CN102816495A - Environment-friendly nano-epoxy silicone heavy anti-corrosion coating and preparation method and using method thereof - Google Patents

Environment-friendly nano-epoxy silicone heavy anti-corrosion coating and preparation method and using method thereof Download PDF

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Publication number
CN102816495A
CN102816495A CN2011101553338A CN201110155333A CN102816495A CN 102816495 A CN102816495 A CN 102816495A CN 2011101553338 A CN2011101553338 A CN 2011101553338A CN 201110155333 A CN201110155333 A CN 201110155333A CN 102816495 A CN102816495 A CN 102816495A
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coating
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CN102816495B (en
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宋逸
宋会军
贾慧霞
丛思程
张美珍
陈瑞
魏巍
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Shanghai Jianye Technology Co ltd
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Shanghai Jianye Technology Engineering Co Ltd
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Abstract

An environment-friendly nano-epoxy silicone heavy anti-corrosion coating comprises a component A and a component B, wherein the component B is polyamide, and the component A is prepared by water-borne epoxy resin, a solvent, silicon carbide, aluminum oxide, nano-quartz powder, titanium dioxide power, zinc powder, aluminum powder, ceramic powder, cobalt-nickel ultrafine metal powder and graphite. A using method of the environment-friendly nano-epoxy silicone heavy anti-corrosion coating is that the component A and the component B are mixed evenly according to the weight ratio of 30-50:1 and then directly sprayed or brushed on the surface of an anti-corrosion object at the normal temperature. A coating layer formed by the coating has good abrasion resistance, corrosion resistance, impact resisting performance and flexibility and can effectively isolate corrosion of acid, alkali, salt and sea water. The surface of the coating layer is compact and smooth and has small resistance to a transmission medium. The coating can be widely applied to oil transportation pipelines, oil storage tanks, chemical equipment, ships, grinding wheel blades, pumps, dust removers, offshore steel structures and the like. In addition, the environment-friendly nano-epoxy silicone heavy anti-corrosion coating is water-based coating, does not contain harmful ingredients and is convenient and efficient in use.

