CN102703238A - Environmental protection water base dewaxing agent and preparation method thereof - Google Patents
Environmental protection water base dewaxing agent and preparation method thereof Download PDFInfo
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- CN102703238A CN102703238A CN2012101518714A CN201210151871A CN102703238A CN 102703238 A CN102703238 A CN 102703238A CN 2012101518714 A CN2012101518714 A CN 2012101518714A CN 201210151871 A CN201210151871 A CN 201210151871A CN 102703238 A CN102703238 A CN 102703238A
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- agent
- protection water
- dewaxing
- solvent
- environment protection
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000003795 chemical substances by application Substances 0.000 title abstract description 12
- 230000007613 environmental effect Effects 0.000 title abstract description 6
- 239000002904 solvent Substances 0.000 claims abstract description 16
- 239000008139 complexing agent Substances 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 8
- 239000013543 active substance Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- HQAITFAUVZBHNB-UHFFFAOYSA-N sodium;pentahydrate Chemical compound O.O.O.O.O.[Na] HQAITFAUVZBHNB-UHFFFAOYSA-N 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
- 150000003016 phosphoric acids Chemical class 0.000 claims description 5
- 150000002170 ethers Chemical class 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 3
- STNSYZSNIYTNMI-UHFFFAOYSA-N azane;[2-[bis(phosphonomethyl)amino]ethyl-(phosphonomethyl)amino]methylphosphonic acid Chemical compound N.OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O STNSYZSNIYTNMI-UHFFFAOYSA-N 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 3
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 3
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 claims description 3
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 3
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims description 2
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 2
- VKEQBMCRQDSRET-UHFFFAOYSA-N Methylone Chemical compound CNC(C)C(=O)C1=CC=C2OCOC2=C1 VKEQBMCRQDSRET-UHFFFAOYSA-N 0.000 claims description 2
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 2
- 238000004945 emulsification Methods 0.000 abstract description 3
- 230000010534 mechanism of action Effects 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 239000004094 surface-active agent Substances 0.000 abstract 3
- 229910019142 PO4 Inorganic materials 0.000 abstract 2
- 239000004115 Sodium Silicate Substances 0.000 abstract 2
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 2
- 239000012153 distilled water Substances 0.000 abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 2
- 239000010452 phosphate Substances 0.000 abstract 2
- 235000019795 sodium metasilicate Nutrition 0.000 abstract 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 2
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 239000005304 optical glass Substances 0.000 abstract 1
- 231100000614 poison Toxicity 0.000 abstract 1
- 230000007096 poisonous effect Effects 0.000 abstract 1
- 229910001220 stainless steel Inorganic materials 0.000 abstract 1
- 239000010935 stainless steel Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 description 7
- 239000003921 oil Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 5
- 239000002585 base Substances 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 239000012467 final product Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- -1 sodium alkyl benzene Chemical class 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000002000 scavenging effect Effects 0.000 description 2
- 238000004506 ultrasonic cleaning Methods 0.000 description 2
- 240000004859 Gamochaeta purpurea Species 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical group 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- PCHPORCSPXIHLZ-UHFFFAOYSA-N diphenhydramine hydrochloride Chemical compound [Cl-].C=1C=CC=CC=1C(OCC[NH+](C)C)C1=CC=CC=C1 PCHPORCSPXIHLZ-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention relates to an environmental protection water base dewaxing agent and a preparation method thereof. The environmental protection water base dewaxing agent comprises, by weight, 1-5% of phosphate, 1-4% of complexing agent, 0-3% of sodium metasilicate, 10-20% of surface active agent, 5-20% of solvent and balanced distilled water. The main preparation steps are firstly adding distilled water, sequentially adding the phosphate, the complexing agent and the sodium metasilicate under stirring condition for stirring 20-30min, adding the surface active agent to continuously stir for 20-30min, and finally adding the solvent to stir until materials are completely dissolved. The environmental protection water base dewaxing agent can completely replace a chloro solvent dewaxing agent which is poisonous and harmful to the environment. The environmental protection water base dewaxing agent is simple and scientific in mechanism of action, achieves functions of stripping, emulsification, wax dissolving, greasy dirt dissolving and metallic oxide through reasonable compounding of the surface active agent, the solvent, the alkalinity assistant, the complexing agent and the like, is safe in use, environment-friendly, non-toxic, high in dewaxing efficiency, applicable to materials of optical glass, stainless steel, aluminum and the like, free of corrosion on washed objects and free of residues after washing, and is an ideal substitute of the chloro solvent.
