CN102836968A - Forging method of high nickel ductile iron pressure-containing member for low temperature gas compression machinery used at temperature of minus 76 DEG C to minus 121 DEG C - Google Patents

Forging method of high nickel ductile iron pressure-containing member for low temperature gas compression machinery used at temperature of minus 76 DEG C to minus 121 DEG C Download PDF

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Publication number
CN102836968A
CN102836968A CN2012103437660A CN201210343766A CN102836968A CN 102836968 A CN102836968 A CN 102836968A CN 2012103437660 A CN2012103437660 A CN 2012103437660A CN 201210343766 A CN201210343766 A CN 201210343766A CN 102836968 A CN102836968 A CN 102836968A
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weight
percentage
content
containing member
parts
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穆尚军
金鑫
耿丽鑫
苏红
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LIAONING YUANYU COMPRESSOR MANUFACTURE CO Ltd
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LIAONING YUANYU COMPRESSOR MANUFACTURE CO Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Abstract

The invention discloses a forging method of a high nickel ductile iron pressure-containing member for a low temperature gas compression machinery used at a temperature of minus 76 DEG C to minus 121 DEG C. The method comprises the steps of moulding and core making, smelting, furnace-front nodulizing, furnace-front inoculation, pouring, banking-up and mold dismantling, desanding, cleaning, polishing and shot blasting. In the smelting step, metal materials are high-purity pig iron, scrap steel and electrolytic nickel; the weight parts of the high-purity pig iron, the scrap steel and the electrolytic nickel respectively are 45 to 50 parts, 20 to 25 parts and 30 to 33 parts; and the smelting process comprises the steps of firstly adding 30 to 33 parts by weight of electrolytic nickel into a furnace floor of a medium-frequency induction furnace, then placing 45 to 50 parts by weight of high-purity pig iron to carry out power-on smelting, adding 20 to 25 parts by weight of scrap steel when the furnace temperature reaches 1,300 to 1,350 DEG C and standing for 10 minutes and purifying to obtain molten metal when the temperature is risen to 1,550 to 1,570 DEG C. The high nickel ductile iron pressure-containing member forged according to the forging method disclosed by the invention can meet the using working condition of the low temperature gas compression machinery used at the temperature of minus 76 DEG C to minus 121 DEG C.