Description

Environment-friendly type nano epoxy silicon heavy-duty coating and preparation method thereof and method of use
Technical field
The present invention relates to coating, particularly a kind of environment-friendly type nano epoxy silicon heavy-duty coating and preparation method thereof and method of use.
Background technology
Along with developing rapidly of marine economy, utilize the process of ocean space to quicken, the ocean structure engineering is used more and more extensive like breakwater, harbour, off-shore airport, subbottom tunnel and bridge spanning the sea etc.Meanwhile, because the impact of seawater long period of soaking, erosion, stormy waves and morning and evening tides, ocean structure engineering etching problem is also outstanding day by day, and the security and the weather resistance of ocean structure engineering in serious harm.Therefore, the corrosion prevention problem of ocean structure engineering more and more comes into one's own.
Coating technology is the important and effective means of ocean structure engineering protection.The marine concrete structure corrosion protective coating had been continued to use the metal protection material in the past, generally adopted coating such as chlorinated rubber, urethane, chlorosuphonated-polyethylene and epoxy, and its over-all properties can't satisfy the requirement of harsh ocean environment to a certain extent.In addition, present conventional water-borne coatings and concrete special protection material like permeable concrete protecting materials and fiber reinforced material etc., also exist construction environment is required height, is difficult to form problems such as effective surfacecti proteon structure and constructional difficulties.Therefore, the research high-performance coating is significant to burn into its security of raising of control marine concrete structure and weather resistance.。
Summary of the invention
The object of the invention in order to solve the problems referred to above that prior art exists, provides a kind of environment-friendly type nano epoxy silicon heavy-duty coating and preparation method thereof and method of use exactly.
To achieve these goals, the present invention has adopted following technical scheme: a kind of environment-friendly type nano epoxy silicon heavy-duty coating, comprise A component and B component, and the B component is a polymeric amide, the A component is prepared from following weight percent material:
Aqueous epoxy resins 10%~40%;
Solvent 30%~60%;
Silit 1%~5%;
Aluminum oxide 1%~6%;
Nanometer silica powder 5%~15%,
White titanium pigment 5%~15%;
Zinc powder 2%~10%;
Aluminium powder 2%~15%;
Ceramics powder 5%~25%;
The ultra tiny metal-powder 0%~5% of cobalt nickel;
Graphite 0%~6%;
Described solvent is water or benzene emulsion.
The preparation method of above-mentioned environment-friendly type nano epoxy silicon heavy-duty coating, B component wherein directly adopts polymeric amide, and the preparation method of A component may further comprise the steps:
A, silit, aluminum oxide, nanometer silica powder, white titanium pigment, zinc powder, aluminium powder, ceramics powder, the ultra tiny metal-powder of cobalt nickel and graphite are carried out the nanometer ultrafining treatment respectively, make granularity reach 15~700nm;
B, form silit, aluminum oxide, nanometer silica powder, white titanium pigment, zinc powder, aluminium powder, ceramics powder, the ultra tiny metal-powder of cobalt nickel and the graphite accurately take by weighing after the nanometer ultrafining treatment by weight percentage and drop into to mix in the sand mill and be mixed fillers;
C, step b gained mixed fillers is placed high speed dispersor, add aqueous epoxy resins and the solvent of forming accurate weighing by weight percentage, stir, obtain work in-process;
D, step c gained work in-process are finished product through filtration, quality inspection, barrelling.
The method of use of above-mentioned environment-friendly type nano epoxy silicon heavy-duty coating, be with A component and B component by 30~50: after 1 weight ratio mixes, instant directly spraying or brush surface at normal temperatures at anticorrosion object.
Environment-friendly type nano epoxy silicon heavy-duty coating of the present invention is a two-component coating; During use; After two components are mixed, need not priming paint, can directly spray at normal temperatures or brush in the metallic surface; The coating that forms has excellent abrasion resistance, erosion resistance, impact resistance and snappiness, can effectively completely cut off the erosion of acid, alkali, salt, seawater.Coatingsurface is fine and close, smooth, and is little to the transmission medium resistance, can be widely used in pipe laying, petroleum storage tank and chemical plant, boats and ships, emery wheel blade, pump, fly-ash separator, marine steelwork etc.Simultaneously, product of the present invention is a water-borne coatings, does not contain harmful ingredients, and is easy to use efficient.
Embodiment
Environment-friendly type nano epoxy silicon heavy-duty coating of the present invention comprises A component and B component, and the B component is a polymeric amide, and A component and preparation method thereof specifies through following examples.
Embodiment 1
Silit, aluminum oxide, nanometer silica powder, white titanium pigment, zinc powder, aluminium powder, ceramics powder, the ultra tiny metal-powder of cobalt nickel and graphite are carried out the nanometer ultrafining treatment respectively, make granularity reach 15~700nm;
Accurately take by weighing to mix in the 1 kilogram of input sand mill of the ultra tiny metal-powder of 10 kilograms of 5 kilograms of 2 kilograms of 10 kilograms of 10 kilograms of 1 kilogram in 1 kilogram in silit, aluminum oxide, nanometer silica powders, white titanium pigments, zinc powders, aluminium powders, ceramics powders, cobalt nickel after the nanometer ultrafining treatment and be mixed fillers;
Above-mentioned mixed fillers is changed in the high speed dispersor, add 40 kilograms in 20 kilograms of aqueous epoxy resins and water, stir, obtain work in-process;
