CN102775098A - Fireproof heat-insulating material as well as preparation method and application thereof - Google Patents
Fireproof heat-insulating material as well as preparation method and application thereof Download PDFInfo
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- CN102775098A CN102775098A CN2012102374611A CN201210237461A CN102775098A CN 102775098 A CN102775098 A CN 102775098A CN 2012102374611 A CN2012102374611 A CN 2012102374611A CN 201210237461 A CN201210237461 A CN 201210237461A CN 102775098 A CN102775098 A CN 102775098A
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- insulation material
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- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 239000011810 insulating material Substances 0.000 title abstract 5
- 239000000843 powder Substances 0.000 claims abstract description 35
- 229920001971 elastomer Polymers 0.000 claims abstract description 21
- 235000019354 vermiculite Nutrition 0.000 claims abstract description 20
- 239000004568 cement Substances 0.000 claims abstract description 18
- 239000010455 vermiculite Substances 0.000 claims abstract description 18
- 229910052902 vermiculite Inorganic materials 0.000 claims abstract description 18
- 239000011324 bead Substances 0.000 claims abstract description 16
- 239000004570 mortar (masonry) Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000012774 insulation material Substances 0.000 claims description 43
- 239000003063 flame retardant Substances 0.000 claims description 41
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 239000011521 glass Substances 0.000 claims description 16
- 239000004575 stone Substances 0.000 claims description 15
- 239000004816 latex Substances 0.000 claims description 14
- 229920000126 latex Polymers 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 11
- 238000010276 construction Methods 0.000 claims description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical group [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- 239000004088 foaming agent Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- 235000017550 sodium carbonate Nutrition 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 6
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 abstract 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 abstract 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 abstract 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 abstract 1
- 239000008262 pumice Substances 0.000 abstract 1
- 238000005469 granulation Methods 0.000 description 21
- 230000003179 granulation Effects 0.000 description 21
- 210000001138 tear Anatomy 0.000 description 12
- 238000005516 engineering process Methods 0.000 description 5
- 238000009413 insulation Methods 0.000 description 5
- 239000004566 building material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- -1 polyphenylene Polymers 0.000 description 2
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006327 polystyrene foam Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Landscapes
- Building Environments (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention relates to a fireproof heat-insulating material as well as a preparation method and application thereof. The fireproof heat-insulating material comprises the following components in percentage by weight: 10-30 percent of monrolite, 10-40 percent of glazed hollow bead, 10-20 percent of pumice, 10-20 percent of vermiculite, 5-20 percent of hydroxypropyl methyl cellulose, 5-20 percent of renewable dispersed emulsion powder, 5-20 percent of cement, 10-20 percent of rubber powder and 5-10 percent of vesicant. The fireproof heat-insulating material is mixed with water to prepare fireproof heat-insulating mortar which is directly smeared on the surface of a wall body. The fireproof heat-insulating material has the advantages of low cost, low water absorption, low coefficient of heat conductivity, stability and favorable heat-insulating and fire resisting effects; and the obtained product is granular and is convenient to transport.
Description
Technical field
The present invention relates to a kind of fire-retardant heat-insulation material and preparation method thereof, belong to building field.
Background technology
The lagging material of market circulation now, performance are perfect inadequately, and fire resistance is poor, need caking agent, the construction trouble, and solid, firm performance reduces relatively, and it is big to cut consumption of natural resource, and structure waits to optimize., still do not prevent fires though have lower water-intake rate and heat conductivility such as (polystyrene foam plate, polyurathamc); With cement is the inorganic heat preserving and heat insulation material of caking agent, (like foamed cement material, cement based perlite material, concrete-based polyphenylene granule putty) water-intake rate and thermal conductivity is higher, energy-saving effect is bad; The warming plate complex manufacturing technology that other inorganic materials (like multicellular glass, float pearl) are produced, fragility is big, and difficulty of construction is big, and cost is high.
Summary of the invention
Technical problem to be solved by this invention provides a kind of fire-retardant heat-insulation material, overcomes in the prior art at the bottom of the lagging material water-intake rate and heat conductivility, and complex process, fragility is big, and difficulty of construction is big, the defective that cost is high.
