CN102702855A - UV (Ultraviolet) offset printing ink and preparation method thereof - Google Patents
UV (Ultraviolet) offset printing ink and preparation method thereof Download PDFInfo
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- CN102702855A CN102702855A CN2012102206584A CN201210220658A CN102702855A CN 102702855 A CN102702855 A CN 102702855A CN 2012102206584 A CN2012102206584 A CN 2012102206584A CN 201210220658 A CN201210220658 A CN 201210220658A CN 102702855 A CN102702855 A CN 102702855A
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Abstract
The invention relates to UV (Ultraviolet) offset printing ink which comprises the following components by weight: 10-20% of pigment, 30-35% of polyester acrylic resin, 15-20% of UV highly-branched polyester acrylic resin, 10-20% of acrylic ester monomer, 5-10% of photoinitiator, 0.5-3% of polymerization inhibitor, 5-20% of filler and 0.2-3% of aid. A preparation method of the UV highly-branched polyester acrylic resin comprises the following steps: preparing UV highly-branched polyester through a ring opening polymerization reaction of methyl tetrahydrophthalic anhydride and glycidol by a one-step method, wherein the number average molar weight of the polyester is 1,500-2,500, and the branching degree is 0.45-0.72; and then modifying the UV highly-branched polyester by using methacrylic acid glycidyl ester to synthesize the highly-branched polyester acrylic resin. The invention aims to provide the UV offset printing ink which has the advantages of low cost, easy synthesis, good resin wetting dispersion and excellent branch reproduction performance and is suitable for high-speed printing.
Description
Technical field:
The present invention relates to the printing-ink field, specifically, relate to a kind of UV flexographic ink that is suitable for high speed printing.
Background technology:
The UV flexographic ink is through action of uv radiation; Rely on the radical or the positively charged ion that form behind the light trigger absorbed radiation energy; Trigger monomer and oligopolymer generation polymerization, crosslinked and graft reaction form the high molecular polymer of crosslinked tridimensional network and realize dry solidification.Most UV flexographic ink is made up of epoxy acrylic resin, polyurethane acrylic resin, polyester acrylic resin, acrylate monomer, light trigger, filler and pigment dyestuff.Because the UV flexographic ink has the incomparable advantage of traditional oil-based ink, more and more causes the generally attention of printing industry, is widely used in field in many ways such as tobacco bale, Jiu Bao, cosmetic package, drug packaging, pressure-sensitive adhesive trade mark.
Tradition UV flexographic ink be owing to will take into account pigment wettability, so multiselect with unsaturated polyester resin and epoxy acrylic resin as matrix resin, but such resin drying speed is limited, the printing ink thixotropy is not enough, skeleton is bad, the very difficult high speed printing that is suitable for.Have the high official of indivedual uses can polyurethane acrylic resin, but cost is too high, and the resin wetted dispersiveness be very good, the practical implementation comparison difficulty of getting up yet.
Summary of the invention:
It is low to the purpose of this invention is to provide a kind of cost, is prone to the UV flexographic ink that is suitable for high speed printing of synthetic, resin wetted good dispersivity and dot reproduction superior performance.
The UV flexographic ink is characterized in that, comprises following component by weight percentage:
The preparation method of the high branched polyester vinyl resin of said UV is following: through the ring-opening polymerization of methyl tetrahydro phthalic anhydride and R-GLYCIDOL; Single stage method prepares the high branched polyester of UV; The mumber average molar mass of polyester is 1500-2500; The degree of branching is used the high branched polyester of SY-Monomer G modification UV again between 0.45-0.72, the synthetic high branched polyester vinyl resin of UV.
Above-mentioned said auxiliary agent is one or more in flow agent, dispersion agent, wetting agent, the smooth agent.
Above-mentioned said flow agent is the UV flow agent, and said dispersion agent is the UV dispersion agent, and said smooth agent is a printing ink dedicated defoamer moral modest 6800.
