CN102747441B - Fibers with characteristics of temperature reducing and cooling, preparation method and textile thereof - Google Patents
Fibers with characteristics of temperature reducing and cooling, preparation method and textile thereof Download PDFInfo
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- CN102747441B CN102747441B CN201210148275.0A CN201210148275A CN102747441B CN 102747441 B CN102747441 B CN 102747441B CN 201210148275 A CN201210148275 A CN 201210148275A CN 102747441 B CN102747441 B CN 102747441B
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- cooling
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
Abstract
The present invention relates to fibers with characteristics of temperature reducing and cooling, a preparation method and a textile thereof. The fibers comprise conventional textile fibers and a nanometer unit, wherein a weight of the nanometer unit is 0.1-4% of the total weight of the fibers, the nanometer unit comprises microparticles with a particle size of 300-8000 nm, and the microparticles comprise cerium or a mixture of cerium and calcium. According to the present invention, a certain proportion of the nanometer unit of the microparticles with a particle size of 300-8000 nm is added to the conventional textile fibers, such that the fibers of the present invention can provide unexpected effects of rapid temperature reducing and cooling after contacting wind. Compared with the existing cooling fibers, the fibers of the present invention have advantages of low preparation cost, simple preparation process, easy industrial production, and the like. In addition, the fibers of the present invention can be prepared into a novel high quality cooling fabric, can be used under conditions of indoor and outdoor sports, exercise and outdoor works in summer, and can provide effects of temperature reducing and cooling.
Description
Technical field
The present invention relates to a kind of chemical fibre, particularly relate to fiber, the preparation method of this fiber and the textiles that contains this fiber that a kind of cooling is felt cold.
Background technology
Current, the early stage making taking heat exchanger and electric power of general cooling textiles carries heat transfer fluid as main, such as US Patent No. 5062424, US5092129, US5263336, US4738119 etc., these technical schemes are only applied to special operating environment, are not suitable for everyday general purpose application.
Moreover except using pipeline, sandwich design is simplified the complex arrangement of pipeline, by the multiple stratification of permeable watertight and pervious bed, make two interlayers have the continuity space of ad hoc structure, in space, have the air-flow that can produce because of temperature or humidity difference, and reach the effect that reduces body heat temperature; As patent US4342203, WO2007088431, JP4209809, US2007050878, US200620lI78, JP4209807 etc., for making air-flow have good circulation to produce radiating effect, the design of sandwich construction is more complicated; And then there is people to introduce the water absorbing material that can contain large quantity of moisture, reinforcement in the intermediate layer of sandwich construction.The cooling degree of entirety, as US2003208831, WO0108883, MXPA01013376, US6516624, US6134714 etc., makes steam turnover intermediate layer reach better cooling effect by air-permeable layer.
Similarly mode is sealed up for safekeeping in specific bag or tubular space as the phase-transition material of water or tool thermal diffusivity, as patent US2006276089, US2006064147, US2005284416, US6134714, US5415222 etc., use water preventing ability gas impermeable material pent-up water or phase-transition material, avoid the loss of liquid heat sink material; But under long-time use, because of extraneous friction and pressure-acting, still have the problem of leaking, the use of phase-transition material exists and cannot keep long-acting, need treat that phase-transition material replys solid-state phase and could have the effect of cooling again; Utilize the metal fibre braiding of high heat transfer property, can make the textiles of long-time cooling effect, as patent IT1251745, high poor with flexibility because of the cost of metal fibre, make the practical not good of this class cooling textiles.
Summary of the invention
The object of the invention is to propose fiber, preparation method and the textiles that a kind of cooling easily manufactured, with low cost, that be easy to industrialized implementation is felt cold.
The fiber that the first object of the present invention provides a kind of cooling to feel cold, described fiber comprises conventional textile fabric and accounts for the nano unit of gross weight 0.1～4% weight portion, described nano unit comprises the particulate of 300～8000 nanometers, and described particulate comprises the mixture of cerium or cerium and calcium.
Preferably, described conventional textile fabric comprises chemical fibre, and described chemical fibre comprises artificial fibre and/or synthetic fiber.
More preferably, described fiber comprises the particulate of 300～4000 nanometers that account for gross weight 2～4% weight portions.
Further, in described nano unit, described particulate comprises the cerium of 200～3000 weight cell and the calcium of 100～1000 weight cell.
