CN102783691A - Calcium-magnesium hydrogen producing agent - Google Patents
Calcium-magnesium hydrogen producing agent Download PDFInfo
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- CN102783691A CN102783691A CN2012102960073A CN201210296007A CN102783691A CN 102783691 A CN102783691 A CN 102783691A CN 2012102960073 A CN2012102960073 A CN 2012102960073A CN 201210296007 A CN201210296007 A CN 201210296007A CN 102783691 A CN102783691 A CN 102783691A
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Abstract
The invention discloses a calcium-magnesium hydrogen producing agent, of which the main component is a hydrogen producing agent. The hydrogen producing agent is selected from one or various combination of calcium hydride, magnesium hydride, calcium hydroxide magnesium, magnesium-magnesium hydride, calcium-calcium hydride, magnesium-calcium hydride, calcium-magnesium hydride, calcium-magnesium-magnesium hydride, calcium-magnesium-calcium hydride, calcium-magnesium-magnesium hydride-calcium hydride, coral calcium hydroxide magnesium, Na MgH3, and Mg2FeH6. the calcium-magnesium hydrogen producing agent can be added into water, beverage or wine as an additive, or can be coated on the surface of skin or taken as soaking liquid to remove internal or surface active oxygen. The calcium-magnesium hydrogen producing agent has a remarkable prompting effect for recovering various oxidized damages, relieving discomfort caused by drinking, diluting stain and wrinkle of the skin, recovering skin elasticity, and delaying senescence.
Description
Technical field
The present invention relates to a kind of anti-oxidant, antidotal compound health preparation.
Background technology
Superfluous active oxygen causes the oxidative damage of DNA, lipid and albumen to constituting histiocytic large biological molecule chemical constitution generation breaking reaction, and wherein the toxicity of hydroxy radical (OH) is the strongest.Progressively expansion along with destroying level can damage normal tissues form and functional integrity property.When degree of injury surpassed reparation or loses its compensatory capacity, the function of histoorgan just progressively got muddled and obstacle, showed body and was tending towards old and feeble gradually.At present, there is the scholar to adopt means such as chemical reaction, cytology, proved that hydrogen is dissolved in the OH in the alternative scavenger-cell system in the liquid.Medical circle also found successively hydrogen can be in cytoprotection and visceral organ injury protection the anti-oxidant and antiinflammatory action of performance.The biological antioxidant effect of hydrogen has high-definition characteristics: at first, the reproducibility of hydrogen is more weak, the reactive oxygen species of only strong and strong toxicity with activity, and not with the reactive oxygen species with signal of interest effect, this is the oxidation resistant basis of hydrogen selectivity; Secondly, the product of hydrogen and radical reaction is also very simple, and for example with the hydroxy radical water generation reaction, unnecessary hydrogen can excrete through breathing, does not have any residually, and this obviously is different from other polyphenoils.
Desire to make and contain more hydrogen in the water, it is one of them way that Xiang Shuizhong charges into hydrogen, but because the low effusion easily of hydrogen solubility in water, and rich hydrogen water can't be preserved.Brine electrolysis also can make and be rich in hydrogen in the water, but brine electrolysis needs comparatively complicated apparatus, and is not easy to carry, and when material in the water was comparatively complicated, electrolysis also possibly produce some to the disadvantageous accessory substance of human body.Adopting the magnesium chemical reduction method is the convenient at present rich hydrogen water method commonly used of producing fast.Woods show light patent " rich hydrogen water generation method and rich hydrogen Water generator " CN 1840487A promptly adopts magnesium granules and the silver-colored particle and the water reaction of crossing through sintering processes, by the rich hydrogen water of silver-colored particulate burning purifying.Huo Tian increases utility model patent " hydrogen water generator " CN 201785234U, and wherein effectively inserts also is a magnesium.Zhang Huiyan " a kind of efficient rich hydrogen water generation method " CN102259939A then adopted add iron as the method for catalyst to accelerate the reaction of magnesium and water.
