CN102826722A - Treatment method for wastewater generated by producing cephalosporin medicines - Google Patents
Treatment method for wastewater generated by producing cephalosporin medicines Download PDFInfo
- Publication number
- CN102826722A CN102826722A CN2012103493603A CN201210349360A CN102826722A CN 102826722 A CN102826722 A CN 102826722A CN 2012103493603 A CN2012103493603 A CN 2012103493603A CN 201210349360 A CN201210349360 A CN 201210349360A CN 102826722 A CN102826722 A CN 102826722A
- Authority
- CN
- China
- Prior art keywords
- waste water
- hydrolysis
- wastewater
- water
- producing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002351 wastewater Substances 0.000 title claims abstract description 47
- 238000000034 method Methods 0.000 title claims abstract description 38
- 229930186147 Cephalosporin Natural products 0.000 title claims abstract description 22
- 229940124587 cephalosporin Drugs 0.000 title claims abstract description 22
- 150000001780 cephalosporins Chemical class 0.000 title claims abstract description 22
- 239000003814 drug Substances 0.000 title claims abstract description 15
- 229940079593 drug Drugs 0.000 title abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 71
- 239000012528 membrane Substances 0.000 claims abstract description 30
- 230000020477 pH reduction Effects 0.000 claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 claims abstract description 15
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 10
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 8
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 7
- 238000000108 ultra-filtration Methods 0.000 claims abstract description 5
- 230000007062 hydrolysis Effects 0.000 claims description 33
- 238000006460 hydrolysis reaction Methods 0.000 claims description 33
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
- 230000000694 effects Effects 0.000 claims description 9
- 238000005286 illumination Methods 0.000 claims description 9
- 229910052742 iron Inorganic materials 0.000 claims description 8
- 238000005374 membrane filtration Methods 0.000 claims description 6
- 239000010802 sludge Substances 0.000 claims description 6
- 230000004907 flux Effects 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 4
- 238000005189 flocculation Methods 0.000 claims description 3
- 230000016615 flocculation Effects 0.000 claims description 3
- 239000013049 sediment Substances 0.000 claims description 3
- 238000004065 wastewater treatment Methods 0.000 claims description 3
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 2
- 238000007664 blowing Methods 0.000 claims description 2
- 239000003610 charcoal Substances 0.000 claims description 2
- 239000000084 colloidal system Substances 0.000 claims description 2
- 229910001447 ferric ion Inorganic materials 0.000 claims description 2
- 238000006479 redox reaction Methods 0.000 claims description 2
- 238000005755 formation reaction Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 14
- 238000005516 engineering process Methods 0.000 abstract description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 4
- 239000001301 oxygen Substances 0.000 abstract description 4
- 229910052760 oxygen Inorganic materials 0.000 abstract description 4
- 230000003301 hydrolyzing effect Effects 0.000 abstract 2
- 238000005273 aeration Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 229940088710 antibiotic agent Drugs 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 2
- 238000002798 spectrophotometry method Methods 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 239000012028 Fenton's reagent Substances 0.000 description 1
- 241000228143 Penicillium Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004159 Potassium persulphate Substances 0.000 description 1
- WYWFMUBFNXLFJK-UHFFFAOYSA-N [Mo].[Sb] Chemical compound [Mo].[Sb] WYWFMUBFNXLFJK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000000843 anti-fungal effect Effects 0.000 description 1
- 230000002924 anti-infective effect Effects 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
The invention provides a treatment method for wastewater generated by producing cephalosporin medicines. The method comprises three treatment steps of as anoxic hydrolytic acidification, electrolysis and membrane bioreactor treatment. Specifically, the method comprises the following steps of: (1) firstly carrying out biological hydrolytic acidification on the wastewater generated by producing cephalosporin synthesis pharmacy in an anaerobic pond, so that the biodegradability of the wastewater can be improved; (2) electrolyzing the discharged water of the step (1) in an electrolytic tank, so that COD (chemical oxygen demand) can be further removed, and the biodegradability of the wastewater can be improved; and (3) enabling the discharged out of the step (2) to flow into the membrane bioreactor for the final aerobiotic biotreatment, wherein the treated wastewater is pumped by a water outlet pump through an ultrafiltration membrane in the membrane bioreactor, and is discharged to an external discharge pipeline or recycled in a production technology after reaching the standard.
Description
Technical field
The present invention relates to a kind of wastewater produced treatment process of medicine of producing, relate to a kind of wastewater produced treatment process of cephalosporins medicine of producing especially.
