CN102807933A - Non-setting adhesive cleaning agent and preparation method thereof - Google Patents
Non-setting adhesive cleaning agent and preparation method thereof Download PDFInfo
- Publication number
- CN102807933A CN102807933A CN2012103051595A CN201210305159A CN102807933A CN 102807933 A CN102807933 A CN 102807933A CN 2012103051595 A CN2012103051595 A CN 2012103051595A CN 201210305159 A CN201210305159 A CN 201210305159A CN 102807933 A CN102807933 A CN 102807933A
- Authority
- CN
- China
- Prior art keywords
- setting adhesive
- percent
- acid ester
- fatty acid
- aeo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 22
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 22
- 239000012459 cleaning agent Substances 0.000 title abstract 4
- 238000002360 preparation method Methods 0.000 title description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 26
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 15
- -1 dehydrated sorbitol fatty acid ester Chemical class 0.000 claims abstract description 13
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 13
- 239000000194 fatty acid Substances 0.000 claims abstract description 13
- 229930195729 fatty acid Natural products 0.000 claims abstract description 13
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 11
- 239000001257 hydrogen Substances 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims abstract description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 13
- 150000002430 hydrocarbons Chemical class 0.000 claims description 13
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 12
- 235000017550 sodium carbonate Nutrition 0.000 claims description 12
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 10
- 239000000600 sorbitol Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- AYAUBWSUZRFVQO-UHFFFAOYSA-N 2-[2-(4-phenyl-5-sulfanylidene-1h-1,2,4-triazol-3-yl)ethyl]benzo[de]isoquinoline-1,3-dione Chemical compound O=C1C(C=23)=CC=CC3=CC=CC=2C(=O)N1CCC1=NNC(=S)N1C1=CC=CC=C1 AYAUBWSUZRFVQO-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000000047 product Substances 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 4
- 239000006210 lotion Substances 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 4
- 238000005303 weighing Methods 0.000 claims description 4
- 238000005984 hydrogenation reaction Methods 0.000 claims description 2
- 239000000706 filtrate Substances 0.000 claims 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 230000009972 noncorrosive effect Effects 0.000 abstract 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract 1
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 1
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 1
- 239000000341 volatile oil Substances 0.000 abstract 1
- 241000196324 Embryophyta Species 0.000 description 11
- 239000004033 plastic Substances 0.000 description 6
- 229920003023 plastic Polymers 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000005976 Citrus sinensis Nutrition 0.000 description 1
- 240000002319 Citrus sinensis Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 201000004681 Psoriasis Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
The invention relates to a cleaning agent, in particular to an environment-friendly, non-corrosive, high-efficient and energy-saving non-setting adhesive cleaning agent with nano submarine natural factors, and the non-setting adhesive cleaning agent is prepared by mixing and reacting following ingredients in percentage by mass: 10 to 20 percent of alkane, 60 to 80 percent of isomeric alkane, 3 to 5 percent of sodium carbonate, 3 to 5 percent of aluminum oxide, 0.3 to 0.5 percent of fatty alcohol-polyoxyethylene ether, 1.0 to 1.5 percent of dehydrated sorbitol fatty acid ester; 1 to 2 percent of essential oil of natural ocean plants and 1 percent by volume ratio of hydrogen.
Description
Technical field
The present invention relates to a kind of clean-out system, especially a kind of environmental protection, non-corrosiveness, have energy-efficient non-setting adhesive clean-out system of the natural factor in nanometer seabed and preparation method thereof.
Background technology
Vast city in China, it is very rampant to do illegal small advertisement such as false evidence, trick " public relations ", its serious harm social conduct, stained buildings and communal facility view.Use conventional approach to be difficult to take effect to the removing of " city psoriasis "; It is to cost an arm and a leg that the method homemade " sensitive material reagent " of import now, Singapore produce " specific reaction agent " and domestic Guangzhou product " the grain grain makes the one spray spirit of non-setting adhesive paster " etc.; The 2nd, it is slow to take effect, thereby relevant departments such as appearance of the city municipal administration are difficult to accept; Plastics such as the Plastic Bottle of salvage station recovery, plastic tank, basin often post adhesive label in addition, and adhesive label is moulded base, paper substrate, paper substrate overlay film etc., and these labels have a strong impact on the quality of reprocessed plastic(s), must clean and remove the use of could regenerating.Just need develop and a kind ofly can thoroughly clean up adhesive label this moment, make do not have stationery in the plastics, glue class impurity, raising plastics quality has been improved urban environment simultaneously, living environment makes modern metropolitan cities be tending towards the environmental protection low-carbon (LC).
