Summary of the invention
In view of this, one of the object of the invention provides the method that a kind of novel employing stacked system is made high voltage output solar cell.Creatively change the series system of solar battery sheet, can under the condition of small size more, realize high voltage output; Two of the object of the invention provides a kind of high voltage solar module.
One of the object of the invention is realized through following technical scheme:
Employing stacked system of the present invention is made the method for high voltage output solar cell, may further comprise the steps:
Step 1: solar battery sheet is cleaned;
Step 2: module output voltage as required; Calculate the good solar battery sheet sheet number that needs series connection; Adopting the solar battery sheet of multi-disc same size in the same way, the mode of lamination overlaps together; The back side of a slice solar battery sheet is provided with conduction adhesion thing towards the front of back a slice solar battery sheet promptly between the adjacent solar battery sheet;
Step 3: adopt technological means to make conduction adhesion thing firmly connect the solar battery sheet of its front and back, carry out Local treatment, obtain the battery chip module;
Step 4: the battery chip module is carried out horizontal resection, obtain to realize the solar module of high voltage output.
Further, said method also comprises step 5, and the periphery that is about to module plates protective layer, obtains finished product.
Further, among the present invention, the conduction adhesion thing described in the said step 2 is an aluminium foil, and the dimensions and the solar battery sheet of said aluminium foil are similar, and when adopting aluminium foil, the technological means that adopts in the said step 3 may further comprise the steps:
Step 31): assembly is put into heater heat, heating-up temperature is 500 ℃ ~ 1000 ℃, and the time is 1 ~ 3min;
Step 32): but the battery chip module after will heating is put into closed chamber, but slowly extract the air in the closed chamber, make it to form negative pressure, through the air bag of exerting pressure of both sides the head and the tail battery sheet of battery chip module is exerted pressure, make it to realize firm adhesion;
Step 33): the battery chip module after the pressing is put into heater, under 250 ℃ ~ 300 ℃ condition, leave standstill 20 ~ 30min, take out then and naturally cool to ambient temperature;
Local treatment in the said step 3 is because during pressing, aluminium foil solidify to form burr owing to pressure stretches out, so need be with its excision behind the assembly natural cooling.
In addition, the conduction adhesion thing described in the step 2 also can adopt aluminium paste, and aluminium paste is brushed on the front and/or the back side of solar battery sheet, and when adopting aluminium paste, the technological means that adopts in the said step 3 may further comprise the steps:
Step 31): assembly is put into sintering equipment carry out sintering, sintering temperature is 500 ~ 900 ℃, and the time is 1 ~ 2min;
Step 32): the battery chip module that sintering is accomplished is put into heater, under 250 ℃ ~ 300 ℃ condition, leave standstill 20 ~ 30min, take out then and naturally cool to ambient temperature;
Local treatment in the said step 3 is the assembly behind the natural cooling to be carried out deflash handle;
Further; When adopting aluminium paste as conduction adhesion thing, in the said step 31, sintering is divided into oven dry, pre-burning, sintering and cooling four-stage; Wherein sintering stage is warming up to rapidly about 850 ℃ from 500 ℃; Sharply cool to then below 500 ℃, the used time of sintering stage is at 8-12s, and stops 3~5s at 850 ℃.
Further, said protective layer adopts individual layer silicon nitride or individual layer silicon dioxide, or both alternately preparations;
Further, the cleaning in the said step 1 is included in and carries out the manual work cleaning under the vacuum condition or pass through ultrasonic waves for cleaning;
Further, said solar battery sheet is monocrystalline silicon or polycrystalline silicon solar cell, and its positive and negative electrode is at the positive and negative of battery;
Further, in the said step 4, the high voltage solar cell both positive and negative polarity that cutting obtains is in both sides, and thickness is at 200-400 μ m.
Two of the object of the invention is realized through following technical scheme:
The solar cell that adopts foregoing method to make.
