CN102648553B - 一种传感器片材和一种制造该传感器片材的方法 - Google Patents

一种传感器片材和一种制造该传感器片材的方法 Download PDF

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CN102648553B
CN102648553B CN201080054490.3A CN201080054490A CN102648553B CN 102648553 B CN102648553 B CN 102648553B CN 201080054490 A CN201080054490 A CN 201080054490A CN 102648553 B CN102648553 B CN 102648553B
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D·W·梅尔
M·豪
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Abstract

这里提供了一种传感器片材和一种制造该传感器片材的方法。该片材设置有：(A)棋盘状拉链图形(20)的相同形状元件(30)，该相同形状元件确定了(i)右侧纵向列(21r)，该右侧纵向列包括右侧组元件(30r)的基部部分(31)；(ii)左侧纵向列(21s)，该左侧纵向列包括左侧组元件(30s)的基部部分(31)；以及(iii)中间纵向列(21i)，该中间纵向列包括交替的右侧(30r)和左侧(30s)元件凸片部分(32)；以及(B)功能材料(70)的连续纵向条带，该功能材料的连续纵向条带只位于中间列(21i)中。

Description

一种传感器片材和一种制造该传感器片材的方法
本申请要求美国专利申请No.12/630058的优先权，该美国专利申请No.12/630058的申请日为2009年12月3日。
背景技术
经常需要将功能材料点布置在表面上用作传感器，以便检测和测量在限定空间(例如碳酸饮料瓶、食品容器、皮氏培养皿、密封运输的容器等)内的状态(例如温度、压力、RH、pH、目标分析物例如O2、O3、CO2、CO的浓度等)。由于大部分功能材料的昂贵，通常希望使用如所需的少量功能材料，通常形成小于100mm2的点，更通常小于25mm2，更通常小于10mm2。
处理这样小的元件很难，特别是当努力避免与功能材料直接接触以避免污染或损坏功能材料时。
因此，基本需要一种便宜的功能材料传感器源，它容易制造、容易处理和容易使用。
发明内容
本发明的第一方面是一种商业物品。该商业物品是片材，该片材设置有：(A)棋盘状拉链图形的相同形状元件，该相同形状元件确定了(i)右侧纵向列，该右侧纵向列包括右侧组元件的基部部分；(ii)左侧纵向列，该左侧纵向列包括左侧组元件的基部部分；以及(iii)中间纵向列，该中间纵向列包括交替的右侧和左侧元件凸片部分；以及(B)功能材料的连续纵向条带，该功能材料的连续纵向条带只在中间列中涂覆在片材上，因此，功能材料层只提供于右侧和左侧元件的凸片部分上。
本发明的第二方面是一种制造商业物品的方法。该方法包括以下步骤：(1)将功能材料的连续纵向条带布置在腹板上；以及(2)将腹板切成棋盘状拉链图形的元件，以便确定这样的图形，该图形包括：(i)右侧纵向列，该右侧纵向列包括右侧组元件的基部部分；(ii)左侧纵向列，该左侧纵向列包括左侧组元件的基部部分；以及(iii)中间纵向列，该中间纵向列包括交替的右侧和左侧元件凸片部分；其中，功能材料的纵向条带只保持在中间列中，以便只存在于右侧和左侧元件的凸片部分上。
附图说明
图1是具有功能材料的完整涂层的本发明一个实施例的俯视图。
图2是具有功能材料的一定图形涂层的本发明另一实施例的俯视图。
图3是图1中所示的本发明沿线3-3的放大侧剖图。
图4A-C表示了适用于本发明中的可选棋盘状图形。
具体实施方式
名称表
10   卡片
20   元件阵列
21r  右侧列
21s  左侧列
21i  中间列
30   元件
30r  右侧元件
30s  左侧元件
31   元件的基部部分
32   元件的凸片部分
40   背衬层
50   压敏粘接剂
60   支承层
70   功能材料层
70r  功能材料层的右侧边缘
70s  功能材料层的左侧边缘
71r  在功能材料层的右侧边缘和右侧列之间的空白处
71s  在功能材料层的左侧边缘和左侧列之间的空白处
80   释放衬垫
定义
这里(包括权利要求)使用的术语“片材”的意思是与它的长度和宽度相比较薄的某些物体，通常具有超过100比1的宽高比。