The common defective of above-mentioned each patent is magnesium and a water sluggish under the normal temperature; And the magnesium hydroxide that reaction generates can stop the further reaction of hydrogen manufacturing agent and water, must clean with acid in use for some time and remove; Make troubles to use; The sediment magnesium hydroxide can not effectively utilize simultaneously, and partly soluble magnesium hydroxide gets into drinking water, suppresses the absorption of calcium in the time of possibly causing independent benefit magnesium and intake too high; If merge renal dysfunction even might cause hypermagnesemia, suppress central nervous system.
Inventor's patent formerly " rich hydrogen water additive of a kind of calcium magnesium and preparation method thereof " though solved above-mentioned technical problem to a certain extent, as preliminary solution, still has certain expanding space.
Summary of the invention
The technical problem that the present invention will solve provides a kind of calcium magnesium hydrogen manufacturing agent; It can be used as additive and adds in entry, beverage or the wine; Also can be applied in skin surface or as soak; Can remove in the body or the active oxygen of body surface, to the recovery of various oxidative damages, alleviate the uncomfortable and desalination skin that causes of drinking color spot, wrinkle, recovery skin elasticity, delaying senility all has obvious facilitation.
For solving the problems of the technologies described above, the technical scheme that the present invention taked is following.
A kind of calcium magnesium hydrogen manufacturing agent; Its key component is the hydrogen manufacturing agent, and this hydrogen manufacturing agent is selected from calcium hydride, magnesium hydride, calcium hydride magnesium, magnesium-magnesium hydride, calcium-calcium hydride, magnesium-calcium hydride, calcium-magnesium hydride, calcium magnesium-magnesium hydride, calcium magnesium-calcium hydride, calcium magnesium-magnesium hydride-calcium hydride, coral calcium hydride magnesium, NaMgH
3, Mg
2FeH
6In one or more combinations.
As a kind of optimal technical scheme of the present invention, also comprise calcium magnesium simple substance or calcium-magnesium alloy in its component.
As a kind of optimal technical scheme of the present invention, the general formula of said hydrogen manufacturing agent can be designated as M
xCa
yMg
zH
n/ mA, wherein M is one or more combinations among Na, K, Fe, Zn, the Mn, X=0～2, y=0～2, z=0～2, n=0～6; The oxidation state of Ca, Mg is 0～2; A is metal oxide, non-metal simple-substance or nonmetal oxide, preferred TiO
2, MgO, Fe
2O
3, Fe
3O
4, SiO
2, C (active carbon, carbon fiber, carbon black, graphite, CNT); M is hydrogen manufacturing agent and A mass ratio, and m preferred 1/10～10/0.25.
As a kind of optimal technical scheme of the present invention, also comprise the pH conditioning agent in its component; This pH conditioning agent is selected from amion acetic acid; Citric acid; Gluconic acid; Glucolactone; Threonic acid; Lysine; The L-lysine hydrochloride; Anhydrous citric acid; The L-ascorbic acid; Daucic acid; Malic acid; L MALIC ACID; Pimelic acid; Niter cake; Tartaric acid or its acid salt; Metatartaric acid or its acid salt; Alanine or its salt; Tranexamic acid or its salt; Taurine or its salt; Butanedioic acid or its acid salt; Fumaric acid or its acid salt; Adipic acid or its acid salt; One or more combinations in chlorogenic acid or its salt; The weight ratio of hydrogen manufacturing agent and pH conditioning agent is 1: (0.72～33).
As a kind of optimal technical scheme of the present invention; Also comprise calcium magnesium ratio conditioning agent in its component, this calcium magnesium ratio conditioning agent is selected from one or more combinations in calcium citrate, magnesium citrate, calcium gluconae, magnesium gluconate, calcium malate, magnesium malate, amion acetic acid calcium, amion acetic acid magnesium, calcium lysinate, lysine magnesium, threonic acid calcium, threonic acid magnesium, calcium monohydrogen phosphate, magnesium monohydrogen phosphate, calcium carbonate, magnesium carbonate, magnesium bicarbonate, the magnesium silicate; The weight ratio of calcium magnesium is 1 among hydrogen manufacturing agent, pH conditioning agent, the calcium magnesium ratio conditioning agent three: (0.25～4).