The invention has the beneficial effects as follows:
Changed to the invention property the series system of solar battery sheet; Can the miniaturization of implement device volume, satisfy the requirement of high voltage output simultaneously, a whole set of processing step is comparatively simple; Adopt existing making apparatus just can realize; And can produce battery module easily as required, have bigger flexibility with multiple power output.
Other advantages of the present invention, target and characteristic will be set forth in specification subsequently to a certain extent; And to a certain extent; Based on being conspicuous to those skilled in the art, perhaps can from practice of the present invention, obtain instruction to investigating of hereinafter.Target of the present invention and other advantages can realize and obtain through following specification and claims.
Embodiment
Below will carry out detailed description to the preferred embodiments of the present invention with reference to accompanying drawing.Should be appreciated that preferred embodiment has been merely explanation the present invention, rather than in order to limit protection scope of the present invention.
Employing lay-up method of the present invention is made the method for high voltage output solar cell, mainly may further comprise the steps:
Step 1: solar battery sheet is cleaned; In the present embodiment, clean to be included in and carry out the manual work cleaning under the vacuum condition or pass through ultrasonic waves for cleaning.
Step 2: module output voltage as required; Calculate the good solar battery sheet sheet number that needs; Adopt range upon range of in the same way mode to overlap together the solar battery sheet of multi-disc same size; The back side of a slice solar battery sheet is provided with conduction adhesion thing towards the front of back a slice solar battery sheet promptly between the adjacent solar battery sheet;
Step 3: adopt technological means to make conduction adhesion thing firmly connect the solar battery sheet of its front and back, carry out Local treatment, obtain the battery chip module;
Step 4: the battery chip module is carried out horizontal resection, obtain the solar module of height at 200-400 μ m.
Step 5: the periphery of module is plated protective layer, obtain finished product.
To adopt the different technologies of aluminium foil and aluminium paste to handle to conduction adhesion thing below describes.
One, conduction adhesion thing adopts aluminium foil, and the dimensions and the solar battery sheet of aluminium foil are similar, and when adopting aluminium foil, the technological means that adopts in the step 3 may further comprise the steps:
Step 31): assembly is put into heater heat, heating-up temperature is 500 ℃ ~ 1000 ℃, and the time is 1 ~ 3min;
Step 32): but the battery chip module after will heating is put into closed chamber, but slowly extract the air in the closed chamber, make it to form negative pressure, through the air bag of exerting pressure of both sides the head and the tail battery sheet of battery chip module is exerted pressure, make it to realize firm adhesion;
Step 33): the battery chip module after the pressing is put into heater, under 250 ℃ ~ 300 ℃ condition, leave standstill 20 ~ 30min, take out then and naturally cool to ambient temperature;
Local treatment in the step 3 is because during pressing, aluminium foil solidify to form burr owing to pressure stretches out, so need be with its excision behind the assembly natural cooling.
Two, conduction adhesion thing adopts aluminium paste, and aluminium paste is brushed on the front and/or the back side of solar battery sheet, and when adopting aluminium paste, the technological means that adopts in the said step 3 may further comprise the steps:
Step 31): assembly is put into sintering equipment carry out sintering, sintering temperature is 500 ~ 900 ℃, and the time length overall is 1 ~ 3min; Particularly, be to be divided into oven dry, pre-burning, sintering and cooling four-stage, wherein sintering stage is warming up to 850 ℃ rapidly from 500 ℃, sharply cool to then below 500 ℃, about during this period of time 8-12s, and only stop 3~5s at 850 ℃;
Step 32): the battery chip module that sintering is accomplished is put into heater, under 250 ℃ ~ 300 ℃ condition, leave standstill 20 ~ 30min, take out then and naturally cool to ambient temperature;
Local treatment in the step 3 is the assembly behind the natural cooling to be carried out deflash handle.
As further improvement, in step 5, protective layer adopts individual layer silicon nitride or individual layer silicon dioxide, or both alternately preparations.
