CN102702832B - Development and application of paint ink solvent - Google Patents
Development and application of paint ink solvent Download PDFInfo
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- CN102702832B CN102702832B CN201210205139.0A CN201210205139A CN102702832B CN 102702832 B CN102702832 B CN 102702832B CN 201210205139 A CN201210205139 A CN 201210205139A CN 102702832 B CN102702832 B CN 102702832B
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- solvent
- coating
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- printing ink
- ink solvent
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- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a paint ink solvent and application thereof. The paint ink solvent comprises the following components in percentage by weight: 15 percent to 65 percent of acetic ester, 5 percent to 45 percent of carbonate ester and 15 percent to 70 percent of alkanes. When the paint ink solvent disclosed by the invention is applied in paint, the using amount of the solvent is 20 percent by weight to 50 percent by weight; and when the paint ink solvent disclosed by the invention is applied in ink, the using amount of the solvent is 20 percent by weight to 50 percent by weight. The paint ink solvent provided by the invention is a novel non-benzene and sulfur-free environmental-friendly solvent which accords with the national paint ink solvent restricted standard and can completely replace aromatics solvents such as dimethylbenzene and the like.
Description
Technical field
The present invention relates to coating and printing ink production technical field, be specifically related to a kind of coating and printing ink solvent.
The invention still further relates to the application of above-mentioned coating printing ink solvent.
Background technology
The Main Function of coating and printing ink solvent is to make film forming base-material to disperse and forms thick liquid, and it contributes to construction and improves some performance of filming.Existing coating and printing ink solvent is most popular is benzene, toluene, the benzene kind solvents such as dimethylbenzene, especially xylene solvent, but along with country is used for the restriction of printing ink paint benzene kind solvent, two indoor decorating compulsory standard GB/18581 that put into effect as calendar year 2001 country and GB/18582, just to the VOC(volatile organic compounds in coating and printing ink), benzene class, heavy metal, the hazardous and noxious substances such as free formaldehyde have clearly been made limit value regulation, develop a kind of without benzene without sulphur, meet national coating and printing ink solvent and limit the use of standard, the new coating ink environmentally friendly solvent of the aromatic solvent such as substituted dimethyl benzene is the active demand in current coating and printing ink solvent market completely.But up to the present, also there is no to occur the environmentally friendly solvent of substituted arene kind solvent completely.
Summary of the invention
Technical problem to be solved by this invention is: provide a kind of without benzene without sulphur, meet national coating and printing ink solvent and limit the use of standard, the novel coating and printing ink environmentally friendly solvent of the aromatic solvent such as substituted dimethyl benzene completely.
For solving the problems of the technologies described above, technical scheme of the present invention is:
A solvent, comprises that following component forms by weight percentage:
Acetic ester 15%～65%,
Carbonic ether 5%～45%,
Alkanes 15%～70%.
Preferred a kind of coating and printing ink solvent, comprises that following component forms by weight percentage:
2-butyl acetate 15%～45%,
N-BUTYL ACETATE 1%～8%,
Amyl acetate-n 1%～10%,
Diethyl carbonate 2%～15%,
Dipropyl carbonate 5%～25%,
C6～C9 straight-chain paraffin 5%～30%,
C6～C9 naphthenic hydrocarbon 10%～40%,
Preferred the first product forms, and comprises that by weight percentage following component forms:
2-butyl acetate 20%～40%,
N-BUTYL ACETATE 2%～5%,
Amyl acetate-n 1%～3%,
Diethyl carbonate 5%～10%,
Dipropyl carbonate 15%～25%,
C6～C9 straight-chain paraffin 10%～20%,
C6～C9 naphthenic hydrocarbon 15%～20%.
Preferred the second product forms, and comprises that by weight percentage following component forms:
2-butyl acetate 20%～35%,
N-BUTYL ACETATE 1%～3%,
Amyl acetate-n 5%～8%,
Diethyl carbonate 4%～9%,
Dipropyl carbonate 5%～15%,
C6～C9 straight-chain paraffin 15%～24%,
C6～C9 naphthenic hydrocarbon 20%～35%.
The application of coating and printing ink solvent in coating, the usage quantity of described solvent is 20wt%～50wt%.
The application of coating and printing ink solvent in ink, the usage quantity of described solvent is 20wt%～50wt%.
Table 1 is the physical and chemical indexes of the first coating and printing ink solvent product and the second coating and printing ink solvent product with table 2:
The physical and chemical indexes of table 1 the first coating and printing ink solvent product
The physical and chemical indexes of table 2 the second coating and printing ink solvent product
Table 3 is solvency power contrast experiment's data that the first coating and printing ink solvent product and xylene solvent dissolve the resins such as Synolac (long oil, short oil), aminoresin, nitro-resin, acrylic resin, urethane resin on application of paints basis.
Table 3 the first coating and printing ink solvent product and dimethylbenzene are to each resin dissolves power correlation data
Table 4 is solvency power contrast experiment's data that the second coating and printing ink solvent product and xylene solvent dissolve the resins such as Synolac (long oil, short oil), aminoresin, nitro-resin, acrylic resin, urethane resin on application of paints basis.
