CN102778775A - Dual-face display smectic phase liquid crystal color display - Google Patents

Dual-face display smectic phase liquid crystal color display Download PDF

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CN102778775A
CN102778775A CN2011101192683A CN201110119268A CN102778775A CN 102778775 A CN102778775 A CN 102778775A CN 2011101192683 A CN2011101192683 A CN 2011101192683A CN 201110119268 A CN201110119268 A CN 201110119268A CN 102778775 A CN102778775 A CN 102778775A
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liquid crystal
conductive electrode
electrode layer
color
layer
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孙刚
万丽芳
田丽
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HALATION PHOTONICS CO Ltd
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HALATION PHOTONICS CO Ltd
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Abstract

The invention discloses a dual-face display smectic phase liquid crystal color display which comprises a liquid crystal display module; the liquid crystal display module comprises a first base layer and a second base layer; a mixed layer is arranged between the first base layer and the second base layer; the mixed layer is mixed from smectic phase liquid crystal, a conductive object and an isolating object or comprises mixture which is packaged in a polymer structure and consists of the smectic phase liquid crystal, the conductive object and the isolating object; one side of the first base layer which is towards the mixed layer is provided with a first conductive electrode layer; one side of the second base layer which is towards the mixed layer is provided with a second conductive electrode layer; and one side of the first base layer or one side of the second base layer is provided with a color pixel layer. According to the dual-face display smectic phase liquid crystal color display, an image can be displayed on a front face and a rear face simultaneously, so that a dual-face display effect is realized, the image effects displayed on dual faces are good; and in addition, the dual-face display smectic phase liquid crystal color display has a high light utilization rate, no radiation, low energy consumption, light weight and strong display contrast, is low in cost, and can serve as an electronic paper product, an advertising device and the like.

Description

Double-sided display smectic liquid crystal color monitor
Technical field
The present invention relates to a kind of smectic liquid crystal display device, refer to a kind of smectic liquid crystal display that can two-sided full color display image especially.
Background technology
LCD be present range of application the most extensively, one of the most promising flat-panel display device.
Traditional LCD all is the back light source structure display, and it comprises a plurality of blooming lamellas such as the polaroid that stacks gradually, prismatic lens, color filter, and polaroid wherein and color filter are to realize that image color shows indispensable important component part.In practical application,, have again during again through the RGB color filter and surpass 40% optical energy loss because light has the optical energy loss about 50% during through polaroid; This makes the light percent of pass of display itself become very little; Therefore, reach suitable brightness and contrast in order to make images displayed, the measure of taking at present is to use the backlight brighter two to three times than indicator screen brightness to replenish; But this just makes the energy consumption of display increase greatly.
What the smectic liquid crystal display device (being called smectic liquid crystal display device again) of present existing ability color display image was used is liquid crystal layering dyeing scheme.This smectic liquid crystal display device generally has bilayer or three-decker.With the three-decker is example; Every layer of structure all mainly is made up of the mixolimnion between upper and lower base layer and upper and lower base layer; Because the color of the dichroic dye that the mixolimnion in every layer of structure adds is different (for example; Three layers of dichroic dye that adds ultramarine, fuchsin, yellow three kinds of different colours respectively), therefore every layer of structure showing various colors, and this three-decker is superimposed mutually and is arranged on the display device that has just formed this three-decker on the white reflecting plate.Through the stack of the dichroic dye color combinations in the three-decker, the display device of this three-decker just can realize the function of multicolour display image, comprises the demonstration of black and white.But the smectic liquid crystal display device of this employing liquid crystal layering dyeing scheme also exists following defective.In practical application, light reflects after through six base layers again, and reflectivity can surpass 30%, and this makes that the reflectivity of display device is very low, does not reach display requirement.In addition, even when the smectic liquid crystal in every layer of structure is in the bright state of full impregnated, the dichroic dye molecule still can have certain absorptive; Demonstrate certain color; This situation can make the transmissivity of light further reduce, generally can be well below 30%, and display effect is difficult to fully up to expectations.Simultaneously; The entire image of this display device is equivalent on three layer planes, show; The reflection of light on Different Plane will produce parallax, influenced display effect, and all will drive the liquid crystal molecule in the three-decker when showing at every turn; So the peripheral drive circuit of this display device is quite complicated, the lightness of whole display device has received influence.
In addition, since the restriction of the backlight of installing on traditional LCD, the restriction of the reflecting plate of installing on the smectic liquid crystal display device of existing ability color display image, and they all can only the single face display image.But along with further developing of lcd technology, people are also more and more diversified to the demand of LCD, and the liquid crystal display of double-sided display also begins to produce application demand in every field, like roadside poster etc.
To sum up visible, designing high, the simple in structure light and handy and colored smectic liquid crystal display can double-sided display of a kind of efficiency of light energy utilization is the problem of needing solution at present badly.
Summary of the invention
The object of the present invention is to provide a kind of double-sided display smectic liquid crystal color monitor, this double-sided display smectic liquid crystal color monitor can the double-sided display coloured image.
To achieve these goals, the present invention has adopted following technical scheme:
A kind of double-sided display smectic liquid crystal color monitor; It is characterized in that: it comprises LCD MODULE; This LCD MODULE comprises first base layer and second base layer; Be provided with mixolimnion between this first base layer and this second base layer, this mixolimnion is mixed by smectic liquid crystal, conducting objects, spacer or this mixolimnion comprises and is encapsulated in the potpourri of being made up of smectic liquid crystal, conducting objects and spacer in the polymer architecture; This first base layer is provided with first conductive electrode layer towards a side of this mixolimnion; This second base layer is provided with second conductive electrode layer towards a side of this mixolimnion, is provided with the colour element layer in a wherein side of this first base layer or a wherein side of this second base layer.
Advantage of the present invention is:
Display of the present invention can show piece image simultaneously on the two sides, front and back, realizes the double-sided display effect, and two sides institute images displayed is respond well; And display light utilization factor of the present invention is high, and radiationless, energy consumption is low; Whole display is very frivolous; Show that contrast is strong, cost is low, can be used as Electronic Paper series products, advertising device etc.
Description of drawings
Fig. 1 is that the structure of first embodiment of display of the present invention is formed schematic top plan view;
Fig. 2 is that the structure of second embodiment of display of the present invention is formed schematic top plan view;
Fig. 3 is the schematic perspective view of the 3rd embodiment of display of the present invention;
Fig. 4 is arranged in the first and second conductive electrode layer synoptic diagram of lattice array shape anyhow;
Fig. 5 is the structural representation of RGBW type colour element layer;
Fig. 6 is the structural representation of RGB type colour element layer;
Fig. 7 is the structural representation of RGBY type colour element layer;
Fig. 8 is the structural representation of CMYK type colour element layer;
Fig. 9 is the shown in red displaying principle key diagram of R color lump (light is from the first base layer incident);
Figure 10 is the shown in red displaying principle key diagram of R color lump (light is from the second base layer incident).
Embodiment
As depicted in figs. 1 and 2; Double-sided display smectic liquid crystal color monitor of the present invention comprises LCD MODULE 10; This LCD MODULE 10 comprises first base layer 11 and second base layer 12; Be provided with mixolimnion 13 between this first base layer 11 and this second base layer 12, (smectic liquid crystal can be described as the smectic phase liquid crystal again to this mixolimnion 13, and microcosmic is the smectic liquid crystal molecule down by smectic liquid crystal; State as follows), conducting objects, spacer mix or this mixolimnion 13 comprises and is encapsulated in the potpourri of being made up of smectic liquid crystal, conducting objects and spacer in the polymer architecture (be made up of polymerizable molecular under the microcosmic, state as follows); This first base layer 11 is provided with first conductive electrode layer 14 towards a side of this mixolimnion 13; This second base layer 12 is provided with second conductive electrode layer 15 towards a side of this mixolimnion 13; First conductive electrode layer 14, second conductive electrode layer 15 are connected with outside driving control device (not shown), are provided with colour element layer 16 in a wherein side of this first base layer 11 or a wherein side of this second base layer 12.
