CN102835411B - Ultralow-volume liquor containing amicarbazone - Google Patents
Ultralow-volume liquor containing amicarbazone Download PDFInfo
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Abstract
The invention relates to an ultralow-volume liquor containing amicarbazone. The ultralow-volume liquor consists of an active ingredient, an auxiliary agent and a dissolvent, wherein the active ingredient is amicarbazone, or complex combination of amicarbazone and an active ingredient II, and the active ingredient II is any one of nicosulfuron, metolachlor and acetochlor. An airplane, a tractor or an ultralow-volume atomizing machine is adopted for carrying out ultralow-volume atomization for preventing and controlling weeds in corn fields and sugarcane fields so as to solve the problems that in the existing weeding work in corn fields and sugarcane fields, the work of water fetching, dispensing and water loading are heavy and much physical labor is required to be wasted; and the ultralow-volume liquor containing amicarbazone has the advantages of simple production technology, high work efficiency and low weeding cost, and medicines are saved.
Description
Technical field
The present invention relates to pesticidal preparations field, specifically a kind of ultra low volume liquids containing amicarbazone.
Background technology
At present, China lacks outstanding sugarcane field weed killer herbicide, and corn field is used after atrazine due to a large amount of, some areas underground water and surface water are polluted, Weed Resistance increases fast, and the lasting period of atrazine in soil is longer, the increase of dosage makes its residual quantity in soil easily injure late stubble sensitive crop.Amicarbazone is as a kind of outstanding inhibitor of photosynthesis, its production and application can produce good economic benefit and social benefit, reasonably the composite active component that makes produces synergistic effect simultaneously, can improve preventive effect, reduce pesticide dosage, cost-saving, delay the drug-fast generation of weeds, and then can alleviate and even avoid the pollution of agricultural chemicals to food and environment.
Amicarbazone, 4-amido-N-tertiary butyl-4,5-dihydro-3-isopropyl-5-oxygen-1-H-1,2,4-triazole-acid amides, belongs to triazolineone weed killer herbicide, mainly by root system of plant and Foliage Absorption, suppresses the photosynthesis of noxious plant, progressively make noxious plant chlorisis, stop growing, organize withered and yellow until finally dead, can effectively prevent and kill off many annual gramineous weeds on the main annual broadleaf weed of corn field and sugarcane field and sugarcane.Amicarbazone has the property of tagging and longer lasting period, can before plantation or after bud, use by soil.When the sugarcane, also can bud after dispenser.
Isopropyl methoxalamine mainly absorbs by young shoot, wherein monocotyledon weed is mainly that bud scale absorbs, and dicotyledon absorbs by young shoot and young root, upwards conduction, suppress the growth of young shoot and root, can make susceptible weeds before germination is unearthed afterwards or just unearthedly be poisoned to death.
Acetochlor is used in the dry crops such as corn, sugarcane, has good sealing herbicide effect, can effectively prevent and kill off annual gramineous weed.
Nicosulfuron can be absorbed rapidly by leaf and root, stops the synthetic of branched-chain amino acid, and then plays herbicide effect, for preventing and kill off the annual single, double leaf weeds of corn field by acetolactate synthestase.
Existing preparation containing amicarbazone is water dispersible granules, water dispersible granules complex process equipment, processing cost is high, use needs secondary dilution, water intaking, make up a prescription and negative water operation heavy, in the Hills of drought, lack of labor and water intaking difficulty, be more difficult to promote, and preventive effect is slightly inferior compared with liquid preparation.
Containing the ultra low volume liquids of amicarbazone and amicarbazone and the composite ultra low volume liquids of other compositions, have no report at home and abroad.
Summary of the invention
The object of this invention is to provide a kind of ultra low volume liquids containing amicarbazone, solve the water intaking that exists in current corn field and sugarcane field weeding operation, make up a prescription and negative water operation heavy, need expend a large amount of blue-collar problems, improve weeding preventive effect, reduce weed killer herbicide consumption, save dispenser cost.