Preferably, described fiber comprises the particulate of 4000～8000 nanometers that account for gross weight 0.1～2% weight portion.
More preferably, in described nano unit, described particulate comprises the cerium of 200～3000 weight cell and the calcium of 100～1000 weight cell.
Further, in described nano unit, described particulate also comprises the germanium of 60～600 weight cell.
The second object of the present invention provides a kind of fiber that wind feels cold of meeting, and it has comprised above-mentioned fiber, and the fiber that described chance wind feels cold temperature in the time that speed air flow is greater than 0.5m/s reduces at least 0.5 DEG C.Preferably, continuing under the environment of Air Flow, the temperature of the fiber that described chance wind feels cold is constantly lower than the temperature of surrounding environment.
The 3rd object of the present invention provides the preparation method of the textile fabric that a kind of cooling feels cold, and described preparation method comprises the steps: A, natural polymer substance or inorganic matter or synthetic polymer substance or inorganic matter are made to spinning melt or solution; B, in described spinning melt or solution, add above-mentioned nano unit; C, extrude through thread spraying structure, form fiber.
The 4th object of the present invention provides the preparation method of the textile fabric that a kind of cooling feels cold, and described preparation method comprises the preparation process of textile fabric chemical fibre master batch, in the preparation process of chemical fibre master batch, adds above-mentioned nano unit
The textiles that the 5th object of the present invention provides a kind of cooling to feel cold, this textiles at least comprises the fiber that part is above-mentioned.
The detection method that the 6th object of the present invention provides a kind of cooling to feel cold fiber, described detection method comprises the steps:
Skin surface before testing sample dress is photographed;
Photographed in instant fabric surface after testing sample dress;
Photograph in the fabric surface that testing sample is worn after persistent state elapsed time T;
Instant skin surface after treating test sample product and taking off is photographed;
Photograph in fabric surface after treating test sample product and taking off.
Preferably, described detection method detects on the human body under constant-temperature constant-humidity environment, and after detecting on symmetrical both sides on human body, then after mutually exchanging, carry out secondary detection. simultaneously
Based on technique scheme, advantage of the present invention is:
Because the present invention has added the particulate nano unit of certain proportion 300～8000 nanometers in conventional textile fabric, make fiber of the present invention to reach the unexpected fast cooling effect of feeling cold after wind meeting, and the present invention is for the existing fiber that feels cold, have that manufacturing cost is lower, manufacturing technique is simple, be easy to the advantages such as suitability for industrialized production, the present invention simultaneously can make the novel fabric that feels cold of high-quality, and be applied under the conditions such as Summer Indoor motion outward, exercise and outwork, reach cool effect.
Brief description of the drawings
Accompanying drawing described herein is used to provide a further understanding of the present invention, forms the application's a part, and schematic description and description of the present invention is used for explaining the present invention, does not form inappropriate limitation of the present invention.In the accompanying drawings:
Fig. 1 is the feel cold testing result schematic diagram of effect of fiber in the embodiment of the present invention 1 cooling;
Fig. 2 is the feel cold testing result schematic diagram of effect of fiber in the embodiment of the present invention 2 cooling;
Fig. 3 is the feel cold testing result schematic diagram of effect of fiber in the embodiment of the present invention 3 cooling;
Fig. 4 is at the skin surface temperature analysis diagram of wearing before fibre of the present invention;
Fig. 5 is at the instant fabric surface temperature analysis diagram of wearing after fibre of the present invention;
Fig. 6 is at the fabric surface temperature analysis diagram of wearing after fibre persistent state elapsed time T of the present invention;
Fig. 7 is the instant skin surface temperature analysis diagram of taking off after fibre of the present invention;
Fig. 8 is the fabric surface temperature analysis diagram of taking off after fibre of the present invention;
Fig. 9 is the detection sample schematic diagram in test shown in Fig. 4～Fig. 8, and wherein A is testing sample of the present invention, the control sample that B is conventional fibre;
Figure 10 is at the skin surface temperature analysis diagram of wearing before fibre of the present invention;
Figure 11 is at the instant fabric surface temperature analysis diagram of wearing after fibre of the present invention;
Figure 12 is at the fabric surface temperature analysis diagram of wearing after fibre persistent state elapsed time T of the present invention;
Figure 13 is the instant skin surface temperature analysis diagram of taking off after fibre of the present invention;
Figure 14 is the fabric surface temperature analysis diagram of taking off after fibre of the present invention;
Figure 15 is the detection sample schematic diagram in test shown in Figure 10～Figure 14, and wherein B is testing sample of the present invention, the control sample that A is conventional fibre.
