanometer powders by high-energy mechanical ball milling, admix tetra isopropyl two (dioctyl phosphorous acid acyloxy) the titanic acid ester agitating that is equivalent to powder weight 3% even, oven dry gets final product
First with block raw material such as the pulverizing such as Wingdale, soda ash, and abundant dried feed, iron-bearing material will carry out deironing to be processed, after pre-treatment of raw material is complete the admixtion that mixes is dropped into tank furnace and carry out heat, temperature is 1600 ℃, and the time is 4h, makes it to form evenly, without calculus, without striped, without bubble, namely get glass metal A, heat preservation for standby use;
(2) preparation of glass metal B
Take off the raw material of row weight part: 50 parts of quartz sands, 25 parts of potassium felspar sands, 12 parts of Calcium of intensifiens, 10 parts of silicon carbide micro-powders, 20 parts of soda ash, 8 parts of saltpetre, 10 parts of electric melting magnesium aluminum spinels, 8 parts of nano aluminium oxides, 0.5 part of yttrium oxide, 0.5 part of Samarium trioxide, 10 parts of modified kaolins, described modified kaolin is that the polyvinylpyrrolidone of adding 0.5% in the kaolin raw material carries out wet ball grinding, ball milling after 90 minutes discharging 105 ℃ of drying in oven, grind afterwards 100 mesh sieves, namely got the modified kaolin powder.
First with pulverizing such as block raw material such as potassium felspar sand, Calcium of intensifiens, soda ash, and abundant dried feed, iron-bearing material will carry out deironing to be processed, after pre-treatment of raw material is complete the admixtion that mixes is dropped into tank furnace and carry out heat, temperature is 1550 ℃, and the time is 4h, makes it to form evenly, without calculus, without striped, without bubble, namely get glass metal B, heat preservation for standby use;
(3) preparation of hybrid glass liquid
The glass metal that the glass metal A that step (1) is made and step (2) make drops in 1180 ℃ of tank furnaces, stirs, and namely gets hybrid glass liquid;
(4) moulding
With mould and die preheating to 850 ℃, then pour hybrid glass liquid in mould compression moulding first, the demoulding after the cooled and solidified typing;
(5) thermal treatment
Glassware after the demoulding is sent in the annealing furnace, annealed according to the annealing temperature curve of formulating, the unrelieved stress of glass is controlled in the claimed range.
(6) aftertreatment
After the annealing, glassware is polished, ponders the processing such as texturing, decoration, color spray, last loading packing, the stacking finished product is sent into stockyard and is got final product.
Claims (3)
1. a high strength heat resistant glassware is characterized in that, it is founded by A material and the mixing of B material equal proportion and forms, and the weight part of its two portions constitutive material is:
The A material:
Quartz sand 50-60, Wingdale 10-15, nano titanium oxide 5-10, soda ash 15-20, salt of wormwood 5-10, aluminium hydroxide 5-10, borax 2-5, cerium oxide 0.5-1, Neodymium trioxide 0.5-1, nano ceramic powder 10-20,
Described nano ceramic powder by calcite, lazurite, white jade stone by weight 1-2:1-2:1 at 600-700 ℃ of lower discharge plasma sintering 4-5 hour, become the 5-10nm nanometer powder by high-energy mechanical ball milling, admix tetra isopropyl two (dioctyl phosphorous acid acyloxy) the titanic acid ester agitating that is equivalent to powder weight 2-4% even, oven dry gets final product;
The B material:
Quartz sand 40-50, potassium felspar sand 20-30, Calcium of intensifiens 10-15, silicon carbide micro-powder 5-10, soda ash 15-20, saltpetre 5-10, electric melting magnesium aluminum spinel 5-10, nano aluminium oxide 5-10, yttrium oxide 0.5-1, Samarium trioxide 0.5-1, modified kaolin 5-10,
Described modified kaolin is that the polyvinylpyrrolidone that adds 0.4-0.6% in the kaolin raw material carries out wet ball grinding, and discharging was ground the 100-120 mesh sieve afterwards 100-110 ℃ of drying in oven after ball milling 80-90 minute, namely got the modified kaolin powder.