The technical scheme that the present invention solves the problems of the technologies described above is following: a kind of fire-retardant heat-insulation material comprises following each component of weight percent: fibrolite 10%～30%, glass bead 10%～40%, float stone 10%～20%, vermiculite 10%～20%, vermiculite 10%～20%, Vltra tears 5%～20%, renewable dispersed latex powder 5%～20%, cement 5%～20%, rubber powder 10%～20%, whipping agent 5%～10%.
The invention has the beneficial effects as follows: this fire-retardant heat-insulation material main raw material has adopted inorganic materials such as fibrolite, glass bead, float stone, vermiculite, vermiculite not only with low cost; And water-intake rate is low, thermal conductivity is low; Stability, insulation, flameproof effect are good; And, be convenient to transportation because the product of processing is a particulate state.
On the basis of technique scheme, the present invention can also do following improvement.
Further, said rubber powder is the resin rubber powder.Like levigated rubber powders such as rubber, resin, high molecular polymers, perhaps adopt pitch is carried out mild oxidation processing, thereby make the improved asphalt mixture of bituminous performance.These materials can play bonding effect.
Further, said whipping agent is an inorganic foaming agent.Further, inorganic foaming agent is sodium hydrogencarbonate or yellow soda ash.Decomposition temperature is about 100～140 ℃, and emits portion C O
2, can produce bubble and play heat insulation effect.
The present invention also comprises a kind of preparation method of fire-retardant heat-insulation material, may further comprise the steps:
(1) takes by weighing following each material by weight percentage: fibrolite 10%～30%, glass bead 10%～40%, float stone 10%～20%, vermiculite 10%～20%, vermiculite 10%～20%, Vltra tears 5%～20%, renewable dispersed latex powder 5%～20%, cement 5%～20%, rubber powder 10%～20%, whipping agent 5%～10%;
(2) material that takes by weighing is mixed spray in the adding tablets press, process the powdery granulation.
Further, also comprise the application of a kind of described fire-retardant heat-insulation material in construction wall, described fire-retardant heat-insulation material and water are processed the fireproof heat insulating mortar behind 2:1～3:1 mixing, directly spread upon the inboard and/or the outside of construction wall.
Further, said fire-retardant heat-insulation material and water are mixed and made into the fireproof heat insulating mortar by weight 2.5:1.
Adopt the beneficial effect of above-mentioned further scheme to be: inorganic fireproofing insulation material and water are mixed into the paste mortar; Directly spread upon on the body of wall, do not shrink at the tie point place, do not ftracture, without grid cloth, the outside directly tiling with whitewash; Promptly form fireproof thermal-insulation layer after the drying; Not only with low cost, technology is simple, has low thermal conductivity simultaneously, has good heat insulation effect.
Embodiment
Below principle of the present invention and characteristic are described, institute gives an actual example and only is used to explain the present invention, is not to be used to limit scope of the present invention.
Embodiment 1
Prepare fire-retardant heat-insulation material of the present invention
Fibrolite 10%, glass bead 40%, float stone 10%, vermiculite 10%, Vltra tears 5%, renewable dispersed latex powder 5%, cement 5%, rubber powder 5%, sodium hydrogencarbonate 10%; After mixing; In granulation, carry out granulation; Promptly be prepared into granular fire-retardant heat-insulation material, be up to the standards and use.
Embodiment 2
Prepare fire-retardant heat-insulation material of the present invention
The renewable dispersed latex powder of fibrolite 25%, glass bead 15%, float stone 10%, vermiculite 15%, Vltra tears 10%, German gill 10%, cement 5%, rubber powder 5%, whipping agent 5%; After mixing; In granulation, carry out granulation; Promptly be prepared into granular fire-retardant heat-insulation material, be up to the standards and use.
Embodiment 3
Prepare fire-retardant heat-insulation material of the present invention
Fibrolite 30%, glass bead 10%, float stone 10%, vermiculite 15%, Vltra tears 5%, renewable dispersed latex powder 10%, cement 5%, rubber powder 10%, yellow soda ash 5%; After mixing; In granulation, carry out granulation; Promptly be prepared into granular fire-retardant heat-insulation material, be up to the standards and use.