The present invention realizes the technical scheme that above-mentioned purpose takes: a kind of ultra low volume liquids containing amicarbazone, by active component, auxiliary agent and solvent composition; Wherein, described active component is amicarbazone, or the compounded combination of amicarbazone and active component II; Active component II is any one in nicosulfuron, isopropyl methoxalamine or Acetochlor.
Described take the ultra low volume liquids that amicarbazone is active component, the mass percent of amicarbazone is 1%～15%, and the mass percent of auxiliary agent is 4%～12%, and solvent supplies 100%; Take the composite ultra low volume liquids as active component of amicarbazone and active component II, the mass percent of amicarbazone is 1%～10%, and the mass percent of active component II is 1%～10%, and the mass percent of auxiliary agent is 4%～12%, and solvent supplies 100%.
Described auxiliary agent is one or more the combination in polyoxyethylene nonylphenol ether, phenethyl phenol polyethenoxy ether, aliphatic alcohol polyoxyvinethene phosphate, phenethyl phenol polyethenoxy ether phosphate, castor oil polyoxyethylene ether or calcium dodecyl benzene sulfonate.
Described solvent is one or more the combination in aromatic hydrocarbon solvent, plant oil solvent or polar solvent; Aromatic hydrocarbon solvent is durene, methyl naphthalene or two wires oil; Plant oil solvent is methyl oleate or ethyl oleate; Polar solvent is 1-METHYLPYRROLIDONE or DMF.
The preparation method of the ultra low volume liquids containing amicarbazone of the present invention is, in the reaction vessel stirring at band, first with solvent by after active component stirring and dissolving, then add auxiliary agent, stir, obtain the ultra low volume liquids containing amicarbazone; Technological parameter is: it is 60～150 revs/min that mixing speed is controlled, and mixing time is 15～60 minutes, and temperature is normal temperature, and pressure is normal pressure.
Ultra low volume liquids containing amicarbazone of the present invention, application process is for adopting aircraft, tractor or ultra-low-volume sprayer to carry out ultra low volume spraying.
Ultra low volume liquids containing amicarbazone of the present invention, for control of maize field and sugarcane field weeds, comprises Tong fiber crops, lamb's-quarters, wild amaranth, Binzhou Siberian cocklebur, wartwort, sweet potato genus, car forearm shape grass and tribulus terrestris grass.
Utilize the ultra low volume liquids containing amicarbazone of the present invention to carry out ultra low volume spraying weeding operation, possess following beneficial effect:
(1) do not need to be watered, saved water intaking, made up a prescription and the heavy physical labor such as negative water operation, at the hilly and mountainous land of drought, manpower shortage and water intaking difficulty, use more convenient.
(2) save medicament, compare with general conventional spray method, can save medicament more than 30%.
(3) work efficiency is high, and the spraying of ultra low volume machine improves work efficiency more than 20 times than conventional compression spraying machine, and adopt aircraft to carry out ultra low volume spraying, than conventional compression spraying machine, improves work efficiency more than 100 times.
(4) weeding expense is low, utilizes the present invention to carry out ultra low volume spraying weeding, save that medicament, work efficiency are high, production and easy-to-use, so weeding expense is lower owing to having advantages of.
Embodiment
Degree of the present invention, outside Special Statement, is mass percentage content.
EXAMPLE l
1% amicarbazone ultra low volume liquids
Formula: amicarbazone 1kg, DMF 10kg, durene 8kg, calcium dodecyl benzene sulfonate 3kg, castor oil polyoxyethylene ether 3kg, two wires oil complements to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 150 revs/min, then adds auxiliary agent, continues to stir after 15 minutes to obtain 1% amicarbazone ultra low volume liquids.
Embodiment 2
3% amicarbazone ultra low volume liquids
Formula: amicarbazone 3kg, aliphatic alcohol polyoxyvinethene phosphate 2kg, phenethyl phenol polyethenoxy ether phosphate 2kg, 1-METHYLPYRROLIDONE 4kg, DMF 5kg, methyl naphthalene complements to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 80 revs/min, then adds auxiliary agent, continues to stir after 40 minutes to obtain 3% amicarbazone ultra low volume liquids.
