CN102658736A - Thermal transfer ribbon for transferring image text to have noctilucent effect and preparation method thereof - Google Patents
Thermal transfer ribbon for transferring image text to have noctilucent effect and preparation method thereof Download PDFInfo
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- CN102658736A CN102658736A CN2012101545711A CN201210154571A CN102658736A CN 102658736 A CN102658736 A CN 102658736A CN 2012101545711 A CN2012101545711 A CN 2012101545711A CN 201210154571 A CN201210154571 A CN 201210154571A CN 102658736 A CN102658736 A CN 102658736A
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- transfer printing
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Abstract
The invention relates to a thermal transfer ribbon for transferring an image text to have a noctilucent effect, which comprises of a ribbon base, and a release layer, a color layer and a bonding layer, which are sequentially coated on the ribbon base. The thermal transfer ribbon is characterized in that the release layer comprises the following components based on percentage by weight: 10-50% of bonding material resin and 50-90% of solid power, wherein the solid power in the release layer consists of noctilucent powder and calcium carbonate; the color layer comprises the following components based on percentage by weight: 10-30% of bonding material resin and 70-90% of solid power, wherein the solid power in the color layer consists of noctilucent powder, calcium carbonate and dye; and the bonding layer comprises the following components based on percentage by weight: 40-80% of bonding material resin and 20-60% of solid power, wherein the solid power in the bonding layer consists of aluminium hydroxide. The thermal transfer ribbon can lead the patterns and characters transferred on a printing stock to send out the fluorescence in the dark, so that the objects are convenient to distinguish in special occasions such as the dark, the night.
Description
Technical field
The invention belongs to technical field of hot stamping materials, be specifically related to a kind of transfer printing image-text and have heat transfer printing carbon tape of luminous effect and preparation method thereof.
Background technology
Hot transfer printing is compared with the liquid ink printing process as a kind of picture and text printing method, because of having energy-conserving and environment-protective, advantage such as convenient and swift, and is used widely in a plurality of fields such as food, medicine, electronics, dress ornaments.Yet, in existing various heat transfer printing carbon tape in the market, find as yet to make the pattern, the literal that are needed on the stock send fluorescence at night, be convenient to heat transfer printing carbon tape at special occasions identify objects such as dark, nights.
Summary of the invention
The object of the invention is to provide a kind of heat transfer printing carbon tape and preparation method thereof, and this carbon ribbon can make the pattern, the literal that are needed on the stock send fluorescence in the dark, is convenient at special occasions identify objects such as dark, nights.
The present invention realizes above-mentioned purpose through following technical scheme:
A kind of transfer printing image-text has the heat transfer printing carbon tape of luminous effect; By tape base and release layer, chromatograph and the tack coat coated successively on the tape base constitute; Wherein: said release layer is processed by following weight percentages: link stuff resin 10-50%; Solid powder 50-90%, the solid powder in the said release layer is made up of luminescent powder and calcium carbonate; Said chromatograph is processed by following weight percentages: link stuff resin 10-30%, and solid powder 70-90%, the solid powder in the said chromatograph is made up of luminescent powder, calcium carbonate and pigment.
Preferably, the solid powder in the said release layer is that luminescent powder and the calcium carbonate of 1:0.25-4 is formed by weight ratio; Each raw material weight percentage of solid powder in the said chromatograph is: luminescent powder 10-60%, calcium carbonate 10-60% and pigment 10-30%.
Said luminescent powder can be ZnS, and particle diameter is below 2 μ m; Said calcium carbonate particle diameter is below 1 μ m; Said pigment is white, redness, yellow or blueness etc., and pigment particle size is below 5 μ m.
Said tack coat is processed by following weight percentages: link stuff resin 40-80%, solid powder 20-60%.
Link stuff resin in the said tack coat can be nitrocotton, and solid powder can be the aluminium hydroxide of particle diameter below 1 μ m.
Link stuff resin in the said release layer can be a polyurethane resin, and the link stuff resin in the said chromatograph can be acrylic resin modified, and said tape base can be the high strength biaxially oriented polyester film.The link stuff resin can be, but be not limited only to polyurethane resin, acrylic resin modified and nitrocotton.Can be according to the difference of heat transfer printing carbon tape application, and select have different physical and chemical performances nitrocotton, the polyurethane resin and acrylic resin modified of (as: softening point, mean molecule quantity or the degree of polymerization etc.) for use, this is a routine techniques in this area.For example, be applied to the carbon ribbon of label trade mark thermoprint, just need select the resin of high softening-point, HMW for use.
