CN102775093A - Artificial stone plate and manufacture method of artificial stone plate - Google Patents
Artificial stone plate and manufacture method of artificial stone plate Download PDFInfo
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- CN102775093A CN102775093A CN2012101339856A CN201210133985A CN102775093A CN 102775093 A CN102775093 A CN 102775093A CN 2012101339856 A CN2012101339856 A CN 2012101339856A CN 201210133985 A CN201210133985 A CN 201210133985A CN 102775093 A CN102775093 A CN 102775093A
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Abstract
The invention discloses an artificial stone plate and a manufacture method of the artificial stone plate. A recipe of the artificial stone plate consists of the following ingredients in percentage by mass: 28 percent to 30 percent of unsaturated polyester resin, 40 percent to 65 percent of aluminium hydroxide, 5 to 30 percent of shells crushed into shells with the grain diameter being 1 to 5cm, 0.02 percent to 0.04 percent of cobalt naphthenate, 0.03 percent to 0.05 percent of methyl ethyl ketone peroxide and 1 percent to 2 percent of pigment paste. The artificial stone plate and the manufacture method have the advantages that 1, the shell plate has the effects that the environment is protected, and the toxicity and the radiation are avoided; 2, the artificial plate has uniform density from the inside to the outside and is solid and integral, the surface is smooth, no fine hole exists, the germ propagation is effectively avoided, and the cleaning is easy; 3, the color is gorgeous, the free matching of the color of the shell plate can be realized, and the effect is incomparable with the single performance of the natural rock; 4, the shell plate can be processed in a seamless split joint manner, and the shell plate can be easily bent to be made into various shapes; and 5, the invention also provides the manufacture method of the artificial stone, which has the advantages that the process is simple, and the manufacture is safe and convenient.
Description
Technical field
The present invention relates to a kind of rostone manufacture technology field, especially refer to a kind of artificial stone plate and preparation method thereof.
Background technology
Lithotome mainly is divided into two kinds: marble and granite.In general, every veined, be called " marble "; With the stigma is main, is called " granite ".On narrow sense, marble refers to the stone material that the Dali produces.In fact, now to have few stone be to come out in Dali in all parts of the country.Both also can distinguish from the geology notion.Granite is volcanic rock, also is the acidic crystallization plutonite, is the widest a kind of rock that distributes in the volcanic rock, is made up of feldspar, quartz and mica, and rock matter is hard closely knit.Its composition is main with silicon-dioxide, accounts for 65%～75%.So-called volcanic rock is exactly the rock that underground magma or the volcano lava condensation-crystallization of spraying and spoiling over forms.The content of silicon-dioxide, felspathic character and content thereof have determined the character of stone material in the volcanic rock.When the content of silicon-dioxide greater than 65%, just belong to persilicic rock, when essential minerals such as potash feldspar, plagioclase, quartz form crystal in this rock, be material shape structure, just be called granite.And marble is the metamorphosed rock that original rock forms through HTHP effect in the earth's crust in the earth's crust.The endogenic process of the earth's crust is impelled the variation of each original rocks generation matter, and promptly the structure of original rocks, structure and mineralogical composition change.The new rock that forms through qualitative change is called metamorphosed rock.
Because there is pore on the lithotome surface, thus aspect resistant relative mistake some, generally all can handle on its surface in source mill.In interior decoration, suitable use marbles such as televisor table top, windowsill, flooring.And threshold, cabinet table top, outdoor ground just are fit to use granite.Wherein the cabinet platform is seen and is to use dark granite.The lithotome of selling on the market now, part color and luster be through manual handling, and these stone materials generally use year will manifest its true appearance half a year to one.Be to be apparent that present Dark Green on the market, a lot of all dyeing form, and are not real primary colors.Be noted that back side grid in addition, this situation occurring has two kinds: 1. stone material itself is more crisp, must add grid, for example Cream Marfil.2. use inferior materials and turn out substandard goods, the thickness of these stone materials is by skiving, and insufficient strength be so need add network.
