CN102765991B - Biological, organic and inorganic compound fertilizer and preparation method thereof - Google Patents

Biological, organic and inorganic compound fertilizer and preparation method thereof Download PDF

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CN102765991B
CN102765991B CN201210263642.1A CN201210263642A CN102765991B CN 102765991 B CN102765991 B CN 102765991B CN 201210263642 A CN201210263642 A CN 201210263642A CN 102765991 B CN102765991 B CN 102765991B
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fertilizer
phosphate
powder
organic
inorganic composite
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CN102765991A (en
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吕志伟
张文会
张思亮
王瑾
郭瑞明
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Liaocheng University
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Liaocheng University
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Abstract

The invention discloses biological, organic and inorganic compound fertilizer. The biological, organic and inorganic compound fertilizer comprises, by weight, 20-30 parts of lignin, 10-20 parts of organic fertilizer, 15-25 parts of nitrogen fertilizer, 30-40 parts of phosphorus fertilizer, 5-15 parts of potassium fertilizer, 0.1-0.2 part of EM (effective microorganisms) fungus powder, and 0.1-0.2 part of bacillus subtilis powder. Therefore, microenvironment of soil can be improved evidently, activity of beneficial microorganisms in soil is facilitated, and releasing of phosphorus in soil is facilitated.

Description

A kind of biologic organic, inorganic composite fertilizer and preparation method thereof
Technical field
The invention belongs to soil and fertilizer technical field, specifically relate to a kind of biologic organic, inorganic composite fertilizer and preparation method thereof.
Background technology
China Shi Ge large agricultural country, Water Consumption in Agriculture is at the forefront in the world, along with the excessive exploitation of underground water and peasant plant, depends on chemical fertilizer unduly, and the Secondary Saline degree of soil increases the weight of year by year.Current agriculture production too relies on chemical fertilizer, and chemical fertilizers production and the usage quantity of China occupy No. 1 in the world, and most areas exist the phenomenon of excessive fertilization.According to statistics, between the several years, China's fertilizer application amount has increased by 36.9% in the past, and in fact total output of grain has only increased by 4.7%, drops into and increases but not increase of output.Due to excessive fertilization, also polluted environment, cause soil compaction, physical structure is destroyed.In addition, the utilization rate of fertilizer of China is also not as good as developed country, and reason is mainly that the structure of soil changes, due to storing water and preserving fertility ability reduces.Although agricultural compost, fertilizer etc. can be evaded the problems referred to above completely, simple application of organic fertilizers is impracticable on modern agricultural production.Therefore, development can improve Soil structure, culture fertility, and to decompose and accelerate the biological organic-inorganic compound fertilizer that stalk in soil transforms to toxic substance in soil be the inexorable trend of fertilizer development from now on.
Xylogen is extensively present in natural each kind of plant, the degradeds such as the lignin peroxidase that can be secreted by Soil Microorganism, manganese peroxidase and laccase, mostly intermediates is the product that has bioactive organic acid and contain various active groups, is finally that plant is used.The source of current industrial xylogen is mainly paper mill waste liquid, and its recycle can be significantly improved to economic worth.
Summary of the invention
For deficiencies such as the soil issues existing in current agriculture production, problem of fertilization, the invention provides a kind of biologic organic, inorganic composite fertilizer and preparation method thereof, basic index.
Technical scheme of the present invention is:
A biologic organic, inorganic composite fertilizer, each feed composition is as follows, is weight part: xylogen 20-30, fertilizer 10-20, nitrogenous fertilizer 15-25, phosphate fertilizer 30-40, potash fertilizer 5-15, EM bacteria powder 0.1-0.2, subtilis bacterium powder 0.1-0.2.
A biologic organic, inorganic composite fertilizer, each feed composition is as follows, is weight part: xylogen 22-28, fertilizer 12-18, nitrogenous fertilizer 16-22, phosphate fertilizer 32-38, potash fertilizer 8-12, EM bacteria powder 0.12-0.18, subtilis bacterium powder 0.12-0.18.
A biologic organic, inorganic composite fertilizer, each feed composition is as follows, is weight part: xylogen 26, fertilizer 16, nitrogenous fertilizer 18, phosphate fertilizer 36, potash fertilizer 10, EM bacteria powder 0.16, subtilis bacterium powder 0.16.