Background technology
Production of antibiotics waste water is one type of high density, contain the organic waste water of multiple hardly degraded organic substance and bio-toxicity material.States such as America and Europe just handled its waste water when 20th century, produced penicillium mould the forties, but failed good terms of settlement always.Rise the seventies in 20th century, and developed country shifts large conventional medicine production to developing country, so China has begun the research and the application of relevant production of antibiotics wastewater processing technology.Compare with other microbiotic, cephalosporin analog antibiotic has characteristics such as has a broad antifungal spectrum, anti-microbial activity is strong, curative effect is high, spinoff is little, in the classes of anti-infective drug market, occupies critical role.The production of cephalosporin analog antibiotic is to adopt microbe fermentation method to obtain cynnematin, adopts chemosynthesis to carry out the production of midbody, bulk drug again, and consequent synthetic wastewater has characteristics such as COD height, complicated component, biodegradability difference.
Can reduce following several kinds in the technology of administering the production waste water that cephalosporins medicine produced at present:
(1) the materialization treatment technology comprises flocculation sediment, electrolysis, and the Fenton reagent oxidation is handled, membrane separation technique etc.(2) biologic treating technique comprises aerobic treatment method (traditional activated sludge process), anaerobic treatment method, anaerobic-aerobic combination process, acidication-aerobic combination process etc.In addition; Membrane bioreactor (MBR) can be kept microorganism concn because it divides reason effective, and is strong to influent load flexibility; Excess sludge production is few; Characteristics such as floor space is little receive publicity in water treatment field more and more, in the treatment process to cephalosporin waste water, the instance that uses the MBR technology are arranged also.
In Chinese patent publication number CN101434437, disclose the wastewater produced treatment process of a kind of cephalosporin synthesis pharmaceutical, the present invention makes on its basis.
Summary of the invention
In order to reach better water treatment effect, we through test of many times, find that therein specific link carries out the effect that the illumination of specific wavelength can significantly improve water treatment on the basis of the cephalosporin waste water treatment process of routine.Concrete technology is following:
By the anaerobic hydrolysis acidifying, these three treatment steps of electrolysis and Membrane Bioreactor for Wastewater Treatment constitute.
(1) waste water that produces in the cephalosporin synthesis pharmaceutical production carries out earlier the biological hydrolysis acidifying in anoxic pond, improve the biodegradability of waste water;
(2) electrolysis is carried out in the water outlet of step (1) in electrolyzer, further removes COD, improves the biodegradability of waste water;
(3) water outlet of step (2) flows into and to carry out final aerobe in the membrane bioreactor and handle, and the waste water after the processing pumps out by going out water pump through the ultra-filtration membrane in the membrane bioreactor, and qualified discharge is to outer discharge pipe or be back to use in the production technique.
Specifically, the biological hydrolysis acidifying of above-mentioned steps (1) comprises hydrolysis stage and souring stage, and these two stages are accomplished anaerobic digestion by acidification bacteria.The acidication bacterium utilizes water power to leave hydrogen ion and hydroxide radical is opened the carbon bond in the organic molecule in this course, can long-chain be hydrolyzed to short chain, and side chain is hydrolyzed to straight chain, opens ring texture, thereby is that the processing of ensuing aerobe is ready.
Preferably, at hydrolysis and souring stage, hydrolysis acidification pool is carried out omnidistance illumination.
More preferably, at hydrolysis and souring stage, hydrolysis acidification pool is carried out omnidistance infrared light irradiation.
Most preferably, at hydrolysis and souring stage, hydrolysis acidification pool is carried out the infrared light irradiation of omnidistance light wave scope at 1100～2500nm.
Electrolysis step in the above-mentioned steps (2) is taked iron charcoal internal electrolysis; In waste water, drop into iron filings and air-blowing in waste water simultaneously; Can in waste water, form countless small galvanic cells like this; Redox reaction taking place, produce divalence and ferric ion simultaneously, produces the flocculation sediment effect thereby in waste water, form colloid.After these deposition removals, effluent can get into step (3) and handle.
Membrane bioreactor in the above-mentioned steps (3) is made up of aeration zone and membrane filtration district; The aeration zone adopts the disc type micro porous aeration head to carry out aeration; Ultra-filtration membrane is placed on the membrane filtration district, and through the waste water after aerobic contact oxidation, the anaerobic hydrolysis acidification, organism wherein is basically by biological degradation; Waste water is extracted out through in the ultra-filtration membrane, and the mikrobe in the reactor drum is blocked in the reactor drum.
