CN102732389B - Vehicle cleaning agent - Google Patents

Vehicle cleaning agent Download PDF

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Publication number
CN102732389B
CN102732389B CN2012102065779A CN201210206577A CN102732389B CN 102732389 B CN102732389 B CN 102732389B CN 2012102065779 A CN2012102065779 A CN 2012102065779A CN 201210206577 A CN201210206577 A CN 201210206577A CN 102732389 B CN102732389 B CN 102732389B
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sodium
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soda ash
citric acid
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CN102732389A (en
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金建麟
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Zhejiang Ops Environmental Protection Technology Co ltd
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Abstract

The invention relates to a vehicle cleaning agent. The vehicle cleaning agent comprises the following components, by weight, 30-70 parts of sodium tripolyphosphate, 20-60 parts of sodium sulfate, 10-40 parts of sodium silicate, 5-20 parts of sodium dodecyl sulfate, 5-20 parts of NP-10, 1-10 parts of OP-10, 1-10 parts of citric acid monohydrate, 1-10 parts of soda ash and 1-10 parts of sulfonic acid or sulfonate. The vehicle cleaning agent provided in the invention has the advantages of realization of whole vehicle wiping without artificial foaming, no generation of scratches on a vehicle paint, working efficiency improvement, workload reduction, and water saving.