Before arbitrary described biologic organic, inorganic composite fertilizer, preferred scheme is, the fertilizer using can be one or more the mixture such as chicken manure after fermentation, pig manure, cow dung.
Before arbitrary described biologic organic, inorganic composite fertilizer, preferred scheme is that described nitrogenous fertilizer can utilize the nitrogen fertilizers such as urea, bicarbonate of ammonia.
Before arbitrary described biologic organic, inorganic composite fertilizer, preferred scheme is that the phosphate fertilizer using can utilize diammonium phosphate, fused(calcium magnesium)phosphate and ground phosphate rock etc. containing phosphatization fertilizer.
Before arbitrary described biologic organic, inorganic composite fertilizer, preferred scheme is that the potash fertilizer using can utilize Repone K, potassium sulfate, saltpetre and potassium breeze etc. containing potassium fertilizer.
Before arbitrary described biologic organic, inorganic composite fertilizer, preferred scheme is that the EM bacteria powder using refers to the EM flora product that cryodrying obtains after solid or liquid fermenting, can make by oneself also and can buy.
Before arbitrary described biologic organic, inorganic composite fertilizer, preferred scheme is that described subtilis bacterium powder refers to the subtilis product that cryodrying obtains after solid or liquid fermenting, can make by oneself also and can buy.
The present invention also provides the preparation method of described biologic organic, inorganic composite fertilizer, comprises that step is as follows:
1, the fertilizer after fermentation is dried in the sun or utilizes dryer to be dried, moisture is down to below 15%, removes foreign material wherein, then with pulverizer, is crushed to certain fineness (preferred powder be broken to 60 orders more than);
2, fertilizer, nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, EM bacterium powder, subtilis bacterium powder and xylogen powder or concentrated solution after pulverizing are mixed in proportion; after stirring, send into tablets press and carry out granulation, after dry (dry at preferred 30-50 ℃), obtain xylogen biologic organic, inorganic composite fertilizer product.
The xylogen that the present invention uses is that the waste liquid in paper mill sprays the dry powdery substance obtaining through concentrating, and main component is calcium lignin sulphonate, is rich in addition the mineral element containing in all timber such as sulphur, phosphorus, potassium.The fertilizer using can be one or more the mixture such as the chicken manure, pig manure, cow dung after fermentation, includes abundant organonitrogen, and also has phosphorus, potassium and trace element etc.Described nitrogenous fertilizer can utilize the nitrogen fertilizers such as urea, bicarbonate of ammonia; Above-mentioned phosphate fertilizer can utilize diammonium phosphate, fused(calcium magnesium)phosphate and ground phosphate rock etc. containing phosphatization fertilizer; Above-mentioned potash fertilizer can utilize Repone K, potassium sulfate, saltpetre and potassium breeze etc. containing potassium fertilizer.Described EM bacterium powder refers to the EM flora product that cryodrying obtains after solid or liquid fermenting, can make by oneself also and can buy.Described subtilis bacterium powder refers to the subtilis product that cryodrying obtains after solid or liquid fermenting, can make by oneself also and can buy.
The object of the invention is to utilize the feature of net macromolecular structure, various active group and its natural slow degradation in soil of lignin molecule, give fertilizer slow release function, improve fertilizer hydrolysis properties.Simultaneously, because lignosulfonic acid calcium product is acid complex compound, after being manured into soil, can improve the potential of hydrogen of soil local microenvironment, reduce the chemical precipitation of reactive phosphate and fix, and can promote degraded and the release of invalid phosphorus in soil, improve the validity of phosphorus.The microbiobacterial agent adding can further improve the effect of utilizing of fertilizer, strengthens soil microbial activities, Promoting plant growth and the ability such as degeneration-resistant.The use of this patent product, can reach the effect that improves soil, the fertile volume increase of joint, protection of the environment, and economic benefit and social benefit are obvious.
In addition, the technical superiority of product of the present invention is also:
1, make full use of all mineral element compositions in the xylogen composition that reclaims and timber from the sewage in paper mill.Can alleviate carrying capacity of environment, turn waste into wealth (discharge of feces of livestock and poultry has at present become one of environmental hazard).
2, improve the utilization ratio of mineral manure, reduce N element, the plain loss of K, improve the utilising efficiency of P element.Improving the organic recycles such as feces of livestock and poultry is worth.
