CN102807331A - Alkali-containing glass fiber direct roving sizing agent for spinning - Google Patents
Alkali-containing glass fiber direct roving sizing agent for spinning Download PDFInfo
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- CN102807331A CN102807331A CN2011101451955A CN201110145195A CN102807331A CN 102807331 A CN102807331 A CN 102807331A CN 2011101451955 A CN2011101451955 A CN 2011101451955A CN 201110145195 A CN201110145195 A CN 201110145195A CN 102807331 A CN102807331 A CN 102807331A
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Abstract
The invention provides an alkali-containing glass fiber direct roving sizing agent for spinning, and relates to a formula of a sizing agent. The formula consists of a coupling agent, a lubricant A, a lubricant B, epoxy resin emulsion, modified polyester resin emulsion, an auxiliary filmogen, a special additive, an antistatic agent and deionized water. By the sizing agent, the performance of alkali-containing glass fiber direct roving can be improved, a small quantity of feathers are generated in weaving, the breaking tenacity of the direct roving is high, and the production performance and application performance are high.
Description
Technical field:
The present invention relates to a kind of prescription of treating compound, be specifically related to a kind of weaving with the direct roving sizing agent of medium-alkali glass fibre.
Background technology:
At present, China's medium-alkali glass fibre development is swift and violent, but general quality is not high; Especially handling huge weaving with medium-alkali glass fibre in the direct yarn process; The problem that exists is that the filoplume amount that produces in weaving is bigger, and the breaking tenacity of yarn is lower, and the production technique more complicated.
Summary of the invention:
The purpose of this invention is to provide a kind of weaving with the direct roving sizing agent of medium-alkali glass fibre; It can improve the performance of the direct roving of medium-alkali glass fibre; The filoplume amount of weaving generation is fewer, and directly the breaking tenacity of roving has production performance and application performance preferably than higher.
In order to solve the existing problem of background technology, the present invention takes following technical scheme: its prescription consists of: coupling agent, lubricant A, lubricant B, epoxy resin latex; The modified polyester resin fat liquor; Secondary film formers, specialist additive, static inhibitor and deionized water.
The solid masses of said treating compound accounts for the 5-15% of treating compound total mass, and surplus is a deionized water, and deionized water accounts for the 85-95% of treating compound total mass.
Described coupling agent is vinyl silicane coupling agent, amino silicane coupling agent, and epoxy silane coupling a kind of accounts for the 0.1-2.0% of treating compound solid masses.
Described lubricant A is a nonionogenic tenside, adopts polyethenoxy ether class, the ester class, and amides, a kind of in the chemical modification mineral oils accounts for the 1-20% of treating compound solid masses.
Described lubricant B is a cats product, adopts a kind of in T 46155 ammonia salt, quaternary ammonium salt, the tetrahydroglyoxaline, accounts for the 0.1-5.0% of treating compound solid masses.
Described epoxy resin latex is the epoxy resin emulsion that the method through outer emulsification and internal emulsification makes, and accounts for the 10-30% of treating compound solid masses.
Described modified polyester resin fat liquor is the epoxy resin emulsion that the method through outer emulsification and internal emulsification makes, and accounts for the 5-25% of treating compound solid masses.
Described secondary film formers adopt through the chemical process modification can be water-soluble modified epoxy or vibrin, account for the 1-20% of treating compound solid masses.
Described specialist additive adopts a kind of in mineral acid, organic acid, the bases PH regulator, accounts for the 0.1-5.0% of treating compound solid masses.
Described static inhibitor adopts has strong water-retaining capacity inorganic salts material, accounts for the 0.1-6.0% of treating compound solid masses.
Compound method of the present invention is: coupling agent and specialist additive disperse with its weight 30-60 deionized water and stirring doubly; Lubricant A and lubricant B carry out dissolved dilution with 60-70 ℃ warm water; All the other raw materials carry out dissolved dilution with its weight 2-5 water doubly, add deionized water at last quantitatively to required gross weight.
The present invention has following beneficial effect: it can improve the performance of the direct roving of medium-alkali glass fibre, and the filoplume amount of weaving generation is fewer, and directly the breaking tenacity of roving has production performance and application performance preferably than higher.
