CN102719841B - Vat leaching ultrasonic washing agent for plane filter aluminum foil expanded metal and preparation method - Google Patents

Vat leaching ultrasonic washing agent for plane filter aluminum foil expanded metal and preparation method Download PDF

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Publication number
CN102719841B
CN102719841B CN201210207187.3A CN201210207187A CN102719841B CN 102719841 B CN102719841 B CN 102719841B CN 201210207187 A CN201210207187 A CN 201210207187A CN 102719841 B CN102719841 B CN 102719841B
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China
Prior art keywords
agent
ultrasonic cleaning
raw material
foaming surfactant
aeo
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Expired - Fee Related
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CN201210207187.3A
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Chinese (zh)
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CN102719841A (en
Inventor
潘德顺
张礼让
耿斌
张国强
戴亿峰
孟兆文
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Dalian Sandaaoke Chemistry Co Ltd
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Dalian Sandaaoke Chemistry Co Ltd
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Publication of CN102719841A publication Critical patent/CN102719841A/en
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Abstract

The invention discloses a vat leaching ultrasonic washing agent for a plane filter aluminum foil expanded metal, which is characterized by being composed of an agent A and an agent B, wherein the agent A is prepared from the following raw materials according to a mass ratio: 0.5-5% of potassium hydroxide, 150-310 of potassium metasilicate hydrate, 350-560 of sodium carbonate, 10-40 of sodium tripolyphosphate, 10-30 of special surfactant for soaking degreasing, 10-30 of AEO-9 (fatty alcohol polyoxyethylene ether N=9), 1-5 of penetrant and 10-20 of defoaming agent; and the agent B is prepared from the following raw material in percentage by weight: 0.1-0.4% of potassium hydroxide, 1-4% of sodium tripolyphosphate, 2-5% of Y-75 low-foaming surfactant for ultrasonic washing, 2-5% of Y-76 low-foaming surfactant for ultrasonic washing, 2-5% of Y-79 low-foaming surfactant for ultrasonic washing, 1-3% of AEO-9, 0.5-1.5% of penetrant, 0.5-1.5% of defoaming agent and the balance of water.