Said transfer printing image-text has the preparation method of the heat transfer printing carbon tape of luminous effect, may further comprise the steps:
A, the release layer that will take by weighing in proportion with toluene, butanone mixed solvent (toluene, butanone with volume ratio 1:1 be mixed into should) connect the material resin and dissolve at normal temperatures; Then with solid powder mixing, grinding; Be coated on the tape base surface; Oven dry (80-100 ℃) forms release layer, enters into subsequent processing;
B, the chromatograph connection material resin that will take by weighing in proportion with xylenes dissolve at normal temperatures, with solid powder mixing, grinding, coat the release layer surface then, and oven dry (80-100 ℃) forms chromatograph, enters into subsequent processing;
C, the tack coat connection material resin that will take by weighing in proportion with butanone dissolve at normal temperatures, with solid powder mixing, grinding, coat the chromatograph surface then, and oven dry (80-100 ℃) promptly gets heat transfer printing carbon tape according to the invention.
Base thick is 8-20 μ m, and release layer thickness is 2.0-3.0 μ m, and chromatograph thickness is 5-10 μ m, and adhesive layer thickness is 2.0-3.0 μ m, and the heat transfer printing carbon tape gross thickness is 17-36 μ m.
Compare advantage of the present invention with prior art:
Heat transfer printing carbon tape according to the invention possesses again and can make transfer printing image-text in the luminous function of dark occasion when having common heat transfer printing carbon tape key property.Why heat transfer printing carbon tape can send fluorescence in dark occasion, and the principle of its utilization is: release layer, the contained luminescent powder of chromatograph absorb radiation energies such as sunlight, light by day in the carbon ribbon, discharge night.In addition, can come corresponding adjustment fluorescence intensity through the consumption of adjustment luminescent powder; Also can come the corresponding adjustment fluorescence retention time through the luminescent powder of selecting different quality, the luminescent powder of high-quality can be kept more than the luminous 10h in the dark.
The specific embodiment:
Through preferred embodiment technical scheme of the present invention is detailed below, but protection scope of the present invention is not limited thereto.
Among following each embodiment, tape base is a biaxially oriented polyester film; Used polyurethane resin softening point range is between 105-160 ℃, and mean molecule quantity is between 5000-35000; Acrylic resin modified softening point range is between 120-230 ℃, and mean molecule quantity is between 5000-65000; The nitrocotton softening point range is between 100-150 ℃, and mean molecule quantity is between 6000-100000.Used luminescent powder is the ZnS of particle diameter below 2 μ m.Used calcium carbonate particle diameter is below 1 μ m.Used pigment particle size is below 5 μ m, and used aluminium hydroxide particle diameter is below 1 μ m; Pigment among the embodiment 1-3 is titanium white powder, and the pigment among the embodiment 4-5 is permanent bordeaux, and the pigment among the embodiment 6-7 is that phthalein is blue or green blue, and the pigment among the embodiment 8-10 is permanent yellow.
Embodiment 1
Transfer printing image-text has the preparation method of the heat transfer printing carbon tape of luminous effect:
A, connect material resin (polyurethane resin) stirring and dissolving at normal temperatures with the toluene of volume ratio 1:1, release layer that the butanone mixed solvent will take by weighing in proportion; Then with solid powder (luminescent powder is 1:2 with the weight of calcium carbonate ratio) mixing; Be ground to maximum particle diameter and below 2 μ m, (wherein do not comprise 0 μ m, down together), be coated on the tape base surface of thick 12 μ m with coating machine; 90 ℃ of oven dry form the release layer of thickness 2.0 μ m, enter into subsequent processing;
B, the chromatograph connection material resin (acrylic resin modified) that will take by weighing in proportion with xylenes dissolve at normal temperatures; Then with solid powder (each raw material weight percentage of solid powder is: luminescent powder 15%, calcium carbonate 55% and pigment 30%) mixing; Be ground to maximum particle diameter below 5 μ m; Coat the release layer surface, 95 ℃ of oven dry form the chromatograph of thickness 6.0 μ m, enter into subsequent processing;
C, the tack coat connection material resin (nitrocotton) that will take by weighing in proportion with butanone dissolve at normal temperatures; Then with solid powder aluminium hydroxide mixing; Be ground to maximum particle diameter below 2 μ m; Coat the chromatograph surface, 90 ℃ of oven dry form the tack coat of thickness 2.0 μ m, promptly get gross thickness has luminous effect at 22 μ m, transfer printing image-text heat transfer printing carbon tape.