这里(包括权利要求)使用的术语“棋盘格状”的意思是在没有交叠和没有间隙的情况下充满平面的一定图形形状。
这里(包括权利要求)使用的术语“腹板”的意思是连续片材，包括连续卷材和一系列分开的单独片材。
这里(包括权利要求)使用的短语“拉链图形”的意思是具有互相结合元件的一对列。
结构
大致参考图1和2，本发明是一种片材，优选是大约2至4英寸乘以2至6英寸的卡片10，棋盘格状拉链图形或阵列20的相同形状元件30形成于其中。阵列确定了(i)右侧纵向列21r，该右侧纵向列21r包括右侧组元件30r的基部部分31；(ii)左侧纵向列21s，该左侧纵向列21s包括左侧组元件30s的基部部分31；以及(iii)中间纵向列21i，该中间纵向列21i包括交替的右侧30r和左侧30s元件凸片部分32。
元件30可以是任意合适形状，该形状能够形成棋盘状拉链图形或阵列20的相同形状元件30。图1和2中表示了T形元件30。可以使用多种其它形状，其中一些在图4A(泪珠形)、4B(销售标签形)和4C(箭头形)中表示。
参考图3，卡片10包括背衬层40，该背衬层40有涂覆在背衬层40的内侧主表面(未标记)上的一层压敏粘接剂50。
背衬层40可以由能够提供所需结构完整性的基本任意材料来制造，特别是包括但不局限于：纸张、卡片原料、纸板、聚合物板、金属板等。优选的背衬层是卡片材料(主要基于价格)。
粘接剂50可以从能够在合适持续时间中向目标表面提供合适水平粘接的、可广泛获得的压敏粘接剂。一旦获知元件30要粘接的表面的性质和典型方位(例如，PET瓶的竖直布置平滑内表面，持续至少48小时；或者干壁砂纸打磨垫的水平布置粗糙表面，持续至少2小时)，本领域普通技术人员就能够选择合适的粘接剂。
功能材料70的连续纵向条带沿中间列21i的纵向长度来涂覆。这在各元件30上提供了一层功能材料70，该功能材料70限制于右侧30r和左侧30s元件的凸片部分32上。这使得用户能够抓住各元件30的基部部分31，用于从卡片10上取下元件30，并将元件30施加在目标表面(未示出)上，而并不直接接触功能材料70，因此没有污染该功能材料70的危险。功能材料70的条带优选是与右侧21r和左侧21s列横向偏离，以便在功能材料70条带的右侧70r和左侧70s边缘以及元件30的基部部分31之间提供右侧71r和左侧71s空白处。这附加防止由功能材料70不希望地涂覆元件30的基部部分31。
对于某些用途，可能需要或希望首先将功能材料70涂覆在支承层60上，然后将支承层60层叠在粘接剂层50上，同时功能材料70层在支承层60的、背离粘接剂50的暴露主表面(未标记)上。
优选是，提供释放衬垫80，用于可释放地保护粘接剂层50的暴露表面和功能材料70层，防止磨损、撕裂和污染，直到各元件30从卡片10上剥离以便施加在目标表面上。合适的释放衬垫80可由多个源广泛获得。本领域普通技术人员应当能够根据使用的粘接剂50的类型来选择合适的释放衬垫80。
功能材料70可以是在某些确定条件下有可检测和优选是可测量的物理、电或化学变化(例如当暴露于酸性环境中时改变颜色；当暴露于目标分析物中时发出电信号；当暴露于目标分析物中时熄灭荧光；由于当暴露于目标分析物中时产生的发热反应而升高温度等)的任意组分或化合物。本发明特别适合通过使用分析物熄灭荧光化合物(例如基于钌的荧光指示器或者铂或钯卟啉的荧光指示器)作为功能材料70而形成用作照相荧光传感器的元件30。这样的荧光组分为公知的，并可由多种商业源来广泛获得。多种合适的、基于钌的分析物熄灭荧光组分的说明在Oxy-Sence,Inc的国际专利申请公开No.2007/120637中提供。多种合适的、基于铂和钯卟啉的分析物熄灭荧光组分的说明在Luxcel Biosciences Ltd的美国专利申请公开No.20060002822中提供。
制造
卡片10能够通过使用普通腹板线转换处理和技术来层叠背衬层40、粘接剂层50、功能材料70层和释放衬垫80而进行制造。棋盘状拉链图形的元件30能够在转换处理过程中的任意时间切成卡片10，但是最优选是在层完全集成之后来进行，同时从腹板上切割各卡片10。
用途
各元件30(通常称为传感器)能够这样使用，即通过简单弯曲卡片以便使得荧光元件30中的一个荧光元件的拐角(未标记)与释放衬垫80分开；将暴露的拐角捏紧在食指和拇指之间；将元件30从卡片10上剥离；以及将元件30粘接在目标表面上，例如食品容器(未示出)的透明或半透明区域的内侧，同时功能材料70可通过容器(未示出)看见，这样，功能材料70能够由合适仪器(未示出)来阅读。