Description

A kind of vehicle cleaning agent
Technical field
The present invention relates to a kind of vehicle cleaning agent, relate in particular to a kind of vehicle cleaning agent of powder-type.
Background technology
The vehicle cleaning agent can remove the various gummed papers vehicle glass surface pasted, labeling, and can remove around wheel, the greasy dirt on splash pan, collision bumper, car body and various tool.Cleaned car uses washing powder to be watered to clean in the past, its deficiency is the scavenging solution that washing powder is watered, can only play soil-removing action, when using wiper to clean, the grains of sand that the car body coating surface is easy to be adhered to car body surface abrade, not only affect car body attractive in appearance, but also can produce dispute.
For overcoming above-mentioned deficiency, CN 1386838A discloses a kind of detergent for automobile, it is with poly amic acid 5~90kg, sodium lauryl sulphate 1~45kg, Sodium dodecylbenzene sulfonate 1~5kg, tripoly phosphate sodium STPP 0.1~1kg, the composition that fatty alcohol-polyoxyethylene ether 1~5kg each component forms, be characterized in highly lubricating, detergency ability is good, while being used for cleaning car, can will adhere to the grains of sand on car body surface and the frictional coefficient between the car body paint film be reduced to the degree that can not abrade the car body coating surface, clean later and form the very thin protective layer of one deck to car body surface, the paint film of car body is effectively protected.But the described clean-out system of this invention is used after still needing to convert into scavenging solution in the ratio of 1:1000, and need to get blisters, clean while cleaning, not only waste water resource, and labor intensive, be unfavorable for raising the efficiency, and economizes on resources.
In addition, commonly used on market also have liquid carwash thing.A kind of efficient automobile washing liquid is disclosed as CN 101092590A, the nano-titanium oxide that contains the 10-80nm of weight percent 1%, the fatty alcohol-polyoxyethylene ether of weight percent 5%, the silicone oil of weight percent 2%, the whiteruss of weight percent 2%, 0.5% boric acid aqueous solution of weight percent 5%, the water of weight percent 85% forms.Formula is unique, and the character gentleness, do not hinder skin.Can dissolve rapidly the greasy dirt dust, not stay washmarking, the powerful light that does not damage the car paint of clean power, be beneficial to environmental protection.CN 101092590A discloses a kind of environmental protective, energy saving cleaning liquid for lacquer finish of car, and the component of its following weight percent forms: carnauba wax 4.1%-6%, coconut oil derivative 7%-9%, active copper 2%-4.15%, the active emulsion 12%-18% of plant surface, silicone 1%-4%, distilled water 58.85%-73.9%.Above-mentioned lacquer painting scavenging solution, its pH value is 7.1-8.5, through cleaning test, the dirt of having realized sticking to rapidly on automobile finish suspends and becomes flexible, and dirt is removed to the raw materials used efficient preservative that contains under professional manual skill wiping, therefore, corrodibility is low, and security is good, is specially adapted to the cleaning on all automobile finishs and family's hard objects surface.
The above-mentioned cleaning vehicle washing lotion cost provided is higher, and also needs manually get blisters foam, wiping while cleaning, and is unfavorable for improving work efficiency.
Summary of the invention
The object of the present invention is to provide a kind of clean, powder-type vehicle cleaning agent that nursing is two-in-one, uses product provided by the invention to economize on water more than 1/3rd than traditional carwash, two workmans' workload a workman can complete.Working efficiency improves more than 1/3rd.Due to the contactless automobile finish of pure water stream, can not produce cut, reduce in usually working the dispute often produced because scratching lacquer painting.
Vehicle cleaning agent provided by the present invention, contain following component: tripoly phosphate sodium STPP 30-70 part by weight; Sodium sulfate 20-60 part; Water glass 10-40 part; Sodium lauryl sulphate 5-20 part; NP-10 5-20 part; OP-10 1-10 part; Citric acid monohydrate Food grade 1-10 part; Soda ash 1-10 part; Sulfonic acid or sulfonate 1-10 part.
As optimal technical scheme, vehicle cleaning agent provided by the present invention, contain following component: tripoly phosphate sodium STPP 40-60 part by weight; Sodium sulfate 40-60 part; Water glass 20-40 part; Sodium lauryl sulphate 5-15 part; NP-10 5-15 part; OP-10 3-8 part; Citric acid monohydrate Food grade 3-8 part; Soda ash 3-8 part; Sulfonic acid or sulfonate 3-8 part.
As optimal technical scheme, vehicle cleaning agent provided by the present invention, contain following component: 50 parts of tripoly phosphate sodium STPPs by weight; 50 parts, sodium sulfate; 25 parts of water glass; 10 parts of sodium lauryl sulphate; NP-1010 part; 5 parts of OP-10; 5 parts of Citric acid monohydrate Food grades; 5 parts of soda ash; 5 parts, sulfonic acid or sulfonate.