Inventive point of the present invention mainly is to have introduced illumination in the acidication stage; This illumination operation has significant lifting (concrete experimental data see after literary composition) to the effect of acidication; And can increase work-ing life of membrane bioreactor, reduce the use cost of membrane bioreactor.Thereby promoted the quality of water treatment on the one hand, reduced the cost of whole process flow on the other hand.
Embodiment
The analytical procedure of using among the present invention: adopt potassium dichromate process to measure COD; Adopt the dilution inoculation method to measure BOD
5Adopt Potassium Persulphate oxidation---determined by ultraviolet spectrophotometry total nitrogen (TN); Adopt molybdenum-antimony anti-spectrophotometric method to measure total phosphorus (TP), adopt the filter paper filtering weighting method to measure suspended substance (SS).
Embodiment 1
Wastewater from cephalosporin synthesis pharmaceutical production 415m
3/ d, the COD value 8000mg/l of water inlet, the BOD of water inlet
5Value 740mg/l, the TN value 480mg/l of water inlet, the value 85mg/l of the TP of water inlet, the SS value 110mg/l of water inlet.
Through the balanced water quality and quantity of equalizing tank and after regulating the pH value, be introduced into hydrolysis acidification pool, be 3 hours at the hydraulic detention time of hydrolysis acidification pool, and above hydrolysis acidification pool, set up light source that whole process is carried out the irradiation that wavelength is the 2200nm infrared light.The COD value 4500mg/l of hydrolysis acidification pool water outlet, the BOD of water outlet
5Value 550mg/l, the TN value 275mg/l of water outlet, the value 58mg/l of the TP of water outlet, the SS value 50mg/l of water outlet.
Water after acidication is handled gets into electrolyzer, presses iron filings 2kg/m in the electrolyzer
3Ratio throw in, hydraulic detention time is 10 hours, and in operation process, uses gas blower in the pond, to be blown into air, thereby guarantees in the water of electrolyzer competent oxygen is arranged.
Membrane bioreactor is advanced in water outlet in the electrolyzer, and the residence time of waste water in membrane bioreactor is 20 hours, and volumetric loading is 6kgCOD/m
3.d, sludge concentration is 7-11g/l, and membrane flux is 15L/m
2.h, resistance of membrane filtration is less than 25kPa; COD value≤the 50mg/l of water outlet, the BOD of water outlet
5Value≤8mg/l, the TN value 156mg/l of water outlet, the value 13mg/l of the TP of water outlet, the SS value of water outlet does not detect.
Embodiment 2
Wastewater from cephalosporin synthesis pharmaceutical production 200m
3/ d, the COD value 13000mg/l of water inlet, the BOD of water inlet
5Value 950mg/l, the TN value 625mg/l of water inlet, the value 112mg/l of the TP of water inlet, the SS value 145mg/l of water inlet.
Through the balanced water quality and quantity of equalizing tank and after regulating the pH value, be introduced into hydrolysis acidification pool, be 4.5 hours at the hydraulic detention time of hydrolysis acidification pool, and above hydrolysis acidification pool, set up light source that whole process is carried out the irradiation that wavelength is the 1500nm infrared light.The COD value 6000mg/l of hydrolysis acidification pool water outlet, the BOD of water outlet
5Value 440mg/l, the TN value 315mg/l of water outlet, the value 74mg/l of the TP of water outlet, the SS value 90mg/l of water outlet.
Water after acidication is handled gets into electrolyzer, presses iron filings 2kg/m in the electrolyzer
3Ratio throw in, hydraulic detention time is 10 hours, and in operation process, uses gas blower in the pond, to be blown into air, thereby guarantees in the water of electrolyzer competent oxygen is arranged.
Membrane bioreactor is advanced in water outlet in the electrolyzer, and the residence time of waste water in membrane bioreactor is 20 hours, and volumetric loading is 6kgCOD/m
3.d, sludge concentration is 7-11g/l, and membrane flux is 15L/m
2.h, resistance of membrane filtration is less than 25kPa; COD value≤the 70mg/l of water outlet, the BOD of water outlet
5Value≤10mg/l, the TN value 146mg/l of water outlet, the value 14mg/l of the TP of water outlet, the SS value of water outlet does not detect.
Embodiment 3
Wastewater from cephalosporin synthesis pharmaceutical production 300m
3/ d, the COD value 3000mg/l of water inlet, the BOD of water inlet
5Value 410mg/l, the TN value 380mg/l of water inlet, the value 86mg/l of the TP of water inlet, the SS value 104mg/l of water inlet.