Summary of the invention
The present invention is directed to the energy-efficient non-setting adhesive clean-out system that above-mentioned technical problem provides a kind of environmental protection, non-corrosiveness, has the natural factor in nanometer seabed.
This non-setting adhesive clean-out system, it carries out hybrid reaction through paraffinic hydrocarbons, isomeric alkane, yellow soda ash, aluminium sesquioxide, AEO, sorbitan fatty acid ester, natural marine essence oil from plant and hydrogen with the ratio of following quality percentage composition and processes:
Paraffinic hydrocarbons: 10-20%;
Isomeric alkane: 60 ~ 80%;
Yellow soda ash: 3-5%;
Aluminium sesquioxide: 3 ~ 5%;
AEO: 0.3 ~ 0.5%;
Anhydrous sorbitol fatty acid ester: 1.0 ~ 1.5%;
Natural marine essence oil from plant: 1 ~ 2%;
Hydrogen: volume ratio 1%.
Preferably, this clean-out system is to be that 10% paraffinic hydrocarbons, 75% isomeric alkane, 5% yellow soda ash, 5% aluminium sesquioxide, 0.5% AEO, 1.5% anhydrous sorbitol fatty acid ester, 2% natural marine essence oil from plant and volume ratio are that 1% hydrogen carries out hybrid reaction and processes by the quality percentage composition.
The present invention also provides a kind of method for preparing above-mentioned non-setting adhesive clean-out system, comprises the steps:
The first step takes by weighing paraffinic hydrocarbons, isomeric alkane, yellow soda ash, aluminium sesquioxide, AEO and anhydrous sorbitol fatty acid ester in proportion and packs in the airtight mixing vessel, under 35-45 ℃ of normal pressure, mixes;
Second step added the natural marine essence oil from plant, under the 2-5MPa pressure environment, reversed to be stirred to evenly;
In the 3rd step, hydrogenation is exquisite to be handled, and staticly settles after-filtration and purifies, and carries out packing behind the constant temperature to be filtrated (about 20 ℃) and forms the non-setting adhesive lotion product.
This technical scheme compared with prior art has following beneficial effect:
1. this clean-out system environmental protection, no burn into have added natural marine essence oil from plant and a large amount of polymer cleaning particles, and cleaning performance has breakthrough lifting, and technical feature is leading.
2. cost, save energy have been reduced more than 50%.
Specific embodiment
This non-setting adhesive clean-out system provided by the present invention, it carries out hybrid reaction through paraffinic hydrocarbons, isomeric alkane, yellow soda ash, aluminium sesquioxide, AEO and anhydrous sorbitol fatty acid ester, natural marine essence oil from plant and hydrogen with the ratio of following quality percentage composition and processes:
Paraffinic hydrocarbons: 10-20%; Isomeric alkane: 60 ~ 80%; Yellow soda ash: 3-5%; Aluminium sesquioxide: 3 ~ 5%; AEO: 0.3 ~ 0.5%; Anhydrous sorbitol fatty acid ester: 1.0 ~ 1.5%; Natural marine essence oil from plant: 1 ~ 2%; Hydrogen: volume ratio is 1%.
Wherein, paraffinic hydrocarbons is the straight-chain paraffin of 2-6 carbon; Isomeric alkane is the oil-based solvent of 10-18 carbon atom; AEO, its general formula is: R-O-(CH
2CH
2O)
n-H, R are that saturated or unsaturated C number is 12 ~ 18 alkyl, can be straight-chain alkyls, also can be branched alkyl, n=6 ~ 8, and the preferred fat polyoxyethylenated alcohol is the AEO series of surfactants; The natural marine essence oil from plant be utilize marine alga, sweet orange, etc. the part such as flower, leaf, root, skin, stem, branch, fruit, seed of ocean scented plants; The oily mater that take to distill, method such as squeezing, extraction, absorption makes with characteristic perfume; In order to prolong its work-ing life; Let its effect keep for a long time; The long-acting natural phant lasting agent with sustained release performance that can also prepare through advanced person's high molecular nanometer microencapsulation technology at present, just industrial essence, the mask agent of using always in a kind of heavy chemicals field.