Embodiment 2
The preparation method: among the step a, the luminescent powder in the release layer solid powder is 1:3, the thick 10 μ m of tape base, 80 ℃ of bake out temperatures, release bed thickness 3 μ m with the weight of calcium carbonate ratio; Each raw material weight percentage of chromatograph solid powder is among the step b: luminescent powder 30%, calcium carbonate 60% and pigment 10%, 90 ℃ of bake out temperatures, the thick 5.0 μ m of chromatograph; Bake out temperature is 80 ℃ among the step c, bonding bed thickness 2.0 μ m; Other is with embodiment 1; The gained transfer printing image-text has the heat transfer printing carbon tape gross thickness 20 μ m of luminous effect.
Embodiment 3
The preparation method: among the step a, the luminescent powder in the release layer solid powder is 1:3, the thick 20 μ m of tape base, 80 ℃ of bake out temperatures, release bed thickness 2 μ m with the weight of calcium carbonate ratio; Each raw material weight percentage of chromatograph solid powder is among the step b: luminescent powder 50%, calcium carbonate 40% and pigment 10%, 85 ℃ of bake out temperatures, the thick 5 μ m of chromatograph; Bake out temperature is 85 ℃ among the step c, bonding bed thickness 2 μ m; Other is with embodiment 1; The gained transfer printing image-text has the heat transfer printing carbon tape gross thickness 29 μ m of luminous effect.
Embodiment 4
The preparation method: among the step a, the luminescent powder in the release layer solid powder is 1:0.25, the thick 20 μ m of tape base, 100 ℃ of bake out temperatures, release bed thickness 3 μ m with the weight of calcium carbonate ratio; Each raw material weight percentage of chromatograph solid powder is among the step b: luminescent powder 10%, calcium carbonate 60% and pigment 30%, 100 ℃ of bake out temperatures, the thick 10 μ m of chromatograph; Bake out temperature is 100 ℃ among the step c, bonding bed thickness 3 μ m; Other is with embodiment 1; The gained transfer printing image-text has the heat transfer printing carbon tape gross thickness 36 μ m of luminous effect.
Embodiment 5
Preparation method: preparation method: among the step a, the luminescent powder in the release layer solid powder is 1:3, the thick 8 μ m of tape base, 80 ℃ of bake out temperatures, release bed thickness 2 μ m with the weight of calcium carbonate ratio; Each raw material weight percentage of chromatograph solid powder is among the step b: luminescent powder 20%, calcium carbonate 60% and pigment 20%, 80 ℃ of bake out temperatures, the thick 8 μ m of chromatograph; Bake out temperature is 80 ℃ among the step c, bonding bed thickness 2 μ m; Other is with embodiment 1; The gained transfer printing image-text has the heat transfer printing carbon tape gross thickness 20 μ m of luminous effect.
Embodiment 6
The preparation method: among the step a, the luminescent powder in the release layer solid powder is 1:0.25, the thick 20 μ m of tape base, 85 ℃ of bake out temperatures, release bed thickness 3 μ m with the weight of calcium carbonate ratio; Each raw material weight percentage of chromatograph solid powder is among the step b: luminescent powder 60%, calcium carbonate 20% and pigment 20%, 100 ℃ of bake out temperatures, the thick 10 μ m of chromatograph; Bake out temperature is 85 ℃ among the step c, bonding bed thickness 3 μ m; Other is with embodiment 1; The gained transfer printing image-text has the heat transfer printing carbon tape gross thickness 36 μ m of luminous effect.
Embodiment 7
The preparation method: among the step a, the luminescent powder in the release layer solid powder is 1:1, the thick 18 μ m of tape base, 90 ℃ of bake out temperatures, release bed thickness 2 μ m with the weight of calcium carbonate ratio; Each raw material weight percentage of chromatograph solid powder is among the step b: luminescent powder 30%, calcium carbonate 60% and pigment 10%, 90 ℃ of bake out temperatures, the thick 5 μ m of chromatograph; Bake out temperature is 90 ℃ among the step c, bonding bed thickness 2 μ m; Other is with embodiment 1; The gained transfer printing image-text has the heat transfer printing carbon tape gross thickness 27 μ m of luminous effect.
Embodiment 8
The preparation method: among the step a, the luminescent powder in the release layer solid powder is 1:4, the thick 10 μ m of tape base, 85 ℃ of bake out temperatures, release bed thickness 3 μ m with the weight of calcium carbonate ratio; Each raw material weight percentage of chromatograph solid powder is among the step b: luminescent powder 60%, calcium carbonate 10% and pigment 30%, 85 ℃ of bake out temperatures, the thick 5 μ m of chromatograph; Bake out temperature is 85 ℃ among the step c, bonding bed thickness 2 μ m; Other is with embodiment 1; The gained transfer printing image-text has the heat transfer printing carbon tape gross thickness 20 μ m of luminous effect.
