CN102632623B - Method for preparing carbon-fibre composite material by utilizing silicon rubber bag mold closing process - Google Patents

Method for preparing carbon-fibre composite material by utilizing silicon rubber bag mold closing process Download PDF

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CN102632623B
CN102632623B CN201210021945.2A CN201210021945A CN102632623B CN 102632623 B CN102632623 B CN 102632623B CN 201210021945 A CN201210021945 A CN 201210021945A CN 102632623 B CN102632623 B CN 102632623B
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silicon rubber
resin
rubber bag
fibre composite
mould
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CN102632623A (en
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李祥伟
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Chery Automobile Co Ltd
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SAIC Chery Automobile Co Ltd
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Abstract

The invention relates to a method for preparing a carbon-fibre composite material by utilizing silicon rubber bag mold closing process. The method comprises the following steps of: preparation of a silicon rubber bag film: utilizing silicone rubber and eyelet fabric to prepare the silicone rubber bag film on the surface of a mould for later use; the molding of the carbon-fibre composite material: paving fortifying fibre cloth on the mould, and using the silicone rubber bag film to seal the mould; and pouring of a resin material in an evacuation manner: maintaining the fixed pressure to lead the material molding, and stripping so as to obtain a product after material solidification.

Description

A kind of silicon rubber bag mold closing technique is prepared the method for carbon fibre composite
Technical field
The present invention relates to forming materials field, be specifically related to a kind of method that silicon rubber bag mold closing technique is prepared carbon fibre composite.
Background technology
Molding carbon fiber composite material technique is taking vacuum perfusion process as main at present, its principle is for airtight by mould with plastic vacuum bag film, form mold closing state, by the mode that vacuumizes, resin is imported in mould and fiber composite compressing, this kind of process principle is simple, equipment is not had to demand, but auxiliary material use quantity is large, the vacuum systems auxiliary material used of each preparation all can not be reused, and the process of closed mould is pure manual operation, artifical influence factor is larger, and stability is general.
Summary of the invention
The object of the present invention is to provide a kind of silicon rubber bag mold closing technique to prepare the method for carbon fibre composite, utilize silicon rubber and eyelet fabric to prepare pellosil at die surface stand-by, on mould, complete cloth of reinforcement fibers, mould is sealed with pellosil, the mode perfusion resin that utilization vacuumizes, maintain fixing pressure and make forming materials, after material cured, the demoulding obtains goods.
Concrete technical scheme is as follows:
Silicon rubber bag mold closing technique is prepared a method for carbon fibre composite, adopts following steps:
The preparation of silicon rubber bag film:
(1) utilize silicon rubber and eyelet fabric to prepare silicon rubber bag film at die surface stand-by;
The moulding of carbon fibre composite:
(2) on mould, complete cloth of reinforcement fibers;
(3) with silicon rubber bag film, mould is sealed;
(4) utilize the mode filling resin material vacuumizing;
(5) maintain fixing pressure and make forming materials;
(6) after material cured, the demoulding obtains goods.
Further, step (1) further comprises:
(1-1) die surface processing;
(1-2) pre-buried gum-injecting port and bleeding point;
(1-3) utilize glue rifle that silicon rubber is coated in to die surface uniformly;
(1-4) at silastic surface paving eyelet fabric;
(1-5), at eyelet fabric surface coated silastic, after solidifying, silicon rubber bag film is deviate from stand-by from die surface.
Further, in step (1-1), remove grease and the moisture of die surface with alcohol or acetone, ensure that die surface is clean dry, in step (1-2) at the pre-buried gum-injecting port in mold center position, at the pre-buried bleeding point in die edge position, in step (1-3), utilize glue rifle silicon rubber to be coated in uniformly to the die surface that comprises die edge part, bleeding point and gum-injecting port position need to retain, silicon rubber used is room temperature vulcanized silicone rubber, it is RTV Methyl Silicone Rubber, the two benzene room temperature vulcanized silicone rubbers of methyl, RTV block methyl silicone rubber, one in fluorosioloxane rubber etc., in step (1-4), spread 1-3 layer eyelet fabric or sandwich eyelet fabric at silastic surface, eyelet fabric thickness is 0.5-5mm, eyelet fabric material is terylene, nylon, one or more in cotton, shape of a mesh is triangle, rhombus, hexagon, one or several in circle, in step (1-5) at eyelet fabric surface coated silastic, silicon rubber used is identical with step (1-3), silicon rubber is cold curing, be 5-24h hardening time.
