CN102720063A - Composite pulp for polyester textile sizing as well as preparation method and application of composite pulp - Google Patents
Composite pulp for polyester textile sizing as well as preparation method and application of composite pulp Download PDFInfo
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- CN102720063A CN102720063A CN2012102134105A CN201210213410A CN102720063A CN 102720063 A CN102720063 A CN 102720063A CN 2012102134105 A CN2012102134105 A CN 2012102134105A CN 201210213410 A CN201210213410 A CN 201210213410A CN 102720063 A CN102720063 A CN 102720063A
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- composite mortar
- textile sizing
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Abstract
The invention discloses composite pulp for polyester textile sizing. The composite pulp is characterized by consisting of the following ingredients through being metered by the weight percent: 30 to 50 percent of water-soluble polyesters and 50 to 70 percent of acrylic ester pulp, wherein the viscosity of the water-soluble polyesters is between 0.15 and 0.3, and the acid value is between 20 mg KOH/g and 60 mg KOH/g. The composite pulp is used for the polyester textile sizing aspect, the pulp performance can be greatly improved, and in addition, the complete desizing can be realized under the condition without changing the existing industrial polyester textile process.
Description
Technical field
The invention belongs to the textile sizing technical field, be specifically related to a kind of composite mortar, preparation method and application that is used for the terylene textile sizing.
Background technology
Pulp natural with synthetic two types.The former has starch, modified starch, algin etc.The latter is with carboxymethyl cellulose (CMC), polyvinyl alcohol, polyacrylate etc.Both also can be made into composite mortar each other.The slurry of present domestic terylene starching mainly is an acrylic size, but general acrylic size film-strength is not enough, is prone to lax.And aspect the polyester filament starching, its adhesiveness, ABRASION RESISTANCE all have much room for improvement, and consumption is excessive in addition is prone to cause that the sizing moisture absorption is glutinous again.
The structure of polyester slurry is similar with polyster fibre thereby terylene had good adhesiveness; Its viscosity in aqueous solution and surface tension are all very little; The polyester serous coat has moderate flexibility and lower hydroscopicity; Make the performance such as adhesive force, tensile force of serous coat obtain very big improvement, and the destarch of polyester slurry is easy.The present invention combines above-mentioned advantage to develop, and solves the starching problem of terylene weaving in the prior art.
Summary of the invention
The object of the invention is to provide a kind of composite mortar that is used for the terylene textile sizing, and slurry adhesiveness when having solved in the prior art polyester filament starching, ABRASION RESISTANCE are not enough, and is prone to cause problems such as the sizing moisture absorption is glutinous again when strengthening consumption.
In order to solve these problems of the prior art, technical scheme provided by the invention is:
A kind of composite mortar that is used for the terylene textile sizing is characterized in that said composite mortar counts with the percentage by weight of its component:
Water-soluble polyester 30～50%;
Acrylate syrup 50～70%;
Wherein the viscosity of water-soluble polyester is between 0.15～0.3, and acid number is between 20～60mg KOH/g.
Preferably, said water-soluble polyester makes through following method:
(1) acid-alcohol ratio is binary acid and the dihydroxylic alcohols mixing of 1.2-1.5, is to carry out esterification or ester exchange reaction under the 220-250 ℃ of condition adding catalyst and reaction temperature, and the unnecessary alcohol of decompression discharge formed the short chain oligomer after reaction was reached home; Wherein binary acid is counted with the molar weight ratio of its all binary acid of ingredients constitute in the reactant:
Terephthalic acid (TPA) or ester 50-80%;
M-phthalic acid or ester 10-20%;
All the other binary acid 10-30%;
Dihydroxylic alcohols is counted with the molar weight ratio of its all dihydroxylic alcohols of ingredients constitute in the reactant:
Ethylene glycol 70-90%;
All the other dihydroxylic alcohols 10-30%;
(2) add trimellitic anhydride after being cooled to 180-210 ℃ and continue reaction, the water-soluble polyester that obtains; The content of the trimellitic anhydride that wherein adds is the 5-15% of binary acid integral molar quantity in the step (1).