Below with the preparation 100KG the non-setting adhesive clean-out system specify this non-setting adhesive clean-out system provided by the present invention with and concrete preparation method.
Embodiment 1:
The anhydrous sorbitol fatty acid ester that takes by weighing AEO, the 1.5Kg of yellow soda ash, 5Kg aluminium sesquioxide, the 0.5Kg of isomeric alkane, the 5Kg of paraffinic hydrocarbons, the 75Kg of 10Kg is respectively packed in the airtight reaction vessel, utilization mixing tank or similar variable-ratio machine (having suitable general the mixing and kneading operation of thruster) stirring 1.5 hours under 35 ℃ of normal pressures; Add 2Kg natural marine essence oil from plant again; Under the 2MPa pressure environment, reverse and stirred 30 minutes; Last 1% the hydrogen of adding by volume carries out exquisiteness and handles, and staticly settles after-filtration and purifies, and carries out packing formation non-setting adhesive lotion product behind the constant temperature to be filtrated (about 20 ℃).
Embodiment 2:
The anhydrous sorbitol fatty acid ester that takes by weighing AEO, the 1.5Kg of yellow soda ash, 6Kg aluminium sesquioxide, the 0.5Kg of isomeric alkane, the 4Kg of paraffinic hydrocarbons, the 70Kg of 15Kg is respectively packed in the airtight reaction vessel, utilization mixing tank or similar variable-ratio machine (having suitable general the mixing and kneading operation of thruster) stirring 2 hours under 45 ℃ of normal pressures; Add 2Kg natural marine essence oil from plant again; Under the 5MPa pressure environment, reverse and stirred 30 minutes; Last 1% the hydrogen of adding by volume carries out exquisiteness and handles, and staticly settles after-filtration and purifies, and carries out packing formation non-setting adhesive lotion product behind the constant temperature to be filtrated (about 20 ℃).
Above disclosedly be merely some preferred embodiments of the present invention, can not limit the present invention's interest field certainly with this, the equivalent variations of therefore doing according to claim of the present invention still belongs to the scope that the present invention is contained.
Claims (3)
1. non-setting adhesive clean-out system, it carries out hybrid reaction through paraffinic hydrocarbons, isomeric alkane, yellow soda ash, aluminium sesquioxide, AEO, sorbitan fatty acid ester, natural marine essence oil from plant and hydrogen with the ratio of following quality percentage composition and processes:
Paraffinic hydrocarbons: 10-20%;
Isomeric alkane: 60 ~ 80%;
Yellow soda ash: 3-5%;
Aluminium sesquioxide: 3 ~ 5%;
AEO: 0.3 ~ 0.5%;
Anhydrous sorbitol fatty acid ester: 1.0 ~ 1.5%;
Natural marine essence oil from plant: 1 ~ 2%;
Hydrogen: volume ratio 1%.
2. non-setting adhesive clean-out system as claimed in claim 1; It is characterized in that its quality percentage composition is that 10% paraffinic hydrocarbons, 75% isomeric alkane, 5% yellow soda ash, 5% aluminium sesquioxide, 0.5% AEO, 1.5% anhydrous sorbitol fatty acid ester, 2% natural marine essence oil from plant and volume ratio are that 1% hydrogen carries out hybrid reaction and processes.