Claims (14)

1.一种传感器片材，包括：
(a)片材，该片材设置有棋盘格状拉链图形的相同形状元件，该相同形状元件确定了(i)右侧纵向列，该右侧纵向列包括右侧组元件的基部部分；(ii)左侧纵向列，该左侧纵向列包括左侧组元件的基部部分；以及(iii)中间纵向列，该中间纵向列包括交替的右侧和左侧元件凸片部分；以及
(b)功能材料的连续纵向条带，该功能材料的连续纵向条带只在中间列中涂覆在片材上，因此，功能材料层只提供于右侧和左侧元件的凸片部分上。
2.根据权利要求1所述的传感器片材，其中：片材包括至少一个背衬层，且该片材还包括一层压敏粘接剂，以便形成背衬、压敏粘接剂和功能材料的连续层。
3.根据权利要求1所述的传感器片材，其中：左侧和右侧元件是左右交替。
4.根据权利要求1所述的传感器片材，其中：功能材料的条带与右侧和左侧列横向偏离，从而在各元件的凸片部分上在基部部分附近提供了没有功能材料的空白处。
5.根据权利要求1所述的传感器片材，其中：功能材料是分析物可熄灭的照相荧光物质，适合用作分析物传感器。
6.根据权利要求5所述的传感器片材，其中：分析物可熄灭的照相荧光物质是铂卟啉。
7.根据权利要求1所述的传感器片材，其中：功能材料层是完整的覆盖层。
8.一种制造传感器片材的方法，包括：以下步骤
(1)将功能材料的连续纵向条带布置在腹板上；以及
(2)将腹板切成棋盘状拉链图形的元件，以便确定这样的图形，该图形包括：(i)右侧纵向列，该右侧纵向列包括右侧组元件的基部部分；(ii)左侧纵向列，该左侧纵向列包括左侧组元件的基部部分；以及(iii)中间纵向列，该中间纵向列包括交替的右侧和左侧元件凸片部分；其中，功能材料的纵向条带只保持在中间列中，以便只存在于右侧和左侧元件的凸片部分上。
9.根据权利要求8所述的方法，还包括：使得腹板涂敷有一层压敏粘接剂的步骤，其中，该层功能材料通过该层粘接剂而粘附在腹板上。
10.根据权利要求8所述的方法，其中：右侧和左侧元件是左右交替。
11.根据权利要求8所述的方法，其中：功能材料的条带与右侧和左侧列横向偏离，从而在各元件的凸片部分上在基部部分附近提供了没有功能材料的空白处。
12.根据权利要求8所述的方法，其中：功能材料是分析物可熄灭的照相荧光物质，适合用作分析物传感器。
13.根据权利要求12所述的方法，其中：分析物可熄灭的照相荧光物质是铂卟啉。
14.根据权利要求8所述的方法，其中：功能材料层是完整的覆盖层。
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