CN102731889B - 一种高硬度高弹性离子化树脂及其制备方法 - Google Patents
一种高硬度高弹性离子化树脂及其制备方法 Download PDFInfo
- Publication number
- CN102731889B CN102731889B CN201210200818.9A CN201210200818A CN102731889B CN 102731889 B CN102731889 B CN 102731889B CN 201210200818 A CN201210200818 A CN 201210200818A CN 102731889 B CN102731889 B CN 102731889B
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- CN
- China
- Prior art keywords
- methacrylic acid
- snappiness
- resin
- high rigidity
- carbon black
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920005989 resin Polymers 0.000 title claims abstract description 22
- 239000011347 resin Substances 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229920001971 elastomer Polymers 0.000 claims abstract description 21
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000006229 carbon black Substances 0.000 claims abstract description 15
- 239000011787 zinc oxide Substances 0.000 claims abstract description 15
- 239000003999 initiator Substances 0.000 claims abstract description 13
- -1 polyethylene Polymers 0.000 claims abstract description 6
- 239000004698 Polyethylene Substances 0.000 claims abstract description 5
- 229920000573 polyethylene Polymers 0.000 claims abstract description 5
- 239000000806 elastomer Substances 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 21
- 238000002156 mixing Methods 0.000 claims description 13
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 12
- 229920001684 low density polyethylene Polymers 0.000 claims description 10
- 239000004702 low-density polyethylene Substances 0.000 claims description 10
- HEAMQYHBJQWOSS-UHFFFAOYSA-N ethene;oct-1-ene Chemical compound C=C.CCCCCCC=C HEAMQYHBJQWOSS-UHFFFAOYSA-N 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 238000005453 pelletization Methods 0.000 claims description 6
- BMFMTNROJASFBW-UHFFFAOYSA-N 2-(furan-2-ylmethylsulfinyl)acetic acid Chemical compound OC(=O)CS(=O)CC1=CC=CO1 BMFMTNROJASFBW-UHFFFAOYSA-N 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 239000000758 substrate Substances 0.000 claims description 3
- 239000003292 glue Substances 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- YQTOVEJEXGTPNM-UHFFFAOYSA-N prop-2-enoic acid;zinc Chemical compound [Zn].OC(=O)C=C YQTOVEJEXGTPNM-UHFFFAOYSA-N 0.000 claims description 2
- 239000005060 rubber Substances 0.000 abstract description 17
- 229920003023 plastic Polymers 0.000 abstract description 4
- 239000004033 plastic Substances 0.000 abstract description 4
- NALFRYPTRXKZPN-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane Chemical compound CC1CC(C)(C)CC(OOC(C)(C)C)(OOC(C)(C)C)C1 NALFRYPTRXKZPN-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 abstract 1
- 239000000463 material Substances 0.000 description 6
- 239000004594 Masterbatch (MB) Substances 0.000 description 4
- 150000007942 carboxylates Chemical class 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 2
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 229920002725 thermoplastic elastomer Polymers 0.000 description 2
- 241000212978 Amorpha <angiosperm> Species 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000001457 metallic cations Chemical class 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
- PIMBTRGLTHJJRV-UHFFFAOYSA-L zinc;2-methylprop-2-enoate Chemical group [Zn+2].CC(=C)C([O-])=O.CC(=C)C([O-])=O PIMBTRGLTHJJRV-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
性能 | 实施方式一 | 实施方式二 | 实施方式三 |
硬度(邵尔A)/度 | 95 | 95 | 96 |
拉伸强度/MPa | 15 | 16 | 16 |
拉断伸长率/% | 450 | 485 | 480 |
300%定伸应力/MPa | 8.26 | 8.3 | 8.3 |
回弹性/% | 60 | 61 | 60 |
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201210200818.9A CN102731889B (zh) | 2012-06-18 | 2012-06-18 | 一种高硬度高弹性离子化树脂及其制备方法 |
Applications Claiming Priority (1)
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CN201210200818.9A CN102731889B (zh) | 2012-06-18 | 2012-06-18 | 一种高硬度高弹性离子化树脂及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN102731889A CN102731889A (zh) | 2012-10-17 |
CN102731889B true CN102731889B (zh) | 2013-10-30 |
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CN201210200818.9A Active CN102731889B (zh) | 2012-06-18 | 2012-06-18 | 一种高硬度高弹性离子化树脂及其制备方法 |
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CN (1) | CN102731889B (zh) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108329558A (zh) * | 2017-12-29 | 2018-07-27 | 浙江省三门中鑫实业有限公司 | 一种环保型挤出片材及其制造方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100594126C (zh) * | 2003-10-07 | 2010-03-17 | 纳幕尔杜邦公司 | 包含离聚物层的多层片材 |
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2012
- 2012-06-18 CN CN201210200818.9A patent/CN102731889B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN100594126C (zh) * | 2003-10-07 | 2010-03-17 | 纳幕尔杜邦公司 | 包含离聚物层的多层片材 |
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CN102731889A (zh) | 2012-10-17 |
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Address after: 266061 Shandong Province, Qingdao city Laoshan District Songling Road No. 99, Qingdao University of Science & Technology College of polymer science and Engineering Applicant after: Qingdao University of Science & Technology Address before: 266042 School of polymer science and engineering, Qingdao University of Science & Technology, 53 Zhengzhou Road, Qingdao, Shandong Applicant before: Qingdao University of Science & Technology |
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Owner name: JIANGSU YANGZHOU HELI RUBBER PRODUCTION CORPORATIO Free format text: FORMER OWNER: QINGDAO UNIVERSITY OF SCIENCE + TECHNOLOGY Effective date: 20130325 |
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Free format text: CORRECT: ADDRESS; FROM: 266061 QINGDAO, SHANDONG PROVINCE TO: 225003 YANGZHOU, JIANGSU PROVINCE |
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Effective date of registration: 20130325 Address after: 225003, No. 36, Shi Jing Road, Guangling District, Jiangsu, Yangzhou Applicant after: Jiangsu Yangzhou Heli Rubber Production Corporation Address before: 266061 Shandong Province, Qingdao city Laoshan District Songling Road No. 99, Qingdao University of Science & Technology College of polymer science and Engineering Applicant before: Qingdao University of Science & Technology |
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