3, can obviously improve the microenvironment of soil, be conducive to beneficial microorganism activity in soil, improve organic transformation efficiency, be conducive to the release of Soil Phosphorus.
4, EM flora can suppress harmful microbe activity in soil, increases the disease resistance of plant, promotes root system development.
5, subtilis can impel the organic matter decomposition in soil to become soil ulmin, stimulates plant growth, has certain fixed nitrogen, phosphorus decomposing, potassium decomposing effect concurrently.
Embodiment
Below in conjunction with embodiment, describe technical scheme of the present invention in detail, but protection domain is not by this restriction.
The present invention is raw materials used all can be bought from market, and such as used xylogen is purchased from Tianjin Ye Zi Chemical Engineering Technology company limited, EM bacteria powder and subtilis bacterium powder are all purchased from the Tian Yi of Zhong Guang group bio tech ltd, Henan.
embodiment 1a kind of biologic organic, inorganic composite fertilizer (granulated product), each feed composition and weight part are as follows, xylogen 30, chicken manure 20, bicarbonate of ammonia 25, diammonium phosphate 32, Repone K 15, EM bacteria powder 0.2, subtilis bacterium powder 0.2.
Preparation method's step is:
1, utilize dryer to be dried the fertilizer after fermentation, moisture is down to below 15%, removes foreign material wherein, more than being then crushed to 60 orders with fertilizer pulverizing machine;
2, fertilizer, nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, EM bacterium powder, subtilis bacterium powder and xylogen powder after pulverizing are mixed in proportion; after stirring, send into tablets press and carry out granulation, after dry at 30-50 ℃ (xylogen) biologic organic, inorganic composite fertilizer product.
embodiment 2a biologic organic, inorganic composite fertilizer, preparation method is with embodiment 1, and still, each feed composition and weight part are as follows, xylogen 20, cow dung 10, urea 15, fused(calcium magnesium)phosphate 38, potassium sulfate 5, EM bacteria powder 0.1, subtilis bacterium powder 0.1.
embodiment 3a biologic organic, inorganic composite fertilizer, preparation method is with embodiment 1, and still, each feed composition and weight part are as follows, xylogen 28, pig manure 18, bicarbonate of ammonia 22, fused(calcium magnesium)phosphate 30, saltpetre 12, EM bacteria powder 0.18, subtilis bacterium powder 0.18.
embodiment 4a biologic organic, inorganic composite fertilizer, preparation method is with embodiment 1, and still, each feed composition and weight part are as follows, xylogen 22, chicken manure, pig manure and cow dung 12, urea 16, ground phosphate rock 40, potassium sulfate 8, EM bacteria powder 0.12, subtilis bacterium powder 0.12.
embodiment 5a biologic organic, inorganic composite fertilizer, preparation method is with embodiment 1, and still, each feed composition and weight part are as follows, xylogen 26, chicken manure 16, urea 18, diammonium phosphate 36, potassium sulfate 10, EM bacteria powder 0.16, subtilis bacterium powder 0.16.
The basic technical indicator of biologic organic, inorganic composite fertilizer of the present invention is:
Xylogen >=20%
N ≥10%
P 2O 5 ≥10%
K 2O ≥5%
Moisture≤5%
CFU/ gram of viable count >=100,000,000 dry weight
Granularity 1~5mm
experimental example:at paving agricultural station, road junction, Dongchangfu District, Liaocheng of Shandong Province Experimental Base, carried out simultaneous test with 2011.Community area is 10 square metres, repeats randomized block design for three times.For examination winter wheat variety, be Jimai 22, it is inorganic fertilizer that control group is used urea, diammonium phosphate, potassium sulfate; Experimental group is used this patent product (embodiment 5 products obtained therefroms) according to the consumption on 300 jin, every mu of ground, guarantees that nitrogen, phosphorus, potassium content are identical with control group.Boot stage, measured the activity of acid phosphatase, saccharase and urase in soil, after results, individual plant species test survey are produced.The results are shown in Table 1.
Table 1 is the result of three kinds of enzymic activitys of rhizosphere soil in boot stage.Compare with control group, acid phosphatase, saccharase and the urease activity of using the experimental group of this patent product all obviously raise.These enzymes in soil are all that the metabolism of soil beneficial microorganism produces, and illustrates after using this product and have promoted beneficial microorganism activity in soil.
Figure 774757DEST_PATH_IMAGE001
Table 2 is yield result.Compare with control group, use the spike number of the experimental group of this patent product, the trend that thousand seed weight has increase, ultimate capacity also increases to some extent, and amplification reaches 15.1%.Effect of increasing production clearly.

