CN102650097B - Foam spraying dyeing method adopting reactive dyes - Google Patents
Foam spraying dyeing method adopting reactive dyes Download PDFInfo
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- CN102650097B CN102650097B CN201110047622.6A CN201110047622A CN102650097B CN 102650097 B CN102650097 B CN 102650097B CN 201110047622 A CN201110047622 A CN 201110047622A CN 102650097 B CN102650097 B CN 102650097B
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Abstract
The invention relates to a foam spraying dyeing method adopting reactive dyes, which comprises the following steps: mixing a reactive dye liquor and a color fixing liquid; applying the mixed liquor to a fabric; and carrying out water washing after fixing the color of the fabric. The method is characterized in that the mixed liquor is foamed before being applied to the fabric, and is applied to the fabric in a foamed manner. The foam spraying dyeing method has the advantages that the stability for controlling the dyeing process is improved; the process flow is short; energy and dye utilization ratios are improved; table salt, glauber salt or urea is not required; and unfixed dyes and the pollution discharge during the dyeing process are reduced.
Description
Technical field
The spray foam colouring method that the present invention relates to use REACTIVE DYES, belongs to dope dyeing technical field.
Background technology
In the dyeing course of textiles, REACTIVE DYES is current to one of most important dyestuff of cellulose dyeing, and pad dyeing is one of important process of reactive dyeing.But the pad dyeing dyeing course of REACTIVE DYES need to consume a large amount of water and chemicals at present, and final discharge has brought immense pressure to environmental protection.The current improvement that dyeing, dyestuff are carried out is all the service efficiency in order to improve dyestuff, reduces disposal of pollutants, saves the energy, reduces the consumption of chemicals.
Tradition REACTIVE DYES continuous knot dyeing conventional process comprise pad dye liquor-dry-pad chemical liquids-decatize-washing, cold rolling-to pile-to wash, roll-dry-roast-wash, roll-steam-wash, roll-short steaming-techniques such as washing wet.Above technique is at patent WO/2009/099420, and US2006/0260073 A1, has relevant introduction in US5885305.In textile dyeing production process in the past, use the continuous dyeing method of REACTIVE DYES substantially to adopt above method to the woven of cellulose fibre.But above method all exists various problems, need to improve at everyways such as reducing dye dosage, the saving energy, minimizing disposal of pollutants, operation convenience.
The technique of the most often applying take traditional continuous dyeing is as example, as shown in Figure 1, for padding dye liquor-dry-pad chemical liquids-decatize-washing process schematic diagram, the color depth that fabric 42 is dying as required carries out the immersion liquid of staining solution in dyestuff squeeze device 1, then use the first padding machine 2 to roll and (comprise the REACTIVE DYES of the variable concentrations adding according to the dye level of difference needs except unnecessary staining solution, may add bleeding agent according to the characteristic of fabric and dyestuff, migration inhibitor, the auxiliary addition agents such as anti-reducing agent).Use the modes such as infrared baking unit 3, baking oven 4 or other mode that can be used for drying to dry fabric at baking stage.In chemical liquids squeeze device 5, carry out fixation solution 6(and comprise the bright mixed solution powder of caustic soda, soda ash and salt or unit of different proportionings) immersion liquid.By the second padding machine 7, fixation solution 6 is applied on fabric 42, generally the liquid carrying rate by fabric after the process of padding 42 (on fabric with staining solution and the gross weight of fixation solution and the ratio of fabric weight) is 60%-120%.Steaming device 8 is in the environment of saturated vapor, makes REACTIVE DYES and cellulose fibre carry out fixation and react under the effect of alkali lye.Water washing device 9 is that the loose colour that the REACTIVE DYES of not fixation or hydrolysis is formed cleans.In above dyeing course, in the time padding the chemical liquids stage, use a large amount of salt or glauber salt to urge to dye to dyestuff, prevent that dyestuff from dropping in chemical liquids 6 in a large number.Fabric 42 is padding after chemical liquids or to enter liquid carrying rate before steam box larger, be generally 60-120%, a large amount of humidity that fabric 42 is brought into after padding makes in next procedure decatize phase process the temperature and humidity balance in steaming box be difficult to control, and consumes a large amount of steam or the energy guarantees stable decatize state.And in this process, owing to having used in a large number salt, chlorion is wherein comparatively serious to the damage of stainless steel equipment, reduce the service life of steam box He Hou road stainless steel equipment.A large amount of uses of salt or glauber salt are for padding in chemical liquids phase process, to REACTIVE DYES rise short dye used, but in the washing stage on fabric 42 with a large amount of salt or glauber salt simultaneously also the loose colour dyestuff after hydrolysis is had to the short effect of dying, reduce greatly the cleaning efficiency of loose colour, in water-washing process, need to use a large amount of water and soaping agent, thereby cause unnecessary wastes and pollution discharge.The most important thing is due to generally in this chemical liquids 6, the concentration of salt is 200 grams per liter left and right, and all salt will all discharge with sewage, and the salt of discharge is difficult to process in sewage, cause environmental pollution, the pollution of salt is also the most reluctant polluter of printing and dyeing enterprise.
