CN102676319B - Washing agent and preparation method and application thereof - Google Patents
Washing agent and preparation method and application thereof Download PDFInfo
- Publication number
- CN102676319B CN102676319B CN 201210148981 CN201210148981A CN102676319B CN 102676319 B CN102676319 B CN 102676319B CN 201210148981 CN201210148981 CN 201210148981 CN 201210148981 A CN201210148981 A CN 201210148981A CN 102676319 B CN102676319 B CN 102676319B
- Authority
- CN
- China
- Prior art keywords
- washing composition
- alkyl
- mixed solution
- antistatic
- washing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
Abstract
The invention provides a washing agent and a preparation method and application thereof. The washing agent comprises the following components in percentage by mass: 10%-30% of cationic surfactant, 50%-80% of a non-ionic surfactant and 5%-20% of assistant. The washing agent provided by the invention can rapidly and thoroughly remove contaminants and the like attached to the anti-static appliance, ensures little damage to the anti-static appliance, and thus can prolong the service life of the anti-static appliance.
Description
Technical field
The present invention relates to a kind of washing composition, relate in particular to the washing composition that can be used in the washing antistatic tool, also relate to the preparation method and application of this washing composition.
Background technology
In the manufacturing enterprise of electronic applications etc., the essential antistatic gloves that the uses when staff works, purpose is the electronic devices and components damage that prevents from causing due to static, aging.At petrochemical industry, for burning and the blast that prevents that static from bringing, also use antistatic gloves.Antistatic gloves is to using the material that is comprised of terylene and electro-conductive fiber as base material, the part antistatic gloves at the finger place and the palm place also contain resin coating.So, adopt general washing composition likely to reduce its work-ing life.
Summary of the invention
The invention provides a kind of washing composition that can be used in the washing antistatic tool, this washing composition can be fast and is removed up hill and dale the pollutent that is attached on antistatic tool etc.Concrete scheme is as follows.
A kind of washing composition, by percentage to the quality, contain 10% ~ 30% cationic surfactant, 50% ~ 80% nonionic surface active agent and 5% ~ 20% auxiliary agent.
In above-mentioned washing composition, described cationic surfactant is ester based quaternary ammonium salt type cationic surfactant, and described ester based quaternary ammonium salt type cationic surfactant has following general formula:
Wherein, each R is identical or different, means the saturated or unsaturated alkyl of straight or branched that carbonatoms is 8 ~ 19, is preferably the straight chained alkyl that carbonatoms is 16 ~ 18.R
1, R
4meaning respectively the straight or branched alkyl that carbonatoms is 1 ~ 4, is for example methyl, ethyl, propyl group and butyl.R
2, R
3meaning respectively the straight or branched alkyl that singly-bound or carbonatoms are 1 ~ 4, is for example methyl, ethyl, propyl group and butyl.X
-meaning halogen anion or oxygen acid negative ion, is for example chlorion, bromide anion, CH
3sO
4 -.
In above-mentioned washing composition, one or more in the group that described nonionic surface active agent selects free fatty alcohol-polyoxyethylene ether and alkylphenol polyoxyethylene to form.
Wherein, the general formula of described fatty alcohol-polyoxyethylene ether is R
1o-(CH
2cH
2o)
nh, wherein R
1mean the saturated or unsaturated alkyl of straight or branched that carbonatoms is 12 ~ 18, n is 3 ~ 9.Fatty alcohol-polyoxyethylene ether is such as enumerating AEO7, AEO9 etc.
The general formula of described alkylphenol polyoxyethylene is R
2c
6h
4o-(CH
2cH
2o)
mh, wherein R
2mean the straight or branched alkyl that carbonatoms is 8 ~ 10, m is 8 ~ 12.
In above-mentioned washing composition, described auxiliary agent is one or more that are selected from sequestrant, static inhibitor, amendment, stablizer, anti-deposition agent, suds-stabilizing agent and thickening material.Described sequestrant, static inhibitor, amendment, stablizer, anti-deposition agent, suds-stabilizing agent and thickening material can be used the normally used material in this area.
Preferred described auxiliary agent at least contains polyol class (for example polyoxyethylene glycol), fatty alkyl sodium sulfate (for example sodium lauryl sulphate) and disodium ethylene diamine tetraacetate.