Above-mentioned said pigment is one or more in pigment dyestuff or the mineral dye.
Above-mentioned said polyester acrylic resin binder is one or more in epoxy acrylic resin, polyalcohol modified epoxy acrylic resin, fatty acid modified epoxy acrylic resin, polyester acrylic urethane resin, polyether-modified acrylated polyurethane resin, the fatty acid modified acrylated polyurethane resin resin.
Above-mentioned said acrylate monomer is one or more in simple function group acrylate monomer, multi-functional acrylate's monomer, simple function group methacrylate monomers, the polyfunctional group methacrylate monomers.
Above-mentioned said acrylate monomer is 1,6 hexanediyl ester.
Above-mentioned said light trigger is one or more in even acyl ketal derivatives, acylphosphine oxide, the amine alkyl phenones; Said filler is a kind of in lime carbonate, silicon-dioxide, the wax powder or two kinds; Said stopper is a para benzoquinone; P-ten.-butylcatechol, one or more in the methylene blue.
As the further improvement project of the present invention, the UV flexographic ink comprises following component by weight percentage:
Said polyester acrylic resin is a tetramethylol methane tetraacrylate UV resin, and said acrylate monomer is 1,6 hexanediyl ester, and said stopper is a para benzoquinone, and said auxiliary agent is a wetting dispersing agent 7710.The UV flexographic ink of this programme is used for high speed rotary press and high speed lithography offset press, and print speed can reach 220m/min and 22000/h.
The preparation method of aforesaid UV flexographic ink is characterized in that comprising the steps:
(1) earlier polyester acrylic resin binder, the high branched polyester propenoate of UV, acrylate monomer, stopper, auxiliary agent, light trigger are mixed, disperse to be prepared into work in-process A until whole dissolvings through impeller;
(2) on the basis of work in-process A, add pigment, filler, fully stir, process work in-process B until preliminary dispersion;
(3) work in-process B is fully ground on three-roller, be ground to the fineness that printing ink reaches regulation;
(4) product tinning.
The present invention compared with prior art has the following advantages:
1, the high branched polyester vinyl resin of UV of the present invention is high dense low sticking, adds to and improves curing speed in the flexographic ink, and pigment wettability is good simultaneously, fully satisfies the demand of high speed printing.
2, UV flexographic ink of the present invention; Be fit to that high speed printing, production cost are low, resin wetted good dispersivity and dot reproduction superior performance; It goes for high speed rotary press and high speed lithography offset press, and print speed can reach 180m/min and 20000/h.
3, synthetic route of the present invention is simple, and production cost is relatively low, and suitability is strong, can be widely used in lottery ticket, bill, books of all sorts, newspaper, comprise tobacco bale etc., accelerates print speed greatly, and print quality is unaffected simultaneously.
Embodiment
Following examples are used to explain the present invention, but are not used for limiting scope of the present invention.Specialize like nothing, the raw material among the embodiment is commercial.Wherein pigment such as fuchsin, the blue or green orchid of phthalein, diarylide yellow are the production of vapour Bagong department; Black smoke is Degussa production, and light trigger 907,1173 etc. are produced for Hua Tai company, and tetramethylol methane tetraacrylate UV resin is that German Kening Co.,Ltd provides; HDDA monomer diluent (1; 6 hexanediyl esters) for U.S.'s Sartomer provides, 7710 dispersion machines are that German EFKA (EFKA) provides, and para benzoquinone is commercially available industrial goods; Lime carbonate is the chemical industry supply of Zhong Shan Yongfeng, and silicon-dioxide is produced for winning wound company.The raw material that the synthetic high branched polyester vinyl resin of UV is selected for use: methyl tetrahydro phthalic anhydride, SY-Monomer G, R-GLYCIDOL are commercially available industrial goods.