Detailed description of the invention
Below by drawings and Examples, technical scheme of the present invention is described in further detail.
Embodiment 1:
The fiber that a kind of cooling of the present invention is felt cold, comprise conventional textile fabric and account for the nano unit of gross weight 0.1～4% weight portion, for example nano unit accounts for 2% of total weight of fiber, nano unit of the present invention comprises the particulate of 300～8000 nanometers, and described particulate mainly comprises cerium, calcium or the mixture of arbitrary proportion between them.
In the present embodiment, in fiber of the present invention, except conventional textile fabric, comprise the particulate of 300～2000 nanometers that account for gross weight 2～4% weight portions.Described particulate comprises the cerium of 200 weight cell and the calcium of 100 weight cell, or only comprises the cerium of 200 weight cell, and certainly, the former effect is more obvious.
It should be noted that: " weight cell " of the present invention is preferably the weight ratio of " micro-g/kg ", also can weigh according to other weight cell according to actual needs.
The cooling that includes nano unit in the present embodiment fiber that feels cold, its cooling is felt cold effect referring to following detection test:
Detect unit: Japanese chemical fibre checks association (Japan Synthetic Textile Inspection Institute Foundation);
Receive the sample date: on December 11st, 2009;
The examining report date: on December 21st, 2009;
Detect certificate number: TH-09-035052-2 (Osaka-7190);
Detect sample:
Sample 1---the fiber (fiber of the present invention) of processing,
Sample 2---undressed fiber (comparative sample),
Amount to 2 samples;
Test item 1: water suction, heat absorption test (N=1 for the first time):
Concrete detection method:
A) in the drying machine of 70 DEG C, testing sample is dried to 2 hours;
B) it is 35 DEG C by the Temperature Setting in sensing chamber;
C) in sensing chamber, put in advance stand-by device;
D) the testing sample doubling 2 times of temperature and humidity will have been regulated, center adds 0.5ml distilled water with liquid-transfering gun, then directly sensor is placed on to the centre of testing sample, in order to make sensor and testing sample close contact, they are clamped with clip, and record temperature over time, see table.
Table 1(N=1)
| Time (min) | Sample 1(DEG C) | Sample 2(DEG C) |
| 0 | 34.5 | 34.5 |
| 5 | 27.9 | 29.6 |
| 10 | 27.2 | 28.7 |
| 15 | 27.1 | 28.6 |
| 20 | 27.3 | 28.8 |
| 25 | 27.6 | 29.0 |
| 30 | 27.6 | 28.8 |
Temperature-the time curve of above-mentioned testing result is referring to shown in accompanying drawing 1;
Check that by this Japan chemical fibre the above-mentioned testing result of association (Japan Synthetic Textile Inspection Institute Foundation) and table 1 and Fig. 1 can draw, the present invention lowers the temperature the fiber that feels cold under identical temperature and humidity condition, has more significant and unforeseeable fast cooling effect than conventional chemical fibre.
Embodiment 2:
The difference of the present embodiment and above-described embodiment is, fiber of the present invention comprises the particulate of 2000～5000 nanometers that account for gross weight 1～2% weight portion.Described particulate comprises the cerium of 2900 weight cell and the calcium of 950 weight cell, or only comprises the cerium of 2900 weight cell, and certainly, the former effect is more obvious.
Nano unit of the present invention can adopt of the prior art any one to add in the technique of fiber manufacture.
For example: the present embodiment has adopted the preparation method of the textile fabric that a kind of cooling feels cold, comprise the steps: A, natural polymer substance or inorganic matter (as: viscose) or synthetic polymer substance or inorganic matter (as: polyamide fibre or acrylic fibers) are made to spinning melt or solution; B, in described spinning melt or solution, add above-mentioned nano unit; C, extrude through thread spraying structure, form fiber.Other processing steps are identical with the fiber preparation method of prior art, do not repeat them here.