Work in-process are promptly obtained the A component finished product of a kind of environment-friendly type nano epoxy silicon heavy-duty coating of the present invention through filtration, quality inspection, barrelling.
Embodiment 2
Silit, aluminum oxide, nanometer silica powder, white titanium pigment, zinc powder, aluminium powder, ceramics powder, the ultra tiny metal-powder of cobalt nickel and graphite are carried out the nanometer ultrafining treatment respectively, make granularity reach 15~700nm;
Accurately take by weighing to mix in 5 kilograms of 2 kilograms of 8 kilograms of 5 kilograms of 5 kilograms of 2 kilograms in 2 kilograms in silit, aluminum oxide, nanometer silica powders, white titanium pigments, zinc powders, aluminium powders, ceramics powders and the 1 kilogram of input sand mill of graphite after the nanometer ultrafining treatment and be mixed fillers;
Above-mentioned mixed fillers is changed in the high speed dispersor, add 30 kilograms of 40 kilograms of aqueous epoxy resins and benzene emulsions, stir, obtain work in-process;
Work in-process are promptly obtained the A component finished product of a kind of environment-friendly type nano epoxy silicon heavy-duty coating of the present invention through filtration, quality inspection, barrelling.
Embodiment 3
Silit, aluminum oxide, nanometer silica powder, white titanium pigment, zinc powder, aluminium powder, ceramics powder, the ultra tiny metal-powder of cobalt nickel and graphite are carried out the nanometer ultrafining treatment respectively, make granularity reach 15~700nm;
Accurately take by weighing 6 kilograms of 4 kilograms of 3 kilograms of 7 kilograms of 8 kilograms of 5 kilograms in 5 kilograms in silit, aluminum oxide, nanometer silica powders, white titanium pigments, zinc powders, aluminium powders and ceramics powders after the nanometer ultrafining treatment, drop into to mix in the sand mill and be mixed fillers;
Above-mentioned mixed fillers is changed in the high speed dispersor, add 50 kilograms in 10 kilograms of aqueous epoxy resins and water, stir, obtain work in-process;
Work in-process are promptly obtained the A component finished product of a kind of environment-friendly type nano epoxy silicon heavy-duty coating of the present invention through filtration, quality inspection, barrelling.
Embodiment 4
Silit, aluminum oxide, nanometer silica powder, white titanium pigment, zinc powder, aluminium powder, ceramics powder, the ultra tiny metal-powder of cobalt nickel and graphite are carried out the nanometer ultrafining treatment respectively, make granularity reach 15~700nm;
Accurately take by weighing to mix in 5 kilograms of the ultra tiny metal-powders of 20 kilograms of 15 kilograms of 2 kilograms of 5 kilograms of 5 kilograms of 6 kilograms in 1 kilogram in silit, aluminum oxide, nanometer silica powders, white titanium pigments, zinc powders, aluminium powders, ceramics powders, cobalt nickel and the 1 kilogram of input sand mill of graphite after the nanometer ultrafining treatment and be mixed fillers;
Above-mentioned mixed fillers is changed in the high speed dispersor, add 30 kilograms of 10 kilograms of aqueous epoxy resins and benzene emulsions, stir, obtain work in-process;
Work in-process are promptly obtained the A component finished product of a kind of environment-friendly type nano epoxy silicon heavy-duty coating of the present invention through filtration, quality inspection, barrelling.
Embodiment 5
Silit, aluminum oxide, nanometer silica powder, white titanium pigment, zinc powder, aluminium powder, ceramics powder, the ultra tiny metal-powder of cobalt nickel and graphite are carried out the nanometer ultrafining treatment respectively, make granularity reach 15~700nm;
Accurately take by weighing to mix in 21 kilograms of 2 kilograms of 9 kilograms of 15 kilograms of 5 kilograms of 1 kilogram in 1 kilogram in silit, aluminum oxide, nanometer silica powders, white titanium pigments, zinc powders, aluminium powders, ceramics powders and the 6 kilograms of input sand mills of graphite after the nanometer ultrafining treatment and be mixed fillers;
Above-mentioned mixed fillers is changed in the high speed dispersor, add 30 kilograms in 10 kilograms of aqueous epoxy resins and water, stir, obtain work in-process;
Work in-process are promptly obtained the A component finished product of a kind of environment-friendly type nano epoxy silicon heavy-duty coating of the present invention through filtration, quality inspection, barrelling.
Embodiment 6
Silit, aluminum oxide, nanometer silica powder, white titanium pigment, zinc powder, aluminium powder, ceramics powder, the ultra tiny metal-powder of cobalt nickel and graphite are carried out the nanometer ultrafining treatment respectively, make granularity reach 15~700nm;
Accurately take by weighing 5 kilograms of 2 kilograms of 2 kilograms of 5 kilograms of 14 kilograms of 1 kilogram in 1 kilogram in silit, aluminum oxide, nanometer silica powders, white titanium pigments, zinc powders, aluminium powders and ceramics powders after the nanometer ultrafining treatment, drop into to mix in the sand mill and be mixed fillers;
Above-mentioned mixed fillers is changed in the high speed dispersor, add 60 kilograms of 10 kilograms of aqueous epoxy resins and benzene emulsions, stir, obtain work in-process;
Work in-process are promptly obtained the A component finished product of a kind of environment-friendly type nano epoxy silicon heavy-duty coating of the present invention through filtration, quality inspection, barrelling.
The concrete method of use of coating of the present invention is following:
The purification rust cleaning of base material reaches St2.5 level or Sa3 level;
With A component and B component by 30~50: shake after 1 weight ratio is mixed and mix evenly;
With instruments such as capillary brush, spray guns, these article are coated in surface of steel workpiece, can carry out follow-up coating process after 6 hours, thick-layer can divide twice application.
The performance test results to the gained coating is seen table 1:
Table 1
Figure BDA0000067400280000051
The present invention can be widely used in the heavy antiseptic project of steelwork of various fields such as boats and ships, offshore platform, harbour, bridge, steel pipe piling, petroleum pipe line, municipal pipeline.