Embodiment 4
Prepare fire-retardant heat-insulation material of the present invention
Fibrolite 15%, glass bead 25%, float stone 10%, vermiculite 15%, Vltra tears 5%, renewable dispersed latex powder 10%, cement 5%, rubber powder 10%, whipping agent 5%; After mixing; In granulation, carry out granulation; Promptly be prepared into granular fire-retardant heat-insulation material, be up to the standards and use.
Embodiment 5
Prepare fire-retardant heat-insulation material of the present invention
Fibrolite 15%, glass bead 25%, float stone 20%, vermiculite 15%, Vltra tears 5%, renewable dispersed latex powder 5%, cement 5%, rubber powder 5%, whipping agent 5%; After mixing; In granulation, carry out granulation, promptly be prepared into granular fire-retardant heat-insulation material, be up to the standards and use.
Embodiment 6
Prepare fire-retardant heat-insulation material of the present invention
Fibrolite 15%, glass bead 20%, float stone 20%, vermiculite 20%, Vltra tears 5%, renewable dispersed latex powder 5%, cement 5%, rubber powder 5%, whipping agent 5%; After mixing; In granulation, carry out granulation, promptly be prepared into granular fire-retardant heat-insulation material, be up to the standards and use.
Embodiment 7
Prepare fire-retardant heat-insulation material of the present invention
Fibrolite 15%, glass bead 10%, float stone 20%, vermiculite 10%, Vltra tears 5%, renewable dispersed latex powder 15%, cement 10%, rubber powder 10%, whipping agent 5%; After mixing; In granulation, carry out granulation; Promptly be prepared into granular fire-retardant heat-insulation material, be up to the standards and use.
Embodiment 8
Prepare fire-retardant heat-insulation material of the present invention
Fibrolite 15%, glass bead 10%, float stone 10%, vermiculite 10%, Vltra tears 5%, renewable dispersed latex powder 20%, cement 20%, rubber powder 5%, whipping agent 5%; After mixing; In granulation, carry out granulation; Promptly be prepared into granular fire-retardant heat-insulation material, be up to the standards and use.
Embodiment 9
Prepare fire-retardant heat-insulation material of the present invention
Take by weighing following each material by weight percentage: 15 kilograms of fibrolites, 10 kilograms of glass beads, 10 kilograms of float stones, 10 kilograms of vermiculites, 20 kilograms of Vltra tearss, 5 kilograms of renewable dispersed latex powder, 20 kilograms of cement, 5 kilograms of rubber powders, 5 kilograms of whipping agents; After mixing; In granulation, carry out granulation; Promptly be prepared into granular fire-retardant heat-insulation material, be up to the standards and use.
Embodiment 10
Take by weighing following each material by weight percentage: 15 kilograms of fibrolites, 10 kilograms of glass beads, 10 kilograms of float stones, 10 kilograms of vermiculites, 20 kilograms of Vltra tearss, 5 kilograms of renewable dispersed latex powder, 20 kilograms of cement, 5 kilograms of rubber powders, 5 kilograms of whipping agents; After mixing; In granulation, carry out granulation; Promptly be prepared into granular fire-retardant heat-insulation material, be up to the standards and use.
Embodiment 11
The application that the fire-retardant heat-insulation material for preparing preparation of the present invention prepares the fireproof heat insulating mortar when mixing with water
67 kilograms of fire-retardant heat-insulation materials, 33 kilograms in water, two component gross weights are 100 kilograms, mix to make the fireproof heat insulating mortar, directly spread upon on the construction wall, about 4 to 5 centimeters.
This fireproof heat insulating mortar ultimate compression strength is greater than 0.15MPa, and cohesive strength is greater than being 80Kpa.
Embodiment 11
The application that the fire-retardant heat-insulation material for preparing preparation of the present invention prepares the fireproof heat insulating mortar when mixing with water
75 kilograms of fire-retardant heat-insulation materials, 25 kilograms in water, two component gross weights are 100 kilograms, mix and make the fireproof heat insulating mortar, directly spread upon on the construction wall.