Washing composition of the present invention preferably contains 15% ~ 25% cationic surfactant, 60% ~ 70% nonionic surface active agent and 15% ~ 20% auxiliary agent.More preferably contain 15% ~ 25% 2 (alkyl acid ester group) hydroxyethyl methylsulfuric acid ammonium methyl, 60% ~ 70% fatty alcohol-polyoxyethylene ether and 15% ~ 20% auxiliary agent.
The present invention also provides a kind of method for preparing above-mentioned washing composition, comprises the following steps:
(1) mixing-in fat sodium alkyl sulfate and nonionogenic tenside obtain mixed solution 1;
(2) mix polyol and cats product and obtain mixed solution 2;
(3) mixed solution 1 and mixed solution 2 are further added to disodium ethylene diamine tetraacetate after mixing.
In addition, the invention still further relates to the application of above-mentioned washing composition in the washing antistatic tool.Described antistatic tool comprises antistatic gloves, antistatic clothing and anti-electrostatic oversleeve etc.
Utilize the washing composition of the present invention can be fast and remove up hill and dale the pollutent that is attached on antistatic tool etc., and little to its damage, thus the work-ing life that can improve antistatic tool.And the antistatic tool that utilizes detergent washing of the present invention to cross keeps good electrostatic-proof function.
Embodiment
Below enumerate preparation method and application thereof that embodiment illustrates washing composition of the present invention.But the present invention is not limited to following embodiment.It should be noted that " part " expression " weight part " of each material of the following stated.
Embodiment 1
The compositing formula of washing composition
Under room temperature, during just sodium lauryl sulphate joins AEO9 under whipped state, obtain mixed solution 1.
Under whipped state, polyoxyethylene glycol is joined in dialkyl hydroxyethyl methylsulfuric acid ammonium methyl, stir under room temperature after 15 minutes and obtain mixed solution 2.
Mixed solution 1 and mixed solution 2 are added wherein to disodium ethylene diamine tetraacetate after mixing mutually under whipped state, continue stirring and obtain washing composition after 20 minutes.
Embodiment 2
The compositing formula of washing composition
Manufacture craft is
Utilize the method identical with embodiment 1 to be prepared.
Embodiment 3
The compositing formula of washing composition
Utilize the method identical with embodiment 1 to be prepared.
Comparative example
According to national standard GB/T 13174-2008 preparation washing powder.
The effect of test washing composition
The washing effect of the washing composition based on preparing in GB GBT 13174-2008 test above-described embodiment and comparative example.
The evaluation index that the B value (whiteness maintenance ratio) of take is washing effect, when B >=1.0, the washing composition detersive power is qualified; B<1.0 o'clock, the washing composition detersive power is defective.
Specimen comprises JB-01 (carbon black greasy dirt cloth), JB-02(albumen soiled cotton), JB-03 (sebum soiled cotton).
Wash conditions: in washings, detergent concentration 0.2%, 30 ℃ of wash temperatures, washing time 20min, water hardness 250mg/kg.
Test result is shown in table 1.
Table 1
Utilize the prepared detergent washing antistatic gloves of embodiment 1 to 3, result can be removed and be attached to the pollutent on antistatic gloves fast and up hill and dale, and little to its damage.
Obviously, those skilled in the art can carry out various changes and modification and not break away from the spirit and scope of the present invention the present invention.Like this, if within of the present invention these are revised and modification belongs to the scope of the claims in the present invention and equivalent technologies thereof, the present invention also is intended to comprise these changes and modification interior.
Claims (5)
1. a washing composition, it is characterized in that, by percentage to the quality, contain 15%～25% cationic surfactant, 60%～70% nonionic surface active agent and 15%～20% auxiliary agent, described cationic surfactant is two (alkyl acid ester group) hydroxyethyl methylsulfuric acid ammonium methyl, wherein, described alkyl is the straight chained alkyl that carbonatoms is 16～18;
Described nonionic surface active agent is fatty alcohol-polyoxyethylene ether, and the general formula of described fatty alcohol-polyoxyethylene ether is R
1o-(CH
2cH
2o)
nh, wherein R
1mean the saturated or unsaturated alkyl of straight or branched that carbonatoms is 12～18, n is 3～9.
2. washing composition according to claim 1, is characterized in that, described auxiliary agent is one or more that are selected from sequestrant, static inhibitor, amendment, stablizer, anti-deposition agent, suds-stabilizing agent and thickening material.
3. washing composition according to claim 2, is characterized in that, described auxiliary agent at least contains polyol class, fatty alkyl sodium sulfate and disodium ethylene diamine tetraacetate.