Table 4 the second coating and printing ink solvent product and dimethylbenzene are to each resin dissolves power correlation data
From table 1, table 2, table 3 and table 4, can find out, adopt after technique scheme, the invention has the beneficial effects as follows: coating and printing ink solvent provided by the invention, it is a kind of mixed solvent, boiling point significantly improves, and not only can meet the use of high-grade paint, but also without benzene without sulphur, low toxic and environment-friendly, meets the mandatory standard limit of coating and printing ink completely; Also because the present invention is in the application process of coating, to the solvency power of resin and evaporation rate all close to the dimethylbenzene of equivalent, therefore, the aromatic solvent such as substituted dimethyl benzene completely.
Specific embodiment
Embodiment 1～9
Embodiment 10
The first coating and printing ink solvent product is applied in coating material production, and table 5 is reference formulation of a kind of zapon varnish.
Table 5 the first coating and printing ink solvent product is made the zapon varnish reference formulation of solvent
| Project | Ratio/wt% |
| Nitro-cotton (70%) | 23 |
| Terpolycyantoamino-formaldehyde resin | 2 |
| Short oil ricinoleyl alcohol acid resin | 20 |
| Phthalic acid dibutyl ester | 3.5 |
| N-BUTYL ACETATE | 13 |
| Vinyl acetic monomer | 8 |
| Butanols | 2 |
| Acetone | 3 |
| Ethanol | 3 |
| The first printing ink paint solvent product | 22.5 |
Embodiment 11
The second coating and printing ink solvent product is applied in coating material production, table 6 is reference formulation of a kind of polyurethane lacquer: during construction, by first component: second component=1.5:1 mixes and mixes well, by urethane thinner or the second printing ink paint solvent product, adjust rare, spraying optimum viscosity is 20-24s(XND-1 type coating-4 viscosity meter, 25 ℃), brushing optimum viscosity is 20-30s(XND-1 type coating-4 viscosity meter, 25 ℃).
Table 6 the second coating and printing ink solvent product is made the zapon varnish reference formulation of solvent
(1) first component:
| Project | Ratio/Wt% |
| Phthalic anhydride | 16.6 |
| Glycerine | 8.5 |
| Viscotrol C | 26.5 |
| The second printing ink paint solvent product | 48.4 |
[0059](2) second component:
| Project | Ratio/Wt% |
| Tolylene diisocyanate | 41.3 |
| TriMethylolPropane(TMP) | 9.2 |
| Pimelinketone | 49.5 |
Embodiment 12
The second coating and printing ink solvent product is applied in Printing ink producing, and the usage quantity of solvent is 30.2wt%.
Embodiment 13
The first coating and printing ink solvent product is applied in Printing ink producing, and the usage quantity of solvent is 20wt%.
Embodiment 14
The second coating and printing ink solvent product is applied in Printing ink producing, and the usage quantity of solvent is 50wt%.
The present invention is not limited to above-mentioned concrete embodiment, and those of ordinary skill in the art is from above-mentioned design, and without performing creative labour, all conversion of having done, within all dropping on protection scope of the present invention.
Claims (5)
1. a coating and printing ink solvent, is characterized in that, composed of the following components by weight percentage:
2. coating and printing ink solvent as claimed in claim 1, is characterized in that, composed of the following components by weight percentage:
3. coating and printing ink solvent as claimed in claim 1, is characterized in that, composed of the following components by weight percentage:
4. the application of a kind of coating and printing ink solvent as claimed in claim 1 in coating, the usage quantity of described solvent is 20wt%～50wt%.
5. the application of a kind of coating and printing ink solvent as claimed in claim 1 in ink, the usage quantity of described solvent is 20wt%～50wt%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210205139.0A CN102702832B (en) | 2012-06-20 | 2012-06-20 | Development and application of paint ink solvent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210205139.0A CN102702832B (en) | 2012-06-20 | 2012-06-20 | Development and application of paint ink solvent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102702832A CN102702832A (en) | 2012-10-03 |
| CN102702832B true CN102702832B (en) | 2014-01-15 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210205139.0A Expired - Fee Related CN102702832B (en) | 2012-06-20 | 2012-06-20 | Development and application of paint ink solvent |
Country Status (1)
| Country | Link |
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| CN (1) | CN102702832B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104087053B (en) * | 2014-07-26 | 2015-08-05 | 潍坊亿兴化工科技有限公司 | A kind of car refinishing paint Environment-friendlydiluent diluent and preparation method thereof |
| CN105885520A (en) * | 2014-12-08 | 2016-08-24 | 施立新 | Novel environment-friendly solvent |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0796880A2 (en) * | 1996-03-21 | 1997-09-24 | Bayer Ag | Moisture curable one component coating composition |
| EP1857510B1 (en) * | 2006-05-19 | 2009-07-29 | Agfa Graphics N.V. | Stable non-aqueous inkjet inks |
| WO2010038669A1 (en) * | 2008-09-30 | 2010-04-08 | 大日本印刷株式会社 | Inkjet ink composition for color filter, color filter, method of producing color filter, and liquid crystal display |
| CN101717596B (en) * | 2009-12-08 | 2012-05-23 | 湖州杭华油墨科技有限公司 | Water-based ink for package printing of high-adhesion film and manufacturing method thereof |
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2012
- 2012-06-20 CN CN201210205139.0A patent/CN102702832B/en not_active Expired - Fee Related
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| CN102702832A (en) | 2012-10-03 |
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