Embodiment 1～4
One, get the raw materials ready: the weight percent with each component shown in the table 1 is prepared burden:
Table 1
| Embodiment 1. | Embodiment 2. | Embodiment 3. | Embodiment 4. | |
| Fuchsin | 20 | |||
| Phthalein is blue or green blue | 20 | |||
| Diarylide yellow | 20 | |||
| Black smoke | 13 | |||
| The high branched polyester vinyl resin of UV | 15 | 17 | 20 | 20 |
| Tetramethylol methane tetraacrylate UV resin | 35 | 33 | 30 | 35 |
| Light trigger 907 | 4 | 4 | 4 | 7 |
| Light trigger 1173 | 3 | 3 | 3 | 3 |
| Wetting dispersing agent 7710 | 2 | 2 | 2 | 3 |
| Para benzoquinone | 1 | 1 | 1 | 1 |
| Lime carbonate | 8 | 8 | 8 | 6 |
| Silicon-dioxide | 2 | 2 | 2 | 2 |
| The HDDA monomer diluent | 10 | 10 | 10 | 10 |
Ring-opening polymerization through methyl tetrahydro phthalic anhydride and R-GLYCIDOL; Single stage method prepares the high branched polyester of UV; The mumber average molar mass of polyester is 1500-2500; The degree of branching is used the high branched polyester of SY-Monomer G modification UV again between 0.45-0.72, the synthetic high branched polyester vinyl resin of UV.
Two, preparation UV flexographic ink:
(1) earlier tetramethylol methane tetraacrylate UV resin, the high branched polyester propenoate of UV, HDDA monomer diluent, para benzoquinone, wetting dispersing agent 7710, light trigger are mixed, disperse to be prepared into work in-process A until whole dissolvings through impeller;
(2) on the basis of work in-process A, add pigment, filler, fully stir, process work in-process B until preliminary dispersion;
(3) work in-process B is fully ground on three-roller, be ground to the fineness that printing ink reaches regulation;
(4) product tinning.
Three, product beta test and detection:
1, use the high speed rotary press printing, speed is 200m/min, and the printing product surface under the ultraviolet high voltage mercury lamp radiation of the paper after printed is dry.Lines are smooth, the full marking good attachment of image.The printing color is full, and svelteness is thoroughly dry, can reach the printing requirement.
Each embodiment all prepares the product of each embodiment respectively with reference to above-mentioned steps, same condition print speed can reach 200,200,220 respectively, 180m/min.
2, with high speed lithographic offset printing machine printing, speed is 22000/h, and the paper printing product surface under the ultraviolet high voltage mercury lamp radiation after printed is dry.Lines are smooth, and the full marking good attachment of image can reach the printing requirement.
Each embodiment all prepares the product of each embodiment respectively with reference to above-mentioned steps, same condition print speed can reach 20000,20000,22000,18000/h respectively.
Embodiment 5～8
One, get the raw materials ready: the weight percent with each component shown in the table 2 is prepared burden:
Table 2
| Embodiment 5 | Embodiment 6 | Embodiment 7 | Embodiment 8 | |
| Fuchsin | 20 | |||
| Phthalein is blue or green blue | 20 | |||
| Diarylide yellow | 20 | |||
| Black smoke | 15 | |||
| The high branched polyester vinyl resin of UV | 20 | 17 | 15 | 15 |
| Epoxy acrylic resin | 30 | 33 | 35 | 35 |
| Light trigger 907 | 4 | 4 | 4 | 7 |
| Light trigger 1173 | 3 | 3 | 3 | 3 |
| Wetting dispersing agent 7710 | 2 | 2 | 2 | 3 |
| Para benzoquinone | 1 | 1 | 1 | 1 |
| Lime carbonate | 8 | 8 | 8 | 6 |
| Silicon-dioxide | 2 | 2 | 2 | 2 |
| The HDDA monomer diluent | 10 | 10 | 10 | 13 |
Ring-opening polymerization through methyl tetrahydro phthalic anhydride and R-GLYCIDOL; Single stage method prepares the high branched polyester of UV; The mumber average molar mass of polyester is 1500-2500; The degree of branching is used the high branched polyester of SY-Monomer G modification UV again between 0.45-0.72, the synthetic high branched polyester vinyl resin of UV.