As a kind of optimal technical scheme of the present invention, also comprise bactericide in its component, this bactericide is selected from one or more in simple substance silver, collargol, Nano Silver, silver zeolite, silver pottery, silver salt, argyrol, the no acyclic polyether complex of silver; The weight ratio of bactericide and hydrogen manufacturing agent is 0.0015%～1.5%.
As a kind of optimal technical scheme of the present invention; Also comprise excipient and carrier in its component, said excipient is selected from one or more combinations in antierythrite, pregelatinized starch, Tagatose, pulullan polysaccharide, sorbierite, dolomol, CMC, starch, dextrin, colloidal silicon dioxide, microcrystalline cellulose, the sodium carboxymethylcellulose; Said carrier is selected from micropore ceramics, micropore glass, molecular sieve, palygorskite, sepiolite, medical stone, concavo-convex rod, active carbon or high pore volume silica.
As a kind of optimal technical scheme of the present invention, also comprise in its component and help absorbent and mineral matter, the said absorbent that helps is a vitamin D class additive, wherein ratio≤the 800IU:1000mg of vitamin D and calcium; Said mineral matter is lithium, strontium, zinc, iodine, selenium or potassium, and the addition of lithium, strontium, zinc, iodine, selenium or potassium is respectively 0.2～5,0.2～5,0.2～5,0.2～1,0.01～0.05,2～15 with the ratio of hydrogen manufacturing agent, and unit is: mg/mmol.
As a kind of optimal technical scheme of the present invention, also comprise metasilicic acid and carbon dioxide in its component, ratio＞25 of metasilicic acid and hydrogen manufacturing agent, unit is: mg/mmol, ratio＞250 of carbon dioxide and hydrogen manufacturing agent, unit is: mg/mmol.
As a kind of optimal technical scheme of the present invention, also comprise the help Chinese herbal medicine in its component, this help Chinese herbal medicine is selected from one or more combinations in tealeaves, safflower, chrysanthemum, date, matrimony vine, the gynostemma pentaphylla; The help Chinese herbal medicine is 1～3 with the ratio of hydrogen manufacturing agent, and unit is: g/mmol.
Adopt the beneficial effect that technique scheme produced to be:
1. calcium magnesium hydrogen manufacturing agent of the present invention adopts hydride as main hydrogen manufacturing composition, and it can more promptly react with water at low temperatures, generates hydrogeneous goods, has the characteristics of instant system; Hydride ion H-in the hydride is one of known highly basic, is very strong reducing agent; Negative hydrogen ion can not stable existence in the aqueous solution, it can be immediately with water in H
+React and generate H
2
Can also be in hydride when 2. specifically using composite calcium magnesium simple substance or its alloy; Hydride can reduce the current potential of water fast; Thereby shorten the reaction time of calcium magnesium simple substance or its alloy and water, the ratio of adjustment hydride and calcium magnesium simple substance or alloy can be adjusted the hydrogen manufacturing time easily.