The artificial stone-like material is to be cakingagent with the unsaturated polyester resin; Be equipped with inorganics powders such as natural marble or calcite, rhombspar, silica sand, glass powder; And an amount of fire retardant, color etc., process through method forming and hardenings such as batch mixes, porcelain casting, vibrocompression, extruding.The artificial stone-like material finds out according to the problem that lithotome is actual in using, and it is all having significant progress aspect protection against the tide, acid-proof, high temperature resistant, the piecing together property.But during artificial stone-like material's shortcoming, rostone general nature property is obviously not enough, and texture is relatively false, thus generally be used to the place that cabinet etc. is had relatively high expectations for practicality, and in the certain adverse environment, for example kitchen, toilet etc.; Ornamental place is stressed on windowsill, ground etc.Another shortcoming is.Because the manufacture craft of rostone is widely different, performance, characteristic are also not quite identical.And a lot of home-made rostones obviously can not be supported this floating of professionals, and polishing is mashed more more.So produce qualified artificial stone-like material and rational manufacture craft, ready-made is the requirements that people urgently hope.
Existing a kind of application number is 03118884.2 and is called the Chinese invention patent of " artificial stone plate's prescription and production technique ", discloses a kind of structure, and this invention is characterised in that: described artificial stone plate's raw material is made up of unsaturated polyester and mica powder basically.Problems such as this artificial stone plate can effectively solve distortion that traditional artificial stone plate occurs in use for some time, fade also have exquisite decorative pattern and abundant colors, are good building materials and decorative materials.But its shortcoming is that prescription is unreasonable, and the wood-based plate surface of production has pore, and slickness is not enough.So in use the phenomenon that dirt penetrates into sheet material will occur, be easy to generate growing of bacterium, be not easy to cleaning.Said its prescription awaits to improve with making method.
Summary of the invention
First technical problem to be solved by this invention is to above-mentioned prior art present situation and provide a kind of density from the inside to surface even, solid one, smooth surface impunctate and in use the artificial stone plate that dirt penetrates into can not occur.
Second technical problem to be solved by this invention is to provide a kind of technology simple to above-mentioned prior art present situation; Make safe ready, the artificial stone plate of making has the smooth surface impunctate and dirt in use can not occur and penetrates into the artificial stone plate's making method in the entering plate.
The present invention solves the technical scheme that above-mentioned first technical problem adopts: this artificial slabstone; It is characterized in that: said artificial stone plate's prescription consists of: unsaturated polyester resin 28%～30%; White lake 40%～65%, the shell 5%～30% that is ground into 1～5 centimetre of particle diameter, cobalt naphthenate 0.02%～0.04%, methylethyl ketone peroxide 0.03%～0.05%, pigment paste 1%～2%, above-mentioned is mass percent.
As improvement, said pigment paste can be preferably the pigment that particle fineness is made through grinding by saturated polyester resin and pigment powder less than 30um.
Improve, said unsaturated polyester resin can be preferably the unsaturated polyester resin of adjacent benzene series row again.
Improve, described shell is preferably the deep-sea shell again.
The present invention solves above-mentioned second technical scheme that technical problem adopted: the making method of this artificial slabstone, and it is characterized in that: the step of said making method is following:
One, is ready to material according to above-mentioned prescription;
Two, in unsaturated polyester resin, add cobalt naphthenate earlier, and stir with stirrer;
Three, add white lake, shell stopping composition, pigment paste then, and stir with stirrer;
Four, add methylethyl ketone peroxide again, stirred 3～5 minutes with stirrer;
The mixture that five, will stir after 3～5 minutes is put on the mould, mould is advanced in the vacuum forming case again, is evacuated to 3～5 minutes while shaking;
Six, then mould is taken out from the vacuum forming case, under state of nature, solidified 2～3 hours;
Seven, the sheet material after will solidifying again takes out from mould, and is to be incubated 10～20 minutes in 75～85 degree with sheet material in temperature, and it is finalized the design fully;
Eight, the slabstone that will finalize the design fully again is smooth fixed thick through grinder, is the finished product artificial stone plate.
As improvement, in the said step 3, the stirrer churning time is 3 to 4 minutes.
As improvement, said mould can be preferably glass article, so that it is more convenient that wood-based plate is made.