In order to solve the consumption of the energy, water, salt and other chemicals a large amount of in REACTIVE DYES continuous dyeing process, dyer author has developed cold rolling-heap-washing process, as shown in Figure 2, for cold rolling-heap-washing process schematic diagram, use proportioning pump 12 that dye solution 10 and alkali lye 11 are added in padding liquor tank 13, fabric 42 first immerses padding liquor tank 13, by padding machine 14, unnecessary alkali lye and REACTIVE DYES liquid are shut out from fabric, by cold dome device 15, carry out reactive dye color fixing through 20-48 hour bank up, after cold dome, fabric is removed loose colour through washing unit 16 again.Although this technique has lowered the consumption of the energy greatly, lower the consumption of salt or glauber salt, but there is the shortcoming that is difficult for consistent and variation of ambient temperature and causes every volume lots processed aberration due to clot padding machine pressure in batches, also there is the defect poor to the spreadability of dead cotton and immature cotton in this technique.And the dyeing time of this technique is longer, production scene can not be corrected coloured light and check fabric quality in time, once occur that quality problems are difficult to revise, and be that property is difficult to revise by the gross.
In traditional dyeing process, some REACTIVE DYES is used rolls-dries-roasting-washing process, as shown in Figure 3, for rolling-dry-roast-washing process schematic diagram, the dye liquor that fabric 42 comprises REACTIVE DYES and alkaline agent by dye liquor alkali lye squeeze device 17() after drying unit 18, carry out fixation through baking device 19 again, then remove loose colour through washing unit 20.Although this technique flow process shortens, in the process of padding, alkali lye and REACTIVE DYES are with bathing, and long time running can make dyestuff hydrolysis cause loose colour to increase, and need to add a large amount of urea to guarantee in the certain humidity baking under condition.This technique is not suitable for the dyeing of regenerated celulose fibre and heavily fabric, easily yellowing after textile dyeing, and it is poor that light and chlorine float fastness, is not suitable for dying bright-colored.
Some dyeing adopts roll-steaming-washing process, as shown in Figure 4, for rolling-steam-washing process schematic diagram, fabric 42 pads the dye liquor of REACTIVE DYES and alkaline agent by dye liquor alkali lye squeeze device 21() after directly in steaming device 22, carry out saturated vapor decatize, and then through washing unit 23 remove loose colour.Although this technique flow process shortens, in the process of padding, alkali lye and REACTIVE DYES are with bathing, and long time running can make dyestuff hydrolysis cause loose colour to increase.And fabric 42 liquid carrying rates are larger after the process of padding, liquid carrying rate, generally all at 60-120%, also can cause decatize condition wayward.This technique fixation rate variance, is not suitable for processing dark product, and the vividness of color is also not ideal enough.