The cooling that includes nano unit in the present embodiment fiber that feels cold, its cooling is felt cold effect referring to following detection test:
Test item 2: water suction, heat absorption test (N=2 for the second time):
Table 2(N=2)
| Time (min) | Sample 1(DEG C) | Sample 2(DEG C) |
| 0 | 34.5 | 34.5 |
| 5 | 28.2 | 29.5 |
| 10 | 27.5 | 28.7 |
| 15 | 27.4 | 28.4 |
| 20 | 27.7 | 28.6 |
| 25 | 28.1 | 28.8 |
| 30 | 28.0 | 28.6 |
Temperature-the time curve of above-mentioned testing result is referring to shown in accompanying drawing 2;
Check that by this Japan chemical fibre the above-mentioned further testing result of association and table 2 and Fig. 2 can draw, the present invention lowers the temperature the fiber that feels cold under identical temperature and humidity condition, has more significant and unforeseeable fast cooling effect than conventional chemical fibre.
Embodiment 3:
The difference of the present embodiment and above-described embodiment is, fiber of the present invention comprises the particulate of 5000～8000 nanometers that account for gross weight 0.1～1% weight portion.Described particulate comprises the cerium of 1300 weight cell and the calcium of 600 weight cell, or only comprises the cerium of 1300 weight cell, and certainly, the former effect is more obvious.Further preferably, in the particulate of the present embodiment, can also comprise the germanium (particularly, the present embodiment comprises the germanium of 300 weight cell) of 60～600 weight cell.
Nano unit of the present invention can adopt of the prior art any one to add in the technique of fiber manufacture.
For example: the present embodiment has adopted the preparation method of the textile fabric that a kind of cooling feels cold, comprise the preparation process of textile fabric chemical fibre master batch, in the preparation process of chemical fibre master batch, add above-mentioned nano unit, then produce fiber.Other processing steps of the present embodiment fiber preparation method are identical with the fiber preparation method of prior art, do not repeat them here.
The cooling that includes nano unit in the present embodiment fiber that feels cold, its cooling is felt cold effect referring to following detection test:
Test item 3: tactility generates heat/feel cold;
Detection method and testing result: as shown in the table
The testing result of this is to certify that laboratory testing sample is as follows, table 3
Relation curve is referring to shown in accompanying drawing 3 over time for the caloric receptivity that the present embodiment detects, and wherein, the curve on top is the curve of sample 1, and the curve of bottom is the curve of sample 2.
Check that by this Japan chemical fibre the testing result of association's said method and table 3 and Fig. 3 can draw, the present invention lowers the temperature the fiber that feels cold under identical temperature and humidity condition, also there is the effect of more significant and unforeseeable quick absorption heat than conventional chemical fibre, and further can make fiber of the present invention there is unforeseeable cooling-down effect.
In addition, another object of the present invention is to provide the textiles that a kind of cooling is felt cold, and for example knitting or tatting product, in this textiles, at least comprises the fiber that part is above-mentioned, and certainly, the fiber that also can all use the present invention to lower the temperature to feel cold is made.
Embodiment 4:
Referring to Fig. 4～Fig. 9, the feel cold preferred embodiment of detection method of fiber of a kind of cooling of the present invention shown in it, its cooling is felt cold effect referring to following detection test:
Detect unit: consumption Science Institute of Amada Co., Ltd.
1, detect sample:
Sample A---the fiber (fiber of the present invention) of processing;
Sample B---undressed fiber (comparative sample);
It should be noted that, the present embodiment sample A meets the fiber that wind feels cold, the fiber that this chance wind feels cold can comprise the fiber described in above-mentioned any one embodiment, the fiber that this chance wind feels cold comprises conventional textile fabric and accounts for the nano unit of gross weight 0.1～4% weight portion, described nano unit comprises the particulate of 300～8000 nanometers, and described particulate comprises the mixture of cerium or cerium and calcium; And the fiber that described chance wind feels cold temperature in the time that speed air flow is greater than 0.5m/s reduces at least 0.5 DEG C.
2, content of the test and condition
Under the following conditions, above-mentioned detection sample and surface skin temperature, surperficial fabric temperature are photographed and carried out surface temperature parsing by observation, this test is greater than for example 2m/s of 0.5m/s(or 3m/s at wind speed (speed air flow)) ventilated environment in carry out, and, environment temperature is preferably 30 ± 1 DEG C, envionmental humidity is 40 ± 2%, and tester is 30 years old women:
(1) skin surface (for example, from elbow to wrist) before testing sample dress is photographed, " photography " of the present embodiment is preferably thermoinduction photography or the photography of infrared hotness;
(2) photographed in the instant fabric surface (for example, from elbow to wrist) after testing sample dress;
(3) photograph in the fabric surface (for example, from elbow to wrist) of testing sample being worn to (in the present embodiment, T is 30 minutes) after persistent state elapsed time T;
(4) the instant skin surface (for example, from elbow to wrist) after treating test sample product and taking off is photographed;
(5) photograph in the fabric surface after treating test sample product and taking off.