Improve, said sheet material can be chosen in and be incubated typing in the baking box again.
Compared with prior art, the invention has the advantages that:
One, the material selected for use of this shell plate (promptly referring to the artificial stone plate) all is high molecular matrix material, has the characteristic of high-tech, environmental protection, and is nontoxic radiationless.
In the process of two, producing, through the chemical reaction of matrix material, through vibrations step such as find time, sheet material forms unified, fine and close integral body again.Density is even from the inside to surface, solid one, smooth surface impunctate.So in use just the phenomenon that dirt penetrates into sheet material can not occur, stopped growing of bacterium effectively, easy to clean.
Three, lucuriant in design: the color of shell plate is by the pigment paste decision of import; The proportioning of different pigment paste has just produced the shell plate of variety of colors, has greatly enriched the leeway that the guest selects; Can indiscriminately ad. as one wishes carry out colour match, this is that the unicity of natural rock is incomparable.
Four, the processing of shell plate can be seamless spliced, and is crooked arbitrarily, makes various moulding easily, can be widely used in various public and home decorations.
Five, making method technology of the present invention is simple, makes safe ready, and the artificial stone plate of making has the smooth surface impunctate and dirt in use can not occur and penetrates in the entering plate, uses more sanitation and hygiene.
Embodiment
Below the present invention is described in further detail.
The artificial stone plate of embodiment one, present embodiment; Said artificial stone plate's prescription consists of: the unsaturated polyester resin 28% of adjacent benzene series row; White lake 65%, the shell 5% that is ground into 1～5 centimetre of particle diameter, cobalt naphthenate 0.02%, methylethyl ketone peroxide 0.03%, pigment paste 1.95%, said pigment paste are the pigment that particle fineness is made through grinding by saturated polyester resin and pigment powder less than 30um.Above-mentioned is mass percent.The shell of present embodiment is chosen as the deep-sea shell.
The step of the artificial stone plate's of present embodiment making method is following:
One, is ready to material according to above-mentioned prescription;
Two, in unsaturated polyester resin, add cobalt naphthenate earlier, and stir with stirrer;
Three, add white lake, shell stopping composition, pigment paste then, stirrer stirred 3 to 4 minutes, to stirring;
Four, add methylethyl ketone peroxide again, stirred 3～5 minutes with stirrer;
The mixture that five, will stir after 3～5 minutes is put on the mould, mould is advanced in the vacuum forming case again, is evacuated to 3～5 minutes while shaking; The mould of present embodiment is chosen as glass article;
Six, then mould is taken out from the vacuum forming case, under state of nature, solidified 2～3 hours;
Seven, the sheet material after will solidifying again takes out from mould, and sheet material is incubated 10～20 minutes in temperature is the baking box of 75～85 degree, and it is finalized the design fully; Sheet material is incubated typing in baking box;
Eight, the slabstone that will finalize the design fully again is smooth fixed thick through grinder, is the finished product artificial stone plate.
The artificial stone plate of embodiment two, present embodiment; Said artificial stone plate's prescription consists of: the unsaturated polyester resin 30% of adjacent benzene series row; White lake 40%, the shell 28.43% that is ground into 1～5 centimetre of particle diameter, cobalt naphthenate 0.03%, methylethyl ketone peroxide 0.04%, pigment paste 1.5%, said pigment paste are the pigment that particle fineness is made through grinding by saturated polyester resin and pigment powder less than 30um.Above-mentioned is mass percent.
The shell of present embodiment is chosen as the deep-sea shell.
The step of the artificial stone plate's of present embodiment making method is following:
One, is ready to material according to above-mentioned prescription;
Two, in unsaturated polyester resin, add cobalt naphthenate earlier, and stir with stirrer;
Three, add white lake, shell stopping composition, pigment paste then, stirrer stirred 3 to 4 minutes, to stirring;
Four, add methylethyl ketone peroxide again, stirred 3～5 minutes with stirrer;
The mixture that five, will stir after 3～5 minutes is put on the mould, mould is advanced in the vacuum forming case again, is evacuated to 3～5 minutes while shaking; The mould of present embodiment is chosen as glass article;
Six, then mould is taken out from the vacuum forming case, under state of nature, solidified 2～3 hours;
Seven, the sheet material after will solidifying again takes out from mould, and sheet material is incubated 10～20 minutes in temperature is the baking box of 75～85 degree, and it is finalized the design fully; Sheet material is incubated typing in baking box;
Eight, the slabstone that will finalize the design fully again is smooth fixed thick through grinder, is the finished product artificial stone plate.