2. the preparation method of a high strength heat resistant glassware as claimed in claim 1 is characterized in that may further comprise the steps:
(1) preparation of glass metal A
Take by weighing each raw material in A material formula ratio, first with block raw material such as the pulverizing such as Wingdale, soda ash, and abundant dried feed, iron-bearing material will carry out deironing to be processed, and after pre-treatment of raw material is complete the admixtion that mixes is dropped into tank furnace and carries out heat, and temperature is 1550-1600 ℃, time is 3-4h, make it to form evenly, without calculus, without striped, without bubble, namely get glass metal A, heat preservation for standby use;
(2) preparation of glass metal B
Take by weighing each raw material in B material formula ratio, first with pulverizing such as block raw material such as potassium felspar sand, Calcium of intensifiens, soda ash, and abundant dried feed, iron-bearing material will carry out deironing to be processed, and after pre-treatment of raw material is complete the admixtion that mixes is dropped into tank furnace and carries out heat, and temperature is 1550-1600 ℃, time is 3-4h, make it to form evenly, without calculus, without striped, without bubble, namely get glass metal B, heat preservation for standby use;
(3) preparation of hybrid glass liquid
The glass metal that the glass metal A that step (1) is made and step (2) make drops in the 1000-1200 ℃ of tank furnace, stirs, and namely gets hybrid glass liquid;
(4) moulding
First with mould and die preheating to 800-900 ℃, then pour hybrid glass liquid in mould compression moulding, the demoulding after the cooled and solidified typing;
(5) thermal treatment
Glassware after the demoulding is sent in the annealing furnace, annealed according to the annealing temperature curve of formulating, the unrelieved stress of glass is controlled in the claimed range;
(6) aftertreatment
After the annealing, glassware is polished, ponders the processing such as texturing, decoration, color spray, last loading packing, the stacking finished product is sent into stockyard and is got final product.
3. high strength heat resistant glassware according to claim 1 is characterized in that, the fineness of described nano titanium oxide is 2-5nm; The fineness of described silicon carbide micro-powder is 2-4 μ m; The fineness of described nano aluminium oxide is 4-6nm.
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| CN103408286A (en) * | 2013-06-24 | 2013-11-27 | 徐传德 | Preparation method of large jade building material |
| CN103922589A (en) * | 2014-03-13 | 2014-07-16 | 安徽省凤阳县前力玻璃制品有限公司 | Transparent environment-friendly glassware |
| CN104016587A (en) * | 2014-05-07 | 2014-09-03 | 薛宗洪 | Low-cost thermos bottle perform material |
| CN104016582A (en) * | 2014-05-07 | 2014-09-03 | 薛宗洪 | Rare-earth-contained thermos flask blank material |
| CN104016584A (en) * | 2014-05-07 | 2014-09-03 | 薛宗洪 | Compact thermos bottle preform material |
| CN104030566A (en) * | 2014-05-07 | 2014-09-10 | 薛宗洪 | High-aluminum borosilicate thermos bottle blank material |
| CN104030564A (en) * | 2014-05-07 | 2014-09-10 | 薛宗洪 | Waste glass-containing thermos bottle blank material |
| CN104986958A (en) * | 2015-06-30 | 2015-10-21 | 安徽鑫民玻璃制品有限公司 | Cracking-resistant glass container and preparation method thereof |
| CN104986957A (en) * | 2015-06-30 | 2015-10-21 | 安徽鑫民玻璃制品有限公司 | Low-temperature-resistant glass container and preparation method thereof |
| CN105000803A (en) * | 2015-06-30 | 2015-10-28 | 安徽鑫民玻璃制品有限公司 | Heat-resistant low-expansion glass container, and preparation method thereof |
| CN105130188A (en) * | 2015-06-30 | 2015-12-09 | 安徽鑫民玻璃制品有限公司 | High-strength fall-resistant glass container and preparation method thereof |
| CN105130189A (en) * | 2015-06-30 | 2015-12-09 | 安徽鑫民玻璃制品有限公司 | Sun-resistant anti-ageing glass container and preparation method thereof |
| CN105314850A (en) * | 2015-09-06 | 2016-02-10 | 东南大学 | High-temperature-resistant phosphate transparent glass and preparing method thereof |
| CN106892558A (en) * | 2017-02-24 | 2017-06-27 | 江西瑞晶家饰有限公司 | A kind of novel high-strength method for glass preparation |