Tripoly phosphate sodium STPP is formed by different sodium hydrogen phosphate molecule condensations, claims again Tri sodium Phosphate.It is a kind of important washing assistant, and large usage quantity, have weakly alkaline, and non-corrosiveness is a kind of inorganic surfaces promoting agent.It has certain emulsifying effect to grease, and the solid dirt is had to dissemination, and the protein in dirt is had and expands and solublization, and the metal ions such as calcium magnesium are had to good sequestering action, metal ion can be sealed, and eliminates its disadvantageous effect to cleaning.In addition, in cleaning process, it can catch the various metal ingredients in dirt, and dirt is dissociated.Simultaneously, the hexahydrate owing to forming after the tripoly phosphate sodium STPP water suction, have dry and comfortable characteristic.When in the sanitising agent formula, a large amount of tripoly phosphate sodium STPP being arranged, just can play and prevent the caking phenomenon caused because of the moisture absorption, keep the dry and comfortable granular of synthectic detergents.Tripoly phosphate sodium STPP is when content is too low in sanitising agent, and emulsification, dispersion effect are not remarkable, content higher than certain value after, its emulsification, dissemination increase not obvious, the present invention is by having determined the suitable content range of tripoly phosphate sodium STPP.
Sodium sulfate, have another name called thenardite, and white, odorless, the crystallization that bitter taste is arranged or powder, have water absorbability.Add in sanitising agent and can improve its surfactivity, impel sanitising agent easily to be adsorbed in particle and washes surface, increase the dispersion stabilization of particle, and then be conducive to prevent deposition.But sodium sulfate during too high levels, can cause that surface potential reduces, thereby be unfavorable for cleaning function, thereby the present invention has been determined the suitable concn scope of sodium sulfate in sanitising agent in sanitising agent.
Water glass is a kind of water-soluble silicate, has share coordinative role with other washing assistant, plays better wash-aid effect.Alkalescence can be provided, maintain high pH value, high pH value can increase surface negative charge, is conducive to washing.Water glass prevents soil redeposition in addition simultaneously, suppresses the effect of metallic corrosion, and calcium ions and magnesium ions is had to certain sequestering action.
Sodium lauryl sulphate belongs to anion surfactant, good with negatively charged ion, nonionic compatibility, has excellent infiltration, washing, wetting, dispersion, decontamination and emulsifying effect, and biological degradation is fast.
NP-10 is polyoxyethylene nonylphenol ether, has good infiltration, emulsification, dispersion, antiacid, alkali resistant, anti-hard water, anti-reduction, oxidation resistant ability.
The OP-10 composition is alkylphenol polyoxyethylene, has good level dyeing, emulsification, wetting, diffusion, antistatic property.
Citric acid monohydrate Food grade is colourless crystallization or white crystalline powder, as neutralizing agent, and the pH value of adjustable product, the while also can be used as the sequestrant of metal ion.
Soda ash is sodium carbonate, adds in sanitising agent and can prevent caking.
Sulfonic acid is a kind of organic acid, general formula R-SO 3H, R representation hydrocarbyl (comprising aryl), strongly-acid, have larger water-solublely, and the sulfonate product that to be hydrogen ion replaced by metal ion such as sodium ion, when generating the powdery clean-out system, can increase the mobility of powdery and play the effect of agglomeration resistance.Can be for example: the sodium salt of the sulfonic acid of Witco 1298 Soft Acid, Sodium dodecylbenzene sulfonate, long-chain such as n-C 11H 23-CH 2SO 3Na etc.
The present invention has determined that by concentrating on studies the composition of vehicle cleaning agent is suitable configuration proportion between tripoly phosphate sodium STPP, sodium sulfate, water glass, sodium lauryl sulphate, NP-10, OP-10, Citric acid monohydrate Food grade, soda ash, sulfonic acid or sulfonate and various component thereof, thereby makes product of the present invention have excellent clean-up performance and good result of use.
As optimal technical scheme, vehicle cleaning agent provided by the present invention, described sanitising agent also contains the essence of 1-5 part by weight or/and the colorant of 1-5 part.
In sanitising agent, add essence, the vehicle after can making to utilize sanitising agent to wash keeps the smell of pleasant.
In sanitising agent, add colorant, can make the product of the color that meets client's needs.
As optimal technical scheme, vehicle cleaning agent provided by the present invention, described sulfonate is Sodium dodecylbenzene sulfonate.Sodium dodecylbenzene sulfonate is a kind of aniorfic surfactant, and production cost is low, performance good.Be difficult for oxidation, foaming power is strong, and detersive power is high, easily with various additive compounds, uses and prepares sanitising agent, and especially to particulate fouling, albumen dirt and oily dirt have significant clean effect.Sodium dodecylbenzene sulfonate and sequestrant are used in conjunction with, and can significantly improve the stability in hard water of sanitising agent.