Preferably, said all the other binary acid are selected from: phthalic acid, malonic acid, adipic acid, azelaic acid, decanedioic acid, 1,4-cyclohexane cyclohexanedimethanodibasic, 1, a kind of or combination in any more than two kinds of 4-naphthalene diacid.
Preferably, said all the other dihydroxylic alcohols are selected from: propylene glycol, butanediol, neopentyl glycol, hexylene glycol, 1,4 cyclohexane dimethanol, diethylene glycol (DEG), polyethylene glycol one or more combination in any wherein.
Preferably, said catalyst consumption is 50～750ppm that the first step is participated in esterification or ester exchange reaction thing gross weight.
Preferably, said catalyst is selected from: the combination in any of one or more of Zn, Mn, Mg, Ca, Co acetate, butyl titanate, isopropyl titanate, Triaethanolamine titanium, Dibutyltin oxide, antimony oxide, antimony glycol;
Preferably, said acrylate syrup is prepared through emulsion copolymerization by acrylic monomer and acrylic ester monomer, and wherein acrylic monomer accounts for the 10-30% of all monomer masses; Acrylic ester monomer accounts for the 70-90% of all monomer masses.
Preferably, said acrylic monomer is selected from: the combination in any of one or both of acrylic acid, methacrylic acid.
Preferably, said acrylate monomer is selected from: the combination in any of one or more of methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, methyl methacrylate, EMA, butyl methacrylate, butyl methacrylate, acrylonitrile, methacrylonitrile, vinylacetate.
Another object of the present invention is to provide a kind of described preparation method who is used for the composite mortar of terylene textile sizing, it is characterized in that said method comprising the steps of:
(1) acid-alcohol ratio is binary acid and the dihydroxylic alcohols mixing of 1.2-1.5, is to carry out esterification or ester exchange reaction under the 220-250 ℃ of condition adding catalyst and reaction temperature, and the unnecessary alcohol of decompression discharge formed the short chain oligomer after reaction was reached home; Wherein binary acid is counted with the molar weight ratio of its all binary acid of ingredients constitute in the reactant:
Terephthalic acid (TPA) or ester 50-80%;
M-phthalic acid or ester 10-20%;
All the other binary acid 10-30%;
Dihydroxylic alcohols is counted with the molar weight ratio of its all dihydroxylic alcohols of ingredients constitute in the reactant:
Ethylene glycol 70-90%;
All the other dihydroxylic alcohols 10-30%;
(2) add trimellitic anhydride after being cooled to 180-210 ℃ and continue reaction, the water-soluble polyester that obtains; The content of the trimellitic anhydride that wherein adds is the 5-15% of binary acid integral molar quantity in the step (1);
(3) prepare acrylate syrup by acrylic monomer and acrylic ester monomer through emulsion copolymerization, wherein acrylic monomer accounts for the 10-30% of all monomer masses; Acrylic ester monomer accounts for the 70-90% of all monomer masses;
(4) will account for the water-soluble polyester of raw material gross mass 30～50% and 50～70% acrylate syrup and prepare, obtain being used for the composite mortar of terylene textile sizing through blend.
Preferably, the pH that needing after the blend preparation to carry out in the said method step (4) being used for the composite mortar of terylene textile sizing is controlled between the 7-7.5.
Another object of the present invention is to provide a kind of described application of composite mortar on the terylene textile sizing that is used for the terylene textile sizing.
The composite mortar that is used for the terylene textile sizing of the present invention, it is made up of water-soluble polyester and acrylate syrup, and wherein water-soluble polyester has high acid value, and viscosity is between 0.15～0.3, and acid number is between 20～60mg KOH/g.
The composite mortar that is used for the terylene textile sizing of the present invention is used for the terylene textile sizing, is used by polyester and acrylic size mix and match, can significantly improve size performance, and not change under the desizing condition, destarch fully.Invention thinking of the present invention is to adopt polyester slurry and being used of acrylic size strong remedying to be provided for the performance of acrylic size in the terylene textile sizing; Improve the serviceability of slurry and viscosity is reduced; The rate of sizing descends; Practice thrift cost, can not change destarch fully under original process conditions simultaneously.