Shown in Fig. 1 is that colour element layer 16 is arranged on the lip-deep situation of this first base layer 11 towards mixolimnion 13 1 sides, and shown in Fig. 2 is the lip-deep situation that colour element layer 16 is arranged on this first base layer 11 one side towards the outside.The wherein situation of a side that colour element layer 16 is arranged on this second base layer 12 does not provide diagram, please refer to the wherein situation of a side that the colour element layer 16 shown in Fig. 1 and Fig. 2 is arranged on this first base layer 11 and understands, and no longer here gives unnecessary details.No matter colour element layer 16 is arranged on a wherein side of this first base layer 11, also is arranged on a wherein side of this second base layer 12, they all can realize the present invention the beneficial effect that will reach.
First base layer 11, second base layer 12 can be made by transparent glass or organic transparent material, and the thickness range of this first, second base layer 11,12 is greater than 0cm and smaller or equal to 5cm.Wherein, glass can be simple glass, vehicle glass, external window of building glass, tempered glass or special glass etc., and organic transparent material can be organic resin hyaline layers such as PET, PMMA, acryl resin, transparent silica gel.First base layer 11, second base layer 12 can be processed for glass or process for organic transparent material simultaneously simultaneously, certainly, also can one process for glass, and another is processed for organic transparent material.
First conductive electrode layer 14, second conductive electrode layer 15 are transparent; Its material can be ITO (tin indium oxide); Also can process for the organic material, inorganic material or the compound substance that possess the electrically conducting transparent performance by carbon nano tube-doped polymer molecule material etc., perhaps add on the basis of any in above-mentioned two kinds of materials metal such as cupric, silver, gold, carbon or nonmetal in any or appoint several kinds of conductive materials that constitute to process.
For mixolimnion 13, the thickness of this mixolimnion 13 is micron order, and it can have two kinds of component composition forms.
First kind of component composition form is that mixolimnion 13 is mixed by smectic liquid crystal, conducting objects, spacer.Smectic liquid crystal is the category-A smectic liquid crystal, for example, with in silica-based compound, four cyano four octyl group biphenyl or tetraacethyl ester in the last of the ten Heavenly stems four cyano biphenyl any or appoint several kinds mixing.Conducting objects is inorganic nano-particle, CNT, Graphene, sodium carbonate, cetyltriethylammonium bromide ethyltriphenylphosphiodide iodide phosphine, (ferrocenyl methyl) trimethyl ammonium iodide, 1 of band conductive characteristic; 2-dimethyl-3-butyl imidazole hexafluorophosphate, tetraethyl amine p-toluenesulfonic esters, phenyl triethyl iodate ammonium, 1-octyl group-3-methylimidazole hexafluorophosphate, two (tetra-n-butyl amine) two (1; 3-dithiole-2-thioketones-4; 5-two mercaptan) palladium (II), tetra-n-butyl close two (1; 3-dithiole-2-thioketones-4; 5-two mercaptan) nickel (III), two (tetra-n-butyl ammoniums) close two (1; 3-dithia cyclopentene-2-thioketones-4,5-two mercaptan) zinc, two (tetra-n-butyl ammoniums) close in four cyano biphenol quinone bismethane, TBAB, cetyl ammonium perchlorate, cetyl bromination four ammoniums, 1-butyl-3-methylimidazole tetrachloro ferrate, methyl triphenyl phosphonium iodide, the tetraphenylphosphoniiodide iodide phosphine any or appoint several kinds mixing.Spacer is transparent batching sphere or the spacer rod that polyester material or polystyrene type macromolecular material or glass material are processed.
Consisting of of the mixolimnion 13 of first kind of composition form: smectic liquid crystal accounts for the 0.0002%-99.99% that mixes general assembly (TW), and conducting objects accounts for the 0.0001%-10% that mixes general assembly (TW), and spacer accounts for the 0.0001%-90% that mixes general assembly (TW).For example, this smectic liquid crystal can account for and mix 99.99% of general assembly (TW), and this conducting objects accounts for mixes 0.0001% of general assembly (TW), and spacer accounts for and mixes 0.0099% of general assembly (TW).Again for example, this smectic liquid crystal can account for and mix 0.0002% of general assembly (TW), and this conducting objects accounts for mixes 9.9998% of general assembly (TW), and spacer accounts for and mixes 90% of general assembly (TW).Again for example, this smectic liquid crystal can account for and mix 89.9999% of general assembly (TW), and this conducting objects accounts for mixes 10% of general assembly (TW), and spacer accounts for and mixes 0.0001% of general assembly (TW).Again for example, this smectic liquid crystal can account for and mix 15% of general assembly (TW), and this conducting objects accounts for mixes 7% of general assembly (TW), and spacer accounts for and mixes 78% of general assembly (TW).Again for example, preferably, this smectic liquid crystal can account for and mix 80% of general assembly (TW), and this conducting objects accounts for mixes 7% of general assembly (TW), and spacer accounts for and mixes 13% of general assembly (TW).
For the mixolimnion of first kind of composition form: conducting objects mainly is the electric conductivity that increases mixolimnion 13; Conducting objects is changed the arrangement form of smectic liquid crystal molecule by the driving and generating motion under the voltage effect; Thereby change the photoelectric properties of smectic liquid crystal, so the consumption of conducting objects should be an amount of.If conducting objects accounts for the ratio of mixing general assembly (TW) less than 0.0001%; Then since conducting objects very little; Ion in the conducting objects changes the arrangement form that the to-and-fro movement that produces can't change the smectic liquid crystal molecule according to electric potential difference between row-column electrode, and promptly the color of uncontrollable sub-pixel point shows.If this conducting objects accounts for the ratio of mixing general assembly (TW) greater than 10%; Then will be between first and second conductive electrode layer because of a large amount of conducting objects and short circuit, can't drive; Simultaneously, a large amount of conducting objects can make the resistivity of mixolimnion 13 reduce, and has influenced its serviceable life.Spacer is passive, is used for controlling the thickness of mixolimnion 13.In practical application, the consumption of spacer is less is advisable, as long as can reach the effect of control mixolimnion 13 thickness.The diameter of spacer promptly is the thickness of mixolimnion, and the quantity of spacer should suitably be confirmed with the selection of adopting ball or rod according to the mixolimnion thickness that reaches in advance.When the smectic liquid crystal molecule is regularly arranged; Because the optical refractive index of spacer is very close with the optical refractive index of smectic liquid crystal molecule; So spacer can not influence the transmittance of light; The optical properties of smectic liquid crystal molecule can not be affected, and spacer can not influence astigmatism property of the present invention and " multistable " characteristic yet.And smectic liquid crystal plays light modulation, image demonstration effect, and therefore, in practical application, the consumption of smectic liquid crystal is more is advisable.