Preferably, complete after above-mentioned test, then carry out secondary detection after mutually exchanging, for example testing for the first time the right hand is sample A, and left hand is sample B, as shown in Fig. 4～Fig. 9; Testing for the second time left hand is sample A, and the right hand is sample B, as shown in Figure 10～Figure 15.
The result of above-mentioned test, referring to Fig. 4～Fig. 9 and Figure 10～Figure 15, be not difficult to find for those of ordinary skill in the art, because the present invention has added the particulate nano unit of certain proportion 300～8000 nanometers in conventional textile fabric, make fiber of the present invention to reach the unexpected fast cooling effect of feeling cold after wind meeting, that is: the present invention meets fiber temperature in the time that speed air flow is greater than 0.5m/s that wind feels cold and reduces at least 0.5 DEG C, certainly be understood that for those skilled in the art, above-mentioned temperature reduction amplitude is the process increasing in time and gradually, but be not unlimited increase, as Fig. 1, shown in Fig. 2 and Fig. 3, and, above-described embodiment 1, 2, 3 and 4 show, under lasting Air Flow environment, the temperature of the fiber that chance wind of the present invention feels cold is constantly lower than the temperature of surrounding environment.
Finally should be noted that: above embodiment is only in order to illustrate that technical scheme of the present invention is not intended to limit; Although the present invention is had been described in detail with reference to preferred embodiment, those of ordinary skill in the field are to be understood that: still can modify or part technical characterictic is equal to replacement the specific embodiment of the present invention; And not departing from the spirit of technical solution of the present invention, it all should be encompassed in the middle of the technical scheme scope of request protection of the present invention.
Claims (10)
1. the application that the mixture of particulate cerium and calcium feels cold in fiber in preparation cooling, described fiber comprises conventional textile fabric and accounts for the nano unit of gross weight 0.1～4% weight portion, described nano unit comprises the particulate of 300～8000 nanometers, described particulate comprises the mixture of cerium and calcium, described fiber temperature in the time that speed air flow is greater than 0.5m/s reduces at least 0.5 DEG C, and continuing under the environment of Air Flow, the temperature of described fiber is constantly lower than the temperature of surrounding environment.
2. application according to claim 1, is characterized in that: described conventional textile fabric comprises chemical fibre, and described chemical fibre comprises artificial fibre and/or synthetic fiber.
3. application according to claim 2, is characterized in that: the particulate that comprises 300～4000 nanometers that account for gross weight 2～4% weight portions.
4. application according to claim 3, it is characterized in that: in described nano unit, described particulate comprises the cerium of 200～3000 weight cell and the calcium of 100～1000 weight cell, and wherein said " weight cell " refers to the weight ratio suitable with " micro-g/kg ".
5. application according to claim 2, is characterized in that: the particulate that comprises 4000～8000 nanometers that account for gross weight 0.1～2% weight portion.
6. application according to claim 5, it is characterized in that: in described nano unit, described particulate comprises the cerium of 200～3000 weight cell and the calcium of 100～1000 weight cell, and wherein said " weight cell " refers to the weight ratio suitable with " micro-g/kg ".
7. according to the application described in claim 4 or 6, it is characterized in that: in described nano unit, described particulate also comprises the germanium of 60～600 weight cell, wherein said " weight cell " refers to the weight ratio suitable with " micro-g/kg ".
8. a preparation method for the textile fabric that cooling is felt cold, is characterized in that: described preparation method comprises the steps:
A, natural polymer substance or inorganic matter or synthetic polymer substance or inorganic matter are made to spinning melt or solution;
B, in described spinning melt or solution, add the nano unit described in above-mentioned any one claim;
C, extrude through thread spraying structure, form fiber.
9. the preparation method of the textile fabric that a cooling is felt cold, it is characterized in that: described preparation method comprises the preparation process of textile fabric chemical fibre master batch, in the preparation process of chemical fibre master batch, add the nano unit described in any one claim in claim 1～7.
