CN102731899A - Inflaming retarding polypropylene composite material - Google Patents
Inflaming retarding polypropylene composite material Download PDFInfo
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- CN102731899A CN102731899A CN2012101880781A CN201210188078A CN102731899A CN 102731899 A CN102731899 A CN 102731899A CN 2012101880781 A CN2012101880781 A CN 2012101880781A CN 201210188078 A CN201210188078 A CN 201210188078A CN 102731899 A CN102731899 A CN 102731899A
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- flame
- composite material
- polypropylene composite
- retardant
- retardant polypropylene
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Abstract
The invention discloses an inflaming retarding polypropylene composite material, which is composed of the following raw materials, by weight: 50-60 parts of polypropylene, 15-20 parts of halogen flame retardant, 15-20 parts of halogen-free flame retardant, 3-5 parts of inflaming retarding synergistic agent, 0.1-0.2 part of antioxidant, 3-5 parts of plasticizer, and 0-2 parts of filler. The composite material prepared by the invention has good inflaming retarding and mechanical properties.
Description
Technical field
The present invention relates to a kind of flame-retardant polypropylene composite material.
Background technology
Bromine antimony flame-retardant system, though can accomplish good vertical combustion grade, like 0.8 mm-3.2mm, V-0 can not bear the high thermal stresses that causes in the high temperature glowing filament short period of time, thereby combustion phenomena occur.
Nitrogen phosphorus expandable flame retardant system also can be accomplished good vertical combustion grade, like 0.8 mm-3.2mm; V-0 possibly also can accomplish 850 ℃ of nonflammable requirements, but it is big to add component; Bigger to the material mechanical performance influence, reduce greatly like toughness, thermotolerance reduces (heat-drawn wire, ball press temperature to reduce); In addition owing to add more fire retardant (APP etc.), this based flame retardant is anti-, and to separate out performance relatively poor relatively, may cause material to separate out.In sum, limited the range of application of material.
Summary of the invention
The purpose of this invention is to provide a kind of flame-retardant polypropylene composite material.
The technical scheme that the present invention taked is:
A kind of flame-retardant polypropylene composite material, its raw material by following mass parts is formed: the fire retarding synergist of the halogenated flame retardant of the Vestolen PP 7052 of 50-60 part, 15-20 part, the halogen-free flame retardants of 15-20 part, 3-5 part, the oxidation inhibitor of 0.1-0.2 part, the softening agent of 3-5 part, the filler of 0-2 part.
Described halogenated flame retardant comprises TDE, eight bromo ether, tetrabromo-bisphenol.
Described halogen-free flame retardants is the N-P expansion type flame retardant.
Described fire retarding synergist comprises Antimony Trioxide: 99.5Min, zinc borate, Ammonium Heptamolybdate, zinc oxide.
Described softening agent comprises phthalic ester, terephthalate, isophthalic acid ester, triphenylphosphate.
Described filler comprises white titanium pigment, carbon black.
Described oxidation inhibitor comprises 1010,168,1076,1098,245.
The invention has the beneficial effects as follows: the matrix material of the present invention's preparation has flame retardant properties and mechanical property preferably.
