CN102712535A - Gypsum board - Google Patents

Gypsum board Download PDF

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Publication number
CN102712535A
CN102712535A CN200980162305XA CN200980162305A CN102712535A CN 102712535 A CN102712535 A CN 102712535A CN 200980162305X A CN200980162305X A CN 200980162305XA CN 200980162305 A CN200980162305 A CN 200980162305A CN 102712535 A CN102712535 A CN 102712535A
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Prior art keywords
gypsum
slurry
plasterboard
paris
plaster
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CN200980162305XA
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藤田巧
本多秀隆
堤康祐
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Chiyoda Ute Co Ltd
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Chiyoda Ute Co Ltd
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Publication of CN102712535A publication Critical patent/CN102712535A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00612Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
    • C04B2111/0062Gypsum-paper board like materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

Provided is a gypsum board which can sufficiently suppress bending, even when produced using a starting gypsum material that contains a large amount of water-soluble salts as impurities. Further, the gypsum board is unproblematic in compressive strength, hardening time, pH, and so on. A gypsum board produced by filling a gypsum-containing slurry into a frame mold and hardening the slurry, wherein the slurry contains both calcined gypsum and 0.2 to 5.0 parts by mass of a cement per 100 parts by mass of the calcined gypsum.

Description

Plasterboard
Technical field
The present invention relates to plasterboard, more detailed, even when relating to the high gypsum of the content that in the modulation of wanting the hardened slurry, uses the water dissolvable salt that is equivalent to impurity, also can fully prevent the plasterboard of bending.
Background technology
In the past, generally through holding concurrently to the surface of the downside of template filling the slurry that contains gypsum between with body paper, and conveying continuously under this state with the back side of body paper and upside, the while during carry out the sclerosis of slurry and the cut-out of sclerotium, thereby the manufacturing plasterboard.The slurry that contains gypsum mixes with each required amount of various mixing materials or drug class and water through the plaster of Paris (semi-hydrated gypsum) that the raw material gypsum calcination is got to be modulated; As the raw material gypsum; Except the plaster of paris; Can use various chemical gypsums, for example phosphoric acid gypsum, flue gas desulfurization gypsum, titanium gypsum (gypsum of by-product when making titanium oxide), hydrofluoric acid gypsum (gypsum of by-product when making hydrofluoric acid), salt manufacturing gypsum, refining gypsum etc.Yet; The plasterboard that gets through said common in the past method of manufacture; Moisture absorption is arranged and water ratio is uprised thereby easily crooked problem, especially when using the high gypsum of the water dissolvable salt content that is equivalent to impurity as the raw material gypsum, the plasterboard that obtains has the problem of serious bending.
As preventing the crooked plasterboard that produces, known in wanting the hardened slurry instance (for example the referenced patent document 1) and the phosphatic instance of coupling aggegation (for example the referenced patent document 2) etc. of this type of coupling copper sulfate crystallization modifier.Yet patent documentation 1 such instance in the past has can't fully prevent the crooked problem that produces, and patent documentation 2 such instances in the past have price height and worry to become the problem of environmental pollution reason in addition.
As the plasterboard of giving resistivity against fire and water-repellancy in addition, also known in wanting the hardened slurry instance (for example the referenced patent document 3) of coupling cement.Patent documentation 3 such instances in the past do, use a large amount of cement with gypsum, are specially the cement about 20~40%.Yet this had the intensity of the plasterboard that obtains in the past in instance for example compressive strength was low, slurry hardens significantly high problem of length consuming time, pH.
The prior art document
Patent documentation
No. the 2007/110428th, [patent documentation 1] International Publication
[patent documentation 2] Japan special table 2001-504795 communique
[patent documentation 3] japanese kokai publication sho 61-83664 communique
Summary of the invention
Invent problem to be solved
The problem that the present invention will solve is to provide plasterboard; When even it is equivalent to the high gypsum of the water dissolvable salt content of impurity as raw material in use; Can fully prevent crooked generation, and aspects such as compressive strength, setting time, pH do not have problems yet.