Further, step (2) further comprises:
(2-1) mould pre-treatment: first with acetone or alcohol by mould wiped clean, then play demoulding wax or releasing agent at die surface;
(2-2) join resin, resin is the one in unsaturated-resin or epoxy resin, according to mass ratio: resin and fiber are 1:1-3:1, and unsaturated-resin and curing agent are 100:2-100:4, and epoxy resin and curing agent are 100:20-100:40;
(2-3) laying: the thickness of carbon cloth is 0.3-0.6mm, weaving manner is unidirectional braiding and/or two-way braiding.
Further, step (3) further comprises:
(3-1) the fiber cloth surface paving one deck flow-guiding screen laying;
(3-2) exhaust tube is fixed at die edge one circle;
(3-3) silicone rubber membrane of making is laid on to die surface;
(3-4) at gum-injecting port connection glue injection pipe;
(3-5) reserved silica gel mould bleeding point internal interface is connected with exhaust tube, external interface is connected with resin trap by pipeline, and resin trap is connected with vavuum pump;
(3-6) with sealant tape by the sealing that makes a circle in pellosil week.
Further, step (4) further comprises: open vavuum pump and bleed, vacuum keep, at-0.05--0.1Mpa, is discharged gas in mould, then imported resin from resin ingress pipe, completely with after fiber cloth infiltration stops vacuumizing until resin.
Further, step (5) further comprises: resin ingress pipe and vacuum-pumping tube sealing pressurize is waited for and being solidified, and unsaturated-resin hardening time is normal temperature 2-10h, and epoxy resin cure temperature is 60-180 DEG C, and the time is 8-24h.
Further, step (6) further comprises: open pellosil goods are taken out, prune the burr of limit portion, at product surface lacquer varnish.
Further, silicone rubber membrane is reused.
Further, be applied to automobile, ship domain.
Compared with currently available technology, the present invention can process simplification, reduce production costs, improve the quality of products, silicone rubber membrane replaces plastic vacuum bag, can reuse, greatly reduce auxiliary material waste, silicone rubber membrane can be made the various structures identical with die surface, is beneficial to formed product simple to operate in the time of closed mould, simplify processing step, improve the quality of products and stability
Detailed description of the invention
Describe the present invention below, it is a kind of preferred embodiment in numerous embodiments of the present invention.
One, the preparation of silicon rubber bag film
1, die surface processing, with grease and the moisture of alcohol or acetone removing die surface, ensures that die surface is clean dry;
2, pre-buried gum-injecting port and bleeding point, at the pre-buried gum-injecting port in mold center position, at the pre-buried bleeding point in die edge position.
3, utilize glue rifle that silicon rubber is coated in to die surface uniformly, comprise die edge part, notice that bleeding point and gum-injecting port position need to retain, silicon rubber used is room temperature vulcanized silicone rubber, can be the one in the two benzene room temperature vulcanized silicone rubbers of RTV Methyl Silicone Rubber, methyl, RTV block methyl silicone rubber, fluorosioloxane rubber etc.
4, silastic surface paving 1---3 layers of eyelet fabric or sandwich eyelet fabric, eyelet fabric thickness is 0.5---5mm, eyelet fabric material is one or more in terylene, nylon, cotton, shape of a mesh can be one or several in triangle, rhombus, hexagon, circle, and the effect of eyelet fabric is to increase silica gel bag film strength and toughness.
5, at eyelet fabric surface coated silastic, silicon rubber used is identical with step 3, and silicon rubber is cold curing, and be 5 hardening time---and 24h, deviates from stand-by by silicon rubber bag film after solidifying from die surface.
Two, molding carbon fiber composite material
1, mould pre-treatment, first with acetone or alcohol by mould wiped clean, then play demoulding wax or releasing agent at die surface, demoulding wax or releasing agent are coated with 2---4 times, after each painting dry 3---10min, then carry out operation next time;
2, join resin, resin can be the one in unsaturated-resin or epoxy resin, the mass ratio of resin and fiber is 1:1---3:1, and the ratio of unsaturated-resin and curing agent is 100:2---100:4, and the ratio of epoxy resin and curing agent is 100:20---100:40;
3, laying, the thickness of carbon cloth can select 0.3---0.6mm, weaving manner can be unidirectional braiding, two-way braiding, first fiber cloth is placed on to 60 before laying---toasting 30 under 80 DEG C of environment---100min, object is to remove moisture, is conducive to the abundant infiltration of resin compound.Select suitable fiber thickness and the number of plies according to the thickness of product.