Recently some researchers roll-wet short steaming-washing process in research reactive dyeing, as shown in Figure 5, for rolling-wet short steaming-washing process schematic diagram, fabric 42 pads the dye liquor of REACTIVE DYES and alkaline agent by dye liquor alkali lye squeeze device 24() after, under the condition of low humidity, enter successively in the first baking device 26 and the second baking device 27 and bake (humidity 20-35%, temperature 120-140 ℃, 30-120s, steam injects from bottom inlet 29) fixation, through washing unit, loose colour is removed in 28 washings.Although this technological process is shortened, Color is better, but be applied to liquid carrying rate on fabric 42 generally all at 60-120% by the process of padding in the process of padding dye liquor and alkali lye, under the condition of this liquid carrying rate, control the condition that bakes (the humidity 20-35% of follow-up low humidity, temperature 120-140 ℃) relatively waste energy, the control of temperature and humidity is also relatively difficult, especially in the time of the thickness difference of fabric, can cause the fluctuation of the humidity and temperature of bringing baking device into, need complicated equipment to carry out accurate humidity and temperature control and abundant operating experience.Owing to passing through this mode, low humidity bakes the more difficult control of degree of stability of condition, so this technique has strict restriction to the variety adoption of REACTIVE DYES, and needs the temperature and humidity in casing to carry out strict detection and control, and equipment investment is larger.
The Chinese patent " a kind of salt-free pad steam continuous dyeing method for active dye " that other dyeing is 200610168121 as application number, publication number is 01244433 Chinese patent " wet short aging continuous dyeing machine ", publication number is the United States Patent (USP) " Process for the continuous dyeing of fabric webs-fixing with steam/air mixture " of US4465490, publication number is the European patent " Process for the continuous dyeing of textile materials in web form " of EP0087740, publication number is the United States Patent (USP) " Continuous textile dyeing apparatus " of US 3945225, application number is 91105678.5 Chinese patent " cold padbatch dyeing process of wet cloth by use of active dyes ", application number is 200710147410.9 Chinese patent " salt free dyeing with reactive dye ", application number is 200810131400.0 Chinese patent " a kind of reactive dye ultra-short rapid dyeing and fixation technology method ", application number is 200910049269.8 Chinese patent " a kind of method for dyeing reactive dye by one-step method without salt ", application number is 200910231682.6 Chinese patent " spray coloring stack dying process for cotton woven fabrics ", application number is 201010296309.1 Chinese patent " a kind of formula of foam dyeing system and preparation method thereof ", fabric all exceedes 60% in the liquid carrying rate ordinary circumstance that enters the fixation stage, major part is all between 70%-120%, more than 60% liquid carrying rate of fixation stage is the main cause that causes various dyeing specks.
Summary of the invention
The object of this invention is to provide and a kind ofly can control the spray foam colouring method of fabric in the use REACTIVE DYES of the liquid carrying rate in fixation stage.
In order to achieve the above object, the invention provides a kind of textiles spray foam colouring method that uses REACTIVE DYES, comprise REACTIVE DYES solution and fixation liquid are mixed, mixed liquor is applied on fabric, by the fabric fixation after washing of gained, it is characterized in that, go forward first mixed liquor foaming mixed liquor being applied to fabric, mixed liquor is to be applied on fabric with the form of foam.The mixture foam that the present invention uses the form of foam to carry chemical liquids and dye solution sprays into fabric, control fabric and under the state of lower liquid carrying rate, carry out reactive dye color fixing, because do not use traditional padding liquor tank and padding machine, in fabric without free moisture, thereby dye liquor can not form and come off, also be difficult for causing the phenomenon of migration, do not need salt or glauber salt to urge to dye.This dyeing course does not have limitation to used REACTIVE DYES, only need to use the applied REACTIVE DYES of traditional handicraft just can exceed the bright-coloured degree of obtained dyeing and the dye level of traditional handicraft.
By foam applying on fabric time, the liquid carrying rate of controlling fabric is 15-70wt%, better 20-50%, best 30-45%.
Described REACTIVE DYES solution and fixation liquid passing ratio pump mix, or directly use tradition to be uniformly mixed mode without proportioning pump to mix.