The means of dealing with problems
The plasterboard that slurry that address the above problem the present invention relates in template to fill contained gypsum and sclerosis form; It is characterized by, the plaster of Paris that said plasterboard is got by per 100 mass parts calcined gypsums uses the slurry sclerosis of the cement of 0.2~5.0 mass parts ratio to form.
The plasterboard that the present invention relates to is the plasterboard that is prepared as follows: the plaster of Paris (semi-hydrated gypsum) that per 100 mass parts calcined gypsums get uses the cement of 0.2~5.0 mass parts ratio; Suitably use various mixing materials or drug class in addition as required; Through being mixed with water, they modulate slurry; Said slurry is filled in the template, for example holds concurrently to the surface of template with body paper and the back side with between the body paper, and harden.
In the plasterboard that the present invention relates to, as gypsum,, can use various chemical gypsums, for example phosphoric acid gypsum, flue gas desulfurization gypsum, titanium gypsum, hydrofluoric acid gypsum, salt manufacturing gypsum, refining gypsum etc. except the plaster of paris.According to kind and the amount and the proterties at that time etc. of the chemical gypsum that uses, the content (concentration) that the gypsum that is used for modulating slurry is equivalent to the water dissolvable salt of impurity changes.In addition,,, can use blast furnace cement, pulverized fuel ash cement, tripoli cement, luminite cement etc., preferred silicate cement, more preferably ordinary Portland cement except various silicate cements as cement.Further,, paper pulp, spun glass, vermiculite etc. can be suitably used,, hardening accelerator, inhibitor, water reducer etc. can be suitably used in addition as drug class as mixture.
The plasterboard that the present invention relates to; As stated; The plaster of Paris that is got by per 100 mass parts calcined gypsums uses the slurry sclerosis of the cement of 0.2~5.0 mass parts ratio to form; Compare with the plasterboard in the past of use cement in the slurry modulation, have the remarkable low characteristic of cement usage quantity with respect to plaster of Paris.Its reason does; Per 100 mass parts plaster of Paris; During usage ratio less than 0.2 mass parts of cement; The plasterboard that obtains can't fully prevent crooked the generation, and the usage ratio of opposite cement is when surpassing 5.0 mass parts, and the compressive strength step-down of the plasterboard that obtains, sclerosis elongated, pH consuming time significantly uprises.
In the plasterboard that the slurry sclerosis of using cement and plaster of Paris jointly forms; For being compared with the situation of not using cement, compressive strength wants high; And it is consuming time shorter to harden, and pH also suppresses to no problem degree in addition, the hardened slurry to be necessary for the cement that per 100 mass parts plaster of Paris use 0.2~5.0 mass parts ratio; Preferably use the cement of 0.3~2.0 mass parts ratio, more preferably use the cement of 0.5~1.0 mass parts ratio.
The plasterboard that the present invention relates to; Compare with above-mentioned plasterboard in the past; Have and fully to prevent crooked generation; And the effect that aspects such as compressive strength, setting time, pH do not have problems can prevent the effect that the surface is peeled off easily because of moisture absorption with the body paper and the back side with body paper in addition in addition.Use calcining be equivalent to impurity the water dissolvable salt the high gypsum of content and plaster of Paris when being used to modulate the plaster of Paris of slurry, the performance of said effect is significant.Mainly result from kind and amount and proterties at that time etc. as the above-mentioned chemical gypsum of raw material gypsum; When the content of the water dissolvable salt that is equivalent to impurity in the raw material gypsum is uprised; Plaster of Paris modulation slurry that uses the such gypsum of calcining and get and hardened plasterboard become crooked easily; Particularly under high humidity, become crooked easily because of moisture absorption; Yet the present invention of the cement of coupling specified amount can fully prevent the generation of such bending during according to the said plaster of Paris of use in the slurry modulation.
Particularly, the plaster of Paris that uses in the slurry modulation adopts the total content of sylvite, sodium salt and the magnesium salts of water dissolvable to be scaled their oxide compound (K 2O, Na 2O and MgO) be the above gypsum of 500mg/kg, for example under the situation of gypsum of 500~2500mg/kg as raw material; The performance of above-mentioned effect of the present invention is significant, and wherein especially the total content of the sylvite of water dissolvable, sodium salt and the magnesium salts oxide compound that is scaled them is remarkable especially under the 600mg/kg situation above, for example 600~2500mg/kg.