Below will adopt concrete embodiment that whole process flow of the present invention is done a detailed explanation, in following examples, polysilicon solar battery slice is 125mm*125mm; Its front is a negative pole, and the back side is anodal, sets output 50v; Because the magnitude of voltage of each sheet solar battery sheet is about 0.5v; Therefore, when needing the output voltage of 50v, need to adopt 100 such solar battery sheets.
Embodiment one
Step 1: solar battery sheet is carried out manual work clean under vacuum condition;
Step 2: adopt range upon range of in the same way mode to overlap together the solar battery sheet of 100 same sizes, promptly the back side of preceding a slice solar battery sheet is provided with aluminium foil towards the front of back a slice solar battery sheet between the adjacent solar battery sheet;
Step 3: adopt technological means to make aluminium foil firmly connect the solar battery sheet of its front and back, obtain the battery chip module, may further comprise the steps:
Step 31: assembly is put into heater heat, heating-up temperature is 600 ℃, and the time is 3min;
Step 32: but the battery chip module after will heating is put into closed chamber, but slowly extract the air in the closed chamber, make it to form negative pressure, through the air bag of exerting pressure of both sides the head and the tail battery sheet of battery chip module is exerted pressure, make it to realize firm adhesion;
Step 33: the battery chip module after the pressing is put into heater, under 250 ℃ condition, leave standstill 30min, take out then and naturally cool to ambient temperature;
Step 34: aluminium foil solidify to form burr owing to pressure stretches out, behind the assembly natural cooling with its excision.
Step 4: the battery chip module is carried out horizontal resection, obtain the solar module of thickness at 320 μ m;
Step 5: the periphery of module is plated silicon dioxide layer of protection, and side vapor deposition top electrode obtains finished product.
Embodiment two
The difference of present embodiment and embodiment one is in the step 3 that the selection of relevant parameter is different, and the step 3 of present embodiment comprises following substep:
Step 31: assembly is put into heater heat, heating-up temperature is 600 ℃, and the time is 1min;
Step 32: but the battery chip module after will heating is put into closed chamber, but slowly extract the air in the closed chamber, make it to form negative pressure, through the air bag of exerting pressure of both sides the head and the tail battery sheet of battery chip module is exerted pressure, make it to realize firm adhesion;
Step 33: the battery chip module after the pressing is put into heater, under 280 ℃ condition, leave standstill 25min, take out then and naturally cool to ambient temperature;
Step 34: aluminium foil solidify to form burr owing to pressure stretches out, behind the assembly natural cooling with its excision.
In addition, in the step 4, the battery chip module is carried out horizontal resection, obtain the solar module of thickness at 200 μ m;
In step 5, the periphery of module is plated silicon nitride protective layer, side vapor deposition top electrode obtains finished product.
Embodiment three
The difference of present embodiment and embodiment one is in the step 3 that the selection of relevant parameter is different, and the step 3 of present embodiment comprises following substep:
Step 31: assembly is put into heater heat, heating-up temperature is 900 ℃, and the time is 1min;
Step 32: but the battery chip module after will heating is put into closed chamber, but slowly extract the air in the closed chamber, make it to form negative pressure, through the air bag of exerting pressure of both sides the head and the tail battery sheet of battery chip module is exerted pressure, make it to realize firm adhesion;
Step 33: the battery chip module after the pressing is put into heater, under 300 ℃ condition, leave standstill 20min, take out then and naturally cool to ambient temperature;
Step 34: aluminium foil solidify to form burr owing to pressure stretches out, behind the assembly natural cooling with its excision.
In addition, in the step 4, the battery chip module is carried out horizontal resection, obtain the solar module of thickness at 400 μ m;
In addition, in the step 5 of present embodiment, the protective layer of employing is to be coated with one deck silicon nitride earlier, and then is coated with the mode of layer of silicon dioxide, the protection better effects if.