Thermal insulation mortar of the present invention is applied in the body of wall of processing on the body of wall, detects through the national building materials center, and this fireproof heat insulating mortar ultimate compression strength is greater than 0.15MPa, and cohesive strength is greater than being 80Kpa, dry density≤250kg/m
3, volumetric shrinkage≤7%, slurry density≤1000kg/m
3
Detect dry density 301～400kg/m through national building materials industrial technology supervision research centre, building material industry dry-mixed mortar product quality supervision and inspection test center
3, thermal conductivity (70 ℃ of medial temperatures)≤0.044 watt/Mi Du.
Building machinery material installation product quality supervision and inspection station is detected through Hebei province, dry density≤300kg/m
3, tensile strength is greater than 0.10Mpa, thermal conductivity≤0.07 watt/Mi Du, and cohesive strength is greater than being 50Kpa, and combustionproperty meets the A1 level, and mass loss is less than 50%, sustained combustion time t
fBe 0, building materials combustion heat value, PCS
a≤2.0, PCS
b≤2.0, PCS
c≤2.0 PCS
d≤2.0.
The above is merely preferred embodiment of the present invention, and is in order to restriction the present invention, not all within spirit of the present invention and principle, any modification of being done, is equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (7)
1. fire-retardant heat-insulation material; It is characterized in that, comprise following each component of weight percent: fibrolite 10%～30%, glass bead 10%～40%, float stone 10%～20%, vermiculite 10%～20%, vermiculite 10%～20%, Vltra tears 5%～20%, renewable dispersed latex powder 5%～20%, cement 5%～20%, rubber powder 10%～20%, whipping agent 5%～10%.
2. fire-retardant heat-insulation material according to claim 1 is characterized in that, said rubber powder is the resin rubber powder.
3. fire-retardant heat-insulation material according to claim 1 is characterized in that, said whipping agent is an inorganic foaming agent.
4. fire-retardant heat-insulation material according to claim 3 is characterized in that, said inorganic foaming agent is sodium hydrogencarbonate or yellow soda ash.
5. the preparation method of each described fire-retardant heat-insulation material of claim 1 to 4 may further comprise the steps:
(1) takes by weighing following each material by weight percentage: fibrolite 10%～30%, glass bead 10%～40%, float stone 10%～20%, vermiculite 10%～20%, Vltra tears 5%～20%, renewable dispersed latex powder 5%～20%, cement 5%～20%, rubber powder 10%～20%, whipping agent 5%～10%;
(2) above-mentioned substance that takes by weighing is mixed spray in the adding tablets press, process powdered granule.
6. the application of each described fire-retardant heat-insulation material of claim 1 to 4; It is characterized in that; Each described fire-retardant heat-insulation material of claim 1 to 4 and water are processed the fireproof heat insulating mortar behind 2:1～3:1 mixing, directly spread upon the inboard and/or the outside of construction wall.
7. according to the application of the said described fire-retardant heat-insulation material of claim 6, it is characterized in that said fire-retardant heat-insulation material and water are mixed and made into the fireproof heat insulating mortar by weight 2.5:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210237461.1A CN102775098B (en) | 2012-07-10 | 2012-07-10 | A kind of fire-retardant heat-insulation material and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210237461.1A CN102775098B (en) | 2012-07-10 | 2012-07-10 | A kind of fire-retardant heat-insulation material and its preparation method and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102775098A true CN102775098A (en) | 2012-11-14 |
| CN102775098B CN102775098B (en) | 2015-12-16 |
Family
ID=47120236
Family Applications (1)
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|---|---|---|---|
| CN201210237461.1A Active CN102775098B (en) | 2012-07-10 | 2012-07-10 | A kind of fire-retardant heat-insulation material and its preparation method and application |
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| Country | Link |