Described mixed liquor is applied on fabric by the slit-shaped outlet contacting with fabric, slit-shaped outlet horizontally set on fabric, and the width of described slit-shaped outlet is 1-8 millimeter, is preferably 2-6 millimeter, the best is 3-5 millimeter.Foam applying is that slit sprays into formula and applies to the mode on fabric, foam applying mode can be the disclosed foam applying mode of Chinese patent that the patent No. is ZL200710047713.3 or number of patent application 201010508087.5 or other can make the mode that foam is horizontal at fabric or width evenly applies, can single when foam applying or repeatedly, to single-sided fabric or two-sided applying, to guarantee that liquid carrying rate reaches predetermined degree and the uniformity coefficient applying.Described foam maker connects PLC.The model of PLC is (MT6100IV2).In the process of foam applying, fabric covers the slit-shaped outlet of foam applying device, and in the process of fabric movement, foam constantly sprays into formula to fabric and applies.Spray into the foam volume of fabric and the operation of fabric synchronously to keep fabric to be issued to the liquid carrying rate of consistent setting in different speed of service situations.The namely speed of service data of fabric, the width data of fabric, the grammes per square metre data of fabric need to be inputted or feed back in the PLC of foam generator, apply to form synchronously.The foam output speed of foam generator is to calculate gained by the PLC in foaming machine according to the speed of fabric operation, the liquid carrying rate setting, bubble ratio, fabric weight, fabric width.
The bubble of described mixed liquor foam is 1:2-1:30 than the ratio of foam cumulative volume (liquid volume containing in foam with), better 1:3-1:10, best 1:4-1:8.
Fixation liquid of the present invention contains alkaline agent and blowing agent, and described alkaline agent is that soda ash, caustic soda, sodium bicarbonate and other can make one or more the mixture in alkaline agent that REACTIVE DYES reacts with cellulose fibre generation fixation.Carry out consumption adjustment according to the degree of depth of the use amount of dyestuff or dyeing, alkaline agent concentration is generally one times of traditional left and right, and what adopt due to the present invention is that low feeding applies alkaline agent, relatively not increase of alkaline agent actual amount and conventional amount aborning.REACTIVE DYES of the present invention is identical with the REACTIVE DYES using in traditional reactive dyeing process.Described blowing agent is by making above-mentioned mixed liquor mix the surfactant bubbling through foaming machine.
Described color-fixing method for baking, decatize or cold dome.Described color-fixing device is baking device, steaming device or cold dome device.Steaming device in the present invention and baking device can use baking oven, steaming box or other device that can reach the described decatize of this patent or bake condition.
When employing bakes method fixation, keep the temperature of baking device at 120-160 ℃, better 130-150 ℃, best 135-145 ℃, humidity control is 10-60%, is preferably 20-50%, the best is 30-35%; While adopting steaming method fixation, keeping the saturated-steam temperature of steaming device is 102-105 ℃.While adopting cold dome method fixation, keep fabric under the state of clot, to carry out constant temperature and bank up, the temperature of banking up is 15-35 ℃, and the time of banking up is 8-48 hour.Described decatize or the temperature and humidity baking are by heating and hot air circulation means such as traditional Steam Heating, heat-conducting oil heating, electrical heating, by the monitoring of temperature humidity, humidity is controlled by steam injection and dehumidifier, and temperature is controlled described decatize or bakes damp condition by heating or stop heating.When employing bakes or decatize carries out fixation, a small amount of moisture that fabric itself is brought into can bake or decatize process in play the supplementary effect of moisture, on fabric, the low strap liquid status of 15-70% can make the temperature required and damp condition in baking device body be easy to control, and can make the REACTIVE DYES on fabric be easy to reach fast its desirable color fixing temperature, reduce the hydrolysis of dyestuff, thereby reach best colour fixation and finally improve the Dry Sack rate of dyeing course.While adopting cold dome fixation, because the liquid carrying rate of fabric is less, the free moisture in fabric is less, can obtain the hydrolysis of more uniform colour fixation and minimizing dyestuff.After fixation, the REACTIVE DYES on fabric completes with the fixation of reacting of fiber.After fixation, remove loose colour through washing unit again.This process is consistent with the washing unit process that tradition is removed loose colour.
Water washing device in the present invention's diagram is that concise representation only indicates three washing unit, uses 5-10 washing unit in the general production time.