The artificial stone plate of embodiment three, present embodiment; Said artificial stone plate's prescription consists of: the unsaturated polyester resin 29% of adjacent benzene series row; White lake 50%, the shell 18.91% that is ground into 1～5 centimetre of particle diameter, cobalt naphthenate 0.04%, methylethyl ketone peroxide 0.05%, pigment paste 2%, said pigment paste are the pigment that particle fineness is made through grinding by saturated polyester resin and pigment powder less than 30um.Above-mentioned is mass percent.
The shell of present embodiment is chosen as the deep-sea shell.
The step of the artificial stone plate's of present embodiment making method is following:
One, is ready to material according to above-mentioned prescription;
Two, in unsaturated polyester resin, add cobalt naphthenate earlier, and stir with stirrer;
Three, add white lake, shell stopping composition, pigment paste then, stirrer stirred 3 to 4 minutes, to stirring;
Four, add methylethyl ketone peroxide again, stirred 3～5 minutes with stirrer;
The mixture that five, will stir after 3～5 minutes is put on the mould, mould is advanced in the vacuum forming case again, is evacuated to 3～5 minutes while shaking; The mould of present embodiment is chosen as glass article;
Six, then mould is taken out from the vacuum forming case, under state of nature, solidified 2～3 hours;
Seven, the sheet material after will solidifying again takes out from mould, and sheet material is incubated 10～20 minutes in temperature is the baking box of 75～85 degree, and it is finalized the design fully; Sheet material is incubated typing in baking box;
Eight, the slabstone that will finalize the design fully again is smooth fixed thick through grinder, is the finished product artificial stone plate.
Below technical process of the present invention is done to advance explanation:
Calculate:, calculate gross weight and produce the needed various materials of this sheet material, like unsaturated polyester resin, stopping composition, auxiliary agent, pigment paste etc. according to the size of required sheet material.
Produce:
1. earlier in unsaturated polyester resin, add cobalt naphthenate, stir about 1 minute of time spent with impeller.
2. and then add ready stopping composition, pigment paste, again with mixing machine stirs about 3 minutes of time spent at a high speed.
3. add methylethyl ketone peroxide at last, stirred 4 minutes with impeller.
4. sling the slurry that has stirred in the bucket with loop wheel machine, pour into above the glass article and wipe off.
5. advance glass article in the vacuum forming case, find time process about 3 minutes and 30 seconds while shaking.
6. find time to finish, pull out mould, wait to solidify.
7. after 2 hours, take out sheet material from mould, put the high temperature baking box into, heat to 80 degree.
8. after sheet material was baked through high temperature, typing fully, smooth fixed thick through grinder, a beautiful shell plate has just been produced.
Claims (8)
1. artificial stone plate; It is characterized in that: said artificial stone plate's prescription consists of: unsaturated polyester resin 28%～30%; White lake 40%～65%, the shell 5%～30% that is ground into 1～5 centimetre of particle diameter, cobalt naphthenate 0.02%～0.04%, methylethyl ketone peroxide 0.03%～0.05%, pigment paste 1%～2%, above-mentioned is mass percent.
2. artificial stone plate according to claim 1 is characterized in that: said pigment paste is the pigment that particle fineness is made through grinding by saturated polyester resin and pigment powder less than 30um.
3. artificial stone plate according to claim 2 is characterized in that: said unsaturated polyester resin is the unsaturated polyester resin of adjacent benzene series row.
4. according to arbitrary described artificial stone plate in the claim 1 to 3, it is characterized in that: described shell is the deep-sea shell.