10. the textiles that cooling is felt cold, is characterized in that: this textiles at least comprises the textile fabric that the cooling described in part claim 8 or 9 is felt cold.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210148275.0A CN102747441B (en) | 2012-05-14 | 2012-05-14 | Fibers with characteristics of temperature reducing and cooling, preparation method and textile thereof |
| PCT/CN2012/080117 WO2013170551A1 (en) | 2012-05-14 | 2012-08-14 | Temperature-reducing and cooling fiber, preparation method, and textile |
| TW101130585A TW201346085A (en) | 2012-05-14 | 2012-08-23 | A temperature-reducing and cooling fiber, a method for preparing the same, and a fabric containing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210148275.0A CN102747441B (en) | 2012-05-14 | 2012-05-14 | Fibers with characteristics of temperature reducing and cooling, preparation method and textile thereof |
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| Publication Number | Publication Date |
|---|---|
| CN102747441A CN102747441A (en) | 2012-10-24 |
| CN102747441B true CN102747441B (en) | 2014-12-17 |
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| CN201210148275.0A Expired - Fee Related CN102747441B (en) | 2012-05-14 | 2012-05-14 | Fibers with characteristics of temperature reducing and cooling, preparation method and textile thereof |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN102747441B (en) |
| TW (1) | TW201346085A (en) |
| WO (1) | WO2013170551A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102912466B (en) * | 2012-05-14 | 2014-12-17 | 毛盈军 | Fiber for warming and heat accumulation and preparation method of fiber and textile |
| CN107022799A (en) * | 2016-01-29 | 2017-08-08 | 朱梦云 | A kind of long acting cooling fiber |
| KR102490200B1 (en) * | 2017-09-28 | 2023-01-20 | 닛폰 에쿠스란 고교 가부시키가이샤 | Fiber with moisture desorbing and cooling characteristics, and fiber structure containing the same |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101929065A (en) * | 2010-07-30 | 2010-12-29 | 毛盈军 | Chemical fibres capable of quickly cooling in wind and textile containing same |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP3664585B2 (en) * | 1998-03-26 | 2005-06-29 | 株式会社クラレ | Fiber with excellent heat radiation |
| JP2001336024A (en) * | 2000-05-30 | 2001-12-07 | Kuraray Co Ltd | Crossalinked fiber with embedded fine particle, and method for producing the same |
| CN100516347C (en) * | 2004-03-02 | 2009-07-22 | 日本爱克兰工业株式会社 | Antiviral fiber and application of the antiviral fiber in virus passivation |
| CN1804160A (en) * | 2005-01-13 | 2006-07-19 | 李官奇 | Functional fiber |
| JP4624929B2 (en) * | 2006-01-19 | 2011-02-02 | 帝人ファイバー株式会社 | Fibers, fiber structures and fiber products whose electrical resistivity varies with temperature |
| JP2008081876A (en) * | 2006-09-27 | 2008-04-10 | Ohara Palladium Kagaku Kk | Fiber processing agent and fiber product using the same |
| JP2008240172A (en) * | 2007-03-26 | 2008-10-09 | Hiroshima Univ | Fibrous body and fluorescent substance utilizing the same |
| CN101709511B (en) * | 2009-11-26 | 2012-05-23 | 毛盈军 | Chemical fiber quickly increasing temperature and heating when encountering light and textile containing fiber |
| KR20110123956A (en) * | 2010-05-10 | 2011-11-16 | 정청식 | Uv protection and performance with many features to textile manufacturing |
| CN102392327A (en) * | 2011-11-24 | 2012-03-28 | 长春理工大学 | Preparation method of cerium-doped yttrium aluminium garnet nanobelt |
| CN102677204A (en) * | 2012-05-14 | 2012-09-19 | 毛盈军 | Fibers capable of warming to emit heat naturally under humid condition, preparation method and fabrics |
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2012
- 2012-05-14 CN CN201210148275.0A patent/CN102747441B/en not_active Expired - Fee Related
- 2012-08-14 WO PCT/CN2012/080117 patent/WO2013170551A1/en active Application Filing
- 2012-08-23 TW TW101130585A patent/TW201346085A/en unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101929065A (en) * | 2010-07-30 | 2010-12-29 | 毛盈军 | Chemical fibres capable of quickly cooling in wind and textile containing same |
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| Publication number | Publication date |
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| WO2013170551A1 (en) | 2013-11-21 |
| TW201346085A (en) | 2013-11-16 |
| CN102747441A (en) | 2012-10-24 |
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