CN102730771A - Production of high purity sodium-free high activity composite nickel carbonate by three-step continuous process - Google Patents
Production of high purity sodium-free high activity composite nickel carbonate by three-step continuous process Download PDFInfo
- Publication number
- CN102730771A CN102730771A CN2012101605587A CN201210160558A CN102730771A CN 102730771 A CN102730771 A CN 102730771A CN 2012101605587 A CN2012101605587 A CN 2012101605587A CN 201210160558 A CN201210160558 A CN 201210160558A CN 102730771 A CN102730771 A CN 102730771A
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- CN
- China
- Prior art keywords
- reaction kettle
- reaction
- cobalt
- carbonate
- nickelous carbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 title claims abstract description 51
- ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 title claims abstract description 26
- 230000000694 effects Effects 0.000 title abstract description 5
- 238000004519 manufacturing process Methods 0.000 title abstract description 4
- 239000002131 composite material Substances 0.000 title abstract 2
- 238000010924 continuous production Methods 0.000 title abstract 2
- 238000006243 chemical reaction Methods 0.000 claims abstract description 70
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 26
- 239000011734 sodium Substances 0.000 claims abstract description 26
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 26
- 238000000034 method Methods 0.000 claims abstract description 24
- 239000000376 reactant Substances 0.000 claims abstract description 22
- 238000005406 washing Methods 0.000 claims abstract description 17
- 238000001035 drying Methods 0.000 claims abstract description 13
- 150000002815 nickel Chemical class 0.000 claims abstract description 10
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000001099 ammonium carbonate Substances 0.000 claims abstract description 7
- -1 compound nickelous carbonate Chemical class 0.000 claims description 28
- 230000009257 reactivity Effects 0.000 claims description 28
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 27
- 238000012545 processing Methods 0.000 claims description 22
- 229910017052 cobalt Inorganic materials 0.000 claims description 20
- 239000010941 cobalt Substances 0.000 claims description 20
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 20
- 229910052759 nickel Inorganic materials 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 12
- 238000003860 storage Methods 0.000 claims description 12
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 11
- 239000002244 precipitate Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 9
- 150000001868 cobalt Chemical class 0.000 claims description 9
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical group [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims description 8
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims description 6
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 claims description 5
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 4
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 4
- 150000007530 organic bases Chemical class 0.000 claims description 4
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 claims description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 19
- 239000001569 carbon dioxide Substances 0.000 abstract description 9
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract description 9
- 235000012501 ammonium carbonate Nutrition 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 150000001412 amines Chemical class 0.000 abstract description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 238000011031 large-scale manufacturing process Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 239000002994 raw material Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 3
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- 229910021588 Nickel(II) iodide Inorganic materials 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- DBAHSLAQEKZNEZ-UHFFFAOYSA-J calcium nickel(2+) dicarbonate Chemical compound C([O-])([O-])=O.[Ca+2].[Ni+2].C([O-])([O-])=O DBAHSLAQEKZNEZ-UHFFFAOYSA-J 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910000001 cobalt(II) carbonate Inorganic materials 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229940078494 nickel acetate Drugs 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- IPLJNQFXJUCRNH-UHFFFAOYSA-L nickel(2+);dibromide Chemical compound [Ni+2].[Br-].[Br-] IPLJNQFXJUCRNH-UHFFFAOYSA-L 0.000 description 1
- BFSQJYRFLQUZKX-UHFFFAOYSA-L nickel(ii) iodide Chemical compound I[Ni]I BFSQJYRFLQUZKX-UHFFFAOYSA-L 0.000 description 1
- DITXJPASYXFQAS-UHFFFAOYSA-N nickel;sulfamic acid Chemical compound [Ni].NS(O)(=O)=O DITXJPASYXFQAS-UHFFFAOYSA-N 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 102220042174 rs141655687 Human genes 0.000 description 1