Claims (3)

1. environment-friendly type nano epoxy silicon heavy-duty coating, it is characterized in that: comprise A component and B component, the B component is a polymeric amide, and the A component is prepared from following weight percent material:
Aqueous epoxy resins 10%~40%;
Solvent 30%~60%;
Silit 1%~5%;
Aluminum oxide 1%~6%;
Nanometer silica powder 5%~15%,
White titanium pigment 5%~15%;
Zinc powder 2%~10%;
Aluminium powder 2%~15%;
Ceramics powder 5%~25%;
The ultra tiny metal-powder 0%~5% of cobalt nickel;
Graphite 0%~6%;
Described solvent is water or benzene emulsion.
2. the preparation method of environment-friendly type nano epoxy silicon heavy-duty coating as claimed in claim 1 is characterized in that B component wherein directly adopts polymeric amide, and the preparation method of A component may further comprise the steps:
A, silit, aluminum oxide, nanometer silica powder, white titanium pigment, zinc powder, aluminium powder, ceramics powder, the ultra tiny metal-powder of cobalt nickel and graphite are carried out the nanometer ultrafining treatment respectively, make granularity reach 15~700nm;
B, form silit, aluminum oxide, nanometer silica powder, white titanium pigment, zinc powder, aluminium powder, ceramics powder, the ultra tiny metal-powder of cobalt nickel and the graphite accurately take by weighing after the nanometer ultrafining treatment by weight percentage and drop into to mix in the sand mill and be mixed fillers;
C, step b gained mixed fillers is placed high speed dispersor, add aqueous epoxy resins and the solvent of forming accurate weighing by weight percentage, stir, obtain work in-process;
D, step c gained work in-process are finished product through filtration, quality inspection, barrelling.
3. the method for use of environment-friendly type nano epoxy silicon heavy-duty coating as claimed in claim 1 is characterized in that: with A component and B component by 30~50: after 1 weight ratio mixes, instant directly spraying or brush surface at normal temperatures at anticorrosion object.
CN201110155333.8A 2011-06-10 2011-06-10 Environment-friendly nano-epoxy silicone heavy anti-corrosion coating and preparation method and using method thereof Active CN102816495B (en)

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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103232789A (en) * 2013-05-20 2013-08-07 邢士波 Marine heavy anticorrosive epoxy aluminum-magnesium-manganese-enriched nano paint and preparation method thereof
CN103254732A (en) * 2013-05-20 2013-08-21 邢士波 Ocean heavy anti-corrosion epoxy aluminum-magnesium-nickel-rich nano-coating and preparation method thereof
CN103642363A (en) * 2013-12-12 2014-03-19 江西恒大高新技术股份有限公司 Wear-resisting epoxy paint
CN103805027A (en) * 2014-02-12 2014-05-21 西安公路研究院 Zinc-rich primer and preparation method thereof
WO2014169866A1 (en) * 2013-03-06 2014-10-23 常州第六元素材料科技股份有限公司 Zinc-rich epoxy anti-corrosion coating and preparation method thereof
CN104179723A (en) * 2014-08-12 2014-12-03 苏州通力电气有限公司 Anti-clamping submersible pump
CN104610841A (en) * 2015-01-20 2015-05-13 安徽斯瑞尔阀门有限公司 Nano-ceramic-modified epoxy resin paint as well as application thereof to metal valves
CN105255310A (en) * 2015-10-08 2016-01-20 江苏科技大学 Ceramic corrosion-preventive and abrasion-resistant coating composition containing corrosion inhibitor and preparation method thereof
CN106433409A (en) * 2016-09-12 2017-02-22 广西大学 Intelligent anticorrosive and self-repairing coating and preparation method thereof
CN107964320A (en) * 2017-08-16 2018-04-27 合肥卓立雅工程材料科技有限公司 A kind of metro shield section of jurisdiction high-efficiency environment friendly anti-corrosive and waterproof paint and preparation method thereof
CN108822682A (en) * 2018-05-29 2018-11-16 芜湖市三山龙城新材料有限公司 A kind of aqueous epoxide resin paint and preparation method thereof
CN108822683A (en) * 2018-05-29 2018-11-16 芜湖市三山龙城新材料有限公司 A kind of epoxy coating and preparation method thereof
CN108912868A (en) * 2018-07-25 2018-11-30 四川省川建管道有限公司 A kind of pipeline special coating
CN112011249A (en) * 2020-08-17 2020-12-01 新昌县旭辉新材料科技有限公司 High-strength flame-retardant water-based epoxy resin coating and preparation method thereof
CN112194957A (en) * 2020-09-15 2021-01-08 西安科技大学 Nano heavy-duty anticorrosive paint and preparation method thereof