Description
Technical field
The invention belongs to the chemical field, relate to dewaxing medium, especially a kind of environment protection water-based dewaxing medium and preparation method thereof.
Background technology
In opticglass processing and manufacturing field, damage in the course of processing for avoiding optical mirror slip, apply one deck cere through its surface of being everlasting, before dispatching from the factory, also to clean paraffin removal to it.In industries such as clock and watch, artwork, ornaments, accurately machined workpiece needs also to be attached with buffing wax on the workpiece after the polishing through polished finish, before dispatching from the factory, need it thoroughly be washed.Above-mentioned wax dirt mainly is made up of paraffin, lipid acid, rosined soap, MOX and some inoganic solids rubbing down small-particle, and traditional dewaxing medium is chlorinated hydrocarbon solvents such as trieline.Though trieline dewaxing oil removal efficiency is high, hydrochloric ether toxicity such as trieline are big, contaminate environment, and damaging the ozone layer is the material that restriction is used among the ODS.Therefore, develop a kind of environment protection water-based dewaxing medium and substitute the needs that the trieline dewaxing is national sustained economic development and protection environment.
Through retrieval, find following two pieces of publication documents relevant with application of the present invention:
1, a kind of water-based dewaxing agent (CN101880607A) comprises following components in weight percentage: composite reactive agent 2～60%, surplus are water.Wherein, said composite reactive agent is to be mixed by following component by mass percent: sodium alkyl benzene sulfonate 5%～8%, AEO 7%～8%; Coconut oil hydramine 2～3%; Fatty alcohol-ether sodium sulfate 4%～8%, trolamine 3～4%, water surplus.The preparation method is: earlier water is placed dispersator, under stirring at low speed, add optical dye, treat that optical dye all after the dissolving, adds the composite reactive agent again, after stirring, add essence and get final product
2, a kind of dewaxing medium (CN102051271A), its component and mass fraction thereof are: permeate agent 1-10 part, solvent 1-30 part, auxiliary agent 1-10 part.
Through the technical characterictic contrast, above-mentioned two pieces of documents and application of the present invention have more different.
Summary of the invention
The objective of the invention is to overcome the weak point of prior art; A kind of environment protection water-based dewaxing medium that can substitute the dewaxing of trieline class and preparation method thereof is provided; Prepared dewaxing medium has the function of dewaxing, oil removing, removing MOX; Harmless to user's safety non-toxic, environment there is not destruction.
The objective of the invention is to realize through following technical scheme:
A kind of environment protection water-based dewaxing medium, its moity and weight percent are:
All the other adding distil waters to 100%
And said phosphoric acid salt is one or more the mixture in tsp, potassium pyrophosphate and the tripoly phosphate sodium STPP.
And said complexing agent is one or more the mixture among HEDP-4Na, EDTA-2Na, EDTA-4Na, the EDTMPS.
And said tensio-active agent is the ethoxylate of aliphatic alcohol polyethenoxy 9 ethers, fatty acid methyl ester or one or more the mixture in alkylphenol-polyethenoxy 10 ethers.
And said solvent is one or more the mixture in dipropylene glycol methyl ether, butyl glycol ether, diethylene glycol ether, USP Kosher ether, Virahol, terepthaloyl moietie, the USP Kosher.
A kind of preparation method of environment protection water-based dewaxing medium, step is following:
⑴ add zero(ppm) water in the reaction kettle, adds the solid materialss such as phosphoric acid salt, complexing agent and metasilicate pentahydrate sodium of reacting weight, stirs to dissolve fully to solid in 20-30 minute.
⑵ the tensio-active agent that add reacting weight stirred 20-30 minute.
⑶ add solvent again and continue to be stirred to material and dissolve fully, promptly gets water base dewaxing medium finished product.
Advantage of the present invention and beneficial effect are:
1, the simple science of the mechanism of action of the present invention; Synergy through each component (emulsification of tensio-active agent, peel off, dispersion and the dissolving of solvent, the complexing of complexing agent) makes the function of dewaxing, oil removing and removing MOX all reach best, and noresidue.
2, the present invention is a water based product, safer, the environmental protection, nontoxic of solvent based product relatively, and use cost is cheaper, can dilute 20-30 and doubly use, and is easy to use, can soak also and can use ultrasonic cleaning.
3, the present invention is applied widely, promptly applicable to opticglass, again applicable to various metal works; Long service life, the on-the-spot use than nearly one times of like product length duration of service changed a not good liquor in original product 2-3 days, and this product can use about 10 days.