The present invention replaces traditional medium to carry chemicals with air, carries chemicals and chemicals is applied to fabric face or inside equably as medium with foam, and in alternative traditional dyeing process, conventional padding machine applies the mode of chemical liquids.This staining method has reduced the consumption of water in traditional dyeing process, and traditional dyeing technical process is optimized.Compared with traditional various continuous dyeing process, the present invention has improved the stability of dyeing control, and technological process is extremely short, has improved the utilization rate of energy utilization rate and dyestuff, do not need to use salt, glauber salt or urea, reduced the disposal of pollutants of loose colour and dyeing course.The present invention's equipment used does not need complicated Temperature and Humidity Control, and less investment just can obtain larger energy-saving and cost-reducing benefit.
Accompanying drawing explanation
Fig. 1 is for padding dye liquor-dry-pad chemical liquids-decatize-washing process schematic diagram;
Fig. 2 is cold rolling-heap-washing process schematic diagram;
Fig. 3 is for rolling-dry-roast-washing process schematic diagram;
Fig. 4 is for rolling-steam-washing process schematic diagram;
Fig. 5 is for rolling-wet short steaming-washing process schematic diagram;
Fig. 6 is the textiles spray foam dyeing apparatus schematic diagram that adopts the use REACTIVE DYES of curing fixation;
Fig. 7 is the textiles spray foam dyeing apparatus schematic diagram that adopts the use REACTIVE DYES of vapour steaming colour fixing;
Fig. 8 is the textiles spray foam dyeing apparatus schematic diagram that adopts the use REACTIVE DYES of cold dome fixation.
concrete embodiment
illustrate the present invention below in conjunction with embodiment.
Embodiment 1
As shown in Figure 6, for adopting the textiles spray foam dyeing apparatus schematic diagram of use REACTIVE DYES of curing fixation, the textiles spray foam dyeing apparatus of the use REACTIVE DYES of described employing curing fixation comprises color-fixing device, described color-fixing device is baking device 36, the outlet side of color-fixing device is provided with water washing device 37, the input side of color-fixing device is provided with foam applying device 35, foam applying device 35 connects foam maker 33 by pipeline 44, foam maker 33 connects the outlet of proportioning pump 32, and the entrance of proportioning pump 32 connects REACTIVE DYES NaOH solution tank NaOH 31 and fixation flow container 30.Described foam applying device 35 has slit-shaped outlet 43, slit-shaped outlet 43 horizontally set on fabric 42.The width of described slit-shaped outlet 43 is 1 millimeter, and described foam maker 33 connects PLC34.
The method that adopts said apparatus dyeing to produce orange cotton woven: comprise REACTIVE DYES solution and fixation liquid are mixed, mixed liquor is foamed, foam applying, to fabric, is adopted the fabric of gained to bake method fixation, fixation after washing.
(1) formula of fixation liquid (solvent is water):
Soda ash 60g/L,
Caustic soda 15g/L,
Blowing agent TSZ(Shanghai Yuhui Chemical Co.Ltd produces) 3g/L;
(2) formula of REACTIVE DYES solution (solvent is water):
Active red dye M-8B 12g/L,
Yellow reactive dyes S-3R 8g/L,
Active red dye M-2B 4.2g/L,
Anti-reducing agent yh-607(Shanghai Yuhui Chemical Co.Ltd produces) 5 g/L;
(3) foam maker that uses Shanghai Yuhui Chemical Co.Ltd to produce, PLC34 setup parameter is as follows:
Fabric width: 1.8m
Bubble compares 1:5
Fabric weight 260g/m
2
Fabric speed of service 40m/min;
(4) foam applying scheme:
The foam applying device that uses Shanghai Yuhui Chemical Co.Ltd to produce;
Adopt foam chemicals slit to spray into formula applying method;
(5) curing fixation technique:
Oven temperature: 140 degrees Celsius;
Humidity: 30-35% in baking oven;
(6) washing process: identical with traditional handicraft.
(7) Color:
Pad compared with dye liquor-dry-pad chemical liquids-decatize-washing process the gained textile dyeing degree of depth dark 10% with traditional; Reach under the prerequisite of same loose colour removal effect, in washing process, reduce water more than 30%; Do not use in process of production urea; Fixation process is easy to control, and the percentage of A-class goods improves at least 20%.