4, make vacuum mould closing process conditions, the fiber cloth surface paving one deck flow-guiding screen first laying, flow-guiding screen is the effect of accelerating resin flows, be conducive to the infiltration of resin and fiber cloth, exhaust tube is fixed at die edge one circle, the silicone rubber membrane of making is laid on to die surface, the shape of noting silicone rubber membrane is corresponding with the shape of mould neat, at gum-injecting port connection glue injection pipe, reserved silica gel mould bleeding point internal interface is connected with exhaust tube, external interface is connected with resin trap by pipeline, and resin trap is connected with vavuum pump;
Finally with sealant tape by the sealing that makes a circle in pellosil week;
5, import resin, vacuum pressing moulding, open vavuum pump and bleed, vacuum keep is-0.05---and-0.1Mpa, discharges gas in mould, import resin from resin ingress pipe again, after resin infiltrates with fiber cloth completely, stop vacuumizing, now resin ingress pipe and vacuum-pumping tube sealing pressurize are waited for curingly, unsaturated-resin hardening time is normal temperature 2---10h, epoxy resin cure temperature is 60---180 DEG C, the time is 8---and 24h;
6, the demoulding, surface treatment, opens pellosil goods is taken out, and prunes the burr of limit portion, at product surface lacquer varnish.
Silicone rubber membrane can be reused.
Above process can be applied to the field such as automobile, boats and ships.
Example 1:
One, the preparation of silicon rubber bag film
1, die surface processing, with grease and the moisture of alcohol removing die surface, ensures that die surface is clean dry;
2, pre-buried gum-injecting port and bleeding point, at the pre-buried gum-injecting port in mold center position, at the pre-buried bleeding point in die edge position.
3, utilize glue rifle that silicon rubber is coated in to die surface uniformly, comprise die edge part, notice that bleeding point and gum-injecting port position need to retain, silicon rubber used is RTV Methyl Silicone Rubber.
4, at 1 layer of eyelet fabric of silastic surface paving, eyelet fabric thickness is 1mm, and eyelet fabric material is terylene, and shape of a mesh is circular, and the effect of eyelet fabric is to increase silica gel bag film strength and toughness.
5, at eyelet fabric surface coated silastic, silicon rubber used is identical with step 3, and silicon rubber is cold curing, and be 8h hardening time, after solidifying, silicon rubber bag film is deviate from stand-by from die surface.
Two, molding carbon fiber composite material
1, mould pre-treatment, first with ethanol by mould wiped clean, then play demoulding wax 2 times at die surface, dry 3min after each painting, then carry out operation next time;
2, join resin, select unsaturated polyester resin, the mass ratio of resin and fiber is 1:1, and the ratio of unsaturated-resin and curing agent is 100:2;
3, laying, the thickness of carbon cloth is 0.6mm, and weaving manner is unidirectional braiding, before laying, first fiber cloth is placed under 70 DEG C of environment and toasts 30min, and object is to remove moisture, is conducive to the abundant infiltration of resin compound.Select suitable fiber thickness and the number of plies according to the thickness of product.
4, make vacuum mould closing process conditions, the fiber cloth surface paving one deck flow-guiding screen first laying, flow-guiding screen is the effect of accelerating resin flows, be conducive to the infiltration of resin and fiber cloth, exhaust tube is fixed at die edge one circle, the silicone rubber membrane of making is laid on to die surface, the shape of noting silicone rubber membrane is corresponding with the shape of mould neat, at gum-injecting port connection glue injection pipe, reserved silica gel mould bleeding point internal interface is connected with exhaust tube, external interface is connected with resin trap by pipeline, and resin trap is connected with vavuum pump;
Finally with sealant tape by the sealing that makes a circle in pellosil week;
5, import resin, vacuum pressing moulding, opening vavuum pump bleeds, vacuum keep is at-0.05Mpa, gas in mould is discharged, then import resin from resin ingress pipe, completely and after fiber cloth infiltration stop vacuumizing until resin, now resin ingress pipe and vacuum-pumping tube sealing pressurize is waited for and being solidified, unsaturated-resin hardening time is normal temperature 5h;
6, the demoulding, surface treatment, opens pellosil goods is taken out, and prunes the burr of limit portion, at product surface lacquer varnish.