Two, preparation UV flexographic ink:
(1) earlier epoxy acrylic resin, the high branched polyester propenoate of UV, HDDA monomer diluent, para benzoquinone, wetting dispersing agent 7710, light trigger are mixed, disperse to be prepared into work in-process A until whole dissolvings through impeller;
(2) on the basis of work in-process A, add pigment, filler, fully stir, process work in-process B until preliminary dispersion;
(3) work in-process B is fully ground on three-roller, be ground to the fineness that printing ink reaches regulation;
(4) product tinning.
Three, product beta test and detection:
1, use the high speed rotary press printing, speed is 200m/min, and the printing product surface under the ultraviolet high voltage mercury lamp radiation of the paper after printed is dry.Lines are smooth, the full marking good attachment of image.The printing color is full, and svelteness is thoroughly dry, can reach the printing requirement.
Other experimental group are prepared the product of each experimental group respectively with reference to above-mentioned steps, and same condition print speed can reach 220,200,200 respectively, 180m/min.
2, with high speed lithographic offset printing machine printing, speed is 22000/h, and the paper printing product surface under the ultraviolet high voltage mercury lamp radiation after printed is dry.Lines are smooth, and the full marking good attachment of image can reach the printing requirement.
Other experimental group are prepared the product of each experimental group respectively with reference to above-mentioned steps, and same condition print speed can reach 20000,20000,20000,18000/h respectively.
Comparative Examples 1～4
Prescription is seen table 3, and the preparation method is the same.
Table 3
| Comparative Examples 1. | Comparative Examples 2. | Comparative Examples 3. | Comparative Examples 4. | |
| Fuchsin (57:1) | 20 | |||
| Phthalein blue or green blue (15:3) | 20 | |||
| Diarylide yellow | 20 | |||
| Black smoke | 15 | |||
| High branched polyester vinyl resin | 10 | 7 | 5 | 5 |
| Tetramethylol methane tetraacrylate UV resin | 40 | 43 | 45 | 50 |
| Light trigger 907 | 4 | 4 | 4 | 7 |
| Light trigger 1173 | 3 | 3 | 3 | 3 |
| Wetting dispersing agent 7710 | 2 | 2 | 2 | 3 |
| Para benzoquinone | 1 | 1 | 1 | 1 |
| Lime carbonate | 8 | 8 | 8 | 6 |
| Silicon-dioxide | 2 | 2 | 2 | 2 |
| The HDDA monomer diluent | 10 | 10 | 10 | 8 |
Product beta test and detection:
1, use the high speed rotary press printing, speed is 200m/min, and the printing product surface under the ultraviolet high voltage mercury lamp radiation of the paper after printed is dry.Difficult upward China ink, and rate of drying does not catch up with.The printing lighter color can't reach the printing requirement.
Other experimental group are prepared the product of each experimental group respectively with reference to above-mentioned steps, same condition print speed only with reach 120,100,100 respectively, 100m/min.
2, with high speed lithographic offset printing machine printing, speed is 22000/h, and the paper printing product surface under the ultraviolet high voltage mercury lamp radiation after printed is dry.Sharpness of dots is not enough, can't be dry, can't reach the printing requirement.
Other experimental group are prepared the product of each experimental group respectively with reference to above-mentioned steps, and same condition print speed is only to reach 6000,6000,6000,4800/h respectively.
Claims (10)
1.UV flexographic ink is characterized in that, comprises following component by weight percentage:
The preparation method of the high branched polyester vinyl resin of said UV is following: through the ring-opening polymerization of methyl tetrahydro phthalic anhydride and R-GLYCIDOL; Single stage method prepares high branched polyester; The mumber average molar mass of polyester is 1500-2500; The degree of branching is used the SY-Monomer G modified poly ester again between 0.45-0.72, the synthetic high branched polyester vinyl resin of UV.