As optimal technical scheme, vehicle cleaning agent provided by the present invention, contain following component: 50 parts of tripoly phosphate sodium STPPs by weight; 50 parts, sodium sulfate; 25 parts of water glass; 10 parts of sodium lauryl sulphate; NP-1010 part; 5 parts of OP-10; 5 parts of Citric acid monohydrate Food grades; 5 parts of soda ash; 5 parts of Sodium dodecylbenzene sulfonatees; 2 parts, essence.
As optimal technical scheme, vehicle cleaning agent provided by the present invention, contain following component: 50 parts of tripoly phosphate sodium STPPs by weight; 50 parts, sodium sulfate; 25 parts of water glass; 10 parts of sodium lauryl sulphate; NP-1010 part; 5 parts of OP-10; 5 parts of Citric acid monohydrate Food grades; 5 parts of soda ash; 5 parts of Sodium dodecylbenzene sulfonatees; 2 parts, colorant.
As optimal technical scheme, vehicle cleaning agent provided by the present invention, contain following component: 50 parts of tripoly phosphate sodium STPPs by weight; 50 parts, sodium sulfate; 25 parts of water glass; 10 parts of sodium lauryl sulphate; NP-1010 part; 5 parts of OP-10; 5 parts of Citric acid monohydrate Food grades; 5 parts of soda ash; 5 parts of Sodium dodecylbenzene sulfonatees; 2 parts, essence; 2 parts, colorant.
Sanitising agent provided by the present invention adopts following preparation method: take by weight each component, then will claim component mix to knock down and in stirrer, stir and obtain product.
The using method of vehicle cleaning agent provided by the present invention is: 1) 1 kilogram of this product is watered 40 kilograms, fully dissolves; 2) use spraying machine that this product is evenly sprayed to vehicle body; 3) the working pressure car washer that is greater than the pressure of 50kg closely rinses the full car of vehicle; 4), after having rinsed, with towel, full car is dried and got final product.
Product of the present invention is used composite etc. and the control group of kinds of surface promoting agent, spot suspension agent, dispersion agent to divide rational content range, makes the product made prevented from caking, is easy to preserve.Make in use that car surface dirt zone of oxidation is softening, emulsification, quick active is being covered spot, makes it be in suspended state, utilizes car washer pressure, and a punching and clean, without the manual wipping operation, also can remove totally the former dead angle that can't clean in gap of serving.
Vehicle cleaning agent provided by the present invention is without the foam of manually getting blisters, the full car of wiping, and such two workmans' workload a workman can complete, and can make working efficiency improve more than 1/3rd; Due to the contactless automobile finish of pure water stream, can not produce cut to the car paint, thereby reduce in usually working the dispute often produced because scratching lacquer painting; Reduce workload, improved working efficiency, more than 1/3rd, saved water than traditional carwash water saving.
Embodiment
For ease of understanding the present invention, it is as follows that the present invention enumerates embodiment.Those skilled in the art should understand, described embodiment only, be used to helping to understand the present invention, should not be considered as concrete restriction of the present invention.
As no specific instructions, various raw material of the present invention all can obtain by commercially available; Or prepare according to the ordinary method of this area.Unless otherwise defined or described herein, the same meaning be familiar with of all specialties used herein and scientific words and those skilled in the art.Any method similar or impartial to described content and material all can be applicable in the inventive method in addition.
The experimental technique of unreceipted actual conditions in the following example, measure according to national standard usually.If there is no corresponding national standard, according to general international standard, normal condition or carry out according to the condition that manufacturer advises.Unless otherwise indicated, otherwise all umbers are weight part, and all per-cents are weight percentage.
Unless otherwise defined or described herein, the same meaning be familiar with of all specialties used herein and scientific words and those skilled in the art.Any method similar or impartial to described content and material all can be applicable in the inventive method in addition.
Embodiment 1
Contain by weight following component: 30 parts of tripoly phosphate sodium STPPs; 60 parts, sodium sulfate; 40 parts of water glass; 20 parts of sodium lauryl sulphate; 20 parts of NP-10; 10 parts of OP-10; 10 parts of Citric acid monohydrate Food grades; 10 parts of soda ash; 10 parts of Witco 1298 Soft Acids.
According to preparation method provided by the present invention, make product.