Through the balanced water quality and quantity of equalizing tank and after regulating the pH value, be introduced into hydrolysis acidification pool, be 2.5 hours at the hydraulic detention time of hydrolysis acidification pool, and above hydrolysis acidification pool, set up light source that whole process is carried out the irradiation that wavelength is the 1100nm infrared light.The COD value 1300mg/l of hydrolysis acidification pool water outlet, the BOD of water outlet
5Value 270mg/l, the TN value 198mg/l of water outlet, the value 52mg/l of the TP of water outlet, the SS value 61mg/l of water outlet.
Water after acidication is handled gets into electrolyzer, presses iron filings 2kg/m in the electrolyzer
3Ratio throw in, hydraulic detention time is 10 hours, and in operation process, uses gas blower in the pond, to be blown into air, thereby guarantees in the water of electrolyzer competent oxygen is arranged.
Membrane bioreactor is advanced in water outlet in the electrolyzer, and 18 hours residence time in membrane bioreactor of waste water, volumetric loading is 6kgCOD/m
3.d, sludge concentration is 7-11g/l, and membrane flux is 15L/m
2.h, resistance of membrane filtration is less than 25kPa; COD value≤the 45mg/l of water outlet, the BOD of water outlet
5Value≤8mg/l, the TN value 108mg/l of water outlet, the value 21mg/l of the TP of water outlet, the SS value of water outlet does not detect.
Table 1 is the experimental data tabulation of carrying out the illumination experiment in the acidication process.From the data of table 1, can see, adopt illumination COD clearance, BOD afterwards
5Clearance and SS clearance all are significantly increased, and the clearance of TN and TP slightly improves.And can find out that when adopting the far red light irradiation, clearance is the highest, effect is best.Explain that photo-irradiation treatment has produced significant effect.Playing the reason of effect and analyze theoretically, possibly be because illumination has produced influence to acting microbial growth metabolism in the acidication process, and the result of acidication has been produced influence.And the illumination of different wave length is variant to the microbial growth metabolic effect, therefore can draw best irradiates light wave band through experiment.
Table 1, annotate: above-mentioned data are the MV and the variance of 4 repeated experiments.
Those skilled in the art can make replacement or modification to content of the present invention according to content disclosed by the invention and the art technology of being grasped; But these replacements or modification should not be regarded as breaking away from the present invention's design, and these replacements or modification are all in the interest field that the present invention requires to protect.
Claims (6)
1. one kind to producing the wastewater produced treatment process of cephalosporins medicine, it is characterized in that this method by the anaerobic hydrolysis acidifying, these three treatment steps formations of electrolysis and Membrane Bioreactor for Wastewater Treatment,
The waste water that produces in step (1) the cephalosporin synthesis pharmaceutical production carries out earlier the biological hydrolysis acidifying in anoxic pond, improve the biodegradability of waste water;
Step (2) is carried out electrolysis with the water outlet of step (1) in electrolyzer, further remove COD, improves the biodegradability of waste water;
Step (3) flows into the water outlet of step (2) carries out final aerobe and handles in the membrane bioreactor, the waste water after the processing pumps out by going out water pump through the ultra-filtration membrane in the membrane bioreactor, and qualified discharge is to outer discharge pipe or be back to use in the production technique.
2. a kind of described in the claim 1 is characterized in that to producing the wastewater produced treatment process of cephalosporins medicine the biological hydrolysis acidifying in the step (1) comprises hydrolysis stage and souring stage, at hydrolysis and souring stage, hydrolysis acidification pool carried out omnidistance illumination.
3. a kind of described in the claim 2 is characterized in that at hydrolysis and souring stage producing the wastewater produced treatment process of cephalosporins medicine, and hydrolysis acidification pool is carried out omnidistance infrared light irradiation.
4. a kind of described in the claim 2 is characterized in that at hydrolysis and souring stage producing the wastewater produced treatment process of cephalosporins medicine, and hydrolysis acidification pool is carried out the infrared light irradiation of omnidistance light wave scope at 1100～2500nm.
5. a kind of described in the claim 2 to producing the wastewater produced treatment process of cephalosporins medicine; It is characterized in that wherein said electrolysis step takes iron charcoal internal electrolysis; In waste water, drop into iron filings and air-blowing in waste water simultaneously, thereby in waste water, form countless small galvanic cells, redox reaction takes place; Produce divalence and ferric ion simultaneously, in waste water, form colloid and produce the flocculation sediment effect.