- 102220076495 rs200649587 Human genes 0.000 description 1
- 102220043159 rs587780996 Human genes 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
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- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
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CN2012101605587A CN102730771B (en) | 2012-05-23 | 2012-05-23 | Production of high purity sodium-free high activity composite nickel carbonate by three-step continuous process |
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CN2012101605587A CN102730771B (en) | 2012-05-23 | 2012-05-23 | Production of high purity sodium-free high activity composite nickel carbonate by three-step continuous process |
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CN102730771A true CN102730771A (en) | 2012-10-17 |
CN102730771B CN102730771B (en) | 2013-11-27 |
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CN2012101605587A Expired - Fee Related CN102730771B (en) | 2012-05-23 | 2012-05-23 | Production of high purity sodium-free high activity composite nickel carbonate by three-step continuous process |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104556248A (en) * | 2013-10-12 | 2015-04-29 | 中国电子科技集团公司第十八研究所 | Method for continuously producing large-particle spherical cobalt carbonate |
CN112939099A (en) * | 2021-02-09 | 2021-06-11 | 荆门市格林美新材料有限公司 | Preparation method of basic nickel carbonate |
CN113044895A (en) * | 2019-12-27 | 2021-06-29 | 荆门市格林美新材料有限公司 | Preparation method of low-impurity high-nickel basic nickel carbonate |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN201046957Y (en) * | 2007-05-22 | 2008-04-16 | 中兴能源技术(武汉)有限公司 | Continuous ester exchange reaction device for preparing fatty acid ester with grease and low-carbon alcohol |
CN101264943A (en) * | 2008-04-24 | 2008-09-17 | 吉林市金泰化工有限公司 | Water-saving discharge-reducing consume-reducing continuous production method and device for nickel carbonate |
US20110311428A1 (en) * | 2009-12-18 | 2011-12-22 | Invista North America S.A R.L. | Nickel compositions for preparing nickel metal and nickel complexes |
-
2012
- 2012-05-23 CN CN2012101605587A patent/CN102730771B/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN201046957Y (en) * | 2007-05-22 | 2008-04-16 | 中兴能源技术(武汉)有限公司 | Continuous ester exchange reaction device for preparing fatty acid ester with grease and low-carbon alcohol |
CN101264943A (en) * | 2008-04-24 | 2008-09-17 | 吉林市金泰化工有限公司 | Water-saving discharge-reducing consume-reducing continuous production method and device for nickel carbonate |
US20110311428A1 (en) * | 2009-12-18 | 2011-12-22 | Invista North America S.A R.L. | Nickel compositions for preparing nickel metal and nickel complexes |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104556248A (en) * | 2013-10-12 | 2015-04-29 | 中国电子科技集团公司第十八研究所 | Method for continuously producing large-particle spherical cobalt carbonate |
CN113044895A (en) * | 2019-12-27 | 2021-06-29 | 荆门市格林美新材料有限公司 | Preparation method of low-impurity high-nickel basic nickel carbonate |
CN113044895B (en) * | 2019-12-27 | 2023-09-05 | 荆门市格林美新材料有限公司 | Preparation method of low-impurity high-nickel basic nickel carbonate |
CN112939099A (en) * | 2021-02-09 | 2021-06-11 | 荆门市格林美新材料有限公司 | Preparation method of basic nickel carbonate |
CN112939099B (en) * | 2021-02-09 | 2023-05-12 | 荆门市格林美新材料有限公司 | Preparation method of basic nickel carbonate |
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CN102730771B (en) | 2013-11-27 |
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C53 | Correction of patent of invention or patent application | ||
CB03 | Change of inventor or designer information |
Inventor after: Zheng Jingyi Inventor after: Lv Wenguang Inventor after: Lv Boyi Inventor after: Zheng Yuqi Inventor after: Chang Qi Inventor after: Chen Yizhe Inventor before: Lv Wenguang Inventor before: Zheng Jingyi Inventor before: Lv Boshen Inventor before: Zheng Yuqi Inventor before: Chang Qi Inventor before: Chen Yizhe |
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COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: LV WENGUANG ZHENG JINGYI LV BO ZHENG YUQI CHANG QI CHEN YIZHE TO: ZHENG JINGYI LV WENGUANG LV BO ZHENG YUQI CHANG QI CHEN YIZHE |
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C14 | Grant of patent or utility model | ||
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Effective date of registration: 20160822 Address after: 518100, Shenzhen, Guangdong, Xixiang, Baoan District, two road forward, Taoyuan, 14, ABC, building C1004 room Patentee after: Zheng Jingyi Address before: 132012 No. 99 Hanjiang Road, fine chemical industrial park, Longtan economic development zone, Jilin, Jilin Patentee before: Jilin City Friend Technology Co., Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20131127 Termination date: 20200523 |