3. the present invention has adopted brand-new pH conditioning agent, and these pH conditioning agents and above-mentioned hydrogen manufacturing agent be composite to have good health-care effect, specific as follows: niter cake and hydrogen manufacturing agent reaction back generate sodium sulphate; Has the reality heat in the stomach; Swing the place dirt in the intestines, moisturize brokenly knot, the effect of clearing heat for detumescence; Tartaric acid can with multiple complexing of metal ion; As anti-oxidant synergist; Can limit or prevent molecular oxidation in the body, prevent to form free radical, metatartaric acid or its acid salt tool complexing, can be combined into soluble complexes with the potassium or the calcium ion of tartrate; Make tartrate be in dissolved state, thus the generation of control deposition; Alanine has facilitation to the metabolism of prevention kidney stone, assistance glucose, also helps mitigation hypoglycemia, improves body energy; Tranexamic acid or its salt are a kind of protease inhibitors; Through the lysine-binding site on the invertibity blocking-up plasminogen molecule; Cause plasminogen can not change fibrinolysin into; Thereby effectively suppress fibrinolysis, produce the pharmacological effect of hemostasis anti-inflammatory, when restraint of tyrosinase is active, can also reduce the vigor of melanocyte; Taurine and salt thereof have strong liver cholagogic, analgesic, anti-inflammatory, step-down, hypoglycemic activity, can obviously promote neural growing and cell proliferation, differentiation, and cholesterol level has special efficacy in the blood to reducing; Butanedioic acid or its acid salt are four important in tricarboxylic acid cycle carbon dicarboxylic acids intermediate products, can suppress passive and the active cutaneous anaphylaxis; Fumarate is used to treat serious psoriasis always, also removes the destructiveness ' oxygen radical ' that discharges in the inflammatory process, in helping prevent multiple sclerosis MS, has occupied specific position as a kind of neuroprotective/anti-oxidant; Adipic acid or its acid salt are non-hygroscopic, and quite stable is used as the pH conditioning agent, and tart flavour is soft, and local flavor is lasting; Polyphenols such as chlorogenic acid are called as " the 7th type of nutrient "; Be a kind of important biological material, have antibiotic, antiviral, increase effect and beauty treatment skin moistens such as white blood cell, hepatic cholagogic, antitumor, hypotensive, reducing blood lipid, removing free radical and stimulating central nervous system system, remove characteristics such as tobacco and wine are too much.
4. calcium, magnesium metal hydride specific activity calcium metal, magnesium are higher, at room temperature just can more violent reaction take place with water, are more suitable for the cold water fast hydrogen making.
5. in addition; The present invention also has advantage: metal hydride and water reaction generate hydroxide; Make water quality present more alkaline the carrying out that also can hinder reaction simultaneously; But this hydroxide can react with the pH conditioning agent among the present invention and generate corresponding soluble-salt, can not influence the further reaction of itself and water; The hydroxide that the pH conditioning agent is useless with major part changes calcium ions and magnesium ions useful to health and that be easy to absorb into, also makes the pH value of the rich hydrogen water of calcium magnesium reach drinking water standard from the strong basicity improvement simultaneously; Additive of the present invention can be coordinated the content of calcium, magnesium ion, has solved because of mending the problem that magnesium stops the absorption of calcium and is prone to cause hypermagnesemia separately; Simultaneously, human body is Mg supplementation when replenishing calcium, can effectively promote the absorption and the deposition of calcium in bone and tooth of calcium, increases the effect of replenishing the calcium; Silver is one of body inner tissue composition; Silver ion drop output is generally the ppm level in the silver sterilization material; So to the effect of human non-toxic evil, active extremely strong Nano Silver particulate possesses superpower antibacterial ability, its antibiotic valid density is in the nanomole level; Be lower than nearly 1000 times of micromole's level of silver ion, add an amount of silver-colored sterilization material ensureing that safe drinking water is highly effective.
The specific embodiment
Following examples have specified the present invention.Various raw material used in the present invention and items of equipment are conventional commercially available prod, all can buy directly through market to obtain.
Embodiment 1
Get high pore volume silica (>2mL/g) 584g puts into ball grinder, vacuumizes the back and adds magnesium hydride 52.6g, charges into 0.1～0.3MPa hydrogen as protection gas, and mechanical ball milling disperses 5h under 350 ℃～380 ℃ conditions, makes silicon dioxide carried magnesium hydride MgH
2/ SiO
2Composite.Add amion acetic acid 60g again, L MALIC ACID 214g is sub-packed in after the mixing in the above close order bag of 350 orders, packs again.