Description

Aircraft purifier aluminium foil expanded metals drill traverse ultrasonic cleaning agent and preparation method
Technical field
The present invention relates to a kind of metal clean-out system and preparation method, especially a kind of cleaning quality is reliable and stable, change groove cycle stretch-out, cost significantly reduced aircraft purifier aluminium foil expanded metals drill traverse ultrasonic cleaning agent and preparation method.
Background technology
Metal cleans, and exactly the metal products with certain dirt is placed in specific solvent, adopts corresponding processing unit and processing method, the dirt removal of surface of metal product is fallen, make product reach the technical requirements of design.Usual cleaning solvent can be divided into protonic solvent, dipole solvent and non-polar solvent three kinds.Protonic solvent and dipole solvent are polar solvent, and containing active hydrogen atom in water, alcohol, ammonia, amine, sour equimolecular, belong to protonic solvent, the water-based solvent used in the market belongs to this type mostly; There is polar group in acetone, acetonitrile, DMF, dimethyl sulfone, hexamethylphosphorictriamide equimolecular, but there is no proton, be referred to as dipole solvent; Hydro carbons, benzene class, ethers and halohydrocarbon etc. are non-polar solvent.Industrially, the cleaning taking water as main solvent is called water solvent cleaning by people, with organic solvent be scavenging solution be called solvent cleaning, existing metal cleaner can be divided into three major types substantially, namely based on the leaning solvent of gasoline, kerosene or halohydrocarbon etc., take tensio-active agent as the aqueous cleaning agent of main component and the emulsion cleaner(s) that is main component with tensio-active agent, organic solvent.
The agent structure of aircraft filter element is exactly the aluminium foil expanded metals of different shape, closely combines according to after variant production specification requirement impact briquetting, thickly reaches more than 360 layers.Must through cleaning after this filter element combination assembling, to reach the completely clean technical requirements in surface (industry standard of Germany's regulation), namely the workpiece after cleaning is put in pitch-dark workplace, adopt ultraviolet rays collection lamp according to the aluminum foil plate net surface of filter element, every light reflected does not present purple and is all judged to be that cleaning degree is defective.Current matting is: ultrasonic cleaning → ultrasonic cleaning → tap water rinse → tap water rinse → pure water rinsing → pressurized air cuts water → hot-air seasoning.The subject matter existed is:
A. clean-out system quality is unstable, just reached the standard grade trial production time, cleaning performance is substantially up to standard, and after running for some time, cleaning performance sharply declines, and cannot normally produce; Production line runs for continuous 24 hours, and within first several hours, cleaning quality is normal, and cleaning quality declined afterwards;
B. clean-out system throws groove amount greatly, and additional amount is also large, and within one day 24 hours, consume clean-out system and reach about 8000 yuan, cost is higher;
C. it is very short to change the groove cycle, within three days, just need change a tank liquor, and waste is serious.
Summary of the invention
The present invention is the above-mentioned technical problem in order to solve existing for prior art, provide a kind of cleaning quality reliable and stable, change groove cycle stretch-out, cost significantly reduced aircraft purifier aluminium foil expanded metals drill traverse ultrasonic cleaning agent and preparation method.
Technical solution of the present invention is: a kind of aircraft purifier aluminium foil expanded metals drill traverse ultrasonic cleaning agent, and it is characterized in that being made up of A agent and B agent, raw material and the mass ratio of described A agent are as follows:
Potassium hydroxide 0.5 ~ 5
Five water potassium metasilicates 150 ~ 310
Sodium carbonate 350 ~ 560
Tripoly phosphate sodium STPP 10 ~ 40
Soak degreasing special surfactant 10 ~ 30
AEO-9 10~30
Permeate agent 1 ~ 5
Defoamer 10 ~ 20
Raw material and the mass percent of described B agent are as follows:
Potassium hydroxide 0.1 ~ 0.4%
Tripoly phosphate sodium STPP 1 ~ 4%
Y-75 ultrasonic cleaning low-foaming surfactant 2 ~ 5%
Y-76 ultrasonic cleaning low-foaming surfactant 2 ~ 5%
Y-79 ultrasonic cleaning low-foaming surfactant 2 ~ 5%
AEO-9 1~3%
Permeate agent 0.5 ~ 1.5%
Defoamer 0.5 ~ 1.5%
Water surplus.
A preparation method for above-mentioned aircraft purifier aluminium foil expanded metals drill traverse ultrasonic cleaning agent, is characterized in that:
Described A agent is carried out as follows: start the spiral powder stirring machine of cylinder type, control rotating speed 10 ~ 15 revs/min, potassium hydroxide calculating weighed successively, sodium carbonate, five water potassium metasilicates, tripoly phosphate sodium STPP, soak degreasing special surfactant, AEO-9, permeate agent, defoamer join in stirrer slowly, often add a kind of raw material and need stir 20min separately, stirring 1 hour is continued again, weighing and bagging after whole raw material adds;