Description

The casting method of the nickelic magnesium iron pressure-containing member of a kind of being used for-76 ℃~-121 ℃ of cryogenic gas compressor mechanicals
Technical field
The present invention relates to a kind of low temperature resistant magnesium iron casting method, specifically relate to the casting method of a kind of being applicable to-76 ℃ nickelic magnesium iron pressure-containing member of the cryogenic gas compressor mechanical of operating temperature between-121 ℃.
Background technology
The intake air temperature of cryogenic gas compressor mechanical pressure-containing member is-121 ℃, and delivery temperature is-76 ℃ to-85 ℃, and the suction and discharge pressure limit requires pressure-containing member that very high impact flexibility is arranged under-121 ℃ worst cold case between 0.2 ~ 0.8MPa.Material requirements to the gas pressure-bearing parts is special; How to make it can in the harsh climate environment, have good low-temperature resistance brittle failure property, corrosion resistance, higher percentage elongation, pressure-bearing property; Having very little linear expansion coefficient and very high low-temperature impact toughness simultaneously, is the key that cryogenic gas compressor mechanical pressure-containing member is made.
Existing gas at normal temperature compressor mechanical parts material mainly is casting pig, alloy cast iron and common spheroidal graphite cast-iron, owing in the defective of aspects such as anti-oxidant, low temperature resistant brittle failure property, can't satisfy the applying working condition of cryogenic gas compressor mechanical.
Summary of the invention
The technical problem that the present invention will solve provides the casting method of the nickelic magnesium iron pressure-containing member of a kind of being used for-76 ℃~-121 ℃ of cryogenic gas compressor mechanicals, uses the nickelic magnesium iron pressure-containing member of casting method casting of the present invention can satisfy the applying working condition of-76 ℃~-121 ℃ of cryogenic gas compressor mechanicals.
For solving the problems of the technologies described above, the present invention is used for the casting method of the nickelic magnesium iron pressure-containing member of-76 ℃~-121 ℃ of cryogenic gas compressor mechanicals, may further comprise the steps:
With the shape of said pressure-containing member, the step of the corresponding molding and core making of structure;
To casting said pressure-containing member carries out melting with metal material step;
Gained molten metal after the melting is carried out the step that stokehold nodularization, stokehold are bred;
Breed the molten metal step of behind molding and core making, pouring into a mould in the gained sand mold of back gained to stokehold nodularization, stokehold, the cast step comprises the step of current-following inoculation and instant inoculation;
Pressure-containing member after the cast is carried out the step of banking fire shake out;
The gained pressure-containing member is carried out the step of desanding, cleaning, polishing and ball blast;
Saidly use the metal material in the step of metal material melting to be high-purity pig iron, steel scrap and electrolytic nickel to casting said pressure-containing member; Weight portion is respectively 45~50 parts, 20~25 parts and 30~33 parts; Content≤0.025% (percentage by weight) of content≤0.03% (percentage by weight) of content≤0.1% (percentage by weight) of content≤1.2% (percentage by weight) of the content of C>=4.35% (percentage by weight), Si, Mn, P, S in the said high-purity pig iron; The content of the content of C≤0.040% (percentage by weight), Si is that the content of (0.034 ~ 0.036) % (percentage by weight), Mn is content≤0.02% (percentage by weight) of (0.11 ~ 0.13) % (percentage by weight), P, content≤0.01% (percentage by weight) of S in the said steel scrap; The content of nickel and cobalt>=99.96% (percentage by weight) in the said electrolytic nickel, the wherein content of cobalt≤0.02% (percentage by weight); The equipment that said melting is adopted is medium-frequency induction furnace; Fusion process comprises that elder generation is added to the medium-frequency induction furnace furnace bottom to the electrolytic nickel of 30~33 weight portions; Put into the high-purity pig iron energising melting of 45~50 weight portions again; Drop into 20~25 weight portion steel scraps when furnace temperature reaches 1300 ~ 1350 ℃, when being warming up to 1550 ~ 1570 ℃, leaving standstill and purified the gained molten metal in 10 minutes; The nodulizer of selecting for use in the step that breed the nodularization of said stokehold, stokehold is the nickel magnesium alloy nodulizer; The granularity of nickel magnesium alloy nodulizer is 5 ~ 25; Bag end addition is 0.9 ~ 1.1 weight portion; The inovulant of selecting for use is a silicon strontium inovulant, and the granularity of silicon strontium inovulant is 10 ~ 20, and bag end addition is 0.35 ~ 0.5 weight portion; The inovulant of selecting for use in current-following inoculation in the said cast step and the instant inoculation step also is silicon strontium inovulant, and current-following inoculation silicon strontium innoculant adding quantity is 0.45 ~ 0.6 weight portion, and instant inoculation silicon strontium innoculant adding quantity is 0.12 ~ 0.2 weight portion.
Adopt the nickelic magnesium iron pressure-containing member superior performance that is used for-76 ℃~-121 ℃ of cryogenic gas compressor mechanicals of casting method casting of the present invention, following through detecting each item performance indications:
Figure 2012103437660100002DEST_PATH_IMAGE002
The specific embodiment
The casting method that the present invention is used for the nickelic magnesium iron pressure-containing member of-76 ℃~-121 ℃ of cryogenic gas compressor mechanicals may further comprise the steps:
With the shape of said pressure-containing member, the step of the corresponding molding and core making of structure.
Select for use the furan resin self curing sand of silicon content more than 95% to fill type, coremaking is selected for use precoated sand 60%, high-purity technical to stir with carborundum 20%, 20% silica sand and furane resins and is formed, and places with the type graphite chilling block at heat energy-saving position; Twice zircon flour coating of sand mold external coating, coating layer thickness 0.8 ~ 1.1mm brushes one deck iron oxide red paint again; Coating layer thickness 0.4 ~ 0.6mm is provided with the special-purpose exothermic riser of corresponding magnesium iron according to magnesium iron graphitization reexpansion feeding principle at end face, and the dimension scale of running gate system sprue, cross gate, ingate is 4:8:3; Whether drill each dimension scale of case check suitable; Add the mould assembling of joint sealing mud bar, clamping after qualified, lay the dirty plate of band retaining, the stifled cup in the mouth of a river, lay secondary current-following inoculation funnel; Put into the inovulant of corresponding proportion, waiting for pouring.
To casting said pressure-containing member carries out melting with metal material step;
Gained molten metal after the melting is carried out the step that stokehold nodularization, stokehold are bred;
Breed the molten metal step of behind molding and core making, pouring into a mould in the gained sand mold of back gained to stokehold nodularization, stokehold, the cast step comprises the step of current-following inoculation and instant inoculation;
Adopt special-purpose magnesium iron bag, press the bag method to be: add nodulizer, inovulant earlier, add special-purpose magnesium iron bits again and cover tamping; Adopt pit to pour method; Go out 60% molten iron earlier, go out 40% molten iron after question response finishes again and carry out the stokehold and breed, beat dirty, pouring temperature and be controlled between 1480 ~ 1500 ℃; Do during cast with stream, instant inoculation, the bleed of igniting.
Pressure-containing member after the cast is carried out the step of banking fire shake out.
Pressure-containing member banking fire below 3 tons was unpacked in 48 hours, and 3.5 ~ 7 tons pressure-containing member banking fire was unpacked in 72 hours, and the pressure-containing member banking fire more than 7 tons was unpacked in 96 hours.
The gained pressure-containing member is carried out the step of desanding, cleaning, polishing and ball blast;
Saidly use the metal material in the step of metal material melting to be high-purity pig iron, steel scrap and electrolytic nickel to casting said pressure-containing member; Weight portion is respectively 45~50 parts, 20~25 parts and 30~33 parts; Content≤0.025% (percentage by weight) of content≤0.03% (percentage by weight) of content≤0.1% (percentage by weight) of content≤1.2% (percentage by weight) of the content of C>=4.35% (percentage by weight), Si, Mn, P, S in the said high-purity pig iron; The content of the content of C≤0.040% (percentage by weight), Si is that the content of (0.034 ~ 0.036) % (percentage by weight), Mn is content≤0.02% (percentage by weight) of (0.11 ~ 0.13) % (percentage by weight), P, content≤0.01% (percentage by weight) of S in the said steel scrap; The content of nickel and cobalt>=99.96% (percentage by weight) in the said electrolytic nickel, the wherein content of cobalt≤0.02% (percentage by weight); The equipment that said melting is adopted is medium-frequency induction furnace; Fusion process comprises that elder generation is added to the medium-frequency induction furnace furnace bottom to the electrolytic nickel of 30~33 weight portions; Put into the high-purity pig iron energising melting of 45~50 weight portions again; Drop into 20~25 weight portion steel scraps when furnace temperature reaches 1300 ~ 1350 ℃, when being warming up to 1550 ~ 1570 ℃, leaving standstill and purified the gained molten metal in 10 minutes; The nodulizer of selecting for use in the step that breed the nodularization of said stokehold, stokehold is the nickel magnesium alloy nodulizer; The granularity of nickel magnesium alloy nodulizer is 5 ~ 25; Bag end addition is 0.9 ~ 1.1 weight portion; The inovulant of selecting for use is a silicon strontium inovulant, and the granularity of silicon strontium inovulant is 10 ~ 20, and bag end addition is 0.35 ~ 0.5 weight portion; The inovulant of selecting for use in current-following inoculation in the said cast step and the instant inoculation step also is silicon strontium inovulant, and current-following inoculation silicon strontium innoculant adding quantity is 0.45 ~ 0.6 weight portion, and instant inoculation silicon strontium innoculant adding quantity is 0.12 ~ 0.2 weight portion.
The nickelic magnesium iron pressure-containing member that is used for-76 ℃~-121 ℃ of cryogenic gas compressor mechanicals that adopts casting method of the present invention casting is through detecting, superior performance, and each item leading indicator is following:
Figure 2012103437660100002DEST_PATH_IMAGE004