6. a kind of to producing the wastewater produced treatment process of cephalosporins medicine described in the claim 2 is characterized in that wherein iron filings are by 2kg/m
3Ratio throw in, the residence time of waste water in membrane bioreactor is 19 hours, volumetric loading is 6kgCOD/m
3.d, sludge concentration is 7-11g/l, and membrane flux is 15L/m
2.h, resistance of membrane filtration is less than 25kPa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210349360.3A CN102826722B (en) | 2012-09-20 | 2012-09-20 | Treatment method for wastewater generated by producing cephalosporin medicines |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210349360.3A CN102826722B (en) | 2012-09-20 | 2012-09-20 | Treatment method for wastewater generated by producing cephalosporin medicines |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102826722A true CN102826722A (en) | 2012-12-19 |
| CN102826722B CN102826722B (en) | 2014-12-17 |
Family
ID=47330069
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210349360.3A Expired - Fee Related CN102826722B (en) | 2012-09-20 | 2012-09-20 | Treatment method for wastewater generated by producing cephalosporin medicines |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102826722B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104773919A (en) * | 2015-04-08 | 2015-07-15 | 常州大学 | Pharmaceutical wastewater advanced treatment system |
| CN106007186A (en) * | 2016-06-28 | 2016-10-12 | 焦作健康元生物制品有限公司 | 7-aminocephalosporanic acid production wastewater treatment method |
| CN107032495A (en) * | 2017-05-22 | 2017-08-11 | 大连理工大学 | A kind of biological treatment group technology of the high salinity pharmacy waste waters of high COD |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000237770A (en) * | 1999-02-17 | 2000-09-05 | Ebara Corp | Purifying method for water by powdery activated carbon and photocatalyst |
| CN101434437A (en) * | 2008-12-02 | 2009-05-20 | 浙江双益环保科技发展有限公司 | Processing method for wastewater from cephalosporin synthesis pharmaceutical production |
| CN101941749A (en) * | 2010-09-27 | 2011-01-12 | 中国环境科学研究院 | Method for treating high-concentration copper-containing antibiotic wastewater and recovering copper by iron-carbon micro-electrolysis |
| CN102372401A (en) * | 2011-09-28 | 2012-03-14 | 同济大学 | Iron-carbon micro-electrolysis-dynamic membrane wastewater deep treatment process |
| CN102531273A (en) * | 2010-12-31 | 2012-07-04 | 上海轻工业研究所有限公司 | Treatment equipment for ammonia nitrogen and COD (Chemical Oxygen Demand) in surface treatment waste water |
-
2012
- 2012-09-20 CN CN201210349360.3A patent/CN102826722B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000237770A (en) * | 1999-02-17 | 2000-09-05 | Ebara Corp | Purifying method for water by powdery activated carbon and photocatalyst |
| CN101434437A (en) * | 2008-12-02 | 2009-05-20 | 浙江双益环保科技发展有限公司 | Processing method for wastewater from cephalosporin synthesis pharmaceutical production |
| CN101941749A (en) * | 2010-09-27 | 2011-01-12 | 中国环境科学研究院 | Method for treating high-concentration copper-containing antibiotic wastewater and recovering copper by iron-carbon micro-electrolysis |
| CN102531273A (en) * | 2010-12-31 | 2012-07-04 | 上海轻工业研究所有限公司 | Treatment equipment for ammonia nitrogen and COD (Chemical Oxygen Demand) in surface treatment waste water |
| CN102372401A (en) * | 2011-09-28 | 2012-03-14 | 同济大学 | Iron-carbon micro-electrolysis-dynamic membrane wastewater deep treatment process |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104773919A (en) * | 2015-04-08 | 2015-07-15 | 常州大学 | Pharmaceutical wastewater advanced treatment system |
| CN104773919B (en) * | 2015-04-08 | 2016-06-29 | 常州大学 | A kind of pharmacy waste water advanced treatment system |
| CN106007186A (en) * | 2016-06-28 | 2016-10-12 | 焦作健康元生物制品有限公司 | 7-aminocephalosporanic acid production wastewater treatment method |
| CN107032495A (en) * | 2017-05-22 | 2017-08-11 | 大连理工大学 | A kind of biological treatment group technology of the high salinity pharmacy waste waters of high COD |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102826722B (en) | 2014-12-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Hom-Diaz et al. | Performance of a microalgal photobioreactor treating toilet wastewater: pharmaceutically active compound removal and biomass harvesting | |
| Chen et al. | Photosynthetic bacteria-based technology is a potential alternative to meet sustainable wastewater treatment requirement? | |