Embodiment 9
Preparation method: preparation method: among the step a, the luminescent powder in the release layer solid powder is 1:0.5, the thick 8 μ m of tape base, 80 ℃ of bake out temperatures, release bed thickness 2 μ m with the weight of calcium carbonate ratio; Each raw material weight percentage of chromatograph solid powder is among the step b: luminescent powder 30%, calcium carbonate 60% and pigment 10%, 80 ℃ of bake out temperatures, the thick 5 μ m of chromatograph; Bake out temperature is 80 ℃ among the step c, bonding bed thickness 2 μ m; Other is with embodiment 1; The gained transfer printing image-text has the heat transfer printing carbon tape gross thickness 17 μ m of luminous effect.
Embodiment 10
The preparation method: among the step a, the luminescent powder in the release layer solid powder is 1:3, the thick 18 μ m of tape base, 85 ℃ of bake out temperatures, release bed thickness 2 μ m with the weight of calcium carbonate ratio; Each raw material weight percentage of chromatograph solid powder is among the step b: luminescent powder 40%, calcium carbonate 50% and pigment 10%, 85 ℃ of bake out temperatures, the thick 5 μ m of chromatograph; Bake out temperature is 85 ℃ among the step c, bonding bed thickness 3 μ m; Other is with embodiment 1; The gained transfer printing image-text has the heat transfer printing carbon tape gross thickness 28 μ m of luminous effect.
Claims (8)
1. a transfer printing image-text has the heat transfer printing carbon tape of luminous effect; By tape base and release layer, chromatograph and the tack coat coated successively on the tape base constitute; It is characterized in that: said release layer is processed by following weight percentages: link stuff resin 10-50%; Solid powder 50-90%, the solid powder in the said release layer is made up of luminescent powder and calcium carbonate; Said chromatograph is processed by following weight percentages: link stuff resin 10-30%, and solid powder 70-90%, the solid powder in the said chromatograph is made up of luminescent powder, calcium carbonate and pigment.
2. transfer printing image-text has the heat transfer printing carbon tape of luminous effect according to claim 1, it is characterized in that: the solid powder in the said release layer is that luminescent powder and the calcium carbonate of 1:0.25-4 is formed by weight ratio; Each raw material weight percentage of solid powder in the said chromatograph is: luminescent powder 10-60%, calcium carbonate 10-60% and pigment 10-30%.
3. have the heat transfer printing carbon tape of luminous effect like the said transfer printing image-text of claim 2, it is characterized in that: said luminescent powder is ZnS, and particle diameter is below 2 μ m; Said calcium carbonate particle diameter is below 1 μ m; Said pigment is white, red, yellow or blue, and pigment particle size is below 5 μ m.
4. transfer printing image-text has the heat transfer printing carbon tape of luminous effect according to claim 1, and it is characterized in that: said tack coat is processed by following weight percentages: link stuff resin 40-80%, solid powder 20-60%.
5. have the heat transfer printing carbon tape of luminous effect like the said transfer printing image-text of claim 4, it is characterized in that: the link stuff resin in the said tack coat is a nitrocotton, and solid powder is the aluminium hydroxide of particle diameter below 1 μ m.
6. transfer printing image-text has the heat transfer printing carbon tape of luminous effect according to claim 1; It is characterized in that: the link stuff resin in the said release layer is a polyurethane resin; Link stuff resin in the said chromatograph is acrylic resin modified, and said tape base is a biaxially oriented polyester film.
7. the arbitrary said transfer printing image-text of claim 1-6 has the preparation method of the heat transfer printing carbon tape of luminous effect, it is characterized in that, may further comprise the steps:
A, the release layer connection material resin that will take by weighing in proportion with toluene, butanone mixed solvent dissolve at normal temperatures, with solid powder mixing, grinding, are coated on the tape base surface then, and oven dry forms release layer, enters into subsequent processing;
B, the chromatograph connection material resin that will take by weighing in proportion with xylenes dissolve at normal temperatures, with solid powder mixing, grinding, coat the release layer surface then, and oven dry forms chromatograph, enters into subsequent processing;
C, the tack coat connection material resin that will take by weighing in proportion with butanone dissolve at normal temperatures, with solid powder mixing, grinding, coat the chromatograph surface then, and oven dry promptly gets heat transfer printing carbon tape according to the invention.