Second kind of component composition form is that mixolimnion 13 comprises and is encapsulated in the potpourri of being made up of smectic liquid crystal, conducting objects and spacer in the polymer architecture.Smectic liquid crystal is the category-A smectic liquid crystal, for example, with in silica-based compound, four cyano four octyl group biphenyl or tetraacethyl ester in the last of the ten Heavenly stems four cyano biphenyl any or appoint several kinds mixing.Conducting objects is inorganic nano-particle, CNT, Graphene, sodium carbonate, cetyltriethylammonium bromide ethyltriphenylphosphiodide iodide phosphine, (ferrocenyl methyl) trimethyl ammonium iodide, 1 of band conductive characteristic; 2-dimethyl-3-butyl imidazole hexafluorophosphate, tetraethyl amine p-toluenesulfonic esters, phenyl triethyl iodate ammonium, 1-octyl group-3-methylimidazole hexafluorophosphate, two (tetra-n-butyl amine) two (1; 3-dithiole-2-thioketones-4; 5-two mercaptan) palladium (II), tetra-n-butyl close two (1; 3-dithiole-2-thioketones-4; 5-two mercaptan) nickel (III), two (tetra-n-butyl ammoniums) close two (1; 3-dithia cyclopentene-2-thioketones-4,5-two mercaptan) zinc, two (tetra-n-butyl ammoniums) close in four cyano biphenol quinone bismethane, TBAB, cetyl ammonium perchlorate, cetyl bromination four ammoniums, 1-butyl-3-methylimidazole tetrachloro ferrate, methyl triphenyl phosphonium iodide or the tetraphenylphosphoniiodide iodide phosphine any or appoint several kinds mixing.Spacer is transparent batching sphere or the spacer rod that polyester material or polystyrene type macromolecular material or glass material are processed.Polymer architecture is transparent; It is got ready on the medial surface of first and/or second conductive electrode layer through direct printing or etching or nano impression or spraying by unimolecule body material or (thermoplasticity) polymerizable molecular material; Heat curing or ultra-violet curing are that the polymerizable molecular material with setting structure forms, and this unimolecule body material is any in epoxy resin, polyacrylate or the polymethacrylate monomer.This polymer architecture is formed with the accommodating chamber of the potpourri that holds smectic liquid crystal, conducting objects and spacer composition; Polymer architecture can be that spherical, little cylindric, thread, hemispherical, parallel strip, cube, rectangular parallelepiped, the intersection of rule is traditional thread binding, in the mixed structure of network structure (like the hexagon cellular wall construction), square grid minor structure, irregular polygon structure or above-mentioned multiple structure any; This polymer architecture can be uniformly, and is also uneven.Between this polymer architecture and smectic liquid crystal, conducting objects and the spacer can be miscible each other, disperse, be in contact with one another or at interval etc.
Consisting of of the mixolimnion of second kind of composition form: smectic liquid crystal accounts for the 0.0002%-99.99% that mixes general assembly (TW); The polymerizable molecular material accounts for the 0.0001%-80% that mixes general assembly (TW); Conducting objects accounts for the 0.0001%-10% that mixes general assembly (TW), and spacer accounts for the 0.0001%-80% that mixes general assembly (TW).For example, smectic liquid crystal accounts for and mixes 99.99% of general assembly (TW), and the polymerizable molecular material accounts for and mixes 0.0098% of general assembly (TW), and conducting objects accounts for mixes 0.0001% of general assembly (TW), and spacer accounts for and mixes 0.0001% of general assembly (TW).Again for example, smectic liquid crystal accounts for and mixes 0.0002% of general assembly (TW), and the polymerizable molecular material accounts for and mixes 45% of general assembly (TW), and conducting objects accounts for mixes 9.9998% of general assembly (TW), and spacer accounts for and mixes 45% of general assembly (TW).Again for example, smectic liquid crystal accounts for and mixes 15% of general assembly (TW), and the polymerizable molecular material accounts for and mixes 80% of general assembly (TW), and conducting objects accounts for mixes 3% of general assembly (TW), and spacer accounts for and mixes 2% of general assembly (TW).Again for example, smectic liquid crystal accounts for and mixes 85% of general assembly (TW), and the polymerizable molecular material accounts for and mixes 0.0001% of general assembly (TW), and conducting objects accounts for mixes 10% of general assembly (TW), and spacer accounts for and mixes 4.9999% of general assembly (TW).Again for example, smectic liquid crystal accounts for and mixes 15% of general assembly (TW), and the polymerizable molecular material accounts for and mixes 3% of general assembly (TW), and conducting objects accounts for mixes 2% of general assembly (TW), and spacer accounts for and mixes 80% of general assembly (TW).Again for example, smectic liquid crystal accounts for and mixes 55% of general assembly (TW), and the polymerizable molecular material accounts for and mixes 30% of general assembly (TW), and conducting objects accounts for mixes 5% of general assembly (TW), and spacer accounts for and mixes 10% of general assembly (TW).
For the mixolimnion of second kind of composition form: conducting objects mainly is the electric conductivity that increases mixolimnion 13; Conducting objects is changed the arrangement form of smectic liquid crystal molecule by the driving and generating motion under the voltage effect; Thereby change the photoelectric properties of smectic liquid crystal, so the consumption of conducting objects should be an amount of.If conducting objects accounts for the ratio of mixing general assembly (TW) less than 0.0001%; Then since conducting objects very little; Ion in the conducting objects changes the arrangement form that the to-and-fro movement that produces can't change the smectic liquid crystal molecule according to electric potential difference between row-column electrode, and promptly the color of uncontrollable sub-pixel point shows.If this conducting objects accounts for the ratio of mixing general assembly (TW) greater than 10%; Then will be between first and second conductive electrode layer because of a large amount of conducting objects and short circuit, can't drive; Simultaneously, a large amount of conducting objects can make the resistivity of mixolimnion 13 reduce, and has influenced its serviceable life.Spacer is passive, is used for controlling the thickness of mixolimnion 13.In practical application, the consumption of spacer is less is advisable, as long as can reach the effect of control mixolimnion 13 thickness.The diameter of spacer promptly is the thickness of mixolimnion, and the quantity of spacer should suitably be confirmed with the selection of adopting ball or rod according to the mixolimnion thickness that reaches in advance.When the smectic liquid crystal molecule is regularly arranged; Because the optical refractive index of spacer is very close with the optical refractive index of smectic liquid crystal molecule; So spacer can not influence the transmittance of light; The optical properties of smectic liquid crystal molecule can not be affected, and spacer can not influence astigmatism property of the present invention and " multistable " characteristic yet.Polymer architecture has been bonding and has supported two base layer effects.In mixolimnion 13; When the smectic liquid crystal molecule is regularly arranged; Because the optical refractive index of polymerizable molecular is very close with the optical refractive index of smectic liquid crystal molecule, so polymerizable molecular can not influence the transmittance of light, the optical properties of smectic liquid crystal molecule can not be affected; Promptly can not influence dimming capability (referring to transmittancy and astigmatic ability); When the irregular alignment of smectic liquid crystal molecule, light can transmission mix layer 13 be not to form because the optical refractive index on the molecular axis both direction of smectic liquid crystal molecule itself is different, and is irrelevant with polymerizable molecular.And " multistable " of the present invention characteristic is the attribute of smectic liquid crystal molecule, and is irrelevant with polymerizable molecular.But the polymerizable molecular material is many more, is used for image and shows that the shared overall ratio of area of (light modulation) is just more little, and display effect naturally will variation.Therefore, in practical application, the consumption of polymerizable molecular material is advisable in right amount, can not be too many.Carry out image demonstration effect and smectic liquid crystal plays light modulation, therefore, in practical application, the consumption of smectic liquid crystal is more is advisable.
In the present invention, colour element layer 16 can be RGBW type colour element layer or RGB type colour element layer or RGBY type colour element layer or CMYK type colour element layer.Certainly, colour element layer 16 certain type the colour element layer that any several kinds of colors constitute of also can serving as reasons, the color composition form can be set by actual needs.