The invention effect
According to the present invention, even when use is equivalent to the high gypsum of the water dissolvable salt content of impurity as raw material, the plasterboard that obtains also can fully prevent crooked generation, and aspects such as compressive strength, setting time, pH do not have problems.
The accompanying drawing summary
Fig. 1 is the addition of middle ordinary Portland cements such as illustration embodiments of the invention and the graphic representation of the relation of the compressive strength of the sclerotium that obtains.
Fig. 2 is the graphic representation of the water dissolvable salts contg in the gypsum that uses as raw material in the illustration embodiments of the invention etc. with the relation of the bending of the test film that cuts out from the plasterboard that obtains.
Embodiment
Below, for clear and definite formation of the present invention and effect and enumerate embodiment and comparative example, but the present invention is not limited by these embodiment.
Test classification 1
Comparative example 1
The oxide compound that the total content of sylvite, sodium salt and the magnesium salts of water dissolvable is scaled them is that the flue gas desulfurization gypsum of 632mg/kg (the following water dissolvable salt content 632mg/kg that only is called) is calcined, as plaster of Paris (semi-hydrated gypsum).In these plaster of Paris 200 mass parts,, modulate slurry with the mixed water of 170 mass parts.With this slurry be filled in the template and make its sclerosis after, carry out the demoulding, under 40 ℃, be dried to constant, obtain the plasterboard of 12.5mm * 900mm * 1820mm.Cut out the test film of 12.5mm * 150mm * 650mm from this plasterboard; This test film 2 points with span 600mm under 40 ℃ * 90%RH condition are supported; Every through the specified time; Bending with the span central authorities that produce on tester (デ ジ マ チ Star Network イ Application ジ ケ one タ that ミ Star ト ヨ society makes, trade(brand)name) the determination test sheet.The result gathers and is shown in table 1.
Comparative example 2~4
The aqueous solution 170 mass parts of copper sulfate pentahydrate of having dissolved the amount of the addition that becomes table 1 record except use replace likewise carrying out with comparative example 1 water 170 mass parts, at the modulation slurry and after obtaining plasterboard, cut out test film, measure crooked.The result gathers and is shown in table 1.
Comparative example 5~7
The aqueous solution 170 mass parts of Trisodium trimetaphosphate of having dissolved the amount of the addition that becomes table 1 record except use replace likewise carrying out with comparative example 1 water 170 mass parts, at the modulation slurry and after obtaining plasterboard, cut out test film, measure crooked.The result gathers and is shown in table 1.
Comparative example 8~11 and embodiment 1~7
Except material 200 mass parts of the ordinary Portland cement that uses the amount in plaster of Paris, mixed the addition that becomes table 1 record replace plaster of Paris 200 mass parts; Likewise carry out with comparative example 1; At the modulation slurry and after obtaining plasterboard, cut out test film, measure crooked.The result gathers and is shown in table 1.
Table 1
Figure BPA00001546841800061
In the table 1,
Addition: the mass parts of the interpolation material of per 100 mass parts plaster of Paris
Also can be clear and definite from the result of table 1, copper sulfate pentahydrate can't fully prevent crooked generation.Although Trisodium trimetaphosphate can fully prevent crooked generation in addition, as stated, not only high price and worry become the reason of environmental pollution.In contrast; Per 100 mass parts plaster of Paris use the above ordinary Portland cement of 0.2 mass parts, the embodiment more than preferred 0.3 mass parts etc.; Then can likewise fully prevent crooked the generation when using Trisodium trimetaphosphate, and not produce problem such when using Trisodium trimetaphosphate.
Test classification 2
Comparative example 12
The flue gas desulfurization gypsum of water dissolvable salt content 632mg/kg is calcined, as plaster of Paris (semi-hydrated gypsum).Mixing water 375g in this plaster of Paris 500g, the modulation slurry.With this slurry be filled into the template of 50mm * 50mm * 50mm and make its sclerosis after, carry out the demoulding, under 40 ℃, be dried to constant, obtain sclerotium.This sclerotium is supplied with オ one ト グ ラ Off (society of Shimadzu Seisakusho Ltd. makes, trade(brand)name, model AG-10TE), carried out loading in 1mm/ minute with loading speed, the loading value when sclerotium is buckled is as compressive strength (N/mm 2).The result is shown in table 2 and Fig. 1.
Embodiment 8~14 and comparative example 13~15