Embodiment:
This embodiment is taked following technical scheme: its prescription consists of: coupling agent, lubricant A, lubricant B, epoxy resin latex, modified polyester resin fat liquor, secondary film formers, specialist additive, static inhibitor and deionized water.
The solid masses of said treating compound accounts for 15% of treating compound total mass, and surplus is a deionized water, and deionized water accounts for 85% of treating compound total mass.
Described coupling agent is vinyl silicane coupling agent, amino silicane coupling agent, and epoxy silane coupling accounts for 2.0% of treating compound solid masses.
Described lubricant A is a nonionogenic tenside, adopts polyethenoxy ether class, the ester class, amides, chemical modification mineral oils a kind of, account for the treating compound solid masses 20%.
Described lubricant B is a cats product, adopts a kind of in T 46155 ammonia salt, quaternary ammonium salt, the tetrahydroglyoxaline, accounts for 5.0% of treating compound solid masses.
Described epoxy resin latex is the epoxy resin emulsion that the method through outer emulsification and internal emulsification makes, and accounts for 20% of treating compound solid masses.
Described modified polyester resin fat liquor is the epoxy resin emulsion that the method through outer emulsification and internal emulsification makes, and accounts for 25% of treating compound solid masses.
Described secondary film formers adopt through the chemical process modification can be water-soluble modified epoxy or vibrin, account for 20% of treating compound solid masses.
Described specialist additive adopts a kind of in mineral acid, organic acid, the bases PH regulator, accounts for 5.0% of treating compound solid masses.
Described static inhibitor adopts has strong water-retaining capacity inorganic salts material, accounts for 3.0% of treating compound solid masses.
The compound method of this embodiment is: coupling agent and specialist additive are disperseed with the deionized water and stirring of 50 times of its weight; Lubricant A and lubricant B carry out dissolved dilution with 70 ℃ warm water; All the other raw materials carry out dissolved dilution with the water of 3 times of its weight, add deionized water at last quantitatively to required gross weight.
This embodiment can improve the performance of the direct roving of medium-alkali glass fibre, and the filoplume amount of weaving generation is fewer, and directly the breaking tenacity of roving has production performance and application performance preferably than higher.
Claims (10)
1. a weaving is characterized in that with the direct roving sizing agent of medium-alkali glass fibre its prescription consists of: coupling agent, lubricant A, lubricant B, epoxy resin latex; The modified polyester resin fat liquor; Secondary film formers, specialist additive, static inhibitor and deionized water.
2. a kind of weaving according to claim 1 is characterized in that with the direct roving sizing agent of medium-alkali glass fibre the solid masses of said treating compound accounts for the 5-15% of treating compound total mass, and surplus is a deionized water, and deionized water accounts for the 85-95% of treating compound total mass.
3. a kind of weaving according to claim 1 is with the direct roving sizing agent of medium-alkali glass fibre; It is characterized in that described coupling agent is vinyl silicane coupling agent, amino silicane coupling agent; Epoxy silane coupling a kind of accounts for the 0.1-2.0% of treating compound solid masses.
4. a kind of weaving according to claim 1 is characterized in that with the direct roving sizing agent of medium-alkali glass fibre described lubricant A is a nonionogenic tenside, adopts polyethenoxy ether class; The ester class; Amides, a kind of in the chemical modification mineral oils accounts for the 1-20% of treating compound solid masses.
5. a kind of weaving according to claim 1 is with the direct roving sizing agent of medium-alkali glass fibre; It is characterized in that described lubricant B is a cats product; Adopt a kind of in T 46155 ammonia salt, quaternary ammonium salt, the tetrahydroglyoxaline, account for the 0.1-5.0% of treating compound solid masses.
6. a kind of weaving according to claim 1 is with the direct roving sizing agent of medium-alkali glass fibre, it is characterized in that described epoxy resin latex is the epoxy resin emulsion that the method through outer emulsification and internal emulsification makes, and accounts for the 10-30% of treating compound solid masses.
7. a kind of weaving according to claim 1 is with the direct roving sizing agent of medium-alkali glass fibre; It is characterized in that described modified polyester resin fat liquor is the epoxy resin emulsion that the method through outer emulsification and internal emulsification makes, and accounts for the 5-25% of treating compound solid masses.