The weight content of water-soluble polyester is 30～50% in the composite mortar that the present invention is made up of water-soluble polyester and acrylate syrup, and the weight content of acrylate syrup is 50～70%; Described water-soluble polyester, viscosity are between 0.15～0.3, and acid number is between 20～60mg KOH/g.
The synthetic first step of water-soluble polyester need add catalyst, and catalyst consumption is 50～750ppm of first step reactant gross weight.Catalyst system therefor is selected from: the combination in any of one or more of Zn, Mn, Mg, C a, Co acetate, butyl titanate, isopropyl titanate, Triaethanolamine titanium, Dibutyltin oxide, antimony oxide, antimony glycol;
The present invention forms composite mortar through adopting the preparation of water-soluble polyester and acrylate blend; Its key is with the water-soluble polyester of acid number at 20-60mg KOH/g; It is used for terylene textile sizing aspect can improve size performance significantly; And can realize complete destarch not changing in the present industry under the terylene textile technology condition.
With respect to scheme of the prior art, advantage of the present invention is:
The present invention adopts the water-soluble polyester slurry because structure is close with polyester filament, so terylene has good adhesiveness, all is greatly improved for the adhesive force and the tensile property of slurry; Can improve simultaneously the permeability of acrylic size; Reduce viscosity, the rate of sizing is descended, practice thrift cost.Collocation through with water-soluble polyester and acrylic size is used, and can not change destarch fully under the original desizing condition, and can improve size performance greatly.
The specific embodiment
Below in conjunction with specific embodiment such scheme is further specified.Should be understood that these embodiment are used to the present invention is described and are not limited to limit scope of the present invention.The implementation condition that adopts among the embodiment can be done further adjustment according to the condition of concrete producer, and not marked implementation condition is generally the condition in the normal experiment.
Embodiment 1 is used for the preparation of the composite mortar of terylene textile sizing
1, water-soluble polyester is synthetic:
The terephthalic acid (TPA) of 249.2kg, the DMIP of 51.2kg, the adipic acid of 27.4kg, the ethylene glycol of 146.6kg, the neopentyl glycol of 27.6kg and the zinc acetate of 150g and the isopropyl titanate mixing of 75g are put in the agitated reactor; Use the nitrogen replacement air; Heat up and stir; Maintain the temperature at reaction between 220-250 ℃, after the accessory substance of collection reaches theoretical value, decompression 30min.Eliminate vacuum with nitrogen then, be cooled between 180-210 ℃, drop into the trimellitic anhydride of 18kg, continue reaction 30min.Obtain water-soluble polyester.
Through detecting its viscosity of water-soluble polyester that obtains is 0.18, and acid number is 46.8mgKOH/g
2, the preparation of acrylic size:
Earlier 21kg acrylic acid, 63.9kg methacrylic acid, 120kg methyl methacrylate, 70.2kg methyl acrylate, 50.4kg butyl methacrylate are mixed; Join then in the water of 651kg; Add lauryl sodium sulfate (emulsifying agent) 1.63kg, stir.The ammonium persulfate (initator) that drips 2.6kg is warmed up between 70-85 ℃ and reacts 4h.
3, will account for gross mass 40% water-soluble polyester and join slowly in the acrylic size that accounts for gross mass 60%, and maintain the temperature between 80-95 ℃, blend dissolving stirs, and adding ammoniacal liquor again, to be neutralized to pH be 7-7.5, promptly obtains composite mortar.
Embodiment 2 is used for the preparation of the composite mortar of terylene textile sizing
1, water-soluble polyester is synthetic:
With 1 of the M-phthalic acid of the terephthalic acid (TPA) of 212.3kg, 62.4kg, 46.8kg; The zinc acetate of the ethylene glycol of 4-cyclohexane cyclohexanedimethanodibasic, 124.6kg, the hexylene glycol of 27.6kg and 180g and the isopropyl titanate of 50g mix to be put in the agitated reactor; Use the nitrogen replacement air, heat up and stir, maintain the temperature at reaction between 220-250 ℃; After the accessory substance of collecting reaches theoretical value, decompression 30min.Eliminate vacuum with nitrogen then, be cooled between 180-210 ℃, drop into the trimellitic anhydride of 16.3kg, continue reaction 30min.Obtain water-soluble polyester.