Use properties: according to using method of the present invention, carry out vehicle cleaning, the vehicle free from smutting during after cleaning is residual, car paint no marking, and working efficiency has improved 1/3rd, than traditional carwash water saving 1/3rd.
Embodiment 2
Contain by weight following component: 70 parts of tripoly phosphate sodium STPPs; 20 parts, sodium sulfate; 10 parts of water glass; 5 parts of sodium lauryl sulphate; 5 parts of NP-10; 1 part of OP-10; 1 part of Citric acid monohydrate Food grade; 1 part of soda ash; 1 part of Sodium dodecylbenzene sulfonate.
According to preparation method provided by the present invention, make product.
Use properties: according to using method of the present invention, carry out vehicle cleaning, the vehicle free from smutting during after cleaning is residual, car paint no marking, and working efficiency has improved 1/3rd, than traditional carwash water saving 1/3rd.
Embodiment 3
Contain by weight following component: 40 parts of tripoly phosphate sodium STPPs; 40 parts, sodium sulfate; 40 parts of water glass; 15 parts of sodium lauryl sulphate; 15 parts of NP-10; 3 parts of OP-10; 3 parts of Citric acid monohydrate Food grades; 8 parts of soda ash; 3 parts of Sodium dodecylbenzene sulfonatees; 1 part, essence.
According to preparation method provided by the present invention, make product.
Use properties: according to using method of the present invention, carry out vehicle cleaning, the vehicle free from smutting during after cleaning is residual, and smell is pure and fresh, car paint no marking, and working efficiency has improved 1/3rd, than traditional carwash water saving 1/3rd.
Embodiment 4
Contain by weight following component: 60 parts of tripoly phosphate sodium STPPs; 60 parts, sodium sulfate; 20 parts of water glass; 5 parts of sodium lauryl sulphate; 5 parts of NP-10; 8 parts of OP-10; 8 parts of Citric acid monohydrate Food grades; 3 parts of soda ash; n-C 11H 23-CH 2SO 38 parts of Na; 5 parts, colorant.
According to preparation method provided by the present invention, make product.
Use properties: according to using method of the present invention, carry out vehicle cleaning, the vehicle free from smutting during after cleaning is residual, car paint no marking, and working efficiency has improved 1/3rd, than traditional carwash water saving 1/3rd.
Embodiment 5
Contain by weight following component: 50 parts of tripoly phosphate sodium STPPs; 50 parts, sodium sulfate; 25 parts of water glass; 10 parts of sodium lauryl sulphate; 10 parts of NP-10; 5 parts of OP-10; 5 parts of Citric acid monohydrate Food grades; 5 parts of soda ash; 5 parts of Sodium dodecylbenzene sulfonatees.
According to preparation method provided by the present invention, make product.
Use properties: according to using method of the present invention, carry out vehicle cleaning, the vehicle free from smutting during after cleaning is residual, car paint no marking, and working efficiency has improved 50%, than traditional carwash water saving 50%.
Embodiment 6
Contain by weight following component: 50 parts of tripoly phosphate sodium STPPs; 50 parts, sodium sulfate; 25 parts of water glass; 10 parts of sodium lauryl sulphate; 10 parts of NP-10; 5 parts of OP-10; 5 parts of Citric acid monohydrate Food grades; 5 parts of soda ash; 5 parts of Sodium dodecylbenzene sulfonatees; 2 parts, essence; 2 parts, colorant.
According to preparation method provided by the present invention, make product.
Use properties: according to using method of the present invention, carry out vehicle cleaning, the vehicle free from smutting during after cleaning is residual, and smell is pure and fresh, car paint no marking, and working efficiency has improved 50%, than traditional carwash water saving 50%.
Embodiment 7
Contain by weight following component: 50 parts of tripoly phosphate sodium STPPs; 50 parts, sodium sulfate; 25 parts of water glass; 10 parts of sodium lauryl sulphate; 10 parts of NP-10; 5 parts of OP-10; 5 parts of Citric acid monohydrate Food grades; 5 parts of soda ash; 5 parts of Sodium dodecylbenzene sulfonatees; 2 parts, essence.
According to preparation method provided by the present invention, make product.
Use properties: according to using method of the present invention, carry out vehicle cleaning, the vehicle free from smutting during after cleaning is residual, and smell is pure and fresh, car paint no marking, and working efficiency has improved 50%, than traditional carwash water saving 50%.
Applicant's statement, the present invention illustrates detailed process equipment and process flow process of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned detailed process equipment and process flow process, do not mean that namely the present invention must rely on above-mentioned detailed process equipment and process flow process and could implement.The person of ordinary skill in the field should understand, any improvement in the present invention, to the interpolation of the equivalence replacement of each raw material of product of the present invention and ancillary component, the selection of concrete mode etc., within all dropping on protection scope of the present invention and open scope.