8. a kind of weaving according to claim 1 is with the direct roving sizing agent of medium-alkali glass fibre; It is characterized in that described secondary film formers adopt through the chemical process modification can be water-soluble modified epoxy or vibrin, account for the 1-20% of treating compound solid masses.
9. a kind of weaving according to claim 1 is with the direct roving sizing agent of medium-alkali glass fibre, it is characterized in that described specialist additive adopts a kind of in mineral acid, organic acid, the bases PH regulator, accounts for the 0.1-5.0% of treating compound solid masses.
10. a kind of weaving according to claim 1 is characterized in that with the direct roving sizing agent of medium-alkali glass fibre described static inhibitor employing has strong water-retaining capacity inorganic salts material, accounts for the 0.1-6.0% of treating compound solid masses.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101451955A CN102807331A (en) | 2011-06-01 | 2011-06-01 | Alkali-containing glass fiber direct roving sizing agent for spinning |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2011101451955A CN102807331A (en) | 2011-06-01 | 2011-06-01 | Alkali-containing glass fiber direct roving sizing agent for spinning |
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| CN102807331A true CN102807331A (en) | 2012-12-05 |
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| CN2011101451955A Pending CN102807331A (en) | 2011-06-01 | 2011-06-01 | Alkali-containing glass fiber direct roving sizing agent for spinning |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103466963A (en) * | 2013-09-10 | 2013-12-25 | 西安友基复合材料有限公司 | Alkali-resistant chopped glass fiber soakage agent |
| CN103911865A (en) * | 2013-12-31 | 2014-07-09 | 上海宏和电子材料有限公司 | Electronic-grade glass fiber cloth edge banding agent material |
| CN104556740A (en) * | 2013-10-17 | 2015-04-29 | 江西大华云通玻纤有限公司 | Formula of impregnating compound for glass fiber twisted yarn for textile use |
| CN105152550A (en) * | 2015-08-10 | 2015-12-16 | 巨石集团有限公司 | Impregnating agent for highly-universal alkali-free glass fiber direct roving |
| CN105174750A (en) * | 2015-09-02 | 2015-12-23 | 巨石集团有限公司 | Impregnating agent for winding reinforcement medium-alkali glass fiber direct yarns |
| CN105541126A (en) * | 2015-12-18 | 2016-05-04 | 中材科技股份有限公司 | Resin compatible type glass fiber yarn impregnation agent, and preparation method thereof |
| CN105585256A (en) * | 2015-12-18 | 2016-05-18 | 中材科技股份有限公司 | High-performance fiberglass winding yarn sizing agent and preparation method thereof |
| CN106630682A (en) * | 2016-12-07 | 2017-05-10 | 巨石集团有限公司 | Impregnating compound of textile GF/PP complex fiber direct yarn |
| CN110104966A (en) * | 2019-05-30 | 2019-08-09 | 韦俊刚 | A kind of preparation method of high bond strength size |
| CN113666647A (en) * | 2021-07-09 | 2021-11-19 | 山东玻纤集团股份有限公司 | Preparation method of high-performance direct twistless roving |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0940443A (en) * | 1995-07-27 | 1997-02-10 | Nitto Boseki Co Ltd | Bundling agent for glass fiber for nonwoven fabric of glass fiber and glass fiber stuck therewith |
| CN101100355A (en) * | 2007-06-12 | 2008-01-09 | 巨石集团有限公司 | Soaking agent capable of increasing glass fiber acid resistance |
| CN101100356A (en) * | 2007-06-12 | 2008-01-09 | 巨石集团有限公司 | Direct untwisted roving soaking agent |
| CN101439937A (en) * | 2008-11-24 | 2009-05-27 | 上海世鹏聚氨酯科技发展有限公司 | Reinforced textile type glass fiber treating compound and preparation thereof |
| CN101553443A (en) * | 2006-02-27 | 2009-10-07 | Ocv智识资本有限责任公司 | Sizing for high performance glass fibers and composite materials incorporating same |