5. arbitrary said artificial stone plate's making method in the claim 1 to 3, it is characterized in that: the step of said making method is following:
One, is ready to material according to above-mentioned prescription;
Two, in unsaturated polyester resin, add cobalt naphthenate earlier, and stir with stirrer;
Three, add white lake, shell stopping composition, pigment paste then, and stir with stirrer;
Four, add methylethyl ketone peroxide again, stirred 3～5 minutes with stirrer;
The mixture that five, will stir after 3～5 minutes is put on the mould, mould is advanced in the vacuum forming case again, is evacuated to 3～5 minutes while shaking;
Six, then mould is taken out from the vacuum forming case, under state of nature, solidified 2～3 hours;
Seven, the sheet material after will solidifying again takes out from mould, and is to be incubated 10～20 minutes in 75～85 degree with sheet material in temperature, and it is finalized the design fully;
Eight, the slabstone that will finalize the design fully again is smooth fixed thick through grinder, is the finished product artificial stone plate.
6. making method according to claim 5 is characterized in that: in the said step 3, the stirrer churning time is 3 to 4 minutes.
7. making method according to claim 5 is characterized in that: said mould is a glass article.
8. making method according to claim 5 is characterized in that: in the said step 7, said sheet material is in baking box, to be incubated typing.
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| CN2012101339856A CN102775093A (en) | 2012-04-28 | 2012-04-28 | Artificial stone plate and manufacture method of artificial stone plate |
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| CN2012101339856A CN102775093A (en) | 2012-04-28 | 2012-04-28 | Artificial stone plate and manufacture method of artificial stone plate |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103358639A (en) * | 2013-07-15 | 2013-10-23 | 肇庆富盛复合材料有限公司 | Jet drawing plate and its manufacturing method |
| CN104725859A (en) * | 2013-12-23 | 2015-06-24 | 唐代全 | Third-dimensional ecologic wallpaper and exterior wall tile |
| CN104802280A (en) * | 2015-04-14 | 2015-07-29 | 天台县德沐洁具厂 | Water tank surface treating method |
| CN107311520A (en) * | 2017-07-29 | 2017-11-03 | 南通戈雅石业有限公司 | A kind of bionical marble formula |
| CN107601968A (en) * | 2017-08-29 | 2018-01-19 | 北京禾木之家科技发展有限公司 | A kind of preparation method of sheet material |
| CN110818338A (en) * | 2019-11-15 | 2020-02-21 | 黄贺明 | Outdoor low-heat-absorption inorganic artificial stone plate and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1335234A (en) * | 2000-07-26 | 2002-02-13 | 李瑞斌 | Making process of artificial shell fossil board |
| CN101003183A (en) * | 2006-01-20 | 2007-07-25 | 金国华 | Method for fabricating artificial stone, and artificial stone with luminescence function, and products |
-
2012
- 2012-04-28 CN CN2012101339856A patent/CN102775093A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1335234A (en) * | 2000-07-26 | 2002-02-13 | 李瑞斌 | Making process of artificial shell fossil board |
| CN101003183A (en) * | 2006-01-20 | 2007-07-25 | 金国华 | Method for fabricating artificial stone, and artificial stone with luminescence function, and products |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103358639A (en) * | 2013-07-15 | 2013-10-23 | 肇庆富盛复合材料有限公司 | Jet drawing plate and its manufacturing method |
| CN103358639B (en) * | 2013-07-15 | 2016-02-03 | 广东富盛新材料股份有限公司 | Air brushing sheet material and manufacture method thereof |
| CN104725859A (en) * | 2013-12-23 | 2015-06-24 | 唐代全 | Third-dimensional ecologic wallpaper and exterior wall tile |
| CN104802280A (en) * | 2015-04-14 | 2015-07-29 | 天台县德沐洁具厂 | Water tank surface treating method |
| CN107311520A (en) * | 2017-07-29 | 2017-11-03 | 南通戈雅石业有限公司 | A kind of bionical marble formula |
| CN107601968A (en) * | 2017-08-29 | 2018-01-19 | 北京禾木之家科技发展有限公司 | A kind of preparation method of sheet material |
| CN110818338A (en) * | 2019-11-15 | 2020-02-21 | 黄贺明 | Outdoor low-heat-absorption inorganic artificial stone plate and preparation method thereof |
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Application publication date: 20121114 |