Embodiment 3
5% amicarbazone ultra low volume liquids
Formula: amicarbazone 5kg, DMF 10kg, 1-METHYLPYRROLIDONE 10kg, calcium dodecyl benzene sulfonate 2.5kg, aliphatic alcohol polyoxyvinethene phosphate 2kg, two wires oil subsidy is to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 60 revs/min, then adds auxiliary agent, continues to stir after 60 minutes to obtain 5% amicarbazone ultra low volume liquids.
Embodiment 4
10% amicarbazone ultra low volume liquids
Formula: amicarbazone 10kg, DMF 15kg, 1-METHYLPYRROLIDONE 10kg, calcium dodecyl benzene sulfonate 3kg, castor oil polyoxyethylene ether 4kg, methyl oleate is mended to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 110 revs/min, then adds auxiliary agent, continues to stir after 30 minutes to obtain 10% amicarbazone ultra low volume liquids.
Embodiment 5
15% amicarbazone ultra low volume liquids
Formula: amicarbazone 15kg, polyoxyethylene nonylphenol ether 3kg, phenethyl phenol polyethenoxy ether phosphate 5kg, 1-METHYLPYRROLIDONE 8kg, DMF 3kg, two wires oil complements to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 100 revs/min, then adds auxiliary agent, continues to stir after 55 minutes to obtain 15% amicarbazone ultra low volume liquids.
Embodiment 6
2% amicarbazone nicosulfuron ultra low volume liquids
Formula: amicarbazone 1kg, nicosulfuron 1kg, calcium dodecyl benzene sulfonate 12kg, durene 3kg, DMF 7kg, methyl naphthalene complements to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 90 revs/min, then adds auxiliary agent, continues to stir after 50 minutes to obtain 2% amicarbazone nicosulfuron ultra low volume liquids.
Embodiment 7
4% amicarbazone nicosulfuron ultra low volume liquids
Formula: amicarbazone 1kg, nicosulfuron 3kg, phenethyl phenol polyethenoxy ether 1kg, aliphatic alcohol polyoxyvinethene phosphate 5kg, DMF 7kg, methyl naphthalene 10kg, methyl oleate complements to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 70 revs/min, then adds auxiliary agent, continues to stir after 50 minutes to obtain 4% amicarbazone nicosulfuron ultra low volume liquids.
Embodiment 8
6% amicarbazone nicosulfuron ultra low volume liquids
Formula: amicarbazone 1kg, nicosulfuron 5kg, castor oil polyoxyethylene ether 9kg, 1-METHYLPYRROLIDONE 9kg, ethyl oleate complements to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 105 revs/min, then adds auxiliary agent, continues to stir after 60 minutes to obtain 6% amicarbazone nicosulfuron ultra low volume liquids.
Embodiment 9
11% amicarbazone nicosulfuron ultra low volume liquids
Formula: amicarbazone 1kg, nicosulfuron 10kg, phenethyl phenol polyethenoxy ether 3kg, castor oil polyoxyethylene ether 4kg, DMF 20kg, ethyl oleate complements to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 100 revs/min, then adds auxiliary agent, continues to stir after 60 minutes to obtain 11% amicarbazone nicosulfuron ultra low volume liquids.
Embodiment 10
15% amicarbazone nicosulfuron ultra low volume liquids
Formula: amicarbazone 10kg, nicosulfuron 5kg, aliphatic alcohol polyoxyvinethene phosphate 3kg, calcium dodecyl benzene sulfonate 7kg, durene 10kg, two wires oil complements to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 120 revs/min, then adds auxiliary agent, continues to stir after 40 minutes to obtain 15% amicarbazone nicosulfuron ultra low volume liquids.
Embodiment 11
5% amicarbazone nicosulfuron ultra low volume liquids
Formula: amicarbazone 4kg, nicosulfuron 1kg, DMF 20kg, 1-METHYLPYRROLIDONE 10kg, calcium dodecyl benzene sulfonate 3kg, castor oil polyoxyethylene ether 4kg, two wires oil subsidy is to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 120 revs/min, then adds auxiliary agent, continues to stir after 35 minutes to obtain 5% amicarbazone nicosulfuron ultra low volume liquids.