Embodiment
Below in conjunction with specific embodiment the present invention is done further explanation:
Embodiment 1:
A kind of flame-retardant polypropylene composite material, its prescription is formed like following table 1:
Table 1: the prescription of flame-retardant polypropylene composite material is formed
| Raw material | Mass parts |
| PP AP03B | 60 |
| TDE | 15 |
| Antimony Trioxide: 99.5Min | 5 |
| Fire retardant PhonitonTM NHFR-8183 | 15 |
| Triphenylphosphate TPP | 5 |
| Antioxidant 1010 | 0.1 |
| Oxidation inhibitor 168 | 0.2 |
Embodiment 2:
A kind of flame-retardant polypropylene composite material, its prescription is formed like following table 2:
Table 2: the prescription of flame-retardant polypropylene composite material is formed
| Raw material | Mass parts |
| PP AP03B | 56 |
| TDE | 18 |
| Antimony Trioxide: 99.5Min | 3 |
| Fire retardant PhonitonTM NHFR-8183 | 18 |
| Triphenylphosphate TPP | 3 |
| Antioxidant 1010 | 0.1 |
| Oxidation inhibitor 168 | 0.2 |
| White titanium pigment | 2 |
Embodiment 3:
A kind of flame-retardant polypropylene composite material, its prescription is formed like following table 3:
Table 3: the prescription of flame-retardant polypropylene composite material is formed
| Raw material | Mass parts |
| PP AP03B | 52 |
| TDE | 20 |
| Antimony Trioxide: 99.5Min | 3 |
| Fire retardant PhonitonTM NHFR-8183 | 20 |
| Triphenylphosphate TPP | 3 |
| Antioxidant 1010 | 0.1 |
| Oxidation inhibitor 168 | 0.2 |
| White titanium pigment | 2 |
Embodiment 4:
A kind of flame-retardant polypropylene composite material, its prescription is formed like following table 4:
Table 4: the prescription of flame-retardant polypropylene composite material is formed
| Raw material | Mass parts |
| PP AP03B | 56 |
| TDE | 18 |
| Antimony Trioxide: 99.5Min | 3 |
| Fire retardant PhonitonTM NHFR-8183 | 18 |
| Triphenylphosphate TPP | 3 |
| Antioxidant 1010 | 0.1 |
| Oxidation inhibitor 168 | 0.2 |
| Carbon black | 2 |
Embodiment 5:
A kind of flame-retardant polypropylene composite material, its prescription is formed like following table 5:
Table 5: the prescription of flame-retardant polypropylene composite material is formed
| Raw material | Mass parts |
| PP AP03B | 52 |
| TDE | 20 |
| Antimony Trioxide: 99.5Min | 3 |
| Fire retardant PhonitonTM NHFR-8183 | 20 |
| Triphenylphosphate TPP | 3 |
| Antioxidant 1010 | 0.1 |
| Oxidation inhibitor 168 | 0.2 |
| Carbon black | 52 |
Compound composition of the present invention can carry out moulding through conventional forming technique, as melt extrudes, and the matrix material of processing with embodiment 1-5 is carried out performance test, and the test result of gained is following:
Table 6: performance of composites of the present invention
Can find out that PP composite material of the present invention possesses good performance.
Claims (7)
1. flame-retardant polypropylene composite material, it is characterized in that: its raw material by following mass parts is formed: the fire retarding synergist of the halogenated flame retardant of the Vestolen PP 7052 of 50-60 part, 15-20 part, the halogen-free flame retardants of 15-20 part, 3-5 part, the oxidation inhibitor of 0.1-0.2 part, the softening agent of 3-5 part, the filler of 0-2 part.
2. a kind of flame-retardant polypropylene composite material according to claim 1 is characterized in that: described halogenated flame retardant comprises TDE, eight bromo ether, tetrabromo-bisphenol.
3. a kind of flame-retardant polypropylene composite material according to claim 1 is characterized in that: described halogen-free flame retardants is the N-P expansion type flame retardant.
4. a kind of flame-retardant polypropylene composite material according to claim 1 is characterized in that: described fire retarding synergist comprises Antimony Trioxide: 99.5Min, zinc borate, Ammonium Heptamolybdate, zinc oxide.
5. a kind of flame-retardant polypropylene composite material according to claim 1 is characterized in that: described softening agent comprises phthalic ester, terephthalate, isophthalic acid ester, triphenylphosphate.
6. a kind of flame-retardant polypropylene composite material according to claim 1 is characterized in that: described filler comprises white titanium pigment, carbon black.