Embodiment 2
As shown in Figure 7, for adopting the textiles spray foam dyeing apparatus schematic diagram of use REACTIVE DYES of vapour steaming colour fixing, the textiles spray foam dyeing apparatus of the use REACTIVE DYES of described employing curing fixation comprises color-fixing device, described color-fixing device is steaming device 38, the outlet side of color-fixing device is provided with water washing device 39, the input side of color-fixing device is provided with foam applying device 35, foam applying device 35 connects foam maker 33 by pipeline 44, foam maker 33 connects the outlet of proportioning pump 32, and the entrance of proportioning pump 32 connects REACTIVE DYES NaOH solution tank NaOH 31 and fixation flow container 30.Described foam applying device 35 has slit-shaped outlet 43, slit-shaped outlet 43 horizontally set on fabric 42.The width of described slit-shaped outlet 43 is 8 millimeters, and described foam maker 33 connects PLC34.
The method that adopts said apparatus dyeing to produce light blue cotton woven: comprise REACTIVE DYES solution and fixation liquid are mixed, mixed liquor is foamed, foam applying, to fabric, is adopted to steaming method fixation, fixation after washing by the fabric of gained.
(1) formula of fixation liquid (solvent is water):
Soda ash 40g/L,
Caustic soda 10g/L,
Blowing agent TSZ(Shanghai Yuhui Chemical Co.Ltd produces) 3g/L;
(2) formula of REACTIVE DYES solution (solvent is water):
Active red M-8B 0.06g/L,
Reactive Brilliant Blue KN-R 0.5g/L,
Reactive navy blue CE 0.3g/L,
Anti-reducing agent yh-607 5g/l;
(3) foam maker that uses Shanghai Yuhui Chemical Co.Ltd to produce, PLC34 setup parameter is as follows:
Fabric width 2.4m;
Bubble compares 1:5
Fabric weight 120g/m
2
Fabric speed of service 60m/min;
(4) foam applying scheme:
The foam applying device that uses Shanghai Yuhui Chemical Co.Ltd to produce;
Adopt foam chemicals slit to spray into formula applying method;
(5) vapour steaming colour fixing technique:
Steaming box temperature: 105 degrees Celsius
Humidity in steaming box: 100%
(6) washing process: identical with traditional handicraft.
(7) Color:
Compared with traditional rolling-dry-roast-washing process, the dark 10-15% of gained textile dyeing depth ratio traditional handicraft; Reach under the prerequisite of same loose colour removal effect, in washing process, reduce water more than 30%; Do not use in process of production glauber salt or salt; Fixation process is easy to control, and the percentage of A-class goods improves 10-20%.
As shown in Figure 8, for adopting the textiles spray foam dyeing apparatus schematic diagram of use REACTIVE DYES of cold dome fixation, the textiles spray foam dyeing apparatus of the use REACTIVE DYES of described employing curing fixation comprises color-fixing device, described color-fixing device is cold dome device 40, the outlet side of color-fixing device is provided with water washing device 41, the input side of color-fixing device is provided with foam applying device 35, foam applying device 35 connects foam maker 33 by pipeline 44, foam maker 33 connects the outlet of proportioning pump 32, and the entrance of proportioning pump 32 connects REACTIVE DYES NaOH solution tank NaOH 31 and fixation flow container 30.Described foam applying device 35 has slit-shaped outlet 43, slit-shaped outlet 43 horizontally set on fabric 42.The width of described slit-shaped outlet 43 is 4 millimeters, and described foam maker 33 connects PLC34.
The method that adopts said apparatus dyeing to produce black cotton woven: comprise REACTIVE DYES solution and fixation liquid are mixed, mixed liquor is foamed, foam applying, to fabric, is adopted to cold dome method fixation, fixation after washing by the fabric of gained.