8. has the preparation method of the heat transfer printing carbon tape of luminous effect like the said transfer printing image-text of claim 7; It is characterized in that: base thick is 8-20 μ m; Release layer thickness is 2.0-3.0 μ m; Chromatograph thickness is 5-10 μ m, and adhesive layer thickness is 2.0-3.0 μ m, and the heat transfer printing carbon tape gross thickness is 17-36 μ m.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101545711A CN102658736A (en) | 2012-05-18 | 2012-05-18 | Thermal transfer ribbon for transferring image text to have noctilucent effect and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101545711A CN102658736A (en) | 2012-05-18 | 2012-05-18 | Thermal transfer ribbon for transferring image text to have noctilucent effect and preparation method thereof |
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| CN102658736A true CN102658736A (en) | 2012-09-12 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2012101545711A Pending CN102658736A (en) | 2012-05-18 | 2012-05-18 | Thermal transfer ribbon for transferring image text to have noctilucent effect and preparation method thereof |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104029448A (en) * | 2014-05-30 | 2014-09-10 | 浙江永成印务有限公司 | Transfer printing film for back face transfer printing of glass or transparent film and production and usage method |
| CN105058999A (en) * | 2015-08-12 | 2015-11-18 | 河南卓立膜材料股份有限公司 | Thermal transfer ribbon with night luminous function and preparation method thereof |
| CN105216460A (en) * | 2015-10-30 | 2016-01-06 | 河南卓立膜材料股份有限公司 | Water-based ink thermal transfer ribbon and preparation method thereof |
| CN106346963A (en) * | 2016-08-25 | 2017-01-25 | 河南卓立膜材料股份有限公司 | Battery label printing thermal transfer ribbon and preparation method thereof |
| CN106427250A (en) * | 2016-09-29 | 2017-02-22 | 河南卓立膜材料股份有限公司 | Glitter luminous thermal transfer ribbon and preparation method thereof |
| CN110143068A (en) * | 2019-05-23 | 2019-08-20 | 广东可得智能科技有限公司 | A kind of printer colour band production technology |
| CN111439045A (en) * | 2020-05-15 | 2020-07-24 | 无锡海特新材料研究院有限公司 | Environment-friendly aqueous thermal transfer ribbon and preparation method thereof |
| CN113444444A (en) * | 2020-03-27 | 2021-09-28 | 湖南鼎一致远科技发展有限公司 | Thermal transfer ribbon and release liquid for thermal transfer ribbon |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104029448A (en) * | 2014-05-30 | 2014-09-10 | 浙江永成印务有限公司 | Transfer printing film for back face transfer printing of glass or transparent film and production and usage method |
| CN104029448B (en) * | 2014-05-30 | 2016-06-29 | 浙江永成印务有限公司 | The transfer film of glass or the transfer of the transparent film back side and production application process thereof |
| CN105058999A (en) * | 2015-08-12 | 2015-11-18 | 河南卓立膜材料股份有限公司 | Thermal transfer ribbon with night luminous function and preparation method thereof |
| CN105216460A (en) * | 2015-10-30 | 2016-01-06 | 河南卓立膜材料股份有限公司 | Water-based ink thermal transfer ribbon and preparation method thereof |
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| CN106346963A (en) * | 2016-08-25 | 2017-01-25 | 河南卓立膜材料股份有限公司 | Battery label printing thermal transfer ribbon and preparation method thereof |
| CN106427250A (en) * | 2016-09-29 | 2017-02-22 | 河南卓立膜材料股份有限公司 | Glitter luminous thermal transfer ribbon and preparation method thereof |
| CN106427250B (en) * | 2016-09-29 | 2018-09-18 | 河南卓立膜材料股份有限公司 | Glitter luminous thermal transfer ribbon and preparation method thereof |
| CN110143068A (en) * | 2019-05-23 | 2019-08-20 | 广东可得智能科技有限公司 | A kind of printer colour band production technology |
| CN113444444A (en) * | 2020-03-27 | 2021-09-28 | 湖南鼎一致远科技发展有限公司 | Thermal transfer ribbon and release liquid for thermal transfer ribbon |
| CN111439045A (en) * | 2020-05-15 | 2020-07-24 | 无锡海特新材料研究院有限公司 | Environment-friendly aqueous thermal transfer ribbon and preparation method thereof |
| CN111439045B (en) * | 2020-05-15 | 2021-12-28 | 无锡海特新材料研究院有限公司 | Environment-friendly aqueous thermal transfer ribbon and preparation method thereof |
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