Viscosity through detecting the water-soluble polyester that obtains is 0.25, and acid number is 28mgKOH/g.
2, the preparation of acrylic size:
Earlier 20kg acrylic acid, 46.9kg methacrylic acid, 100kg EMA, 80.9kg butyl acrylate, 76.8kg butyl methacrylate, 20kg acrylonitrile are mixed; Join then in the water of 756kg; Add lauryl sodium sulfate (emulsifying agent) 1.68kg, stir.The ammonium persulfate (initator) that drips 2.4kg is warmed up between 70-85 ℃ and reacts 4h.
3, will account for gross mass 35% water-soluble polyester and join slowly in the acrylic size that accounts for gross mass 65%, and maintain the temperature between 80-95 ℃, blend dissolving stirs, and adding ammoniacal liquor again, to be neutralized to pH be 7-7.5, promptly obtains composite mortar.
Embodiment 3 is used for the preparation of the composite mortar of terylene textile sizing
1, water-soluble polyester is synthetic:
The terephthalic acid (TPA) of 212.3kg, the M-phthalic acid of 48.9kg, the decanedioic acid of 50.4kg, the ethylene glycol of 124.6kg, the diethylene glycol (DEG) of 27.6kg and the zinc acetate of 180g and the isopropyl titanate mixing of 50g are put in the agitated reactor; Use the nitrogen replacement air; Heat up and stir; Maintain the temperature at reaction between 220-250 ℃, after the accessory substance of collection reaches theoretical value, decompression 30min.Eliminate vacuum with nitrogen then, be cooled between 180-210 ℃, drop into the trimellitic anhydride of 16.3kg, continue reaction 30min.Obtain water-soluble polyester.
Advancing to detect its viscosity of water-soluble polyester that obtains is 0.29, and acid number is 22.5mgKOH/g.
2, the preparation of acrylic size:
Earlier with 10kg acrylic acid, 63.2kg methacrylic acid, 140kg EMA, 72.6kg butyl acrylate, 80.5kg butyl methacrylate, mix; Join then in the water of 756kg; Add lauryl sodium sulfate (emulsifying agent) 1.68kg, stir.Drip the ammonium persulfate (initator) of 2.4kg, be warmed up between 70-85 ℃ and react 4h.
3, will account for gross mass 45% water-soluble polyester and join slowly in the acrylic size that accounts for gross mass 55%, and maintain the temperature between 80-95 ℃, blend dissolving stirs, and adding ammoniacal liquor again, to be neutralized to pH be 7-7.5, promptly obtains composite mortar.
Embodiment 4 investigates contrast with the rerum natura of homemade commercially available acrylic size
Comparative Examples adopts homemade acrylic size, and the composite mortar that is used for the terylene textile sizing of the present invention adopts the composite mortar of embodiment 1 ~ 3 preparation, and the rerum natura when carrying out terylene starching practical application is investigated.The result is as shown in table 1.
Table 1 composite mortar of the present invention and the Comparative Examples performance comparison result in terylene starching practical application
Can know that by table 1 composite mortar of the present invention has reduced the rate of sizing in terylene starching practical application, can practice thrift cost like this.The adhesive force of slurry and cohesive force all improve greatly, increase interaction force between the yarn, make the cohesive force of warp thread and ABRASION RESISTANCE all improve a lot.Slashing strength and percentage elongation aspect also improve a lot simultaneously, thereby the slurry combination property is improved greatly.
Above-mentioned instance only is explanation technical conceive of the present invention and characteristics, and its purpose is to let the people who is familiar with this technology can understand content of the present invention and enforcement according to this, can not limit protection scope of the present invention with this.All equivalent transformations that spirit is done according to the present invention or modification all should be encompassed within protection scope of the present invention.
Claims (11)
1. composite mortar that is used for the terylene textile sizing is characterized in that said composite mortar counts with the percentage by weight of its component:
Water-soluble polyester 30～50%;
Acrylate syrup 50～70%;
Wherein the viscosity of water-soluble polyester is between 0.15～0.3, and acid number is between 20～60mg KOH/g.