Silicone rubber membrane can be reused.
Example 2:
One, the preparation of silicon rubber bag film
1, die surface processing, with grease and the moisture of acetone removing die surface, ensures that die surface is clean dry;
2, pre-buried gum-injecting port and bleeding point, at the pre-buried gum-injecting port in mold center position, at the pre-buried bleeding point in die edge position.
3, utilize glue rifle that silicon rubber is coated in to die surface uniformly, comprise die edge part, notice that bleeding point and gum-injecting port position need to retain, silicon rubber used is the two benzene room temperature vulcanized silicone rubbers of methyl.
4, at 2 layers of eyelet fabric of silastic surface paving, eyelet fabric thickness is 0.5mm and 2mm, and eyelet fabric material is respectively cotton and nylon, and shape of a mesh is hexagon, and the effect of eyelet fabric is to increase silica gel bag film strength and toughness.
5, at eyelet fabric surface coated silastic, silicon rubber used is identical with step 3, and silicon rubber is cold curing, and be 18h hardening time, after solidifying, silicon rubber bag film is deviate from stand-by from die surface.
Two, molding carbon fiber composite material
1, mould pre-treatment, first with ethanol by mould wiped clean, then play releasing agent 3 times at die surface, dry 5min after each painting, then carry out operation next time;
2, join resin, select epoxy resin, the mass ratio of resin and fiber is 2:1, and the ratio of resin and curing agent is 100:30;
3, laying, the thickness of carbon cloth is 0.35mm, and weaving manner is two-way braiding, before laying, first fiber cloth is placed under 90 DEG C of environment and toasts 20min, and object is to remove moisture, is conducive to the abundant infiltration of resin compound.Select suitable fiber thickness and the number of plies according to the thickness of product.
4, make vacuum mould closing process conditions, the fiber cloth surface paving one deck flow-guiding screen first laying, flow-guiding screen is the effect of accelerating resin flows, be conducive to the infiltration of resin and fiber cloth, exhaust tube is fixed at die edge one circle, the silicone rubber membrane of making is laid on to die surface, the shape of noting silicone rubber membrane is corresponding with the shape of mould neat, at gum-injecting port connection glue injection pipe, reserved silica gel mould bleeding point internal interface is connected with exhaust tube, external interface is connected with resin trap by pipeline, and resin trap is connected with vavuum pump;
Finally with sealant tape by the sealing that makes a circle in pellosil week;
5, import resin, vacuum pressing moulding, opening vavuum pump bleeds, vacuum keep, at-0.075Mpa, is discharged gas in mould, then is imported resin from resin ingress pipe, completely and after fiber cloth infiltration stop vacuumizing until resin, now resin ingress pipe and vacuum-pumping tube sealing pressurize wait are solidified, epoxy resin cure temperature is 100 DEG C, and the time is 8.5h;
6, the demoulding, surface treatment, opens pellosil goods is taken out, and prunes the burr of limit portion, at product surface lacquer varnish.
Silicone rubber membrane can be reused.
Above the present invention is exemplarily described; obviously specific implementation of the present invention is not subject to the restrictions described above; as long as the various improvement that adopted method of the present invention design and technical scheme to carry out, or directly apply to other occasion without improvement, all within protection scope of the present invention.