| CN101633567A (en) * | 2009-08-17 | 2010-01-27 | 巨石集团有限公司 | Glass fiber impregnating agent for transparent plate |
-
2011
- 2011-06-01 CN CN2011101451955A patent/CN102807331A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0940443A (en) * | 1995-07-27 | 1997-02-10 | Nitto Boseki Co Ltd | Bundling agent for glass fiber for nonwoven fabric of glass fiber and glass fiber stuck therewith |
| CN101553443A (en) * | 2006-02-27 | 2009-10-07 | Ocv智识资本有限责任公司 | Sizing for high performance glass fibers and composite materials incorporating same |
| CN101100355A (en) * | 2007-06-12 | 2008-01-09 | 巨石集团有限公司 | Soaking agent capable of increasing glass fiber acid resistance |
| CN101100356A (en) * | 2007-06-12 | 2008-01-09 | 巨石集团有限公司 | Direct untwisted roving soaking agent |
| CN101439937A (en) * | 2008-11-24 | 2009-05-27 | 上海世鹏聚氨酯科技发展有限公司 | Reinforced textile type glass fiber treating compound and preparation thereof |
| CN101633567A (en) * | 2009-08-17 | 2010-01-27 | 巨石集团有限公司 | Glass fiber impregnating agent for transparent plate |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103466963A (en) * | 2013-09-10 | 2013-12-25 | 西安友基复合材料有限公司 | Alkali-resistant chopped glass fiber soakage agent |
| CN104556740A (en) * | 2013-10-17 | 2015-04-29 | 江西大华云通玻纤有限公司 | Formula of impregnating compound for glass fiber twisted yarn for textile use |
| CN103911865B (en) * | 2013-12-31 | 2016-05-11 | 上海宏和电子材料有限公司 | Electronic-grade glass fiber cloth edge sealing agent material |
| CN103911865A (en) * | 2013-12-31 | 2014-07-09 | 上海宏和电子材料有限公司 | Electronic-grade glass fiber cloth edge banding agent material |
| CN105152550A (en) * | 2015-08-10 | 2015-12-16 | 巨石集团有限公司 | Impregnating agent for highly-universal alkali-free glass fiber direct roving |
| CN105152550B (en) * | 2015-08-10 | 2018-11-30 | 巨石集团有限公司 | A kind of size of the direct yarn of highly versatile alkali-free glass fibre |
| CN105174750A (en) * | 2015-09-02 | 2015-12-23 | 巨石集团有限公司 | Impregnating agent for winding reinforcement medium-alkali glass fiber direct yarns |
| CN105541126A (en) * | 2015-12-18 | 2016-05-04 | 中材科技股份有限公司 | Resin compatible type glass fiber yarn impregnation agent, and preparation method thereof |
| CN105585256A (en) * | 2015-12-18 | 2016-05-18 | 中材科技股份有限公司 | High-performance fiberglass winding yarn sizing agent and preparation method thereof |
| CN106630682A (en) * | 2016-12-07 | 2017-05-10 | 巨石集团有限公司 | Impregnating compound of textile GF/PP complex fiber direct yarn |
| CN110104966A (en) * | 2019-05-30 | 2019-08-09 | 韦俊刚 | A kind of preparation method of high bond strength size |
| CN113666647A (en) * | 2021-07-09 | 2021-11-19 | 山东玻纤集团股份有限公司 | Preparation method of high-performance direct twistless roving |
| CN113666647B (en) * | 2021-07-09 | 2022-11-15 | 山东玻纤集团股份有限公司 | Preparation method of high-performance direct twistless roving |
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| ASS | Succession or assignment of patent right |
Owner name: JIANGXI DAHUA YUNTONG FIBERGLASS CO., LTD. Free format text: FORMER OWNER: JIANGXI DAHUA FIBERGLASS GROUP CO., LTD. Effective date: 20140320 |
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| C41 | Transfer of patent application or patent right or utility model | ||
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Effective date of registration: 20140320 Address after: 330700 Fengxin Industrial Park, Fengxin, Jiangxi, Yichun Applicant after: JIANGSU DAHUA YUNTONG FIBERGLASS GROUP CO., LTD. Address before: 330700 Yichun Economic Development Zone, Fengxin County, Jiangxi Applicant before: Jiangxi Dahua Fiberglass Group Co., Ltd. |
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| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20121205 |