4. prepare the method for washing composition claimed in claim 3, it is characterized in that, comprise the following steps:
(1) mixing-in fat sodium alkyl sulfate and nonionogenic tenside obtain mixed solution 1;
(2) mix polyol and cats product and obtain mixed solution 2;
(3) mixed solution 1 and mixed solution 2 are further added to disodium ethylene diamine tetraacetate after mixing.
5. the application of the described washing composition of any one in the washing antistatic tool in claim 1-3, described antistatic tool comprises antistatic gloves, antistatic clothing or anti-electrostatic oversleeve.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210148981 CN102676319B (en) | 2012-05-14 | 2012-05-14 | Washing agent and preparation method and application thereof |
| PCT/CN2012/084845 WO2013170596A1 (en) | 2012-05-14 | 2012-11-19 | Detergent and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210148981 CN102676319B (en) | 2012-05-14 | 2012-05-14 | Washing agent and preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102676319A CN102676319A (en) | 2012-09-19 |
| CN102676319B true CN102676319B (en) | 2013-12-25 |
Family
ID=46808875
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201210148981 Expired - Fee Related CN102676319B (en) | 2012-05-14 | 2012-05-14 | Washing agent and preparation method and application thereof |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN102676319B (en) |
| WO (1) | WO2013170596A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102676319B (en) * | 2012-05-14 | 2013-12-25 | 北京京东方光电科技有限公司 | Washing agent and preparation method and application thereof |
| CN107821423B (en) * | 2017-10-18 | 2021-04-02 | 福建恒安集团有限公司 | Preservative |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1240472A (en) * | 1996-10-18 | 2000-01-05 | 普罗格特-甘布尔公司 | Detergent compositions comprising a mixture of cationic, anionic and nonionic surfactants |
| CN101514309A (en) * | 2009-03-19 | 2009-08-26 | 厦门市捷瑞静电设备有限公司 | An antistatic non-dust cloth detergent and the preparation thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3048642A1 (en) * | 1980-12-23 | 1982-07-15 | Hoechst Ag, 6000 Frankfurt | "TENSIDE MIXTURE FOR CLEANING HARD SURFACES" |
| US20030228991A1 (en) * | 2002-05-31 | 2003-12-11 | Johnson Andress Kirsty | Premix compositions suitable for the preparation of aqueous or semi-aqueous cleaning and degreasing formulations with low VOCs. |
| US20080188397A1 (en) * | 2005-01-25 | 2008-08-07 | Akzo Nobel N.V. | Use of a Quaternary Ammonium Compound as a Hydrotrope and a Composition Containing the Quaternary Ammonium Compound |
| CN102643722B (en) * | 2011-11-18 | 2013-06-12 | 北京京东方光电科技有限公司 | Washing agent and preparation method thereof |
| CN102676319B (en) * | 2012-05-14 | 2013-12-25 | 北京京东方光电科技有限公司 | Washing agent and preparation method and application thereof |
-
2012
- 2012-05-14 CN CN 201210148981 patent/CN102676319B/en not_active Expired - Fee Related
- 2012-11-19 WO PCT/CN2012/084845 patent/WO2013170596A1/en active Application Filing
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1240472A (en) * | 1996-10-18 | 2000-01-05 | 普罗格特-甘布尔公司 | Detergent compositions comprising a mixture of cationic, anionic and nonionic surfactants |
| CN101514309A (en) * | 2009-03-19 | 2009-08-26 | 厦门市捷瑞静电设备有限公司 | An antistatic non-dust cloth detergent and the preparation thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013170596A1 (en) | 2013-11-21 |
| CN102676319A (en) | 2012-09-19 |
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Owner name: BEIJING BOE PHOTOELECTRICITY SCIENCE + TECHNOLOGY Effective date: 20150624 Owner name: JINGDONGFANG SCIENCE AND TECHNOLOGY GROUP CO., LTD Free format text: FORMER OWNER: BEIJING BOE PHOTOELECTRICITY SCIENCE + TECHNOLOGY CO., LTD. Effective date: 20150624 |
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Effective date of registration: 20150624 Address after: 100015 Jiuxianqiao Road, Beijing, No. 10, No. Patentee after: BOE Technology Group Co., Ltd. Patentee after: Beijing BOE Photoelectricity Science & Technology Co., Ltd. Address before: 100176 Beijing city in Western Daxing District economic and Technological Development Zone, Road No. 8 Patentee before: Beijing BOE Photoelectricity Science & Technology Co., Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
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Granted publication date: 20131225 Termination date: 20200514 |