If colour element layer 16 is a RGBW type colour element layer; As shown in Figure 5; Then: (circle among Fig. 5 shows a colour developing unit 161 to RGBW type colour element layer by M * N colour developing unit 161; The colour developing unit is with M * N matrix structure) to form, each this colour developing unit 161 is made up of the R that is arranged in 2 * 2 matrix structures (redness) color lump, G (green) color lump, B (blueness) color lump, four color lumps of W color lump.If colour element layer 16 adopts RGBW type colour element layer; Then first conductive electrode layer 14, second conductive electrode layer 15 need be provided with as follows: first conductive electrode layer 14 is formed (having a determining deviation between the adjacent lines electrode) by 2M strip line electrode 141 that is arranged in parallel; Second conductive electrode layer 15 is formed (having a determining deviation between the adjacent columns electrode) by 2N strip row electrode 151 that is arranged in parallel; 2N strip row electrode 151 of the 2M of first conductive electrode layer 14 strip line electrode 141 and second conductive electrode layer 15 be quadrature mutually, so that first conductive electrode layer 14 and second conductive electrode layer 15 form the sub-pixel lattice array of a 2M * 2N.Like Fig. 4, schematically show the formed sub-pixel lattice array of row-column electrode among the figure, label 20 indications partly are subpixels point among the figure.First conductive electrode layer 14 is corresponding one by one with 2M * 2N color lump of RGBW type colour element layer 16 with 2M * 2N subpixels point 20 that second conductive electrode layer 15 is constituted; Just color lump of RGBW type colour element layer and a corresponding subpixels put 20 corresponding, and pixel of four color lumps pairing 4 subpixels points 20 formations in should colour developing unit 161.For the present invention who adopts RGBW type colour element layer 16; Pixel is the base unit of display image; Institute's images displayed is made up of plurality of pixels point, and a pixel is by common structure of 4 corresponding respectively subpixels points of its corresponding four color lumps.This first, second conductive electrode layer 14,15 and 13 middle of mixolimnions have formed a capacitance structure that area is very big, and four subpixels point positions in each pixel have formed four capacitance structures that independent area is very little.
Colour element layer among the present invention also can be RGB type colour element layer.As shown in Figure 6; (circle among Fig. 6 shows a colour developing unit 162 to RGB type colour element layer 16 by M * N colour developing unit 162; The colour developing unit is with M * N matrix structure) to form, each this colour developing unit 162 is made up of the R color lump that is arranged in 1 * 3 matrix structure, G color lump, three color lumps of B color lump.If the colour element layer adopts RGB type colour element layer; Then first conductive electrode layer 14, second conductive electrode layer 15 need be provided with as follows: first conductive electrode layer 14 is formed (having a determining deviation between the adjacent lines electrode) by M strip line electrode 141 that is arranged in parallel; Second conductive electrode layer 15 is formed (having a determining deviation between the adjacent columns electrode) by 3N strip row electrode 151 that is arranged in parallel; 3N strip row electrode 151 of the M of first conductive electrode layer 14 strip line electrode 141 and second conductive electrode layer 15 be quadrature mutually, so that first conductive electrode layer 14 and second conductive electrode layer 15 form the sub-pixel lattice array of a M * 3N.Like Fig. 4, schematically show the formed sub-pixel lattice array of row-column electrode among the figure, label 20 indications partly are subpixels point among the figure.First conductive electrode layer 14 is corresponding one by one with M * 3N color lump of RGB type colour element layer with M * 3N subpixels point 20 that second conductive electrode layer 15 is constituted; Just color lump of RGB type colour element layer and a corresponding subpixels put 20 corresponding, and pixel of three color lumps pairing 3 subpixels points 20 formations in should colour developing unit 162.For the present invention who adopts RGB type colour element layer; Pixel is the base unit of display image; Institute's images displayed is made up of plurality of pixels point, and a pixel is by common structure of 3 corresponding respectively subpixels points of its corresponding three color lumps.This first, second conductive electrode layer 14,15 and 13 middle of mixolimnions have formed a capacitance structure that area is very big, and three subpixels point positions in each pixel have formed three capacitance structures that independent area is very little.
If colour element layer 16 is a RGBY type colour element layer; As shown in Figure 7; Then: (circle among Fig. 7 shows a colour developing unit 163 to RGBY type colour element layer by M * N colour developing unit 163; The colour developing unit is with M * N matrix structure) to form, each this colour developing unit 163 is made up of the R that is arranged in 2 * 2 matrix structures (redness) color lump, G (green) color lump, B (blueness) color lump, four color lumps of Y (yellow) color lump.If colour element layer 16 adopts RGBY type colour element layer; Then first conductive electrode layer 14, second conductive electrode layer 15 need be provided with as follows: first conductive electrode layer 14 is formed (having a determining deviation between the adjacent lines electrode) by 2M strip line electrode 141 that is arranged in parallel; Second conductive electrode layer 15 is formed (having a determining deviation between the adjacent columns electrode) by 2N strip row electrode 151 that is arranged in parallel; 2N strip row electrode 151 of the 2M of first conductive electrode layer 14 strip line electrode 141 and second conductive electrode layer 15 be quadrature mutually, so that first conductive electrode layer 14 and second conductive electrode layer 15 form the sub-pixel lattice array of a 2M * 2N.Like Fig. 4, schematically show the formed sub-pixel lattice array of row-column electrode among the figure, label 20 indications partly are subpixels point among the figure.First conductive electrode layer 14 is corresponding one by one with 2M * 2N color lump of RGBY type colour element layer 16 with 2M * 2N subpixels point 20 that second conductive electrode layer 15 is constituted; Just color lump of RGBY type colour element layer and a corresponding subpixels put 20 corresponding, and pixel of four color lumps pairing 4 subpixels points 20 formations in should colour developing unit 163.For the present invention who adopts RGBY type colour element layer 16; Pixel is the base unit of display image; Institute's images displayed is made up of plurality of pixels point, and a pixel is by common structure of 4 corresponding respectively subpixels points of its corresponding four color lumps.This first, second conductive electrode layer 14,15 and 13 middle of mixolimnions have formed a capacitance structure that area is very big, and four subpixels point positions in each pixel have formed four capacitance structures that independent area is very little.
If colour element layer 16 is a CMYK type colour element layer; As shown in Figure 8; Then: (circle among Fig. 8 shows a colour developing unit 164 to CMYK type colour element layer by M * N colour developing unit 164; The colour developing unit is with M * N matrix structure) to form, each this colour developing unit 164 is made up of the C that is arranged in 2 * 2 matrix structures (cyan) color lump, M (magenta) color lump, Y (yellow) color lump, four color lumps of K (black) color lump.If colour element layer 16 adopts CMYK type colour element layer; Then first conductive electrode layer 14, second conductive electrode layer 15 need be provided with as follows: first conductive electrode layer 14 is formed (having a determining deviation between the adjacent lines electrode) by 2M strip line electrode 141 that is arranged in parallel; Second conductive electrode layer 15 is formed (having a determining deviation between the adjacent columns electrode) by 2N strip row electrode 151 that is arranged in parallel; 2N strip row electrode 151 of the 2M of first conductive electrode layer 14 strip line electrode 141 and second conductive electrode layer 15 be quadrature mutually, so that first conductive electrode layer 14 and second conductive electrode layer 15 form the sub-pixel lattice array of a 2M * 2N.Like Fig. 4, schematically show the formed sub-pixel lattice array of row-column electrode among the figure, label 20 indications partly are subpixels point among the figure.First conductive electrode layer 14 is corresponding one by one with 2M * 2N color lump of CMYK type colour element layer 16 with 2M * 2N subpixels point 20 that second conductive electrode layer 15 is constituted; Just color lump of CMYK type colour element layer and a corresponding subpixels put 20 corresponding, and pixel of four color lumps pairing 4 subpixels points 20 formations in should colour developing unit 164.For the present invention who adopts CMYK type colour element layer 16; Pixel is the base unit of display image; Institute's images displayed is made up of plurality of pixels point, and a pixel is by common structure of 4 corresponding respectively subpixels points of its corresponding four color lumps.This first, second conductive electrode layer 14,15 and 13 middle of mixolimnions have formed a capacitance structure that area is very big, and four subpixels point positions in each pixel have formed four capacitance structures that independent area is very little.