Described B agent is carried out as follows: first join in reactor by calculating the water weighed, start stirrer, control rotating speed 60 revs/min, then potassium hydroxide calculating weighed successively, tripoly phosphate sodium STPP, Y-75 ultrasonic cleaning low-foaming surfactant, Y-76 ultrasonic cleaning low-foaming surfactant, Y-79 ultrasonic cleaning low-foaming surfactant, AEO-9, permeate agent, defoamer join in reactor slowly, often add a raw material to need to stir 10 ~ 20min separately, continue to be stirred to the transparent shape uniform liquid of solution after whole raw material adds, blowing is packed.
The present invention cleaning quality reach JB-4322 ministerial standard, Germany regulation industry standard and keep original production line work tempo (every 10min beat) prerequisite under, compared with prior art tool has the following advantages:
1. after first 12 hours of every day, the cleaning quality of 12 hours is identical, and cleaning quality is reliable and stable;
2. changing the groove cycle extended to 5 days by original 3 days;
3. every day 24 continuous throughout the twenty-four hour24, the additional amount of clean-out system is relatively fixing, in five days without cross big-difference;
4. process costs drops to less than 3600 yuan by consuming 8000 yuan original every day.
Embodiment
Embodiment 1:
Be made up of A agent and B agent, raw material and the mass ratio of described A agent are as follows:
Potassium hydroxide 0.5
Five water potassium metasilicates 150
Sodium carbonate 350
Tripoly phosphate sodium STPP 10
Soak degreasing special surfactant 10
AEO-9 10
Permeate agent 1
Defoamer 10
Raw material and the mass percent of described B agent are as follows:
Potassium hydroxide 0.1%
Tripoly phosphate sodium STPP 1%
Y-75 ultrasonic cleaning low-foaming surfactant 2%
Y-76 ultrasonic cleaning low-foaming surfactant 2%
Y-79 ultrasonic cleaning low-foaming surfactant 2%
AEO-9 1%
Permeate agent 0.5%
Defoamer 0.5%
Water surplus.
Described A agent is carried out as follows: start the spiral powder stirring machine of cylinder type, control rotating speed 10 ~ 15 revs/min, potassium hydroxide calculating weighed successively, sodium carbonate, five water potassium metasilicates, tripoly phosphate sodium STPP, soak degreasing special surfactant, AEO-9, permeate agent, defoamer join in stirrer slowly, often add a kind of raw material and need stir 20min separately, stirring 1 hour is continued again, weighing and bagging after whole raw material adds;
Described B agent is carried out as follows: first join in reactor by calculating the water weighed, start stirrer, control rotating speed 60 revs/min, then potassium hydroxide calculating weighed successively, tripoly phosphate sodium STPP, Y-75 ultrasonic cleaning low-foaming surfactant, Y-76 ultrasonic cleaning low-foaming surfactant, Y-79 ultrasonic cleaning low-foaming surfactant, AEO-9, permeate agent, defoamer join in reactor slowly, often add a raw material to need to stir 10 ~ 20min separately, continue to be stirred to the transparent shape uniform liquid of solution after whole raw material adds, blowing is packed.
All raw materials are commercially available prod, and wherein soak degreasing special surfactant, ultrasonic cleaning low-foaming surfactant are the products of Qi Yanglong Science and Technology Ltd. of Shenzhen, and product type is respectively QYL-10F, Y-75, Y-75, Y-79.
Embodiment 2:
Be made up of A agent and B agent, raw material and the mass ratio of described A agent are as follows:
Potassium hydroxide 5
Five water potassium metasilicates 310
Sodium carbonate 560
Tripoly phosphate sodium STPP 40
Soak degreasing special surfactant 30
AEO-9 30
Permeate agent 5
Defoamer 20
Raw material and the mass percent of described B agent are as follows:
Potassium hydroxide 0.4%
Tripoly phosphate sodium STPP 4%
Y-75 ultrasonic cleaning low-foaming surfactant 5%
Y-76 ultrasonic cleaning low-foaming surfactant 5%
Y-79 ultrasonic cleaning low-foaming surfactant 5%
AEO-9 3%
Permeate agent 1.5%
Defoamer 1.5%
Water surplus.
Preparation method and raw material sources are with embodiment 1.
Embodiment 3:
Be made up of A agent and B agent, raw material and the mass ratio of described A agent are as follows:
Potassium hydroxide 3
Five water potassium metasilicates 225
Sodium carbonate 450
Tripoly phosphate sodium STPP 25
Soak degreasing special surfactant 20
AEO-9 20
Permeate agent 3
Defoamer 15
Raw material and the mass percent of described B agent are as follows:
Potassium hydroxide 0.3%
Tripoly phosphate sodium STPP 2%
Y-75 ultrasonic cleaning low-foaming surfactant 3%
Y-76 ultrasonic cleaning low-foaming surfactant 3%
Y-79 ultrasonic cleaning low-foaming surfactant 3%
AEO-9 2%
Permeate agent 1.0%
Defoamer 1.0%
Water surplus.
Preparation method and raw material sources are with embodiment 1.
The present invention changes existing technical process, changes first of the first two road ultrasonic cleaning slot into chemical enhanced pre-washing, then on second slot, carries out the main cleaning of ultrasonic wave.Wherein the working conditions of chemical precleaning spout is: the A agent concentration 5%(aqueous solution), free alkalinity 28 ~ 36Pt, temperature 60 C, the circulation of work nest liquid pump adds that pressurized air bubbling stirs, and soaks 10min; The working conditions of the main rinse bath of ultrasonic wave is: the A agent concentration 2%(aqueous solution)+B agent concentration 8%(the aqueous solution), free alkalinity 16 ~ 22Pt, temperature 60 C, work nest liquid pump circulates, ultrasonic cleaning 10min.The embodiment of the present invention changes 5 days groove cycles, and every day, additional amount was fixing, cleaning steady quality, workpiece cleaning quality examination (ministerial standard of JB-4322, the industry standard of Germany's regulation) up to standard.