Embodiment 12
11% amicarbazone nicosulfuron ultra low volume liquids
Formula: amicarbazone 10kg, nicosulfuron 1kg, phenethyl phenol polyethenoxy ether phosphate 1kg, castor oil polyoxyethylene ether 8kg, methyl oleate 12kg, ethyl oleate complements to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 120 revs/min, then adds auxiliary agent, continues to stir after 35 minutes to obtain 11% amicarbazone nicosulfuron ultra low volume liquids.
Embodiment 13
2% amicarbazone Acetochlor ultra low volume liquids
Formula: amicarbazone 1kg, Acetochlor 1kg, polyoxyethylene nonylphenol ether 2kg, phenethyl phenol polyethenoxy ether 10kg, methyl oleate is mended to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 90 revs/min, then adds auxiliary agent, continues to stir after 45 minutes to obtain 2% amicarbazone Acetochlor ultra low volume liquids.
Embodiment 14
6% amicarbazone Acetochlor ultra low volume liquids
Formula: amicarbazone 1kg, Acetochlor 5kg, polyoxyethylene nonylphenol ether 1kg, castor oil polyoxyethylene ether 9kg, durene 3kg, two wires oil 30kg, methyl oleate is mended to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 100 revs/min, then adds auxiliary agent, continues to stir after 60 minutes to obtain 6% amicarbazone Acetochlor ultra low volume liquids.
Embodiment 15
11% amicarbazone Acetochlor ultra low volume liquids
Formula: amicarbazone 1kg, Acetochlor 10kg, phenethyl phenol polyethenoxy ether 2kg, phenethyl phenol polyethenoxy ether phosphate 3kg, DMF 18kg, 1-METHYLPYRROLIDONE 11kg, ethyl oleate is mended to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 60 revs/min, then adds auxiliary agent, continues to stir after 60 minutes to obtain 11% amicarbazone Acetochlor ultra low volume liquids.
Embodiment 16
12% amicarbazone Acetochlor ultra low volume liquids
Formula: amicarbazone 10kg, Acetochlor 2kg, polyoxyethylene nonylphenol ether 1kg, aliphatic alcohol polyoxyvinethene phosphate 3kg, DMF 30kg, methyl oleate is mended to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 80 revs/min, then adds auxiliary agent, continues to stir after 30 minutes to obtain 12% amicarbazone Acetochlor ultra low volume liquids.
Embodiment 17
10% amicarbazone Acetochlor ultra low volume liquids
Formula: amicarbazone 5kg, Acetochlor 5kg, DMF 15kg, 1-METHYLPYRROLIDONE 8kg, calcium dodecyl benzene sulfonate 3kg, polyoxyethylene nonylphenol ether 3kg, ethyl oleate is mended to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 90 revs/min, then adds auxiliary agent, continues to stir after 45 minutes to obtain 10% amicarbazone Acetochlor ultra low volume liquids.
Embodiment 18
15% amicarbazone Acetochlor ultra low volume liquids
Formula: amicarbazone 5kg, Acetochlor 10kg, DMF 15kg, 1-METHYLPYRROLIDONE 8kg, methyl naphthalene 5kg, calcium dodecyl benzene sulfonate 2.5kg, polyoxyethylene nonylphenol ether 4kg, two wires oil subsidy is to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 100 revs/min, then adds auxiliary agent, continues to stir after 50 minutes to obtain 15% amicarbazone Acetochlor ultra low volume liquids.
Embodiment 19
2% amicarbazone isopropyl methoxalamine ultra low volume liquids
Formula: amicarbazone 1kg, isopropyl methoxalamine 1kg, aliphatic alcohol polyoxyvinethene phosphate 3kg, calcium dodecyl benzene sulfonate 8kg, methyl naphthalene 10kg, durene is mended to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 90 revs/min, then adds auxiliary agent, continues to stir after 40 minutes to obtain 2% amicarbazone isopropyl methoxalamine ultra low volume liquids.