When reality was implemented, above-mentioned color lump can be optical filter or fluorescent powder is processed.In the present invention, except the foregoing description that the colour element layer is carried out, all belong to known technology, be not described in detail about other aspects of colour element layer.
In the present invention; Colour element layer 16 can adopt the mode of printing or being coated on the base layer to make; First, second conductive electrode layer 14,15 can adopt sputter to make in the lip-deep mode of equivalent layer, and mixolimnion 13 can adopt the mode of recording interlayer or the mode of coating to make.
To adopt RGBW type colour element layer 16 and colour element layer 16 to be arranged on the present invention on mixolimnion 13 1 side surfaces of first base layer 11 the image displaying principle is described below.
According to image demonstration needs; Drive control device controls is applied to the voltage signal of each electrode on first conductive electrode layer 14 and second conductive electrode layer 15; Make the R of each colour developing in unit 161, G, B, the mixolimnion that the W color lump is corresponding respectively partly be rendered as vaporific lucifuge state or the bright state of full impregnated or other progressive states; Thereby R, G, B, W color lump in each colour developing unit 161 externally demonstrate corresponding color.Because the area of the colour developing unit 161 that R, G, B, W color lump are formed very little (area of colour developing unit is the area of pixel); Be micron order; 107 ± 5 μ m for example; Therefore, for a colour developing unit 161, the color that the color that the blend of colors that the R in this colour developing unit 161, G, B, W color lump show is respectively constituted together finally externally demonstrates for these colour developing unit 161 pairing pixels (being the actual color of seeing of beholder's ability).That is to say, make each pixel demonstrate required color through the color of controlling each colour developing unit 161 pairing 4 subpixels points 20, thereby make display demonstrate required colored show state.Wherein, The color that the W color lump is shown can be decided by the Show Color of other three R in its colour developing unit 161, place, G, B color lump, and the adjusting target of W color lump is to make the brightness and the colour purity of the pixel of its colour developing unit, place 161 correspondences reach an equilibrium point.
Be that example specifies with a pixel below:
If it is shown in red that this pixel needs; Then on the corresponding pairing row-column electrode of R color lump of this pixel, apply low-frequency high-voltage electric signal (the positive and negative bidirectional pulse about 100v, 50Hz for example; The voltage magnitude of the voltage waveform that the low-frequency high-voltage electric signal stack back that applies on the row-column electrode forms is greater than threshold voltage magnitude; Threshold voltage is for making the smectic liquid crystal molecule by driving the magnitude of voltage that arrangement form changes taken place; It is to confirm according to the composition of mixolimnion and thickness, is generally more than the 5V.); On the corresponding G of this pixel, the pairing row-column electrode of B color lump, all apply high-frequency and high-voltage electric signal (for example the positive and negative bidirectional pulse about 100v, 1kHz, the voltage magnitude of the voltage waveform that the high-frequency and high-voltage electric signal that applies on row-column electrode stack back forms is greater than threshold voltage magnitude).Smectic liquid crystal molecule in the mixolimnion part of this R color lump correspondence twists, and becomes out of order arrangement form.Smectic liquid crystal molecule in the mixolimnion part of this G color lump, B color lump correspondence becomes regularly arranged form.From the light 30 of first base layer, 11 1 side incidents via first base layer 11, colour element layer 16, first conductive electrode layer, 14 directive mixolimnions 13.In the corresponding mixolimnion part of R color lump; Like Fig. 9; Because each of smectic liquid crystal molecule is to diversity (promptly because the light of this mixolimnion part of incident is different through the long optical axis of each liquid crystal molecule, the anaclasis angle of each liquid crystal molecule is different, thereby the refractive index of each liquid crystal molecule is different); There is very big-difference in the ray refraction of each smectic liquid crystal molecule of incident; Promptly in the corresponding very thin mixolimnion part of this R color lump, optical index has produced violent variation, and light in the corresponding mixolimnion part of this R color lump strong scattering takes place; (mixolimnion that this R color lump is corresponding partly demonstrates vaporific lucifuge state to be seen as a kind of astigmatic effect on the macroscopic view; As acute-matte), (in this mixolimnion part, the light of other color lump of light directive of scattering is seldom at this R color lump of a large amount of directives of light of the corresponding mixolimnion part inscattering of this R color lump; The light that penetrates via second base layer 12 can not impact the color demonstration of colour element layer 16, and also very faint via the light of second base layer, 12 reflected backs.)。If the R color lump adopts optical filter to process, then the R color lump has the selective permeation function to ruddiness, thereby makes the R color lump externally demonstrate redness.If the R color lump adopts fluorescent powder to process, the light that then is mapped to the R color lump produces stimulated radiation, thereby makes the R color lump externally demonstrate redness.In the present invention, the mode of above-mentioned this Show Color has adopted scattered beam mode image-forming principle.In the corresponding mixolimnion part of G color lump; The long optical axis of regularly arranged smectic liquid crystal molecule is perpendicular to the plane of first, second conductive electrode layer 14,15; Thereby the ray refraction of each smectic liquid crystal molecule of incident does not produce acute variation, and light can freely see through the corresponding mixolimnion part of this G color lump (demonstrating the bright state of full impregnated on the mixolimnion part macroscopic view of this G color lump correspondence) and directly penetrate from second base layer 12; Because the display display image is to rely on surround lighting to realize; The light of vertical incidence first base layer 11 is seldom, and light is that oblique incidence is to viewing area 50, therefore mostly; The light that finally can see through the G color lump is seldom, and the G color lump externally is not shown as any color.In like manner; In the corresponding mixolimnion part of B color lump, the long optical axis of regularly arranged smectic liquid crystal molecule is perpendicular to the plane of first, second conductive electrode layer 14,15, thereby; The ray refraction of each smectic liquid crystal molecule of incident does not produce acute variation; Light can freely see through the corresponding mixolimnion part of this B color lump (demonstrating the bright state of full impregnated on the mixolimnion part macroscopic view of this B color lump correspondence) and directly penetrate from second base layer 12, because the display display image is to rely on surround lighting to realize, the light of vertical incidence first base layer 11 is seldom; Light is that oblique incidence is to viewing area 50 mostly; Therefore, the light that finally can see through the B color lump also is seldom, and the B color lump externally is not shown as any color yet.So, the R color lump of exhibit red and G, the B color lump of Show Color do not combine and make that just their pairing pixels are finally shown in red.
If the mixolimnion that the R color lump is corresponding partly is rendered as progressive state (the smectic liquid crystal molecule twists form for part); Then the R color lump demonstrate progressive state redness (for example; The redness of translucent), thus whole pixel externally demonstrates the redness of this progressive state.