Claims (10)

1. a vehicle cleaning agent, is characterized in that, is following component by weight: tripoly phosphate sodium STPP 30-70 part; Sodium sulfate 20-60 part; Water glass 10-40 part; Sodium lauryl sulphate 5-20 part; Polyoxyethylene nonylphenol ether 5-20 part; Alkylphenol polyoxyethylene 1-10 part; Citric acid monohydrate Food grade 1-10 part; Soda ash 1-10 part; Sulfonic acid or sulfonate 1-10 part.
2. sanitising agent according to claim 1, is characterized in that, is following component by weight: tripoly phosphate sodium STPP 40-60 part; Sodium sulfate 40-60 part; Water glass 20-40 part; Sodium lauryl sulphate 5-15 part; Polyoxyethylene nonylphenol ether 5-15 part; Alkylphenol polyoxyethylene 3-8 part; Citric acid monohydrate Food grade 3-8 part; Soda ash 3-8 part; Sulfonic acid or sulfonate 3-8 part.
3. according to sanitising agent claimed in claim 1, it is characterized in that, is following component by weight: 50 parts of tripoly phosphate sodium STPPs; 50 parts, sodium sulfate; 25 parts of water glass; 10 parts of sodium lauryl sulphate; 10 parts of polyoxyethylene nonylphenol ethers; 5 parts of alkylphenol polyoxyethylene; 5 parts of Citric acid monohydrate Food grades; 5 parts of soda ash; 5 parts, sulfonic acid or sulfonate.
4. a vehicle cleaning agent, is characterized in that, is following component by weight: tripoly phosphate sodium STPP 30-70 part; Sodium sulfate 20-60 part; Water glass 10-40 part; Sodium lauryl sulphate 5-20 part; Polyoxyethylene nonylphenol ether 5-20 part; Alkylphenol polyoxyethylene 1-10 part; Citric acid monohydrate Food grade 1-10 part; Soda ash 1-10 part; Sulfonic acid or sulfonate 1-10 part; The essence of 1-5 part is or/and the colorant of 1-5 part.
5. sanitising agent according to claim 4, is characterized in that, is following component by weight: tripoly phosphate sodium STPP 40-60 part; Sodium sulfate 40-60 part; Water glass 20-40 part; Sodium lauryl sulphate 5-15 part; Polyoxyethylene nonylphenol ether 5-15 part; Alkylphenol polyoxyethylene 3-8 part; Citric acid monohydrate Food grade 3-8 part; Soda ash 3-8 part; Sulfonic acid or sulfonate 3-8 part; The essence of 1-5 part is or/and the colorant of 1-5 part.
6. sanitising agent according to claim 4, is characterized in that, is following component by weight: 50 parts of tripoly phosphate sodium STPPs; 50 parts, sodium sulfate; 25 parts of water glass; 10 parts of sodium lauryl sulphate; 10 parts of polyoxyethylene nonylphenol ethers; 5 parts of alkylphenol polyoxyethylene; 5 parts of Citric acid monohydrate Food grades; 5 parts of soda ash; 5 parts, sulfonic acid or sulfonate; The essence of 1-5 part is or/and the colorant of 1-5 part.
7. according to the described sanitising agent of claim 1-6 any one, it is characterized in that, described sulfonate is Sodium dodecylbenzene sulfonate.
8. sanitising agent according to claim 4, is characterized in that, is following component by weight: 50 parts of tripoly phosphate sodium STPPs; 50 parts, sodium sulfate; 25 parts of water glass; 10 parts of sodium lauryl sulphate; 10 parts of polyoxyethylene nonylphenol ethers; 5 parts of alkylphenol polyoxyethylene; 5 parts of Citric acid monohydrate Food grades; 5 parts of soda ash; 5 parts of Sodium dodecylbenzene sulfonatees; 2 parts, essence.
9. sanitising agent according to claim 4, is characterized in that, is following component by weight: 50 parts of tripoly phosphate sodium STPPs; 50 parts, sodium sulfate; 25 parts of water glass; 10 parts of sodium lauryl sulphate; 10 parts of polyoxyethylene nonylphenol ethers; 5 parts of alkylphenol polyoxyethylene; 5 parts of Citric acid monohydrate Food grades; 5 parts of soda ash; 5 parts of Sodium dodecylbenzene sulfonatees; 2 parts, colorant.
10. according to sanitising agent claimed in claim 4, it is characterized in that, is following component by weight: 50 parts of tripoly phosphate sodium STPPs; 50 parts, sodium sulfate; 25 parts of water glass; 10 parts of sodium lauryl sulphate; 10 parts of polyoxyethylene nonylphenol ethers; 5 parts of alkylphenol polyoxyethylene; 5 parts of Citric acid monohydrate Food grades; 5 parts of soda ash; 5 parts of Sodium dodecylbenzene sulfonatees; 2 parts, essence; 2 parts, colorant.
CN2012102065779A 2012-06-21 2012-06-21 Vehicle cleaning agent Active CN102732389B (en)

