CN102627746B - 一种阳离子无皂聚合物akd中/碱性施胶剂的制备方法 - Google Patents
一种阳离子无皂聚合物akd中/碱性施胶剂的制备方法 Download PDFInfo
- Publication number
- CN102627746B CN102627746B CN201210136197.2A CN201210136197A CN102627746B CN 102627746 B CN102627746 B CN 102627746B CN 201210136197 A CN201210136197 A CN 201210136197A CN 102627746 B CN102627746 B CN 102627746B
- Authority
- CN
- China
- Prior art keywords
- grams
- akd
- mass ratio
- hours
- add
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000004513 sizing Methods 0.000 title claims abstract description 83
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 59
- 238000002360 preparation method Methods 0.000 title claims abstract description 22
- -1 alkyl ketene Chemical compound 0.000 title abstract description 4
- 125000002091 cationic group Chemical group 0.000 title abstract description 3
- 239000003513 alkali Substances 0.000 title abstract 3
- 230000007935 neutral effect Effects 0.000 title abstract 3
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 80
- 229920000642 polymer Polymers 0.000 claims abstract description 50
- 239000000839 emulsion Substances 0.000 claims abstract description 49
- 239000003999 initiator Substances 0.000 claims abstract description 43
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 31
- IVKNZCBNXPYYKL-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[4-(2,4,4-trimethylpentan-2-yl)phenoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 IVKNZCBNXPYYKL-UHFFFAOYSA-N 0.000 claims abstract description 29
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 29
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims abstract description 18
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 16
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims abstract description 15
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 15
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims abstract description 15
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 claims abstract description 15
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims abstract description 15
- 238000002156 mixing Methods 0.000 claims description 49
- 150000001768 cations Chemical class 0.000 claims description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 40
- 239000008367 deionised water Substances 0.000 claims description 32
- 229910021641 deionized water Inorganic materials 0.000 claims description 32
- 238000006243 chemical reaction Methods 0.000 claims description 30
- 229960000583 acetic acid Drugs 0.000 claims description 28
- 239000007787 solid Substances 0.000 claims description 28
- 238000010792 warming Methods 0.000 claims description 28
- 239000003643 water by type Substances 0.000 claims description 24
- 238000013019 agitation Methods 0.000 claims description 14
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 14
- 238000007599 discharging Methods 0.000 claims description 14
- 238000001914 filtration Methods 0.000 claims description 14
- 238000009413 insulation Methods 0.000 claims description 14
- 238000002844 melting Methods 0.000 claims description 14
- 230000008018 melting Effects 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 14
- 150000000211 1-dodecanols Chemical class 0.000 claims description 12
- 239000004160 Ammonium persulphate Substances 0.000 claims description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 5
- 238000004945 emulsification Methods 0.000 abstract description 4
- 230000014759 maintenance of location Effects 0.000 abstract description 3
- 239000002245 particle Substances 0.000 abstract description 3
- 230000002378 acidificating effect Effects 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 230000001804 emulsifying effect Effects 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000003381 stabilizer Substances 0.000 abstract description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 abstract 1
- 235000011130 ammonium sulphate Nutrition 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- 239000012747 synergistic agent Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 8
- 239000007844 bleaching agent Substances 0.000 description 7