2. the composite mortar that is used for the terylene textile sizing according to claim 1 is characterized in that said water-soluble polyester makes through following method:
(1) acid-alcohol ratio is binary acid and the dihydroxylic alcohols mixing of 1.2-1.5, is to carry out esterification or ester exchange reaction under the 220-250 ℃ of condition adding catalyst and reaction temperature, and the unnecessary alcohol of decompression discharge formed the short chain oligomer after reaction was reached home; Wherein the binary acid in the reactant is counted with the molar weight ratio of its all binary acid of ingredients constitute:
Terephthalic acid (TPA) or ester 50-80%;
M-phthalic acid or ester 10-20%;
All the other binary acid 10-30%;
Dihydroxylic alcohols is counted with the molar weight ratio of its all dihydroxylic alcohols of ingredients constitute in the reactant:
Ethylene glycol 70-90%;
All the other dihydroxylic alcohols 10-30%;
(2) add trimellitic anhydride after being cooled to 180-210 ℃ and continue reaction, the water-soluble polyester that obtains; The content of the trimellitic anhydride that wherein adds is the 5-15% of binary acid integral molar quantity in the step (1).
3. the composite mortar that is used for the terylene textile sizing according to claim 2; It is characterized in that said all the other binary acid are selected from: phthalic acid, malonic acid, adipic acid, azelaic acid, decanedioic acid, 1; 4-cyclohexane cyclohexanedimethanodibasic, 1, a kind of or combination in any more than two kinds of 4-naphthalene diacid.
4. the composite mortar that is used for the terylene textile sizing according to claim 2; It is characterized in that said all the other dihydroxylic alcohols are selected from: propylene glycol, butanediol, neopentyl glycol, hexylene glycol, 1,4 cyclohexane dimethanol, diethylene glycol (DEG), polyethylene glycol one or more combination in any wherein.
5. the composite mortar that is used for the terylene textile sizing according to claim 2 is characterized in that said catalyst consumption is 50～750ppm that the first step is participated in esterification or ester exchange reaction thing gross weight.
6. the composite mortar that is used for the terylene textile sizing according to claim 2 is characterized in that said catalyst is selected from: the combination in any of one or more of Zn, Mn, Mg, Ca, Co acetate, butyl titanate, isopropyl titanate, Triaethanolamine titanium, Dibutyltin oxide, antimony oxide, antimony glycol.
7. the composite mortar that is used for the terylene textile sizing according to claim 1; It is characterized in that said acrylate syrup is prepared through emulsion copolymerization by acrylic monomer and acrylic ester monomer, wherein acrylic monomer accounts for the 10-30% of all monomer masses; Acrylic ester monomer accounts for the 70-90% of all monomer masses.
8. the composite mortar that is used for the terylene textile sizing according to claim 7 is characterized in that said acrylic monomer is selected from: the combination in any of one or both of acrylic acid, methacrylic acid.
9. the composite mortar that is used for the terylene textile sizing according to claim 7 is characterized in that said acrylic ester monomer is selected from: the combination in any of one or more of methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, methyl methacrylate, EMA, butyl methacrylate, butyl methacrylate, acrylonitrile, methacrylonitrile, vinylacetate.
10. described preparation method who is used for the composite mortar of terylene textile sizing of claim 1 is characterized in that said method comprising the steps of:
(1) acid-alcohol ratio is binary acid and the dihydroxylic alcohols mixing of 1.2-1.5, is to carry out esterification or ester exchange reaction under the 220-250 ℃ of condition adding catalyst and reaction temperature, and the unnecessary alcohol of decompression discharge formed the short chain oligomer after reaction was reached home; Wherein binary acid is counted with the molar weight ratio of its all binary acid of ingredients constitute in the reactant:
Terephthalic acid (TPA) or ester 50-80%;
M-phthalic acid or ester 10-20%;
All the other binary acid 10-30%;
Dihydroxylic alcohols is counted with the molar weight ratio of its all dihydroxylic alcohols of ingredients constitute in the reactant:
Ethylene glycol 70-90%;
All the other dihydroxylic alcohols 10-30%;
(2) add trimellitic anhydride after being cooled to 180-210 ℃ and continue reaction, the water-soluble polyester that obtains; The content of the trimellitic anhydride that wherein adds is the 5-15% of binary acid integral molar quantity in the step (1);
(3) prepare acrylate syrup by acrylic monomer and acrylic ester monomer through emulsion copolymerization, wherein acrylic monomer accounts for the 10-30% of all monomer masses; Acrylic ester monomer accounts for the 70-90% of all monomer masses;
(4) will account for the water-soluble polyester of raw material gross mass 30～50% and 50～70% acrylate syrup and prepare, obtain being used for the composite mortar of terylene textile sizing through blend.