Embodiment 20
11% amicarbazone isopropyl methoxalamine ultra low volume liquids
Formula: amicarbazone 1kg, isopropyl methoxalamine 10kg, phenethyl phenol polyethenoxy ether phosphate 2kg, calcium dodecyl benzene sulfonate 9kg, durene 10kg, methyl oleate is mended to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 110 revs/min, then adds auxiliary agent, continues to stir after 50 minutes to obtain 11% amicarbazone isopropyl methoxalamine ultra low volume liquids.
Embodiment 21
15% amicarbazone isopropyl methoxalamine ultra low volume liquids
Formula: amicarbazone 5kg, isopropyl methoxalamine 10kg, DMF 15kg, 1-METHYLPYRROLIDONE 8kg, calcium dodecyl benzene sulfonate 3kg, phenethyl phenol polyethenoxy ether 3kg, two wires oil subsidy is to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 90 revs/min, then adds auxiliary agent, continues to stir after 40 minutes to obtain 15% amicarbazone isopropyl methoxalamine ultra low volume liquids.
Embodiment 22
7% amicarbazone isopropyl methoxalamine ultra low volume liquids
Formula: amicarbazone 1kg, isopropyl methoxalamine 6kg, phenethyl phenol polyethenoxy ether phosphate 1kg, polyoxyethylene nonylphenol ether 6kg, 1-METHYLPYRROLIDONE 3kg, two wires oil 30kg, ethyl oleate is mended to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 110 revs/min, then adds auxiliary agent, continues to stir after 50 minutes to obtain 7% amicarbazone isopropyl methoxalamine ultra low volume liquids.
Embodiment 23
12% amicarbazone isopropyl methoxalamine ultra low volume liquids
Formula: amicarbazone 4kg, isopropyl methoxalamine 8kg, phenethyl phenol polyethenoxy ether 2kg, castor oil polyoxyethylene ether 8kg, 1-METHYLPYRROLIDONE 3kg, durene 30kg, methyl naphthalene is mended to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 100 revs/min, then adds auxiliary agent, continues to stir after 50 minutes to obtain 12% amicarbazone isopropyl methoxalamine ultra low volume liquids.
Embodiment 24
11% amicarbazone isopropyl methoxalamine ultra low volume liquids
Formula: amicarbazone 10kg, isopropyl methoxalamine 1kg, polyoxyethylene nonylphenol ether 10kg, aliphatic alcohol polyoxyvinethene phosphate 1kg, DMF 3kg, two wires oil subsidy is to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 110 revs/min, then adds auxiliary agent, continues to stir after 30 minutes to obtain 11% amicarbazone isopropyl methoxalamine ultra low volume liquids.
Embodiment 25
20% amicarbazone isopropyl methoxalamine ultra low volume liquids
Formula: amicarbazone 10kg, isopropyl methoxalamine 10kg, phenethyl phenol polyethenoxy ether phosphate 3kg, aliphatic alcohol polyoxyvinethene phosphate 7kg, durene 5kg, methyl naphthalene 5kg, ethyl oleate is mended to 100kg.
Above-mentioned active component is dissolved by stirring solvent, and mixing speed is 120 revs/min, then adds auxiliary agent, continues to stir after 20 minutes to obtain 20% amicarbazone isopropyl methoxalamine ultra low volume liquids.
Application Example 1
Reagent agent: embodiment 1-12 products obtained therefrom.
Contrast medicament: 70% amicarbazone water dispersible granules, 70% water dispersible granule of nicosulfuron.
Controlling object: sugarcane field broad leaved weed and grassy weed.
Test method: on cost budget arranges a mu consumption, dispenser after weeds are unearthed 15 days, embodiment 1-12 products obtained therefrom is sprayed with ultra-low-volume sprayer, contrast medicament is sprayed with conventional compression sprayer, 30d investigation result after medicine, and add up preventive effect, final result is as shown in the table:
As can be known from the above table, embodiment 1-12 products obtained therefrom is all high than contrast medicament to the preventive effect of sugarcane broad leaved weed and grassy weed.