- 239000011436 cob Substances 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 7
- 239000000835 fiber Substances 0.000 description 6
- 238000006460 hydrolysis reaction Methods 0.000 description 6
- 230000007062 hydrolysis Effects 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 description 1
- 241000202567 Fatsia japonica Species 0.000 description 1
- 206010016590 Fibrin deposition on lens postoperative Diseases 0.000 description 1
- 241000533901 Narcissus papyraceus Species 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Paper (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210136197.2A CN102627746B (zh) | 2012-05-04 | 2012-05-04 | 一种阳离子无皂聚合物akd中/碱性施胶剂的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210136197.2A CN102627746B (zh) | 2012-05-04 | 2012-05-04 | 一种阳离子无皂聚合物akd中/碱性施胶剂的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102627746A CN102627746A (zh) | 2012-08-08 |
CN102627746B true CN102627746B (zh) | 2014-01-29 |
Family
ID=46586157
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201210136197.2A Expired - Fee Related CN102627746B (zh) | 2012-05-04 | 2012-05-04 | 一种阳离子无皂聚合物akd中/碱性施胶剂的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN102627746B (zh) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103410050B (zh) * | 2013-07-09 | 2015-11-25 | 上海东升新材料有限公司 | 表面施胶剂乳液及其制备方法和应用 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101649581A (zh) * | 2009-09-01 | 2010-02-17 | 陕西科技大学 | 两性高分子基akd乳液的制备方法 |
CN101649584A (zh) * | 2009-09-01 | 2010-02-17 | 陕西科技大学 | 一种二次纤维纸用表面涂布增强剂的制备方法 |
-
2012
- 2012-05-04 CN CN201210136197.2A patent/CN102627746B/zh not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101649581A (zh) * | 2009-09-01 | 2010-02-17 | 陕西科技大学 | 两性高分子基akd乳液的制备方法 |
CN101649584A (zh) * | 2009-09-01 | 2010-02-17 | 陕西科技大学 | 一种二次纤维纸用表面涂布增强剂的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN102627746A (zh) | 2012-08-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102660897B (zh) | 一种高分散阳离子akd中/碱性施胶剂的制备方法 | |
CN102627732B (zh) | 一种高活性半交联akd中/碱性施胶剂的制备方法 | |
CN102635021B (zh) | 一种高反应活性阳离子akd中/碱性施胶剂的制备方法 | |
CN102635033B (zh) | 一种无施胶滞后蜂蜡/akd中/碱性施胶剂的制备方法 | |
CN102627746B (zh) | 一种阳离子无皂聚合物akd中/碱性施胶剂的制备方法 | |
CN102627737B (zh) | 一种高分散akd中/碱性施胶剂的制备方法 | |
CN102627735B (zh) | 一种高分散阳离子半交联akd中/碱性施胶剂的制备方法 | |
CN102660896B (zh) | 一种氧化聚乙烯蜡/akd中/碱性施胶剂的制备方法 | |
CN102627734B (zh) | 一种无施胶滞后两性akd中/碱性施胶剂的制备方法 | |
CN102660895A (zh) | 一种高效akd中/碱性施胶剂的制备方法 | |
CN102627745B (zh) | 一种高反应活性聚合物akd中/碱性施胶剂的制备方法 | |
CN102660894A (zh) | 一种阳离子akd中/碱性施胶剂的制备方法 | |
CN102635020B (zh) | 一种反应性乳化剂聚合物akd中/碱性施胶剂的制备方法 | |
CN102635024B (zh) | 一种无皂阳离子聚合物akd中/碱性施胶剂的制备方法 | |
CN102660903B (zh) | 一种无皂聚合物阳离子akd中/碱性施胶剂的制备方法 | |
CN102635025B (zh) | 一种两性玉米淀粉akd中/碱性施胶剂的制备方法 | |
CN102635015B (zh) | 一种阳离子高分散半交联akd中/碱性施胶剂的制备方法 | |
CN102660898B (zh) | 一种高分散半交联akd中/碱性施胶剂的制备方法 | |
CN102635026B (zh) | 一种无施胶熟化期akd中/碱性施胶剂的制备方法 | |
CN102635036B (zh) | 一种两性红薯淀粉akd中/碱性施胶剂的制备方法 | |
CN102635022B (zh) | 一种高活性地蜡/akd中/碱性施胶剂的制备方法 | |
CN102635023A (zh) | 一种阳离子聚合物akd中/碱性施胶剂的制备方法 | |
CN102627733B (zh) | 一种高活性半交联两性akd中/碱性施胶剂的制备方法 | |
CN102627739B (zh) | 一种高活性两性akd中/碱性施胶剂的制备方法 | |
CN102660902B (zh) | 一种高活性akd中/碱性施胶剂的制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20201224 Address after: 518000 No.6 Qinglong Road, Qinglong Road, Qinghua community, Longhua street, Longhua District, Shenzhen City, Guangdong Province Patentee after: Shenzhen Pengbo Information Technology Co.,Ltd. Address before: 710021 Shaanxi province Xi'an Weiyang university campus of Shaanxi University of Science and Technology Patentee before: SHAANXI University OF SCIENCE & TECHNOLOGY Effective date of registration: 20201224 Address after: 224000 Qingyang Road (within Qingdun Office), Nanyang Town, Tinghu District, Yancheng City, Jiangsu Province (8) Patentee after: Yancheng Qinglong Jinbang water Co.,Ltd. Address before: 518000 No.6 Qinglong Road, Qinglong Road, Qinghua community, Longhua street, Longhua District, Shenzhen City, Guangdong Province Patentee before: Shenzhen Pengbo Information Technology Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140129 |
|
CF01 | Termination of patent right due to non-payment of annual fee |