For the W color lump, the arrangement form of liquid crystal molecule receives the control of the voltage signal on the corresponding row-column electrode equally and is arranged as out of order state (presenting vaporific lucifuge state) or rule state (presenting the bright state of full impregnated) or other transition states (presenting progressive state) in its pairing mixolimnion part.The W color lump does not have selective permeation function or stimulated radiation effect to light, and all light are always all through this W color lump, therefore; For example, if the corresponding mixolimnion of W color lump partly is vaporific lucifuge state, the external show white of W color lump then; So the brightness of this pixel increases, but the red purity that this pixel shows has received influence; If the mixolimnion that the W color lump is corresponding partly is the bright state of full impregnated, the external Show Color (principle is with above-mentioned G, B color lump) not of W color lump then, so; The red purity that this pixel shows improves (highest purity), but the relative step-down of the brightness of this pixel.In reality is implemented, reach balance in order to make between brightness of image and the colour purity, the demonstration of W color lump can be determined that for example, the mean value of desirable R, G, B color lump three color value is used as the brightness value of W color lump jointly by R, G, B color lump.
When light 30 when second base layer, 12 1 sides are injected; Displaying principle (like Figure 10) and above-mentioned light 30 that the R color lump is shown in red are basic identical from the situation of first base layer, 11 1 side directive R color lumps; Different is; Compare with light case of incident shown in Figure 9, the R color lump is a little to evening time of ruddiness selective permeation (for the color lump of optical filter making) or stimulated radiation (for the color lump of fluorescent powder making).And G, B color lump the situation injected from first base layer, 11 1 sides of principle and the above-mentioned light 30 of Show Color is not identical.
Pixel is except can being shown as the red, green, blue look; Also can make pixel be shown as other color through mixolimnion control partly to R, G, B color lump correspondence; So the whole screen of display has just had colourful color effects, reached the requirement that full color shows.Pixel displaying principle shown in green, blue and other color is identical with the displaying principle of above-mentioned pixel exhibit red, so here do not give unnecessary details.No matter which kind of color pixel is shown as; Displaying principle all can reduce: control the voltage signal (pulse of controlling this voltage signal is to number, frequency, voltage magnitude) that applies on the row-column electrode of R, G, B, W color lump correspondence respectively; Make the interior smectic liquid crystal molecules align of mixolimnion part of R, G, B, W color lump correspondence (for example become corresponding form; Regularly arranged form, out of order arrangement form, part are twisted form etc.); The mixolimnion part of R, G, B, W color lump correspondence (for example produces corresponding astigmatic effect respectively; Vaporific lucifuge state, the bright state of full impregnated, such as progressive state of translucent etc.), thereby R, G, B, W color lump demonstrate corresponding color respectively, the color combination that R, G, B, W color lump are shown gets up to be the color that their pairing pixels finally demonstrate.
For RGB type colour element layer 16; The difference of itself and RGBW type colour element layer is not have the W color lump; RGB type colour element layer can not be regulated the brightness and the colour purity of pixel Show Color, but its image displaying principle is identical with RGBW type colour element layer, here repeats no more.
In like manner; For RGBY type colour element layer 16; The difference of itself and RGBW type colour element layer is not have the W color lump, and RGBY type colour element layer can not be regulated the brightness and the colour purity of pixel Show Color, and the color that pixel finally demonstrates is to be got up to constitute by the color combination that R, G, B, four color lumps of Y show separately; The image displaying principle of RGBY type colour element layer is identical with RGBW type colour element layer, here repeats no more.
In like manner; For CMYK type colour element layer 16; The difference of itself and RGBW type colour element layer also is not have the W color lump, and CMYK type colour element layer can not be regulated the brightness and the colour purity of pixel Show Color, and the color that pixel finally demonstrates is to be got up to constitute by the color combination that C, M, Y, four color lumps of K show separately; The image displaying principle of CMYK type colour element layer is identical with RGBW type colour element layer, here repeats no more.
Can know by above-mentioned displaying principle; When display of the present invention is in outdoor light better in the environment of (bright and clear) time; Ambient light is from this display of all angles incident; So this display can before and after the two sides same width of cloth image of clear demonstration simultaneously, the relative another side images displayed of one side images displayed content content is overturn.That is to say that the beholder can see the image with identical display effect regardless of which side at display.
But; When display of the present invention be in indoor or environment that light is bad in the time, ambient light too a little less than, just can't satisfy the brightness requirement that image shows; Therefore; In order to improve the brightness that image shows, can at least one side of the LCD MODULE 10 of display of the present invention or near illumination module 17 is set, the two sides, front and back of LCD MODULE 10 is viewing area 50 (like Fig. 1 and Fig. 2); Illumination module 17 can not block viewing area 50; Illumination module comprises a plurality of irradiation lights 171, and these a plurality of irradiation lights 171 other light that are provided with irradiation light 171 emissions carry out deflection, the lens 172 so that light tilts on one of them viewing area 50 of directive equably or two viewing areas 50.The inclination directive here is meant that the light of directive viewing area 50 and the plane of viewing area 50 form an acute angle; And light is equably to the whole planar transmit of viewing area 50, and the whole plane of viewing area 50 is appeared needs images displayed.Irradiation light 171 can adopt LED or CCFL, and LED can be blueness or white.Lens 172 can be that transparent materials such as PMMA, PC are processed.In display of the present invention, these illumination module 17 roles promptly are outdoor preferably light roles, and the light of their directive viewing areas 50 all tilts.
As shown in Figure 3; Shown in the figure is near the situation the lower side of illumination module 17 LCD MODULE 10 that is arranged on display of the present invention; This illumination module 17 is positioned at the front of LCD MODULE 10; The light of irradiation light 171 emission of this illumination module 17 through lens 172 (lens 172 are arranged on the top of irradiation light 171) deflection after, on that viewing area 50 of directive LCD MODULE 10 fronts equably of tilting.As shown in Figure 3, these illumination module 17 roles promptly are outdoor preferably light roles, and the light of this viewing area 50 of their directives all tilts.Because display of the present invention shown in Figure 3 only is provided with the illumination module 17 to viewing area 50 irradiation light; There is not another viewing area 50 of light source irradiation can only receive the irradiation of more weak surround lighting; Therefore, though this display can show same width of cloth image in the two sides, front and back simultaneously; The viewing area 50 of having only light source irradiation is display image clearly, and the image that does not have the viewing area 50 of light source irradiation to demonstrate is not very clear.The image displaying principle of display of the present invention shown in Figure 3 is identical with the present invention that illumination module 17 is not set, and here repeats no more.
Tilt evenly to two viewing areas 50 of the LCD MODULE 10 of display of the present invention that the illumination module 17 of emission light does not provide diagram, please combine situation shown in Figure 3 to understand.When all there is the irradiate light that irradiation light 171 sends former and later two viewing areas 50 of the LCD MODULE 10 of display of the present invention; Display of the present invention can before and after the two sides same width of cloth image of clear demonstration simultaneously; Its image displaying principle is identical with the present invention that illumination module 17 is not set, and here repeats no more.
It should be noted that; Because on light source (referring to illumination module 17) direction of illumination, there are a large amount of transmitted lights, rather than the required scattered light of image demonstration, and these transmitted lights can make each color lump Show Color all the time; Therefore; It is parallel with the illumination direction of light source that view direction will be avoided as far as possible, and the illumination direction of light source should stagger with beholder's direction of visual lines mutually, so just can reach good viewing effect.
Also can consult number of patent application about the light modulation principle in the mixolimnion (being how the smectic liquid crystal molecule is arranged by driving accordingly) is that 200710175959.9 Chinese invention patent application " a kind of electric-controlled light-regulating medium " and number of patent application are that corresponding description in Chinese invention patent application " electric-controlled light-regulating medium " of 200810102000.7 etc. is understood.