Embodiment 2
Get SBA-15 molecular sieve 467g, put into ball grinder, vacuumize the back and add calcium hydride 42.1g, charge into 0.1～0.3MPa hydrogen as protection gas, mechanical ball milling disperses 5h under 350 ℃～380 ℃ conditions, makes silicon dioxide carried calcium hydride CaH
2/ SiO
2Composite.Add malic acid 13g again, citric acid 115g is sub-packed in after the mixing in the above close order bag of 350 orders, packs.
Embodiment 3
With gluconic acid 132g, L malic acid 256g is dissolved in 337mL water, adds high pore volume silica (>2mL/g) 365g, behind the mixing in 110 ℃ of crushed after being dried; (20Ca80Mg) is crushed to 60～250 orders with calcium-magnesium alloy, gets 39.6g powder and CaMgH
3.7227.5g be sub-packed in the close order bag more than 350 orders after the above-mentioned carrier that is loaded with gluconic acid and malic acid mixes, pack.
Embodiment 4
To be crushed to after 200～325 purpose magnesium powder 24.3g and magnesium hydride 39.5g mix; Get 31.9mg; Add calcium citrate 756mg, gluconic acid 392mg, amion acetic acid 37mg; Mix the back and add chrysanthemum 3g, be sub-packed in the heat-sealing type tea in bag filter paper, process the rich hydrogen chrysanthemum tea of calcic magnesium after the packing.
Embodiment 5
To be crushed to 100～250 purpose calcium powder and Mg/MgH
2Powder is got 57kg after mixing by weight 2.4:1, adds Tagatose 31kg, threonic acid 113kg, amion acetic acid 187kg then, mixes the back compressing tablet, overlay film, packing.
Embodiment 6
Calcium-magnesium alloy (75Ca25Mg) is pulverized 20～150 orders, get powder 69kg, add Ca/MgH
222kg adds lysine 233kg, threonic acid 508kg, silver sol 23g, mixes the back compressing tablet, packing.
Embodiment 7
(30Ca70Mg) is crushed to 20～250 orders with calcium-magnesium alloy, gets powder 55kg, MgH
2-CaH
234kg adds L-lysine hydrochloride 191kg, anhydrous citric acid 249kg, 100 hot eyes moss sugar alcohol 25kg, mixes the back compressing tablet, packing.
Embodiment 8
(20Ca80Mg) is crushed to 20～250 orders with calcium-magnesium alloy, gets powder 26.4kg, adds 5%Mg/MgH
213.4kg, add L-lysine hydrochloride 165Kg, L-ascorbic acid 213kg, 100 hot eyes moss sugar alcohol 45kg, mix the back compressing tablet, packing.
Embodiment 9
Put into the hydrogen reaction stove after 1109g coral calcium and 34.5g be crushed to 60～250 purpose calcium-magnesium alloys (75Ca25Mg) and 760g porous silica catalyst mixing.Feed hydrogen-nitrogen mixture gas, wherein the ratio of nitrogen and hydrogen is 1:20～1:10, and blast pipe is through emptying behind the mineral oil bubbler.Reaction temperature is controlled at 300～380 ℃, and about 2～10h of reaction time generates coral calcium hydride magnesium.The cooling back adds malic acid 633g, citric acid 739g, after mixing, is sub-packed in the above close order bag of 350 orders, packs again.
Embodiment 10
With the magnesium powder 48.6g and the Ca/CaH that are crushed to 400 orders or higher order number
2Powder 54.8g mixes, after adding daucic acid 173g, tranexamic acid 524g and mixing, and packing.
Embodiment 11
To be crushed to 20～150 purpose calcium powders and 36.5kg and Mg/CaH
211.1kg after mixing back adding sodium dihydrogen phosphate 242kg, daucic acid 86kg mixing, packing.
Embodiment 12
To be crushed to 100～250 purpose calcium-magnesium alloy (30Ca70Mg) 27.6kg and Mg/Ca/CaH
2Powder 53.2kg mixes, and adds potassium dihydrogen phosphate 612kg, chlorogenic acid 177kg, after mixing, is sub-packed in the above close order bag of 350 orders, packs again.