4, the preparation method who the present invention relates to is simple, and raw materials used wide material sources, obtains easily, is highly suitable for large-scale industrial production.
Embodiment,
Below in conjunction with embodiment, the present invention is further specified, following embodiment is illustrative, is not determinate, can not limit protection scope of the present invention with following embodiment.
Embodiment 1:
The raw material of the embodiment of the invention is marketable material.
A kind of environment protection water-based dewaxing medium, its moity is (is example with the water base dewaxing medium of 1000g):
Potassium pyrophosphate: proportioning 30g;
EDTA-4Na: proportioning 20g;
Metasilicate pentahydrate sodium: proportioning 5g
The total alkali content of metasilicate pentahydrate sodium (in Na2O) is 28.5-30.5%;
TX-10: proportioning 70g;
FMEE: proportioning 70g;
Virahol: proportioning 30g;
Diethylene glycol ether: proportioning 100g;
Zero(ppm) water: proportioning 675g.
A kind of preparing method's of water base dewaxing medium step is following:
⑴ add zero(ppm) water in the reaction kettle, adds the solid materialss such as phosphoric acid salt, complexing agent and metasilicate pentahydrate sodium of reacting weight, stirs to dissolve fully to solid in 20-30 minute.
⑵ the tensio-active agent that add reacting weight stirred 20-30 minute.
⑶ add solvent again and continue to be stirred to material and dissolve fully, promptly gets water base dewaxing medium finished product.
Embodiment 2:
A kind of moity of water base dewaxing medium is (is example with the 1000g water-based antirust):
Tripoly phosphate sodium STPP: proportioning 15g;
EDTMPS: proportioning 40g;
Metasilicate pentahydrate sodium: proportioning 10g
The total alkali content of metasilicate pentahydrate sodium (in Na2O) 28.5-30.5%;
AEO-9: proportioning 50g;
FMEE: proportioning 60g;
Virahol: proportioning 40g;
Butyl glycol ether: proportioning 80g;
Zero(ppm) water: proportioning 705g.
The step of its preparation method is same as embodiment 1.
The mechanism of action of the present invention: rationally composite through various tensio-active agents, solvent, alkaline assistant, complexing agent reaches the purpose of oil removing, paraffin removal and removing MOX.Rely on tensio-active agent emulsification, peel off; The dissolving of solvent, is dissolved and is peeled off at the infiltration of alkaline assistant, thus make that workpiece after the cleaning not only dewaxes soon, oil removing rapidly thoroughly but also do not have the corrosion noresidue, it is best that cleaning performance reaches.
This dewaxing medium application example 1:
Concentration by 3-5% is made into scavenging solution, and temperature 60-80 ℃, the opticglass that will contain cere soaks wherein, takes out then in ultrasonic cleaning 3-5 minute in zero(ppm) water rinsing 3-5 minute, cuts with wind or isopropanol dehydration gets final product again.
Conclusion: opticglass light as new after microscopic examination is cleaned, no wax, oil and foreign matter.Clean thorough, no burn into noresidue.
This dewaxing medium application example 2:
Concentration by 5% is made into scavenging solution, temperature 60-80 ℃, the metal works after the polishing is soaked 30-40 minute.Took out then in zero(ppm) water rinsing 3-5 minute, and cut or the dewatering agent dehydration gets final product with wind.
Conclusion: clean back metal works light as new, no burn into noresidue.
This environment protection water-based dewaxing medium quality standard:
Outward appearance: colourless to light yellow transparent liquid
Density (20 ℃, g/ml): 1.045-1.065 (g/100ml)
pH（3%）：10.8-11.8
Water-soluble: 100%
Working concentration: 3-5%
Cleaning way: UW or immersion
Cleaning temperature: 60-80 ℃.
Claims (6)
1. environment protection water-based dewaxing medium, it is characterized in that: its moity and weight percent are:
2. according to the described environment protection water-based dewaxing medium of claim l, it is characterized in that: said phosphoric acid salt is one or more the mixture in tsp, potassium pyrophosphate and the tripoly phosphate sodium STPP.
3. according to the described environment protection water-based dewaxing medium of claim l, it is characterized in that: said complexing agent is one or more the mixture among HEDP-4Na, EDTA-2Na, EDTA-4Na, the EDTMPS.