Application Example 2
Reagent agent: embodiment 13-25 products obtained therefrom.
Contrast medicament: 70% amicarbazone water dispersible granules, 70% acetochlor ec, 70% isopropyl methoxalamine missible oil.
Controlling object: corn field broad leaved weed and grassy weed.
Test method: on cost budget arranges a mu consumption, dispenser before weeds are unearthed, embodiment 13-25 products obtained therefrom is sprayed with ultra-low-volume sprayer, contrast medicament is sprayed with conventional compression sprayer, 30d investigation result after medicine, and add up preventive effect, final result is as shown in the table:
As can be known from the above table, embodiment 13-25 products obtained therefrom is all high than contrast medicament to the sealing preventive effect of corn broad leaved weed and grassy weed.
Claims (3)
1. contain a ultra low volume liquids for amicarbazone, by active component, auxiliary agent and solvent composition; It is characterized in that, described active component is the compounded combination of amicarbazone and active component II; Active component II is nicosulfuron; The mass percent of amicarbazone is 1%～10%, and the mass percent of active component II is 1%～10%, and the mass percent of auxiliary agent is 4%～12%, and solvent supplies 100%.
2. the ultra low volume liquids containing amicarbazone according to claim 1, it is characterized in that, described auxiliary agent is one or more the combination in polyoxyethylene nonylphenol ether, phenethyl phenol polyethenoxy ether, aliphatic alcohol polyoxyvinethene phosphate, phenethyl phenol polyethenoxy ether phosphate, castor oil polyoxyethylene ether or calcium dodecyl benzene sulfonate.
3. the ultra low volume liquids containing amicarbazone according to claim 2, is characterized in that, described solvent is one or more the combination in aromatic hydrocarbon solvent, plant oil solvent or polar solvent; Aromatic hydrocarbon solvent is durene, methyl naphthalene or two wires oil; Plant oil solvent is methyl oleate or ethyl oleate; Polar solvent is 1-METHYLPYRROLIDONE or DMF.
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Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103651480A (en) * | 2013-12-18 | 2014-03-26 | 山东滨农科技有限公司 | Weeding composition containing trifloxysulfuron and amicarbazone |
| CN104585203A (en) * | 2014-12-16 | 2015-05-06 | 广东中迅农科股份有限公司 | Post-emergence herbicide composition used in corn fields |
| CN104542662A (en) * | 2014-12-16 | 2015-04-29 | 广东中迅农科股份有限公司 | Weeding composition containing amicarbazone, fluroxypyr and nicosulfuron |
| CN104621136B (en) * | 2015-02-11 | 2017-09-29 | 四川国光农化股份有限公司 | Application of the triazolinones on plant bud picking control shoot, composition |
| CN106561696A (en) * | 2016-11-14 | 2017-04-19 | 安徽众邦生物工程有限公司 | Corn field three-element weeding composition containing amicarbazone |
| CN107136114A (en) * | 2017-06-23 | 2017-09-08 | 浙江天丰生物科学有限公司 | A kind of synergistic herbicidal compositions |
| CN110432284A (en) * | 2019-09-05 | 2019-11-12 | 安徽华星化工有限公司 | It is a kind of containing nicosulfuron, the mixed herbicide of amicarbazone and its application |
| CN115399327A (en) * | 2022-09-23 | 2022-11-29 | 山东绿邦作物科学股份有限公司 | Composite weeding composition of tembotrione and herbicide for corn field |
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| CN1425297A (en) * | 2001-12-12 | 2003-06-25 | 马韵升 | Nicosulfuron herbicide composition |
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| JP2012529489A (en) * | 2009-06-09 | 2012-11-22 | アリスタ ライフサイエンス株式会社 | Combination and method of use of herbicides based on carbamoyltriazolinone |
| AR085074A1 (en) * | 2011-01-20 | 2013-09-11 | Ishihara Sangyo Kaisha | HERBICIDE COMPOSITION |
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| CN1425297A (en) * | 2001-12-12 | 2003-06-25 | 马韵升 | Nicosulfuron herbicide composition |
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