Claims (7)

1. silicon rubber bag mold closing technique is prepared a method for carbon fibre composite, it is characterized in that, adopts following steps:
The preparation of silicon rubber bag film:
(1) utilize silicon rubber and eyelet fabric to prepare silicon rubber bag film at die surface stand-by;
(1-1) die surface processing, with grease and the moisture of alcohol or acetone removing die surface, ensures that die surface is clean dry;
(1-2) pre-buried gum-injecting port and bleeding point, at the pre-buried gum-injecting port in mold center position, at the pre-buried bleeding point in die edge position;
(1-3) utilize glue rifle that silicon rubber is coated in to die surface uniformly, utilize glue rifle silicon rubber to be coated in uniformly to the die surface that comprises die edge part, bleeding point and gum-injecting port position need to retain, silicon rubber used is room temperature vulcanized silicone rubber, and it is the one in the two benzene room temperature vulcanized silicone rubbers of RTV Methyl Silicone Rubber, methyl, RTV block methyl silicone rubber, fluorosioloxane rubber etc.;
(1-4) at silastic surface paving eyelet fabric, at silastic surface paving 1-3 layer eyelet fabric or sandwich eyelet fabric, eyelet fabric thickness is 0.5-5mm, eyelet fabric material is one or more in terylene, nylon, cotton, and shape of a mesh is one or several in triangle, rhombus, hexagon, circle;
(1-5) at eyelet fabric surface coated silastic, after solidifying, silicon rubber bag film to be deviate from stand-by from die surface, silicon rubber used is identical with step (1-3), and silicon rubber is cold curing, and be 5-24h hardening time;
The moulding of carbon fibre composite:
(2) on mould, complete cloth of reinforcement fibers;
(3) with silicon rubber bag film, mould is sealed;
(4) utilize the mode filling resin material vacuumizing;
(5) maintain fixing pressure and make forming materials;
(6) after material cured, the demoulding obtains goods.
2. silicon rubber bag mold closing technique as claimed in claim 1 is prepared the method for carbon fibre composite, it is characterized in that, step (2) further comprises:
(2-1) mould pre-treatment: first with acetone or alcohol by mould wiped clean, then play demoulding wax or releasing agent at die surface;
(2-2) join resin, resin is the one in unsaturated-resin or epoxy resin, according to mass ratio: resin and fiber are 1: 1-3: 1, unsaturated-resin and curing agent are 100: 2-100: 4, epoxy resin and curing agent are 100: 20-100: 40;
(2-3) laying: the thickness of carbon cloth is 0.3-0.6mm, weaving manner is unidirectional braiding and/or two-way braiding.
3. silicon rubber bag mold closing technique as claimed in claim 1 or 2 is prepared the method for carbon fibre composite, it is characterized in that, step (3) further comprises:
(3-1) the fiber cloth surface paving one deck flow-guiding screen laying;
(3-2) exhaust tube is fixed at die edge one circle;
(3-3) silicone rubber membrane of making is laid on to die surface;
(3-4) at gum-injecting port connection glue injection pipe;
(3-5) reserved silica gel mould bleeding point internal interface is connected with exhaust tube, external interface is connected with resin trap by pipeline, and resin trap is connected with vavuum pump;
(3-6) with sealant tape by the sealing that makes a circle in pellosil week.
4. silicon rubber bag mold closing technique as claimed in claim 1 or 2 is prepared the method for carbon fibre composite, it is characterized in that, step (5) further comprises: resin ingress pipe and vacuum-pumping tube sealing pressurize are waited for curing, unsaturated-resin hardening time is normal temperature 2-10h, epoxy resin cure temperature is 60-180 DEG C, and the time is 8-24h.
5. silicon rubber bag mold closing technique as claimed in claim 1 or 2 is prepared the method for carbon fibre composite, it is characterized in that, step (6) further comprises: open pellosil goods are taken out, prune the burr of limit portion, at product surface lacquer varnish.
6. silicon rubber bag mold closing technique as claimed in claim 1 or 2 is prepared the method for carbon fibre composite, it is characterized in that, silicone rubber membrane is reused.
7. silicon rubber bag mold closing technique as claimed in claim 1 or 2 is prepared the method for carbon fibre composite, it is characterized in that, is applied to automobile, ship domain.
CN201210021945.2A 2012-01-31 2012-01-31 Method for preparing carbon-fibre composite material by utilizing silicon rubber bag mold closing process Active CN102632623B (en)

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CN105216344B (en) * 2015-09-15 2018-07-27 江苏金风科技有限公司 Vacuum infusion molding process for compound
CN105568586B (en) * 2015-12-08 2017-07-25 江南大学 Mesh fabric surface is coated the equipment and painting method of processing
CN106166846A (en) * 2016-09-26 2016-11-30 肇庆福田化学工业有限公司 Automatization's vacuum imports former
CN106584884B (en) * 2016-11-22 2018-09-07 昌河飞机工业(集团)有限责任公司 A method of carrying out carbon one-way tape forming parts using auxiliary lining mould
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