(1) formula of fixation liquid (solvent is water):
Soda ash 60g/L,
Caustic soda 15g/L,
Blowing agent TSZ(Shanghai Yuhui Chemical Co.Ltd produces) 3g/L;
(2) formula of REACTIVE DYES solution (solvent is water):
Active red M-8B 2.8g/L,
Active yellow S-3R 3.5g/L,
Reactive black S-NE 18.5g/L,
Anti-reducing agent yh-607 5 g/L;
(3) foam maker that uses Shanghai Yuhui Chemical Co.Ltd to produce, PLC34 setup parameter is as follows:
Fabric width 1.8m,
Steep than 1:5,
Fabric weight 260g/m
2,
Fabric speed of service 30m/min;
(4) foam applying scheme:
The foam applying device that uses Shanghai Yuhui Chemical Co.Ltd to produce;
Adopt foam chemicals slit to spray into formula applying method;
(5) cold dome color fixing process:
Bank up the time: 24 hours
The humidity of banking up: 25 degrees Celsius
(6) washing process: identical with traditional handicraft.
(7) Color:
With traditional cold rolling-heap-washing process compared with, gained textile dyeing depth ratio traditional handicraft dark 15%; Reach under the prerequisite of same loose colour removal effect, reduce water more than 30% in washing process, fixation process is easy to control, and the percentage of A-class goods improves at least 20%.
Claims (8)
1. one kind uses the textiles spray foam colouring method of REACTIVE DYES, it is characterized in that, comprise REACTIVE DYES solution and fixation liquid passing ratio pump are mixed, foam maker (33) connects the outlet of proportioning pump (32), first mixed liquor is foamed, again mixed liquor is applied on fabric (42) by the slit-shaped outlet (43) contacting with fabric with the form of foam, slit-shaped outlet (43) is at the upper horizontally set of fabric (42), the width of slit-shaped outlet (43) is 1-8 millimeter, by the fabric fixation after washing of gained.
2. the textiles of use REACTIVE DYES as claimed in claim 1 spray foam colouring method, is characterized in that, by foam applying to fabric when (42), the liquid carrying rate of controlling fabric is 15-70wt%.
3. the textiles of use REACTIVE DYES as claimed in claim 1 spray foam colouring method, is characterized in that, the bubble of described mixed liquor foam is than being 1:2-1:30.
4. the textiles of use REACTIVE DYES as claimed in claim 1 spray foam colouring method, is characterized in that, described color-fixing method for baking, decatize or cold dome.
5. the textiles of use REACTIVE DYES as claimed in claim 4 spray foam colouring method, is characterized in that, adopts while baking method fixation, keeps the temperature of baking device (36) at 120-160 ℃; Humidity control is 10-60%.
6. the textiles of use REACTIVE DYES as claimed in claim 4 spray foam colouring method, is characterized in that, while adopting steaming method fixation, keeping the saturated-steam temperature of steaming device (38) is 102-105 ℃.
7. the textiles of use REACTIVE DYES as claimed in claim 4 spray foam colouring method, is characterized in that, while adopting cold dome method fixation, keeps fabric under the state of clot, to carry out constant temperature and banks up, and the temperature of banking up is 15-35 ℃, and the time of banking up is 8-48 hour.
8. the textiles of use REACTIVE DYES as claimed in claim 1 spray foam colouring method, is characterized in that, in the mixture of described dyeing liquor and fixation liquid, contains blowing agent.
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CN114657731B (en) * | 2022-04-20 | 2023-08-29 | 广东溢达纺织有限公司 | Foam dyeing method capable of dyeing uneven fashion effect and obtained ready-made clothes or fabric |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101143356A (en) * | 2007-11-01 | 2008-03-19 | 上海誉辉化工有限公司 | Foam applying device |
CN101956335A (en) * | 2010-09-29 | 2011-01-26 | 华纺股份有限公司 | Formula of foam dyeing system and preparation method thereof |
Family Cites Families (3)
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CN101168924A (en) * | 2006-10-26 | 2008-04-30 | 张志军 | Application of chemical foam finishing in weave dyeing and finishing technique |
CN101435162A (en) * | 2008-12-29 | 2009-05-20 | 郑州枫林无纺科技有限公司 | Formula of foam dyeing system and foam dyeing method of base cloth for multifunctional water stabbed superfine fiber leather |
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Patent Citations (2)
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---|---|---|---|---|
CN101143356A (en) * | 2007-11-01 | 2008-03-19 | 上海誉辉化工有限公司 | Foam applying device |
CN101956335A (en) * | 2010-09-29 | 2011-01-26 | 华纺股份有限公司 | Formula of foam dyeing system and preparation method thereof |
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