Claims (2)

1. an aircraft purifier aluminium foil expanded metals drill traverse ultrasonic cleaning agent, it is characterized in that being made up of A agent and B agent, raw material and the mass ratio of described A agent are as follows:
Potassium hydroxide 0.5 ~ 5
Five water potassium metasilicates 150 ~ 310
Sodium carbonate 350 ~ 560
Tripoly phosphate sodium STPP 10 ~ 40
Qi Yanglong Science and Technology Ltd. of Shenzhen product type is QYL-10F's
Soak degreasing special surfactant 10 ~ 30
AEO-9 10~30
Permeate agent 1 ~ 5
Defoamer 10 ~ 20
Raw material and the mass percent of described B agent are as follows:
Potassium hydroxide 0.1 ~ 0.4%
Tripoly phosphate sodium STPP 1 ~ 4%
Qi Yanglong Science and Technology Ltd. of Shenzhen product type is
The ultrasonic cleaning low-foaming surfactant 2 ~ 5% of Y-75
Qi Yanglong Science and Technology Ltd. of Shenzhen product type is
The ultrasonic cleaning low-foaming surfactant 2 ~ 5% of Y-76
Qi Yanglong Science and Technology Ltd. of Shenzhen product type is
The ultrasonic cleaning low-foaming surfactant 2 ~ 5% of Y-79
AEO-9 1~3%
Permeate agent 0.5 ~ 1.5%
Defoamer 0.5 ~ 1.5%
Water surplus.
2. an aircraft purifier aluminium foil expanded metals preparation method for drill traverse ultrasonic cleaning agent as claimed in claim 1, is characterized in that:
Described A agent is carried out as follows: start the spiral powder stirring machine of cylinder type, control rotating speed 10 ~ 15 revs/min, potassium hydroxide calculating weighed successively, sodium carbonate, five water potassium metasilicates, tripoly phosphate sodium STPP, soak degreasing special surfactant, AEO-9, permeate agent, defoamer join in stirrer slowly, often add a kind of raw material and need stir 20min separately, stirring 1 hour is continued again, weighing and bagging after whole raw material adds;
Described B agent is carried out as follows: first join in reactor by calculating the water weighed, start stirrer, control rotating speed 60 revs/min, then potassium hydroxide calculating weighed successively, tripoly phosphate sodium STPP, Y-75 ultrasonic cleaning low-foaming surfactant, Y-76 ultrasonic cleaning low-foaming surfactant, Y-79 ultrasonic cleaning low-foaming surfactant, AEO-9, permeate agent, defoamer join in reactor slowly, often add a raw material to need to stir 10 ~ 20min separately, continue to be stirred to the transparent shape uniform liquid of solution after whole raw material adds, blowing is packed.
CN201210207187.3A 2012-06-21 2012-06-21 Vat leaching ultrasonic washing agent for plane filter aluminum foil expanded metal and preparation method Expired - Fee Related CN102719841B (en)

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Application Number Priority Date Filing Date Title
CN201210207187.3A CN102719841B (en) 2012-06-21 2012-06-21 Vat leaching ultrasonic washing agent for plane filter aluminum foil expanded metal and preparation method

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CN102719841B true CN102719841B (en) 2015-06-03

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Publication number Priority date Publication date Assignee Title
CN103276400B (en) * 2013-05-06 2015-11-04 大庆宝丰科技有限公司 Environment-friendlycompound compound metal degreasant and preparation method
CN106086911A (en) * 2016-08-27 2016-11-09 合肥普庆新材料科技有限公司 A kind of aluminium degreasing agent suppressing corrosion and preparation method thereof

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CN101956199A (en) * 2010-11-03 2011-01-26 大连三达奥克化学股份有限公司 Non-phosphorus environment-friendly water-based degreasing agent and manufacturing method thereof
CN102418108A (en) * 2011-12-30 2012-04-18 大连三达奥克化学股份有限公司 Spraying normal temperature degreasing agent for galvanized steel sheet and production method thereof
CN102424978A (en) * 2011-12-30 2012-04-25 大连三达奥克化学股份有限公司 Common ultrasonic dewaxing cleaning agent for steel, aluminum and copper and preparation method thereof
CN102433567A (en) * 2011-12-30 2012-05-02 大连三达奥克化学股份有限公司 Tank leaching type steel room-temperature degreasing agent and production method thereof

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Publication number Priority date Publication date Assignee Title
US20080274928A1 (en) * 2007-05-04 2008-11-06 Ecolab Inc. Water soluble magnesium compounds as cleaning agents and methods of using them
CN101956199A (en) * 2010-11-03 2011-01-26 大连三达奥克化学股份有限公司 Non-phosphorus environment-friendly water-based degreasing agent and manufacturing method thereof
CN102418108A (en) * 2011-12-30 2012-04-18 大连三达奥克化学股份有限公司 Spraying normal temperature degreasing agent for galvanized steel sheet and production method thereof
CN102424978A (en) * 2011-12-30 2012-04-25 大连三达奥克化学股份有限公司 Common ultrasonic dewaxing cleaning agent for steel, aluminum and copper and preparation method thereof
CN102433567A (en) * 2011-12-30 2012-05-02 大连三达奥克化学股份有限公司 Tank leaching type steel room-temperature degreasing agent and production method thereof

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