| Tang et al. | Effect of aeration rate on performance and stability of algal-bacterial symbiosis system to treat domestic wastewater in sequencing batch reactors | |
| Selvamurugan et al. | An integrated treatment system for coffee processing wastewater using anaerobic and aerobic process | |
| Xie et al. | Immobilized microalgae for anaerobic digestion effluent treatment in a photobioreactor-ultrafiltration system: Algal harvest and membrane fouling control | |
| Zhang et al. | The biological performance of a novel microalgal-bacterial membrane photobioreactor: Effects of HRT and N/P ratio | |
| Tang et al. | Calcium ions-effect on performance, growth and extracellular nature of microalgal-bacterial symbiosis system treating wastewater | |
| Lu et al. | A novel wastewater treatment and biomass cultivation system combining photosynthetic bacteria and membrane bioreactor technology | |
| CN100349811C (en) | Process for treating yellow ginger saponin waste water by hydrochloric acid method | |
| CN101434437B (en) | Processing method for wastewater from cephalosporin synthesis pharmaceutical production | |
| CN105254155B (en) | A kind of biological wall breaking method improving dewatering performance of sludge | |
| CN105481174A (en) | Wastewater treatment system in rubber and synthetic plastic industry | |
| CN104118957A (en) | Traditional water purification process based land saving reconstruction upgrade method | |
| Liu et al. | Understanding the effects of algae growth on algae-bacterial granular sludge formation: from sludge characteristics, extracellular polymeric substances, and microbial community | |
| CN106186554A (en) | A kind of to PTA sewage after double film desalination reuses the preprocess method of the remaining dense water of RO | |
| Zhang et al. | Sludge predation by aquatic worms: Physicochemical characteristics of sewage sludge and implications for dewaterability | |
| CN102826722B (en) | Treatment method for wastewater generated by producing cephalosporin medicines | |
| CN107935309A (en) | Priming produces waste water physicochemical pre-treat biological intensive treatment integrated technique | |
| CN102001800A (en) | Method for purifying wastewater containing organosilicon | |
| Laurent et al. | Finding optimal algal/bacterial inoculation ratio to improve algal biomass growth with wastewater as nutrient source | |
| CN102730898A (en) | Community domestic sewage treatment technology | |
| CN108865892A (en) | A method of utilizing livestock breeding biogas slurry high yield microalgae | |
| CN114751520B (en) | Method for treating ammonia sugar processing wastewater by utilizing fungus microalgae symbiotic system | |
| CN208649040U (en) | A kind of proprietary processing unit of high concentration antibiotic organic wastewater | |
| CN106082564A (en) | A kind of membrane bioreactor sludge reduction sewage disposal technology |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: JIANGSU AITEKE ENVIRONMENTAL ENGINEERING CO., LTD. Free format text: FORMER OWNER: ATK HOLDING GROUP CO., LTD. Effective date: 20140102 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 214214 WUXI, JIANGSU PROVINCE TO: 214214 ZHENJIANG, JIANGSU PROVINCE |
|
| TA01 | Transfer of patent application right |
Effective date of registration: 20140102 Address after: Jiangnan Gaocheng Town Road 214214 Jiangsu city of Yixing province No. 68 Applicant after: JIANGSU ATK ENVIRONMENTAL ENGINEERING LTD. Address before: 214214 Jiangsu province Yixing gaochengzhen Foreign Investment Industrial Park Yi Road No. 68 Applicant before: ATK Holdings Group Co.,Ltd. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160309 Address after: Jiangnan Gaocheng Town Road 214214 Jiangsu city of Yixing province No. 68 Patentee after: JIANGSU ATK ENVIRONMENTAL ENGINEERING LTD. Patentee after: ATK HOLDINGS GROUP Co.,Ltd. Address before: Jiangnan Gaocheng Town Road 214214 Jiangsu city of Yixing province No. 68 Patentee before: JIANGSU ATK ENVIRONMENTAL ENGINEERING LTD. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210825 Address after: No.68, Yigao Road, foreign invested industrial park, Gaocheng Town, Yixing City, Wuxi City, Jiangsu Province Patentee after: JIANGSU ATK ENVIRONMENTAL ENGINEERING Ltd. Address before: 214214 No. 68, Jiangnan West Road, Gaocheng Town, Yixing City, Jiangsu Province Patentee before: JIANGSU ATK ENVIRONMENTAL ENGINEERING Ltd. Patentee before: ATK HOLDINGS GROUP Co.,Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20141217 |