11. the described application of composite mortar on the terylene textile sizing that is used for the terylene textile sizing of claim 1.
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| CN201210213410.5A CN102720063B (en) | 2012-06-27 | 2012-06-27 | Composite pulp for polyester textile sizing as well as preparation method and application of composite pulp |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103224584A (en) * | 2013-04-28 | 2013-07-31 | 徐州众恒淀粉科技有限公司 | Water soluble copolymerization synthesis slurry and synthesis method thereof |
| CN105755825A (en) * | 2016-05-05 | 2016-07-13 | 无锡市长安曙光手套厂 | Textile sizing agent composition used for polyester fabric as well as preparation method and application of textile sizing agent composition |
| CN114032689A (en) * | 2021-12-15 | 2022-02-11 | 温州百德富新材料有限公司 | Water-based woven tape sizing slurry and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4725500A (en) * | 1983-07-25 | 1988-02-16 | Goo Chemical Industries Co., Ltd. | Sizing compositions and yarns sized therewith |
| CN1152949A (en) * | 1994-07-22 | 1997-06-25 | 罗纳·布朗克化学公司 | Latex composition for sizing yarns or textile fibres and sizing method |
| CN101967225A (en) * | 2010-10-11 | 2011-02-09 | 苏州瀚海化学有限公司 | Method for preparing water-soluble sulfo-copolyester |
| CN102079812A (en) * | 2010-11-16 | 2011-06-01 | 苏州瀚海化学有限公司 | Water-soluble copolyester and preparation method thereof |
-
2012
- 2012-06-27 CN CN201210213410.5A patent/CN102720063B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4725500A (en) * | 1983-07-25 | 1988-02-16 | Goo Chemical Industries Co., Ltd. | Sizing compositions and yarns sized therewith |
| CN1152949A (en) * | 1994-07-22 | 1997-06-25 | 罗纳·布朗克化学公司 | Latex composition for sizing yarns or textile fibres and sizing method |
| CN101967225A (en) * | 2010-10-11 | 2011-02-09 | 苏州瀚海化学有限公司 | Method for preparing water-soluble sulfo-copolyester |
| CN102079812A (en) * | 2010-11-16 | 2011-06-01 | 苏州瀚海化学有限公司 | Water-soluble copolyester and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 《纺织科技进展》 20091025 吴长春等 "聚酯/聚丙烯酸浆料对涤纶粗纱粘附性影响" 4-5 , 第5期 * |
| 吴长春等: ""聚酯/聚丙烯酸浆料对涤纶粗纱粘附性影响"", 《纺织科技进展》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103224584A (en) * | 2013-04-28 | 2013-07-31 | 徐州众恒淀粉科技有限公司 | Water soluble copolymerization synthesis slurry and synthesis method thereof |
| CN103224584B (en) * | 2013-04-28 | 2015-09-16 | 徐州众恒淀粉科技有限公司 | A kind of water-soluble copolymer synthetic slurry and synthetic method thereof |
| CN105755825A (en) * | 2016-05-05 | 2016-07-13 | 无锡市长安曙光手套厂 | Textile sizing agent composition used for polyester fabric as well as preparation method and application of textile sizing agent composition |
| CN105755825B (en) * | 2016-05-05 | 2018-06-22 | 上海咏姿时装有限公司 | Size composition for textile for polyester fabric and its preparation method and application |
| CN114032689A (en) * | 2021-12-15 | 2022-02-11 | 温州百德富新材料有限公司 | Water-based woven tape sizing slurry and preparation method thereof |
| CN114032689B (en) * | 2021-12-15 | 2023-12-26 | 温州百德富新材料有限公司 | Aqueous braid sizing slurry and preparation method thereof |
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| CN102720063B (en) | 2014-01-08 |
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