| CN107265849A (en) * | 2017-06-12 | 2017-10-20 | 和县晶晶玻璃制品有限公司 | A kind of production technology of high intensity antibiotic glass vessel |
| CN107954598A (en) * | 2017-12-27 | 2018-04-24 | 安徽凤阳亚欧玻璃工艺品有限公司 | A kind of High-strength heat-resistant glassware |
| CN108117266A (en) * | 2017-12-30 | 2018-06-05 | 安徽杜氏高科玻璃有限公司 | A kind of wear-resisting acid corrosion-resistant glass |
| CN109942187A (en) * | 2019-04-15 | 2019-06-28 | 安徽省凤阳县华夏玻璃制品有限公司 | A kind of resistance to temperature difference glass and its preparation process |
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| CN101613217A (en) * | 2008-06-26 | 2009-12-30 | 广东科达机电股份有限公司 | The method of one-time sintering of ceramic-microcrystalline glass composite board |
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| US5516388A (en) * | 1994-09-11 | 1996-05-14 | The United States Of America As Represented By The Secretary Of The Navy | Sol-gel bonding |
| CN101613217A (en) * | 2008-06-26 | 2009-12-30 | 广东科达机电股份有限公司 | The method of one-time sintering of ceramic-microcrystalline glass composite board |
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Cited By (23)
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| CN103408286B (en) * | 2013-06-24 | 2016-05-11 | 徐传德 | A kind of preparation method of large-scale jade construction material |
| CN103408286A (en) * | 2013-06-24 | 2013-11-27 | 徐传德 | Preparation method of large jade building material |
| CN103922589A (en) * | 2014-03-13 | 2014-07-16 | 安徽省凤阳县前力玻璃制品有限公司 | Transparent environment-friendly glassware |
| CN104030566B (en) * | 2014-05-07 | 2016-08-17 | 金艳萍 | A kind of high aluminoborosilicate thermos flask bottle base material |
| CN104016582A (en) * | 2014-05-07 | 2014-09-03 | 薛宗洪 | Rare-earth-contained thermos flask blank material |
| CN104030566A (en) * | 2014-05-07 | 2014-09-10 | 薛宗洪 | High-aluminum borosilicate thermos bottle blank material |
| CN104030564A (en) * | 2014-05-07 | 2014-09-10 | 薛宗洪 | Waste glass-containing thermos bottle blank material |
| CN104016584B (en) * | 2014-05-07 | 2016-08-24 | 王红亮 | A kind of thermos flask bottle base material of densification |
| CN104016584A (en) * | 2014-05-07 | 2014-09-03 | 薛宗洪 | Compact thermos bottle preform material |
| CN104016587A (en) * | 2014-05-07 | 2014-09-03 | 薛宗洪 | Low-cost thermos bottle perform material |
| CN104030564B (en) * | 2014-05-07 | 2016-05-18 | 杜仁波 | A kind of cullet heating bottle bottle base material |
| CN104986957A (en) * | 2015-06-30 | 2015-10-21 | 安徽鑫民玻璃制品有限公司 | Low-temperature-resistant glass container and preparation method thereof |
| CN105130189A (en) * | 2015-06-30 | 2015-12-09 | 安徽鑫民玻璃制品有限公司 | Sun-resistant anti-ageing glass container and preparation method thereof |
| CN105130188A (en) * | 2015-06-30 | 2015-12-09 | 安徽鑫民玻璃制品有限公司 | High-strength fall-resistant glass container and preparation method thereof |
| CN105000803A (en) * | 2015-06-30 | 2015-10-28 | 安徽鑫民玻璃制品有限公司 | Heat-resistant low-expansion glass container, and preparation method thereof |
| CN104986958A (en) * | 2015-06-30 | 2015-10-21 | 安徽鑫民玻璃制品有限公司 | Cracking-resistant glass container and preparation method thereof |
| CN105314850A (en) * | 2015-09-06 | 2016-02-10 | 东南大学 | High-temperature-resistant phosphate transparent glass and preparing method thereof |
| CN105314850B (en) * | 2015-09-06 | 2017-10-03 | 东南大学 | A kind of high temperature resistant phosphate clear glass and preparation method thereof |
| CN106892558A (en) * | 2017-02-24 | 2017-06-27 | 江西瑞晶家饰有限公司 | A kind of novel high-strength method for glass preparation |
| CN107265849A (en) * | 2017-06-12 | 2017-10-20 | 和县晶晶玻璃制品有限公司 | A kind of production technology of high intensity antibiotic glass vessel |
| CN107954598A (en) * | 2017-12-27 | 2018-04-24 | 安徽凤阳亚欧玻璃工艺品有限公司 | A kind of High-strength heat-resistant glassware |
| CN108117266A (en) * | 2017-12-30 | 2018-06-05 | 安徽杜氏高科玻璃有限公司 | A kind of wear-resisting acid corrosion-resistant glass |
| CN109942187A (en) * | 2019-04-15 | 2019-06-28 | 安徽省凤阳县华夏玻璃制品有限公司 | A kind of resistance to temperature difference glass and its preparation process |
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