2. UV flexographic ink according to claim 1 is characterized in that: said auxiliary agent is one or more in flow agent, dispersion agent, wetting agent, the smooth agent.
3. UV flexographic ink according to claim 2 is characterized in that: said flow agent is the UV flow agent, and said dispersion agent is the UV dispersion agent, and said smooth agent is a printing ink dedicated defoamer moral modest 6800.
4. UV flexographic ink according to claim 3 is characterized in that: said pigment is one or more in pigment dyestuff or the mineral dye.
5. according to the arbitrary described UV flexographic ink of claim 1 to 4, it is characterized in that: said polyester acrylic resin is one or more in epoxy acrylic resin, polyalcohol modified epoxy acrylic resin, fatty acid modified epoxy acrylic resin, polyester acrylic urethane resin, polyether-modified acrylated polyurethane resin, the fatty acid modified acrylated polyurethane resin resin.
6. UV flexographic ink according to claim 5 is characterized in that: said acrylate monomer is one or more in simple function group acrylate monomer, multi-functional acrylate's monomer, simple function group methacrylate monomers, the polyfunctional group methacrylate monomers.
7. UV flexographic ink according to claim 5 is characterized in that: said acrylate monomer is 1,6 hexanediyl ester.
8. UV flexographic ink according to claim 5; It is characterized in that: said light trigger is one or more in even acyl ketal derivatives, acylphosphine oxide, the amine alkyl phenones; Said filler is a kind of in lime carbonate, silicon-dioxide, the wax powder or two kinds; Said stopper is a para benzoquinone, p-ten.-butylcatechol, one or more in the methylene blue.
9. UV flexographic ink according to claim 1 is characterized in that: comprise following component by weight percentage:
Said polyester acrylic resin is a tetramethylol methane tetraacrylate UV resin, and said acrylate monomer is 1,6 hexanediyl ester, and said stopper is a para benzoquinone, and said auxiliary agent is a wetting dispersing agent 7710.
10. the preparation method of UV flexographic ink as claimed in claim 1 is characterized in that comprising the steps:
(1) earlier polyester acrylic resin, the high branched polyester propenoate of UV, acrylate monomer, stopper, auxiliary agent, light trigger are mixed, disperse to be prepared into work in-process A until whole dissolvings through impeller;
(2) on the basis of work in-process A, add pigment, filler, fully stir, process work in-process B until preliminary dispersion;
(3) work in-process B is fully ground on three-roller, be ground to the fineness that printing ink reaches regulation;
(4) product tinning.
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666116A (en) * | 2013-12-06 | 2014-03-26 | 上海德粼水性油墨有限公司 | Black offset printing ink capable of generating red fluorescence under UV irradiation |
| CN103666074A (en) * | 2013-11-29 | 2014-03-26 | 当涂县科辉商贸有限公司 | Safe and environmental-friendly ultraviolet curing ink and preparation method thereof |
| CN103666069A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Ultraviolet light cured printing ink with good adhesive attraction and toughness and preparation method thereof |
| CN104789037A (en) * | 2015-03-27 | 2015-07-22 | 桐城市新丰彩印包装有限公司 | Printing ink |
| CN105802326A (en) * | 2014-12-30 | 2016-07-27 | 天津天女化工集团股份有限公司 | UV offset printing colored ink for label printing |
| CN105885523A (en) * | 2015-02-12 | 2016-08-24 | 施乐公司 | Hyperbranched Ink Compositions For Controlled Dimensional Change And Low Energy Curing |