Except the material 500g of the ordinary Portland cement that uses the amount in plaster of Paris, mixed the addition that becomes table 1 record replaces likewise carrying out with comparative example 12 the plaster of Paris 500g,, measure compressive strength at the modulation slurry and after obtaining plasterboard.The result is shown in table 2 and Fig. 1.
Table 2
Figure BPA00001546841800071
In the table 2,
Addition: per 100 mass parts plaster of Paris add the mass parts of ordinary Portland cement
Also can be clear and definite from the result of table 2 and Fig. 1; Although per 100 mass parts plaster of Paris add the mass parts of ordinary Portland cement when 0.20~5.0 scope; Compare with the situation of not adding ordinary Portland cement (comparative example 12), compressive strength more than roughly the same degree, but in the mass parts of adding ordinary Portland cement than this more for a long time; For example be 10.0 when above, it is also lower than the situation of not adding ordinary Portland cement (comparative example 12) that compressive strength becomes.From the viewpoint of compressive strength, the mass parts that preferred per 100 mass parts plaster of Paris add ordinary Portland cement is 0.3~2.0.
Test classification 3
Comparative example 16
The flue gas desulfurization gypsum of water dissolvable salt content 632mg/kg is calcined, as plaster of Paris (semi-hydrated gypsum).Use this plaster of Paris modulation slurry, and use this slurry, below measure setting time (termination minute) according to JIS-R9112.In addition for the sclerotium that obtains, below measure pH according to JIS-R9102.The result gathers and is shown in table 3.
Embodiment 15 and comparative example 17~19
Except the material of the ordinary Portland cement that uses the amount in plaster of Paris, mixed the addition that becomes table 1 record replaces the plaster of Paris; Likewise carry out with comparative example 16; The modulation slurry, and measure setting time when obtaining sclerotium (termination minute) and pH.The result gathers and is shown in table 3.
Table 3
Figure BPA00001546841800081
In the table 3,
Addition: per 100 mass parts plaster of Paris add the mass parts of ordinary Portland cement
Also can be clear and definite from the result of table 3, the mass parts increase of per 100 mass parts plaster of Paris being added ordinary Portland cement is 20~30 o'clock, compares with the situation of not adding ordinary Portland cement (comparative example 16), setting time is elongated, and pH significantly uprises.
Test classification 4
Comparative example 20
The plaster of paris of water dissolvable salt content 227mg/kg and the mixture of flue gas desulfurization gypsum are calcined, as plaster of Paris (semi-hydrated gypsum).Use this plaster of Paris, below likewise carry out,, cut out test film, measure through the bending after 48 hours at the modulation slurry and after obtaining plasterboard with the comparative example 1 of test classification 1.The result is shown in table 4 and Fig. 2.
Comparative example 21~31
Change the source (kind) and the blending ratio of flue gas desulfurization gypsum, the gypsum of the water dissolvable salt content of record in the table 4 is calcined, as plaster of Paris (semi-hydrated gypsum).Use these plaster of Paris, below likewise carry out,, cut out test film, measure through the bending after 48 hours at the modulation slurry and after obtaining plasterboard with comparative example 20.The result gathers and is shown in table 4 and Fig. 2.
Embodiment 16
The material of ordinary Portland cement that has mixed the amount of the addition that becomes table 4 record except use replaces likewise carrying out with comparative example 27 plaster of Paris, at the modulation slurry and after obtaining plasterboard, cuts out test film, measures through the bending after 48 hours.The result gathers and is shown in table 4 and Fig. 2.
Embodiment 17
The material of ordinary Portland cement that has mixed the amount of the addition that becomes table 4 record except use replaces likewise carrying out with comparative example 30 plaster of Paris, at the modulation slurry and after obtaining plasterboard, cuts out test film, measures through the bending after 48 hours.The result gathers and is shown in table 4 and Fig. 2.
Embodiment 18
The material of ordinary Portland cement that has mixed the amount of the addition that becomes table 4 record except use replaces likewise carrying out with comparative example 31 plaster of Paris, at the modulation slurry and after obtaining plasterboard, cuts out test film, measures through the bending after 48 hours.The result gathers and is shown in table 4 and Fig. 2.
Table 4
Figure BPA00001546841800101
Also can be clear and definite from the result of table 4 and Fig. 2; Although it is big that the bending that produces when the solubility salt content in the gypsum that uses as raw material uprises becomes; Particularly to be that 500mg/kg is crooked when above become big to solubility salt content; But,, also can fully prevent crooked generation even when using solubility salt content is high like this gypsum as raw material according to the present invention.