Claims (5)

1. a biologic organic, inorganic composite fertilizer, it is characterized in that, each feed composition is as follows, be weight part: xylogen 20-30, fertilizer 10-20, nitrogenous fertilizer 15-25, phosphate fertilizer 30-40, potash fertilizer 5-15, EM bacteria powder 0.1-0.2, subtilis bacterium powder 0.1-0.2, the fertilizer using is chicken manure, pig manure, the mixture of one or more in cow dung, described nitrogenous fertilizer is selected bicarbonate of ammonia, the phosphate fertilizer using is diammonium phosphate, fused(calcium magnesium)phosphate and/or ground phosphate rock, the potash fertilizer using is Repone K, potassium sulfate, saltpetre and potassium breeze, preparation method, step is as follows:
(1) utilize dryer to be dried the fertilizer after fermentation, moisture is down to below 15%, removes foreign material wherein, then with pulverizer, pulverizes;
(2) fertilizer, nitrogenous fertilizer, phosphate fertilizer, potash fertilizer, EM bacteria powder, subtilis bacterium powder and xylogen powder after pulverizing are mixed in proportion, after stirring, send into tablets press and carry out granulation, after being dried, obtain biologic organic, inorganic composite fertilizer product.
2. biologic organic, inorganic composite fertilizer according to claim 1, is characterized in that, xylogen 22-28, fertilizer 12-18, nitrogenous fertilizer 16-22, phosphate fertilizer 32-38, potash fertilizer 8-12, EM bacteria powder 0.12-0.18, subtilis bacterium powder 0.12-0.18.
3. biologic organic, inorganic composite fertilizer according to claim 1, is characterized in that, xylogen 26, fertilizer 16, nitrogenous fertilizer 18, phosphate fertilizer 36, potash fertilizer 10, EM bacteria powder 0.16, subtilis bacterium powder 0.16.
4. according to the arbitrary described biologic organic, inorganic composite fertilizer of claim 1-3, it is characterized in that, step (1) be organic fertilizer powder is broken to 60 orders more than.
5. according to the arbitrary described biologic organic, inorganic composite fertilizer of claim 1-3, it is characterized in that, being dried after granulation will be at 30-50 ℃.
CN201210263642.1A 2012-07-28 2012-07-28 Biological, organic and inorganic compound fertilizer and preparation method thereof Expired - Fee Related CN102765991B (en)

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CN103012005B (en) * 2013-01-18 2014-07-02 鄂州市广丰生态农业开发有限责任公司 Special bio-organic fertilizer for sweet corns and preparation method of bio-organic fertilizer
CN103483102A (en) * 2013-09-10 2014-01-01 安徽省成仓复合肥有限公司 Bio-enzyme fertilizer and preparation method thereof
CN103755477B (en) * 2014-01-17 2015-11-18 河北利土生物科技有限公司 A kind of Biological water soluble fertilizer and preparation method thereof
CN103922830B (en) * 2014-05-07 2015-11-18 娄志 One cultivates peanut composite fertilizer
CN105085073A (en) * 2015-09-02 2015-11-25 黄冈师范学院 Special microbial compound fertilizer for controlling powdery mildew of sweet persimmons and preparation method
CN106467428A (en) * 2015-11-19 2017-03-01 东莞市神州生物科技有限公司 A kind of nursery stock biological organic-inorganic compound fertilizer compositionss and preparation method thereof
CN106467429A (en) * 2015-11-19 2017-03-01 东莞市神州生物科技有限公司 One cultivates peanut biological organic-inorganic compound fertilizer compositionss and preparation method thereof
CN106008060A (en) * 2016-05-14 2016-10-12 淄博夸克医药技术有限公司 Crop residue compound fertilizer
CN106187514A (en) * 2016-07-20 2016-12-07 安徽三星化工有限责任公司 A kind of lignin particles fertilizer
CN106348824A (en) * 2016-11-02 2017-01-25 岑溪市辰运生态农业开发有限公司 Organic fertilizer special for citrus gonggan cultivation
CN108383617A (en) * 2018-04-27 2018-08-10 杨宗贤 A kind of preparation method of organophosphor composite fertilizer
CN109020673A (en) * 2018-09-26 2018-12-18 安徽华冠食品科技有限公司 Ecological compound fertilizer, preparation method and the application in yellow peach plantation
CN111848272A (en) * 2020-07-13 2020-10-30 广西伟恒生态农业有限公司 Complete compound fertilizer and preparation method thereof

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CN102442846B (en) * 2010-10-12 2013-03-27 上海绿乐生物科技有限公司 Method for producing bio-organic fertilizer by performing spraying granulation
CN102442847B (en) * 2010-10-12 2013-06-19 上海绿乐生物科技有限公司 Method for producing bio-organic fertilizer by using lignin organic granules

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