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| CN (1) | CN102775098B (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103804012A (en) * | 2012-11-14 | 2014-05-21 | 神华集团有限责任公司 | Fireproof thermal insulation material and preparation method and application thereof |
| CN103964775A (en) * | 2014-05-20 | 2014-08-06 | 潜山县新型工程建筑材料有限公司 | Fireproof thermal-insulation material |
| CN104909670A (en) * | 2015-06-16 | 2015-09-16 | 合肥吉科新材料有限公司 | Light waterproof glass bead thermal insulation mortar and manufacturing method thereof |
| CN106587767A (en) * | 2016-12-05 | 2017-04-26 | 苏州洛特兰新材料科技有限公司 | Fireproof weather-proof heat-insulating paint used for building exterior wall and preparation method thereof |
| CN106673528A (en) * | 2017-01-03 | 2017-05-17 | 佛山石湾鹰牌陶瓷有限公司 | High-strength unfired water-permeable brick and preparation method thereof |
| CN106904887A (en) * | 2017-03-03 | 2017-06-30 | 安徽省宿州市贯华化工有限公司 | A kind of thermal insulation mortar |
| CN108298883A (en) * | 2018-03-29 | 2018-07-20 | 福建三凯建筑材料有限公司 | It is a kind of using useless brick powder as the heat preserving dry powder mortar of raw material |
| CN109081659A (en) * | 2018-08-08 | 2018-12-25 | 赵丽敏 | A kind of heat insulating board and preparation method thereof with fire-proof function |
| CN109231919A (en) * | 2018-10-16 | 2019-01-18 | 安徽省绩溪县华宇防火滤料有限公司 | A kind of antibacterial fire proofing material and its preparation method and application |
| CN109305783A (en) * | 2018-10-16 | 2019-02-05 | 安徽省绩溪县华宇防火滤料有限公司 | A kind of fire proofing material and its preparation method and application for wall |
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| CN102359237A (en) * | 2011-08-30 | 2012-02-22 | 信阳金固建筑节能保温工程有限公司 | Inorganic vitrified micro bubble external heat-insulating system for outer wall |
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| JP2001019566A (en) * | 1999-07-07 | 2001-01-23 | Ngk Insulators Ltd | Heat-insulating spraying material and forming of furnace wall structure using the material |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103804012A (en) * | 2012-11-14 | 2014-05-21 | 神华集团有限责任公司 | Fireproof thermal insulation material and preparation method and application thereof |
| CN103804012B (en) * | 2012-11-14 | 2015-07-29 | 神华集团有限责任公司 | A kind of fire-retardant heat-insulation material and its preparation method and application |
| CN103964775A (en) * | 2014-05-20 | 2014-08-06 | 潜山县新型工程建筑材料有限公司 | Fireproof thermal-insulation material |
| CN103964775B (en) * | 2014-05-20 | 2016-02-17 | 潜山县新型工程建筑材料有限公司 | A kind of fire-retardant heat-insulation material |
| CN104909670A (en) * | 2015-06-16 | 2015-09-16 | 合肥吉科新材料有限公司 | Light waterproof glass bead thermal insulation mortar and manufacturing method thereof |
| CN106587767B (en) * | 2016-12-05 | 2018-11-02 | 河北晨阳工贸集团有限公司 | A kind of weather-proof thermal insulation coatings and preparation method thereof used for building exterior wall of preventing fires |
| CN106587767A (en) * | 2016-12-05 | 2017-04-26 | 苏州洛特兰新材料科技有限公司 | Fireproof weather-proof heat-insulating paint used for building exterior wall and preparation method thereof |
| CN106673528A (en) * | 2017-01-03 | 2017-05-17 | 佛山石湾鹰牌陶瓷有限公司 | High-strength unfired water-permeable brick and preparation method thereof |
| CN106673528B (en) * | 2017-01-03 | 2020-03-31 | 佛山石湾鹰牌陶瓷有限公司 | High-strength baking-free water permeable brick and preparation method thereof |
| CN106904887A (en) * | 2017-03-03 | 2017-06-30 | 安徽省宿州市贯华化工有限公司 | A kind of thermal insulation mortar |
| CN108298883A (en) * | 2018-03-29 | 2018-07-20 | 福建三凯建筑材料有限公司 | It is a kind of using useless brick powder as the heat preserving dry powder mortar of raw material |
| CN109081659A (en) * | 2018-08-08 | 2018-12-25 | 赵丽敏 | A kind of heat insulating board and preparation method thereof with fire-proof function |
| CN109231919A (en) * | 2018-10-16 | 2019-01-18 | 安徽省绩溪县华宇防火滤料有限公司 | A kind of antibacterial fire proofing material and its preparation method and application |
| CN109305783A (en) * | 2018-10-16 | 2019-02-05 | 安徽省绩溪县华宇防火滤料有限公司 | A kind of fire proofing material and its preparation method and application for wall |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102775098B (en) | 2015-12-16 |
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