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CN1740393A (en) * 2005-09-15 2006-03-01 邹志尚 Technological process of making ferrous metal surface anticorrosive, antiwear, antishock and insulating

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014169866A1 (en) * 2013-03-06 2014-10-23 常州第六元素材料科技股份有限公司 Zinc-rich epoxy anti-corrosion coating and preparation method thereof
US9982142B2 (en) 2013-03-06 2018-05-29 The Sixth Element (Changzhou) Meterials Technology Co., Ltd. Zinc-rich epoxy anti-corrosion coating and preparation method thereof
CN103254732A (en) * 2013-05-20 2013-08-21 邢士波 Ocean heavy anti-corrosion epoxy aluminum-magnesium-nickel-rich nano-coating and preparation method thereof
CN103232789A (en) * 2013-05-20 2013-08-07 邢士波 Marine heavy anticorrosive epoxy aluminum-magnesium-manganese-enriched nano paint and preparation method thereof
CN103254732B (en) * 2013-05-20 2015-03-18 山东龙泉管道工程股份有限公司 Ocean heavy anti-corrosion epoxy aluminum-magnesium-nickel-rich nano-coating and preparation method thereof
CN103232789B (en) * 2013-05-20 2015-04-22 山东龙泉管道工程股份有限公司 Marine heavy anticorrosive epoxy aluminum-magnesium-manganese-enriched nano paint and preparation method thereof
CN103642363A (en) * 2013-12-12 2014-03-19 江西恒大高新技术股份有限公司 Wear-resisting epoxy paint
CN103642363B (en) * 2013-12-12 2015-11-18 江西恒大高新技术股份有限公司 A kind of wear-resisting epoxy coating
CN103805027B (en) * 2014-02-12 2015-12-09 西安公路研究院 A kind of zinc rich primer and preparation method thereof
CN103805027A (en) * 2014-02-12 2014-05-21 西安公路研究院 Zinc-rich primer and preparation method thereof
CN104179723A (en) * 2014-08-12 2014-12-03 苏州通力电气有限公司 Anti-clamping submersible pump
CN104610841A (en) * 2015-01-20 2015-05-13 安徽斯瑞尔阀门有限公司 Nano-ceramic-modified epoxy resin paint as well as application thereof to metal valves
CN105255310A (en) * 2015-10-08 2016-01-20 江苏科技大学 Ceramic corrosion-preventive and abrasion-resistant coating composition containing corrosion inhibitor and preparation method thereof
CN106433409A (en) * 2016-09-12 2017-02-22 广西大学 Intelligent anticorrosive and self-repairing coating and preparation method thereof
CN107964320A (en) * 2017-08-16 2018-04-27 合肥卓立雅工程材料科技有限公司 A kind of metro shield section of jurisdiction high-efficiency environment friendly anti-corrosive and waterproof paint and preparation method thereof
CN108822682A (en) * 2018-05-29 2018-11-16 芜湖市三山龙城新材料有限公司 A kind of aqueous epoxide resin paint and preparation method thereof
CN108822683A (en) * 2018-05-29 2018-11-16 芜湖市三山龙城新材料有限公司 A kind of epoxy coating and preparation method thereof
CN108912868A (en) * 2018-07-25 2018-11-30 四川省川建管道有限公司 A kind of pipeline special coating
CN112011249A (en) * 2020-08-17 2020-12-01 新昌县旭辉新材料科技有限公司 High-strength flame-retardant water-based epoxy resin coating and preparation method thereof
CN112011249B (en) * 2020-08-17 2021-11-30 湖南开磷雁峰塔涂料有限公司 High-strength flame-retardant water-based epoxy resin coating and preparation method thereof
CN112194957A (en) * 2020-09-15 2021-01-08 西安科技大学 Nano heavy-duty anticorrosive paint and preparation method thereof

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