| CN110053409A (en) * | 2019-04-26 | 2019-07-26 | 苏州镓祥新材料科技有限公司 | A kind of high rigidity, resistant to pollution color coating printed metal sheet |
| CN112011214A (en) * | 2020-09-04 | 2020-12-01 | 苏州工业园区彩迪包装印刷有限公司 | Offset printing ultraviolet curing scratch-resistant oil and production process thereof |
| CN113072837A (en) * | 2021-03-31 | 2021-07-06 | 中山市中益油墨涂料有限公司 | UV-LED two-piece can high-flexibility offset printing ink and preparation method thereof |
| CN115491077A (en) * | 2022-09-21 | 2022-12-20 | 刘智惠 | Quick-drying high-stability printing ink and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101560348A (en) * | 2009-05-25 | 2009-10-21 | 王景泉 | Ultraviolet light curing offset printing ink and preparation method thereof |
| CN101818005A (en) * | 2010-02-21 | 2010-09-01 | 苏州科斯伍德油墨股份有限公司 | Antibacterial and bacteriostatic UV offset printing ink |
-
2012
- 2012-06-28 CN CN201210220658.4A patent/CN102702855B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101560348A (en) * | 2009-05-25 | 2009-10-21 | 王景泉 | Ultraviolet light curing offset printing ink and preparation method thereof |
| CN101818005A (en) * | 2010-02-21 | 2010-09-01 | 苏州科斯伍德油墨股份有限公司 | Antibacterial and bacteriostatic UV offset printing ink |
Non-Patent Citations (1)
| Title |
|---|
| 罗凯等: "超支化聚酯的合成及光固化性能研究", 《涂料工业》, vol. 34, no. 6, 30 June 2004 (2004-06-30), pages 6 - 9 * |
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| CN103666069A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Ultraviolet light cured printing ink with good adhesive attraction and toughness and preparation method thereof |
| CN103666074B (en) * | 2013-11-29 | 2016-04-27 | 当涂县科辉商贸有限公司 | A kind of safety and environmental protection UV curable ink and preparation method thereof |
| CN103666074A (en) * | 2013-11-29 | 2014-03-26 | 当涂县科辉商贸有限公司 | Safe and environmental-friendly ultraviolet curing ink and preparation method thereof |
| CN103666116B (en) * | 2013-12-06 | 2015-06-03 | 上海德粼水性油墨有限公司 | Black offset printing ink capable of generating red fluorescence under UV irradiation |
| CN103666116A (en) * | 2013-12-06 | 2014-03-26 | 上海德粼水性油墨有限公司 | Black offset printing ink capable of generating red fluorescence under UV irradiation |
| CN105802326A (en) * | 2014-12-30 | 2016-07-27 | 天津天女化工集团股份有限公司 | UV offset printing colored ink for label printing |
| CN105885523A (en) * | 2015-02-12 | 2016-08-24 | 施乐公司 | Hyperbranched Ink Compositions For Controlled Dimensional Change And Low Energy Curing |
| CN105885523B (en) * | 2015-02-12 | 2019-01-08 | 施乐公司 | Realize the cured hyperbranched printing ink composition of controlled change in size and low energy |
| CN104789037A (en) * | 2015-03-27 | 2015-07-22 | 桐城市新丰彩印包装有限公司 | Printing ink |
| CN110053409A (en) * | 2019-04-26 | 2019-07-26 | 苏州镓祥新材料科技有限公司 | A kind of high rigidity, resistant to pollution color coating printed metal sheet |
| CN112011214A (en) * | 2020-09-04 | 2020-12-01 | 苏州工业园区彩迪包装印刷有限公司 | Offset printing ultraviolet curing scratch-resistant oil and production process thereof |
| CN113072837A (en) * | 2021-03-31 | 2021-07-06 | 中山市中益油墨涂料有限公司 | UV-LED two-piece can high-flexibility offset printing ink and preparation method thereof |
| CN115491077A (en) * | 2022-09-21 | 2022-12-20 | 刘智惠 | Quick-drying high-stability printing ink and preparation method thereof |
| CN115491077B (en) * | 2022-09-21 | 2023-09-15 | 武汉易锦包装印务有限公司 | Quick-drying high-stability printing ink and preparation method thereof |
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