4. according to the described environment protection water-based dewaxing medium of claim l, it is characterized in that: said tensio-active agent is the ethoxylate of aliphatic alcohol polyethenoxy 9 ethers, fatty acid methyl ester or one or more the mixture in alkylphenol-polyethenoxy 10 ethers.
5. according to the described environment protection water-based dewaxing medium of claim l, it is characterized in that: said solvent is one or more the mixture in dipropylene glycol methyl ether, butyl glycol ether, diethylene glycol ether, USP Kosher ether, Virahol, terepthaloyl moietie, the USP Kosher.
6. the preparation method of an environment protection water-based dewaxing medium as claimed in claim 1, it is characterized in that: the step of preparation is following:
(1) zero(ppm) water is added in the reaction kettle, add the solid materialss such as phosphoric acid salt, complexing agent and metasilicate pentahydrate sodium of reacting weight, stir and dissolved fully to solid in 20-30 minute.
(2) tensio-active agent that adds reacting weight stirred 20-30 minute.
(3) add solvent again and continue to be stirred to material and dissolve fully, promptly get water base dewaxing medium finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210151871 CN102703238B (en) | 2012-05-16 | 2012-05-16 | Environmental protection water base dewaxing agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210151871 CN102703238B (en) | 2012-05-16 | 2012-05-16 | Environmental protection water base dewaxing agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN102703238A true CN102703238A (en) | 2012-10-03 |
| CN102703238B CN102703238B (en) | 2013-06-19 |
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| CN 201210151871 Expired - Fee Related CN102703238B (en) | 2012-05-16 | 2012-05-16 | Environmental protection water base dewaxing agent and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104120047A (en) * | 2014-07-18 | 2014-10-29 | 青岛蓬勃石油技术服务有限公司 | Oil pipeline detergent and preparation method thereof |
| CN104514148A (en) * | 2013-09-26 | 2015-04-15 | 五邑大学 | Fabric oil-removing agent |
| CN105002007A (en) * | 2015-07-29 | 2015-10-28 | 福建福晶科技股份有限公司 | Environment-friendly optical glass water-base cleaning agent |
| CN106967513A (en) * | 2017-03-30 | 2017-07-21 | 柳州立洁科技有限公司 | A kind of glass cleaner and preparation method thereof |
| CN107118854A (en) * | 2017-03-10 | 2017-09-01 | 广东华普科技股份有限公司 | Acid paraffin removal water composition |
| CN107418771A (en) * | 2017-05-23 | 2017-12-01 | 上海宇昂水性新材料科技股份有限公司 | Exfoliated water base cleaning agent for optical glass |
| CN109370801A (en) * | 2018-11-26 | 2019-02-22 | 蓝思科技（长沙）有限公司 | A kind of glass Wax removal water and bonding wax cleaning method |
| CN113686634A (en) * | 2021-08-10 | 2021-11-23 | 杭州迪英加科技有限公司 | Dewaxing repair liquid beneficial to acquisition of paraffin section images |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104514148A (en) * | 2013-09-26 | 2015-04-15 | 五邑大学 | Fabric oil-removing agent |
| CN104120047A (en) * | 2014-07-18 | 2014-10-29 | 青岛蓬勃石油技术服务有限公司 | Oil pipeline detergent and preparation method thereof |
| CN105002007A (en) * | 2015-07-29 | 2015-10-28 | 福建福晶科技股份有限公司 | Environment-friendly optical glass water-base cleaning agent |
| CN107118854A (en) * | 2017-03-10 | 2017-09-01 | 广东华普科技股份有限公司 | Acid paraffin removal water composition |
| CN106967513A (en) * | 2017-03-30 | 2017-07-21 | 柳州立洁科技有限公司 | A kind of glass cleaner and preparation method thereof |
| CN107418771A (en) * | 2017-05-23 | 2017-12-01 | 上海宇昂水性新材料科技股份有限公司 | Exfoliated water base cleaning agent for optical glass |
| CN107418771B (en) * | 2017-05-23 | 2020-04-17 | 上海宇昂水性新材料科技股份有限公司 | Stripping type water-based optical glass cleaning agent |
| CN109370801A (en) * | 2018-11-26 | 2019-02-22 | 蓝思科技（长沙）有限公司 | A kind of glass Wax removal water and bonding wax cleaning method |
| CN113686634A (en) * | 2021-08-10 | 2021-11-23 | 杭州迪英加科技有限公司 | Dewaxing repair liquid beneficial to acquisition of paraffin section images |
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| CN102703238B (en) | 2013-06-19 |
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