In the present invention, after producing luminous effects such as scattering, full impregnated be bright for first, second conductive electrode layer on-load voltage signal, the present invention, just can remove voltage.The maintenance of this luminous effect does not need voltage to keep, promptly remove voltage after, the luminous effect that the present invention produces in the time of still can keeping on-load voltage, and the voltage signal of effect is just in order to change the arrangement form of smectic liquid crystal molecule.In the present invention, this state that does not need electricity to drive and keep luminous effect is called " multistable " or " quasistatic ".And this " multistable " is because conducting objects has adopted the compound of band conductive characteristic; When voltage signal is applied on first, second conductive electrode layer; Ion in the compound of band conductive characteristic changes the generation to-and-fro movement according to electric potential difference; This motion can change the arrangement form of smectic liquid crystal molecule, and the smectic liquid crystal molecules align form after changing does not need the persistent movement of ion to keep, and is stable.
In the present invention, also can be mixed with dichroic dye in the mixolimnion 13.Preferably, dichroic dye can account for and mix 5% of general assembly (TW).Through an amount of dichroic dye is mixed into mixolimnion 13, can make the mixolimnion of display of the present invention realize bright, the coloured shading of full impregnated, the various switching that has between the color shade attitude.For the display of the present invention that is mixed with dichroic dye in the mixolimnion 13, its images displayed be the color that shows of colour element layer 16 with mixolimnion 13 in the stack of color of dichroic dye demonstration.The image displaying principle that is mixed with the display of the present invention of dichroic dye in the mixolimnion 13 is essentially identical with the present invention who does not add dichroic dye; Different just these displays one deck color that on the basis of colour element layer 16 display image, superposeed again shows; Make the colour of display abundanter; Therefore, the image displaying principle that is mixed with the display of the present invention of dichroic dye in the mixolimnion 13 no longer here details.
Advantage of the present invention is:
1, display of the present invention can show piece image simultaneously on the two sides, front and back, realizes the double-sided display effect, and two sides institute images displayed is respond well; And display light utilization factor of the present invention is high, and radiationless, energy consumption is low; Whole display is very frivolous; Show that contrast is strong, cost is low, can be used as Electronic Paper series products, advertising device etc.
2, compare with the smectic liquid crystal display device of existing ability color display image with traditional LCD; Display of the present invention does not use polaroid, does not use sandwich construction, therefore yet; Display of the present invention has significantly reduced because the optical energy loss that polaroid or sandwich construction cause; Greatly improve the utilization factor of luminous energy, increased the brightness and the color saturation of display, improved display effect.
3, for the display of the present invention that the colour element layer only is set; The present invention just can reach the effect that full color shows through using individual layer colour element layer, and simultaneously, the smectic liquid crystal display device of having eliminated existing ability color display image is because the parallax defective that sandwich construction produced; The image clear display; Contrast is high, and peripheral drive circuit is simple, uncomplicated, and the complex manufacturing technology degree and the cost of manufacture of display are low.For for the display of the present invention that increases dichroic dye in the mixolimnion; The color that the present invention is had through the colour element layer and to the control of smectic liquid crystal in the mixolimnion and dichroic dye ordered state; Realized the color effect of abundant full color display image more, the image clear display, contrast is high; Peripheral drive circuit is simple, uncomplicated, and the complex manufacturing technology degree and the cost of manufacture of display are low.
4, display of the present invention adopts scattered beam mode image-forming principle; Compare with transmission or reflective imaging; The light of scattering is that all directions all exist, and has so just increased the visible angle of display of the present invention, makes display of the present invention on all directions, all have good display effect.
5, because display design of the present invention has mixolimnion, thereby it also has many advantages of bringing because of mixolimnion, for example, the multistable characteristic, energy consumption is low, electromagnetic-radiation-free, health environment-friendly, switch speed is fast etc.
Above-mentioned is preferred embodiment of the present invention and the know-why used thereof; For a person skilled in the art; Under the situation that does not deviate from the spirit and scope of the present invention; Any based on conspicuous changes such as the equivalent transformation on the technical scheme of the present invention basis, simple replacements, all belong within the protection domain of the present invention.

Claims (9)

1. double-sided display smectic liquid crystal color monitor; It is characterized in that: it comprises LCD MODULE; This LCD MODULE comprises first base layer and second base layer; Be provided with mixolimnion between this first base layer and this second base layer, this mixolimnion is mixed by smectic liquid crystal, conducting objects, spacer or this mixolimnion comprises and is encapsulated in the potpourri of being made up of smectic liquid crystal, conducting objects and spacer in the polymer architecture; This first base layer is provided with first conductive electrode layer towards a side of this mixolimnion; This second base layer is provided with second conductive electrode layer towards a side of this mixolimnion, is provided with the colour element layer in a wherein side of this first base layer or a wherein side of this second base layer.
2. double-sided display smectic liquid crystal color monitor as claimed in claim 1 is characterized in that:
Said colour element layer is RGBW type colour element layer or RGB type colour element layer or RGBY type colour element layer or CMYK type colour element layer.
3. double-sided display smectic liquid crystal color monitor as claimed in claim 2 is characterized in that:
If said colour element layer is a RGBW type colour element layer; Then: said first conductive electrode layer is made up of 2M strip line electrode that is arranged in parallel; Said second conductive electrode layer is made up of 2N strip row electrode that is arranged in parallel; 2N strip row electrode of the 2M of said first conductive electrode layer strip line electrode and said second conductive electrode layer be quadrature mutually, so that said first conductive electrode layer and said second conductive electrode layer form the sub-pixel lattice array of a 2M * 2N; Said RGBW type colour element layer is made up of M * N colour developing unit, and each this colour developing unit is made up of the R color lump that is arranged in 2 * 2 matrix structures, G color lump, B color lump, four color lumps of W color lump; Said first conductive electrode layer is corresponding one by one with 2M * 2N color lump with 2M * 2N subpixels point that said second conductive electrode layer is constituted; The pairing 4 subpixels points of four color lumps that are somebody's turn to do in the colour developing unit constitute a pixel;
If said colour element layer is a RGB type colour element layer; Then: said first conductive electrode layer is made up of M strip line electrode that is arranged in parallel; Said second conductive electrode layer is made up of 3N strip row electrode that is arranged in parallel; 3N strip row electrode of the M of said first conductive electrode layer strip line electrode and said second conductive electrode layer be quadrature mutually, so that said first conductive electrode layer and said second conductive electrode layer form the sub-pixel lattice array of a M * 3N; Said RGB type colour element layer is made up of M * N colour developing unit, and each this colour developing unit is made up of the R color lump that is arranged in 1 * 3 matrix structure, G color lump, three color lumps of B color lump; Said first conductive electrode layer is corresponding one by one with M * 3N color lump with M * 3N subpixels point that said second conductive electrode layer is constituted; The pairing 3 subpixels points of three color lumps that are somebody's turn to do in the colour developing unit constitute a pixel;
If said colour element layer is a RGBY type colour element layer; Then: said first conductive electrode layer is made up of 2M strip line electrode that is arranged in parallel; Said second conductive electrode layer is made up of 2N strip row electrode that is arranged in parallel; 2N strip row electrode of the 2M of said first conductive electrode layer strip line electrode and said second conductive electrode layer be quadrature mutually, so that said first conductive electrode layer and said second conductive electrode layer form the sub-pixel lattice array of a 2M * 2N; Said RGBY type colour element layer is made up of M * N colour developing unit, and each this colour developing unit is made up of the R color lump that is arranged in 2 * 2 matrix structures, G color lump, B color lump, four color lumps of Y color lump; Said first conductive electrode layer is corresponding one by one with 2M * 2N color lump with 2M * 2N subpixels point that said second conductive electrode layer is constituted; The pairing 4 subpixels points of four color lumps that are somebody's turn to do in the colour developing unit constitute a pixel;
If said colour element layer is a CMYK type colour element layer; Then: said first conductive electrode layer is made up of 2M strip line electrode that is arranged in parallel; Said second conductive electrode layer is made up of 2N strip row electrode that is arranged in parallel; 2N strip row electrode of the 2M of said first conductive electrode layer strip line electrode and said second conductive electrode layer be quadrature mutually, so that said first conductive electrode layer and said second conductive electrode layer form the sub-pixel lattice array of a 2M * 2N; Said CMYK type colour element layer is made up of M * N colour developing unit, and each this colour developing unit is made up of the C color lump that is arranged in 2 * 2 matrix structures, M color lump, Y color lump, four color lumps of K color lump; Said first conductive electrode layer is corresponding one by one with 2M * 2N color lump with 2M * 2N subpixels point that said second conductive electrode layer is constituted; The pairing 4 subpixels points of four color lumps that are somebody's turn to do in the colour developing unit constitute a pixel.