Claims (4)

1. plasterboard, it is in template, to fill the plasterboard that the slurry that contains gypsum and sclerosis form, and it is characterized by: by per 100 mass parts calcined gypsums plaster of Paris use the slurry sclerosis of the cement of 0.2~5.0 mass parts ratio to form.
2. the described plasterboard of claim 1, wherein per 100 mass parts plaster of Paris use the cement of 0.3~2.0 mass parts ratio in the slurry.
3. claim 1 or 2 described plasterboards, the oxide compound that wherein total content of the sylvite of water dissolvable, sodium salt and magnesium salts is scaled them in the gypsum is more than the 500mg/kg.
4. the plasterboard described in each of claim 1~3, wherein cement is ordinary Portland cement.
CN200980162305XA 2009-10-28 2009-10-28 Gypsum board Pending CN102712535A (en)

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Cited By (2)

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CN105328943A (en) * 2014-08-15 2016-02-17 北新集团建材股份有限公司 Gypsum board capable of increasing resource energy utilization efficiency and production method thereof
WO2020224120A1 (en) * 2019-05-08 2020-11-12 北新集团建材股份有限公司 High impurity ion content desulfurized gypsum paper-faced gypsum board and manufacturing method therefor

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Publication number Priority date Publication date Assignee Title
UA124000C2 (en) * 2015-11-30 2021-07-07 Кнауф Ґіпс Кґ Additive for gypsum building materials
JP6341952B2 (en) * 2016-04-14 2018-06-13 チヨダウーテ株式会社 Gypsum board and method for producing gypsum board
US11993054B2 (en) 2019-11-05 2024-05-28 United States Gypsum Company Method of preparing gypsum wallboard from high salt gypsum, and related product
US11891336B2 (en) 2019-11-22 2024-02-06 United States Gypsum Company Gypsum board containing high absorption paper and related methods
CN114349449B (en) * 2021-11-23 2023-03-17 北新集团建材股份有限公司 Paper-surface gypsum board and preparation method thereof

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JPS582189B2 (en) * 1979-11-16 1983-01-14 川崎重工業株式会社 Method for preventing efflorescence of hardened gypsum
JPH11116319A (en) * 1997-10-07 1999-04-27 Yoshino Gypsum Co Ltd Gypsum-based building material having suppressed elution of heavy metal and its production

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105328943A (en) * 2014-08-15 2016-02-17 北新集团建材股份有限公司 Gypsum board capable of increasing resource energy utilization efficiency and production method thereof
CN105328943B (en) * 2014-08-15 2018-08-14 北新集团建材股份有限公司 A kind of plasterboard and its manufacturing method improving energy resource utilization ratio
WO2020224120A1 (en) * 2019-05-08 2020-11-12 北新集团建材股份有限公司 High impurity ion content desulfurized gypsum paper-faced gypsum board and manufacturing method therefor

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Application publication date: 20121003