Claims (1)

1. casting method that is used for the nickelic magnesium iron pressure-containing member of-76 ℃~-121 ℃ of cryogenic gas compressor mechanicals may further comprise the steps:
With the shape of said pressure-containing member, the step of the corresponding molding and core making of structure;
To casting said pressure-containing member carries out melting with metal material step;
Gained molten metal after the melting is carried out the step that stokehold nodularization, stokehold are bred;
Breed the molten metal step of behind molding and core making, pouring into a mould in the gained sand mold of back gained to stokehold nodularization, stokehold, the cast step comprises the step of current-following inoculation and instant inoculation;
Pressure-containing member after the cast is carried out the step of banking fire shake out;
The gained pressure-containing member is carried out the step of desanding, cleaning, polishing and ball blast;
It is characterized in that: saidly use the metal material in the step of metal material melting to be high-purity pig iron, steel scrap and electrolytic nickel casting said pressure-containing member; Weight portion is respectively 45~50 parts, 20~25 parts and 30~33 parts; Content≤0.025% (percentage by weight) of content≤0.03% (percentage by weight) of content≤0.1% (percentage by weight) of content≤1.2% (percentage by weight) of the content of C>=4.35% (percentage by weight), Si, Mn, P, S in the said high-purity pig iron; The content of the content of C≤0.040% (percentage by weight), Si is that the content of (0.034 ~ 0.036) % (percentage by weight), Mn is content≤0.02% (percentage by weight) of (0.11 ~ 0.13) % (percentage by weight), P, content≤0.01% (percentage by weight) of S in the said steel scrap; The content of nickel and cobalt>=99.96% (percentage by weight) in the said electrolytic nickel, the wherein content of cobalt≤0.02% (percentage by weight); The equipment that said melting is adopted is medium-frequency induction furnace; Fusion process comprises that elder generation is added to the medium-frequency induction furnace furnace bottom to the electrolytic nickel of 30~33 weight portions; Put into the high-purity pig iron energising melting of 45~50 weight portions again; Drop into 20~25 weight portion steel scraps when furnace temperature reaches 1300 ~ 1350 ℃, when being warming up to 1550 ~ 1570 ℃, leaving standstill and purified the gained molten metal in 10 minutes; The nodulizer of selecting for use in the step that breed the nodularization of said stokehold, stokehold is the nickel magnesium alloy nodulizer; The granularity of nickel magnesium alloy nodulizer is 5 ~ 25; Bag end addition is 0.9 ~ 1.1 weight portion; The inovulant of selecting for use is a silicon strontium inovulant, and the granularity of silicon strontium inovulant is 10 ~ 20, and bag end addition is 0.35 ~ 0.5 weight portion; The inovulant of selecting for use in current-following inoculation in the said cast step and the instant inoculation step also is silicon strontium inovulant, and current-following inoculation silicon strontium innoculant adding quantity is 0.45 ~ 0.6 weight portion, and instant inoculation silicon strontium innoculant adding quantity is 0.12 ~ 0.2 weight portion.
CN2012103437660A 2012-09-17 2012-09-17 Forging method of high nickel ductile iron pressure-containing member for low temperature gas compression machinery used at temperature of minus 76 DEG C to minus 121 DEG C Pending CN102836968A (en)

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CN103266262A (en) * 2013-04-25 2013-08-28 中国石油天然气股份有限公司 High-nickel ductile iron used at low-temperature and casting method thereof
CN103589938A (en) * 2013-10-29 2014-02-19 吴江市液铸液压件铸造有限公司 Smelting method of alloy for pressurizer shell
CN103725949A (en) * 2013-07-04 2014-04-16 陕西柴油机重工有限公司 Method for producing high-Ni austenite ductile iron exhaust pipe

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103266262A (en) * 2013-04-25 2013-08-28 中国石油天然气股份有限公司 High-nickel ductile iron used at low-temperature and casting method thereof
CN103266262B (en) * 2013-04-25 2015-02-18 中国石油天然气股份有限公司 High-nickel ductile iron used at low-temperature and casting method thereof
CN103725949A (en) * 2013-07-04 2014-04-16 陕西柴油机重工有限公司 Method for producing high-Ni austenite ductile iron exhaust pipe
CN103725949B (en) * 2013-07-04 2016-01-06 陕西柴油机重工有限公司 The production method of high Ni austenite spheroidal iron vapor pipe
CN103589938A (en) * 2013-10-29 2014-02-19 吴江市液铸液压件铸造有限公司 Smelting method of alloy for pressurizer shell

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Application publication date: 20121226