4. double-sided display smectic liquid crystal color monitor as claimed in claim 3 is characterized in that:
Said color lump is that optical filter or fluorescent powder are processed.
5. like claim 1 or 2 or 3 described double-sided display smectic liquid crystal color monitors, it is characterized in that:
When said mixolimnion by smectic liquid crystal, conducting objects, when spacer mixes:
Said smectic liquid crystal be with in silica-based compound, four cyano four octyl group biphenyl or tetraacethyl ester in the last of the ten Heavenly stems four cyano biphenyl any or appoint several kinds mixing;
Said conducting objects is inorganic nano-particle, CNT, Graphene, sodium carbonate, cetyltriethylammonium bromide ethyltriphenylphosphiodide iodide phosphine, (ferrocenyl methyl) trimethyl ammonium iodide, 1 of band conductive characteristic; 2-dimethyl-3-butyl imidazole hexafluorophosphate, tetraethyl amine p-toluenesulfonic esters, phenyl triethyl iodate ammonium, 1-octyl group-3-methylimidazole hexafluorophosphate, two (tetra-n-butyl amine) two (1; 3-dithiole-2-thioketones-4; 5-two mercaptan) palladium (II), tetra-n-butyl close two (1; 3-dithiole-2-thioketones-4; 5-two mercaptan) nickel (III), two (tetra-n-butyl ammoniums) close two (1; 3-dithia cyclopentene-2-thioketones-4,5-two mercaptan) zinc, two (tetra-n-butyl ammoniums) close in four cyano biphenol quinone bismethane, TBAB, cetyl ammonium perchlorate, cetyl bromination four ammoniums, 1-butyl-3-methylimidazole tetrachloro ferrate, methyl triphenyl phosphonium iodide, the tetraphenylphosphoniiodide iodide phosphine any or appoint several kinds mixing;
Said spacer is batching sphere or the spacer rod that polyester material or polystyrene type macromolecular material or glass material are processed;
Consisting of of said mixolimnion: said smectic liquid crystal accounts for the 0.0002%-99.99% that mixes general assembly (TW), and said conducting objects accounts for the 0.0001%-10% that mixes general assembly (TW), and said spacer accounts for the 0.0001%-90% that mixes general assembly (TW).
6. like claim 1 or 2 or 3 described double-sided display smectic liquid crystal color monitors, it is characterized in that:
When said mixolimnion comprises when being encapsulated in the potpourri of being made up of smectic liquid crystal, conducting objects and spacer in the polymer architecture:
Said smectic liquid crystal be with in silica-based compound, four cyano four octyl group biphenyl or tetraacethyl ester in the last of the ten Heavenly stems four cyano biphenyl any or appoint several kinds mixing;
Said conducting objects is inorganic nano-particle, CNT, Graphene, sodium carbonate, cetyltriethylammonium bromide ethyltriphenylphosphiodide iodide phosphine, (ferrocenyl methyl) trimethyl ammonium iodide, 1 of band conductive characteristic; 2-dimethyl-3-butyl imidazole hexafluorophosphate, tetraethyl amine p-toluenesulfonic esters, phenyl triethyl iodate ammonium, 1-octyl group-3-methylimidazole hexafluorophosphate, two (tetra-n-butyl amine) two (1; 3-dithiole-2-thioketones-4; 5-two mercaptan) palladium (II), tetra-n-butyl close two (1; 3-dithiole-2-thioketones-4; 5-two mercaptan) nickel (III), two (tetra-n-butyl ammoniums) close two (1; 3-dithia cyclopentene-2-thioketones-4,5-two mercaptan) zinc, two (tetra-n-butyl ammoniums) close in four cyano biphenol quinone bismethane, TBAB, cetyl ammonium perchlorate, cetyl bromination four ammoniums, 1-butyl-3-methylimidazole tetrachloro ferrate, methyl triphenyl phosphonium iodide or the tetraphenylphosphoniiodide iodide phosphine any or appoint several kinds mixing;
Said spacer is batching sphere or the spacer rod that polyester material or polystyrene type macromolecular material or glass material are processed;
Said polymer architecture by unimolecule body material or polymerizable molecular material through direct printing or etching or nano impression or spraying get ready said first and/or the medial surface of second conductive electrode layer on; Heat curing or ultra-violet curing are that the polymerizable molecular material with setting structure forms, and this unimolecule body material is any in epoxy resin, polyacrylate or the polymethacrylate monomer;
Consisting of of said mixolimnion: said smectic liquid crystal accounts for the 0.0002%-99.99% that mixes general assembly (TW); Said polymerizable molecular material accounts for the 0.0001%-80% that mixes general assembly (TW); Said conducting objects accounts for the 0.0001%-10% that mixes general assembly (TW), and said spacer accounts for the 0.0001%-80% that mixes general assembly (TW).
7. double-sided display smectic liquid crystal color monitor as claimed in claim 6 is characterized in that:
Said polymer architecture is formed with the accommodating chamber of holding the potpourri that said smectic liquid crystal, conducting objects and spacer form, and said polymer architecture is that spherical, little cylindric, thread, hemispherical, parallel strip, cube, rectangular parallelepiped, the intersection of rule is traditional thread binding, in the mixed structure of network structure, square grid minor structure, irregular polygon structure or above-mentioned multiple structure any; Said polymer architecture is even or inhomogeneous; Each other miscible or disperse or be in contact with one another or at interval between said polymer architecture and said smectic liquid crystal, conducting objects and the spacer.
8. double-sided display smectic liquid crystal color monitor as claimed in claim 1 is characterized in that:
Said mixolimnion is mixed with dichroic dye.
9. like claim 1 or 2 or 3 described double-sided display smectic liquid crystal color monitors, it is characterized in that:
The two sides, front and back of said LCD MODULE is the viewing area, at least one side of said LCD MODULE or near be provided with illumination module; This illumination module comprises a plurality of irradiation lights, and these a plurality of irradiation lights are other to be provided with the lens on the light deflection of irradiation light emission, tilt one of them viewing area of even directive or two viewing areas.
CN2011101192683A 2011-05-10 2011-05-10 Dual-face display smectic phase liquid crystal color display Pending CN102778775A (en)

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CN103257474A (en) * 2013-03-15 2013-08-21 京东方科技集团股份有限公司 Double-sided display panel and double-sided display device
CN106125386A (en) * 2016-06-27 2016-11-16 京东方科技集团股份有限公司 Polymer dispersed liquid-crystal film and preparation and control method, display floater and device
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Application publication date: 20121114