Embodiment four
Step 1: solar battery sheet is cleaned; In the present embodiment, clean to be included in and carry out the manual work cleaning under the vacuum condition or pass through ultrasonic waves for cleaning.
Step 2: module output voltage as required; Calculate the good solar battery sheet sheet number that needs; Adopt range upon range of in the same way mode to overlap together the solar battery sheet of multi-disc same size; The back side of a slice solar battery sheet is provided with conduction adhesion thing towards the front of back a slice solar battery sheet promptly between the adjacent solar battery sheet;
Step 3: conduction adhesion thing adopts aluminium paste, and aluminium paste is brushed on the front and/or the back side of solar battery sheet, comprises following substep:
Step 31: assembly is put into sintering equipment carry out sintering, sintering temperature is 500 ~ 900 ℃, and the time length overall is 1 ~ 3min; In the present embodiment, sintering is divided into oven dry, pre-burning, sintering and cooling four-stage, and wherein sintering stage is warming up to rapidly about 850 ℃ from 500 ℃, sharply cools to then below 500 ℃, and the used time of sintering stage is at 8s, and stops 3s at 850 ℃.
Step 32: the battery chip module that sintering is accomplished is put into heater, under 250 ℃ condition, leave standstill 30min, take out then and naturally cool to ambient temperature;
Step 33: the assembly behind the natural cooling is carried out deflash handle.
Step 4: the battery chip module is carried out horizontal resection, obtain the solar module of thickness 320 μ m.
Step 5: the periphery of module is plated silicon dioxide layer of protection, and side vapor deposition top electrode obtains finished product.
Embodiment five
The difference of present embodiment and embodiment one is in the step 3 that the selection of relevant parameter is different, and the step 3 of present embodiment comprises following substep:
Step 31: assembly is put into sintering equipment carry out sintering, sintering temperature is 500 ~ 900 ℃, and the time length overall is 1 ~ 3min; In the present embodiment, sintering is divided into oven dry, pre-burning, sintering and cooling four-stage, and wherein sintering stage is warming up to 850 ℃ rapidly from 500 ℃, sharply cools to then below 500 ℃, and the used time of sintering stage is at 12s, and stops 5s at 850 ℃;
Step 32: the heater of putting into the sintering completion, under 280 ℃ condition, leave standstill 25min, take out then and naturally cool to ambient temperature;
Step 33: the assembly behind the natural cooling is carried out deflash handle.
In addition, in step 5,The periphery of module is plated silicon nitride protective layer, and side vapor deposition top electrode obtains finished product.
Embodiment six
The difference of present embodiment and embodiment one is in the step 3 that the selection of relevant parameter is different, and the step 3 of present embodiment comprises following substep:
Step 31: assembly is put into sintering equipment carry out sintering, sintering temperature is 500 ~ 900 ℃, and the time length overall is 1 ~ 3min; In the present embodiment, sintering is divided into oven dry, pre-burning, sintering and cooling four-stage, and wherein sintering stage is warming up to 850 ℃ rapidly from 500 ℃, sharply cools to then below 500 ℃, and the used time of sintering stage is at 10s, and stops 4s at 850 ℃;
Step 32: the heater of putting into the sintering completion, under 300 ℃ condition, leave standstill 20min, take out then and naturally cool to ambient temperature;
Step 33: the assembly behind the natural cooling is carried out deflash handle.
In addition, in the present embodiment, the protective layer of employing is to be coated with one deck silicon nitride earlier, and then is coated with the mode of layer of silicon dioxide, the protection better effects if.
Explanation is at last; Above embodiment is only unrestricted in order to technical scheme of the present invention to be described; Although with reference to preferred embodiment the present invention is specified, those of ordinary skill in the art should be appreciated that and can make amendment or be equal to replacement technical scheme of the present invention; And not breaking away from the aim and the scope of present technique scheme, it all should be encompassed in the middle of the claim scope of the present invention.