Embodiment 13
To be crushed to 100～250 purpose calcium-magnesium alloy (20Ca80Mg) 52.8kg and Mg/Ca/MgH
2Powder 45.4kg mixes, and adds niter cake 336kg, pimelic acid 112kg, after mixing, is sub-packed in the above close order bag of 350 orders, packs again.
Embodiment 14
Calcium-magnesium alloy (75Ca25Mg) is pulverized 20～150 orders, get powder 34.5kg, add Mg/Ca/MgH
2/ CaH
222.1kg, after adding fumaric acid 135kg, niter cake 60kg mix, be sub-packed in the above close order bag of 350 orders, pack again.
Embodiment 15
To be crushed to 20～150 purpose calcium powder 80.2kg and Mg/MgH
2/ CaH
2After powder 18.5kg mixes, after adding pimelic acid 312kg, fumaric acid 75kg mix, be sub-packed in the above close order bag of 350 orders, pack again.
Embodiment 16
With the meta particle diameter is magnesium powder 24.3mg and the Ca/MgH of 80nm
2/ CaH
2After powder 65.1mg mixes, overlay film; With chlorogenic acid 198mg, potassium dihydrogen phosphate 686mg, after the mixing, overlay film; Sealing attaches together.
Embodiment 17
To be crushed to 100～250 purpose calcium-magnesium alloy (20Ca80Mg) 26.4kg and NaMgH
333.5kg after mixing, adding gluconic acid 157kg, L MALIC ACID 214kg mix the back packing.
Embodiment 18
Under argon shield, with 52.6kgMgH
2Add 5% graphite ball milling 8h, add 47kgTiO again
2, add tartaric acid 180kg, taurine 200kg behind the mixing, mix the back packing.
Embodiment 19
With glucolactone 119g, L malic acid 256g is dissolved in 337mL water, adds high pore volume silica (>2mL/g) 365g, behind the mixing in 110 ℃ of crushed after being dried; (20Ca80Mg) is crushed to 60～250 orders with calcium-magnesium alloy, gets 39.6g powder and CaMgH
3.7227.5g be sub-packed in the close order bag more than 350 orders after the above-mentioned carrier that is loaded with gluconic acid and malic acid mixes, pack.
Embodiment 20
To be crushed to 100～250 purpose calcium-magnesium alloy (20Ca80Mg) 26.4kg and NaMgH
333.5kg after mixing, adding glucolactone 142g, L MALIC ACID 214kg mix the back packing.
Calcium magnesium hydrogen manufacturing agent in the foregoing description is made generally in sheet or the packed goods that contain 0.1mmol～3mmol hydrogen manufacturing agent as required, puts into water container and reacts the rich hydrogen water that generates calcic magnesium with water, can handle 200mL～2000mL water; Also can be processed into graininess, bar-shaped or other shape, the hydrogen manufacturing agent content also can adjust accordingly according to required processing water yield difference.PH conditioning agent consumption also can adjust accordingly according to required pH difference.
Foregoing description only proposes as the enforceable technical scheme of the present invention, not as the single restrictive condition to its technical scheme itself.
Claims (9)
1. calcium magnesium hydrogen manufacturing agent; It is characterized in that: its key component is the hydrogen manufacturing agent, and this hydrogen manufacturing agent is selected from calcium hydride, magnesium hydride, calcium hydride magnesium, magnesium-magnesium hydride, calcium-calcium hydride, magnesium-calcium hydride, calcium-magnesium hydride, calcium magnesium-magnesium hydride, calcium magnesium-calcium hydride, calcium magnesium-magnesium hydride-calcium hydride, coral calcium hydride magnesium, NaMgH
3, Mg
2FeH
6In one or more combinations.
2. calcium magnesium hydrogen manufacturing agent according to claim 1 is characterized in that: also comprise calcium magnesium simple substance or calcium-magnesium alloy in its component.