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CN102965220A (en) * 2012-12-17 2013-03-13 邹品生 Traceless washing-free wax solvent for vehicle
CN104099188A (en) * 2013-04-03 2014-10-15 李冬可 Solid windshield washer fluid and preparation method thereof
CN103666876A (en) * 2013-12-02 2014-03-26 南通瑞普埃尔生物工程有限公司 Vehicle cleaning fluid and preparation method thereof
CN104745314B (en) * 2013-12-25 2018-09-18 安徽明讯新材料科技股份有限公司 A kind of coating apparatus heat exchanger cleaning agent
CN105220168A (en) * 2014-06-25 2016-01-06 天津龙尚洁科技有限公司 A kind of carwash wax powder and using method thereof
CN104212654A (en) * 2014-09-17 2014-12-17 遵义市斌灏信息咨询有限公司 Toilet cleaner
CN105296183A (en) * 2015-10-08 2016-02-03 广州粤润汽车服务有限公司 Preparation method of essence for cleaning automobile mudguard without water
CN106190634A (en) * 2016-07-07 2016-12-07 宋建设 A kind of multiple-effect Dry Cleaners and preparation method thereof
CN107971192A (en) * 2017-12-12 2018-05-01 安徽启东热能科技有限公司 A kind of method for improving lighter hydrocarbons generating means surface resistance to soiling

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Address after: 321000 Zhejiang city of Jinhua Province East Street Jindong east of Li Yu north of Wanda Plaza 4 Building 7 floor, room 715

Patentee after: ZHEJIANG OPS ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD.

Address before: 321000 Zhejiang province Jinhua City Jindong No. 115 Cao Zhai Zhen Qiao Xi Cun

Patentee before: Jin Jianlin

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Denomination of invention: A vehicle cleaner

Effective date of registration: 20230829

Granted publication date: 20131127

Pledgee: Industrial and Commercial Bank of China Limited Jinhua Wucheng sub branch

Pledgor: ZHEJIANG OPS ENVIRONMENTAL PROTECTION TECHNOLOGY CO.,LTD.

Registration number: Y2023980054160

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