3. one kind prepares the method for non-setting adhesive clean-out system according to claim 1 or claim 2, and it comprises the steps:
The first step takes by weighing paraffinic hydrocarbons, isomeric alkane, yellow soda ash, aluminium sesquioxide, AEO and anhydrous sorbitol fatty acid ester in proportion and packs in the airtight mixing vessel, under 35-45 ℃ of normal pressure, mixes;
Second step added the natural marine essence oil from plant, under the 2-5MPa pressure environment, reversed to be stirred to evenly;
In the 3rd step, hydrogenation is exquisite to be handled, and staticly settles after-filtration and purifies, and carries out packing behind the constant temperature of waiting to filtrate and forms the non-setting adhesive lotion product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210305159.5A CN102807933B (en) | 2012-08-24 | 2012-08-24 | Non-setting adhesive cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210305159.5A CN102807933B (en) | 2012-08-24 | 2012-08-24 | Non-setting adhesive cleaning agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102807933A true CN102807933A (en) | 2012-12-05 |
| CN102807933B CN102807933B (en) | 2014-04-09 |
Family
ID=47231805
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210305159.5A Expired - Fee Related CN102807933B (en) | 2012-08-24 | 2012-08-24 | Non-setting adhesive cleaning agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102807933B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103789108A (en) * | 2014-03-05 | 2014-05-14 | 宫翊 | Gel scavenger for mucilage glue and asphalt |
| CN103849496A (en) * | 2014-03-19 | 2014-06-11 | 广州麦饭石化工技术有限公司 | Adhesive residue detergent of adhesive sticker and production process of adhesive residue detergent |
| CN107629896A (en) * | 2017-10-09 | 2018-01-26 | 安徽源美广告传媒有限公司 | A kind of adhesive sticker cleaning agent and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1490390A (en) * | 2003-09-17 | 2004-04-21 | 刘凤雷 | Stain cleaning agent for pressure-sensitive adhesive and chewing gum |
| CN1524939A (en) * | 2003-09-15 | 2004-09-01 | 李伟光 | Multifunctional scrubbing cleanser |
| CN1524940A (en) * | 2003-02-27 | 2004-09-01 | 顺 梁 | Cleaning agent for remnant of chewing gum glue and self-adhesive glue |
| CN101130718A (en) * | 2006-08-23 | 2008-02-27 | 荆门市良龙化工有限公司 | Compositions for cleaning ''scaly tetter'' and processes for producing same |
-
2012
- 2012-08-24 CN CN201210305159.5A patent/CN102807933B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1524940A (en) * | 2003-02-27 | 2004-09-01 | 顺 梁 | Cleaning agent for remnant of chewing gum glue and self-adhesive glue |
| CN1524939A (en) * | 2003-09-15 | 2004-09-01 | 李伟光 | Multifunctional scrubbing cleanser |
| CN1490390A (en) * | 2003-09-17 | 2004-04-21 | 刘凤雷 | Stain cleaning agent for pressure-sensitive adhesive and chewing gum |
| CN101130718A (en) * | 2006-08-23 | 2008-02-27 | 荆门市良龙化工有限公司 | Compositions for cleaning ''scaly tetter'' and processes for producing same |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103789108A (en) * | 2014-03-05 | 2014-05-14 | 宫翊 | Gel scavenger for mucilage glue and asphalt |
| CN103849496A (en) * | 2014-03-19 | 2014-06-11 | 广州麦饭石化工技术有限公司 | Adhesive residue detergent of adhesive sticker and production process of adhesive residue detergent |
| CN103849496B (en) * | 2014-03-19 | 2016-08-17 | 广州麦饭石化工技术有限公司 | A kind of adhesive sticker removing residual glue stain cleanser and production technology thereof |
| CN107629896A (en) * | 2017-10-09 | 2018-01-26 | 安徽源美广告传媒有限公司 | A kind of adhesive sticker cleaning agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102807933B (en) | 2014-04-09 |
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| C14 | Grant of patent or utility model | ||
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Owner name: HUASHENG TECH CO., LTD., SHENZHEN CITY Free format text: FORMER OWNER: LIU JIE Effective date: 20150331 |
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| TR01 | Transfer of patent right |
Effective date of registration: 20150331 Address after: Longgang District of Shenzhen City, Guangdong province 518112 streets of Buji hundred star city building D 5H Patentee after: Huasheng Tech Co., Ltd., Shenzhen City Address before: Longgang District of Shenzhen City, Guangdong province 518112 streets of Buji hundred star city building D 5H Patentee before: Liu Jie |
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| CF01 | Termination of patent right due to non-payment of annual fee |
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