3. calcium magnesium hydrogen manufacturing agent according to claim 1 is characterized in that: also comprise the pH conditioning agent in its component; This pH conditioning agent is selected from amion acetic acid; Citric acid; Gluconic acid; Glucolactone; Threonic acid; Lysine; The L-lysine hydrochloride; Anhydrous citric acid; The L-ascorbic acid; Daucic acid; Malic acid; L MALIC ACID; Pimelic acid; Niter cake; Tartaric acid or its acid salt; Metatartaric acid or its acid salt; Alanine or its salt; Tranexamic acid or its salt; Taurine or its salt; Butanedioic acid or its acid salt; Fumaric acid or its acid salt; Adipic acid or its acid salt; One or more combinations in chlorogenic acid or its salt; The weight ratio of hydrogen manufacturing agent and pH conditioning agent is 1: (0.72～33).
4. calcium magnesium hydrogen manufacturing agent according to claim 1; It is characterized in that: also comprise calcium magnesium ratio conditioning agent in its component, this calcium magnesium ratio conditioning agent is selected from one or more combinations in calcium citrate, magnesium citrate, calcium gluconae, magnesium gluconate, calcium malate, magnesium malate, amion acetic acid calcium, amion acetic acid magnesium, calcium lysinate, lysine magnesium, threonic acid calcium, threonic acid magnesium, calcium monohydrogen phosphate, magnesium monohydrogen phosphate, calcium carbonate, magnesium carbonate, magnesium bicarbonate, the magnesium silicate; The weight ratio of calcium magnesium is 1 among hydrogen manufacturing agent, pH conditioning agent, the calcium magnesium ratio conditioning agent three: (0.25～4).
5. calcium magnesium hydrogen manufacturing agent according to claim 1; It is characterized in that: also comprise bactericide in its component, this bactericide is selected from one or more in simple substance silver, collargol, Nano Silver, silver zeolite, silver pottery, silver salt, argyrol, the no acyclic polyether complex of silver; The weight ratio of bactericide and hydrogen manufacturing agent is 0.0015%～1.5%.
6. calcium magnesium hydrogen manufacturing agent according to claim 1; It is characterized in that: also comprise excipient and carrier in its component, said excipient is selected from one or more combinations in antierythrite, pregelatinized starch, Tagatose, pulullan polysaccharide, sorbierite, dolomol, CMC, starch, dextrin, colloidal silicon dioxide, microcrystalline cellulose, the sodium carboxymethylcellulose; Said carrier is selected from micropore ceramics, micropore glass, molecular sieve, palygorskite, sepiolite, medical stone, concavo-convex rod, active carbon or high pore volume silica.
7. calcium magnesium hydrogen manufacturing agent according to claim 1 is characterized in that: also comprise in its component and help absorbent and mineral matter, the said absorbent that helps is a vitamin D class additive, wherein ratio≤the 800IU:1000mg of vitamin D and calcium; Said mineral matter is lithium, strontium, zinc, iodine, selenium or potassium, and the addition of lithium, strontium, zinc, iodine, selenium or potassium is respectively 0.2～5,0.2～5,0.2～5,0.2～1,0.01～0.05,2～15 with the ratio of hydrogen manufacturing agent, and unit is: mg/mmol.
8. calcium magnesium hydrogen manufacturing agent according to claim 1 is characterized in that: also comprise metasilicic acid and carbon dioxide in its component, and ratio＞25 of metasilicic acid and hydrogen manufacturing agent, unit is: mg/mmol, ratio＞250 of carbon dioxide and hydrogen manufacturing agent, unit is: mg/mmol.
9. calcium magnesium hydrogen manufacturing agent according to claim 1 is characterized in that: also comprise the help Chinese herbal medicine in its component, this help Chinese herbal medicine is selected from one or more combinations in tealeaves, safflower, chrysanthemum, date, matrimony vine, the gynostemma pentaphylla; The help Chinese herbal medicine is 1～3 with the ratio of hydrogen manufacturing agent, and unit is: g/mmol.
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