7. a kind of flame-retardant polypropylene composite material according to claim 1 is characterized in that: described oxidation inhibitor comprises 1010,168,1076,1098,245.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101880781A CN102731899A (en) | 2012-06-08 | 2012-06-08 | Inflaming retarding polypropylene composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101880781A CN102731899A (en) | 2012-06-08 | 2012-06-08 | Inflaming retarding polypropylene composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102731899A true CN102731899A (en) | 2012-10-17 |
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ID=46988248
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012101880781A Pending CN102731899A (en) | 2012-06-08 | 2012-06-08 | Inflaming retarding polypropylene composite material |
Country Status (1)
| Country | Link |
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| CN (1) | CN102731899A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102964682A (en) * | 2012-12-03 | 2013-03-13 | 金发科技股份有限公司 | BDDP (Benzene-1,(1-methyl-eehylidene)bis[(3,-5di-bromo)-4-(2,3-dibrono-propoxy)]) inflaming-retarding polypropylene composite material and preparation method thereof |
| CN103554659A (en) * | 2013-10-18 | 2014-02-05 | 惠州市昌亿新材料有限公司 | High-performance flame-retardant PP (polypropylene), and preparation method and application thereof |
| CN107973975A (en) * | 2016-10-21 | 2018-05-01 | 合肥杰事杰新材料股份有限公司 | A kind of low halogen V-0 flame-retardant polypropylene composite materials and preparation method thereof |
| CN109135048A (en) * | 2018-06-20 | 2019-01-04 | 金发科技股份有限公司 | A kind of flame retardant polyolefin compound and preparation method thereof |
| CN112625359A (en) * | 2020-12-09 | 2021-04-09 | 上海普利特复合材料股份有限公司 | High-impact-resistance flame-retardant polypropylene composite material for interior decoration of passenger car and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1847301A (en) * | 2006-05-11 | 2006-10-18 | 宁波福天工程塑料有限公司 | Environment friendly halogen-free fireproof polypropylene material |
| CN101220183A (en) * | 2007-12-26 | 2008-07-16 | 深圳市科聚新材料有限公司 | Environment-protection flame-proof electrostatic resistance polypropylene material and method for producing the same |
-
2012
- 2012-06-08 CN CN2012101880781A patent/CN102731899A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1847301A (en) * | 2006-05-11 | 2006-10-18 | 宁波福天工程塑料有限公司 | Environment friendly halogen-free fireproof polypropylene material |
| CN101220183A (en) * | 2007-12-26 | 2008-07-16 | 深圳市科聚新材料有限公司 | Environment-protection flame-proof electrostatic resistance polypropylene material and method for producing the same |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102964682A (en) * | 2012-12-03 | 2013-03-13 | 金发科技股份有限公司 | BDDP (Benzene-1,(1-methyl-eehylidene)bis[(3,-5di-bromo)-4-(2,3-dibrono-propoxy)]) inflaming-retarding polypropylene composite material and preparation method thereof |
| CN102964682B (en) * | 2012-12-03 | 2014-09-24 | 金发科技股份有限公司 | BDDP (Benzene-1,(1-methyl-eehylidene)bis[(3,-5di-bromo)-4-(2,3-dibrono-propoxy)]) inflaming-retarding polypropylene composite material and preparation method thereof |
| CN103554659A (en) * | 2013-10-18 | 2014-02-05 | 惠州市昌亿新材料有限公司 | High-performance flame-retardant PP (polypropylene), and preparation method and application thereof |
| CN107973975A (en) * | 2016-10-21 | 2018-05-01 | 合肥杰事杰新材料股份有限公司 | A kind of low halogen V-0 flame-retardant polypropylene composite materials and preparation method thereof |
| CN109135048A (en) * | 2018-06-20 | 2019-01-04 | 金发科技股份有限公司 | A kind of flame retardant polyolefin compound and preparation method thereof |
| CN109135048B (en) * | 2018-06-20 | 2021-10-12 | 金发科技股份有限公司 | Flame-retardant polyolefin composition and preparation method thereof |
| CN112625359A (en) * | 2020-12-09 | 2021-04-09 | 上海普利特复合材料股份有限公司 | High-impact-resistance flame-retardant polypropylene composite material for interior decoration of passenger car and preparation method thereof |
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Application publication date: 20121017 |