CN102626101A - Efficient insecticidal composition containing cyflumetofen - Google Patents
Efficient insecticidal composition containing cyflumetofen Download PDFInfo
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- CN102626101A CN102626101A CN2012100929127A CN201210092912A CN102626101A CN 102626101 A CN102626101 A CN 102626101A CN 2012100929127 A CN2012100929127 A CN 2012100929127A CN 201210092912 A CN201210092912 A CN 201210092912A CN 102626101 A CN102626101 A CN 102626101A
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- Prior art keywords
- mite ester
- fluorine mite
- fluorine
- bifenazate
- instance
- Prior art date
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- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- ZJRCIQAMTAINCB-UHFFFAOYSA-N benzoylacetonitrile Chemical class N#CCC(=O)C1=CC=CC=C1 ZJRCIQAMTAINCB-UHFFFAOYSA-N 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
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- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940043237 diethanolamine Drugs 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N dimethylmethane Natural products CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
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- 229930195729 fatty acid Natural products 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000003958 fumigation Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
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- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 238000003197 gene knockdown Methods 0.000 description 1
- 230000012447 hatching Effects 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
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- 235000019426 modified starch Nutrition 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- OWIUPIRUAQMTTK-UHFFFAOYSA-M n-aminocarbamate Chemical compound NNC([O-])=O OWIUPIRUAQMTTK-UHFFFAOYSA-M 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
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- 244000144977 poultry Species 0.000 description 1
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- 239000001294 propane Substances 0.000 description 1
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an efficient insecticidal composition containing cyflumetofen, which is an insecticidal composition containing an active ingredient A and an active ingredient B, wherein the active ingredient A is selected from the cyflumetofen; the active ingredient B is selected from any one of the following compounds including azocyclotin, bifenazate, fenbutatin oxide and fenpropathrin; and the weight ratio of the active ingredient A to the active ingredient B is 1:70-70:1. The invention has the beneficial effects that the composition has the synergistic effects on pests on wheat, cotton, fruit trees, vegetables and tea trees; the pesticide consumption is reduced, the residual amount of pesticides on crops is reduced, and the environmental contamination is reduced; the safety of human beings and livestock is ensured, the environmental compatibility is good, and the resistance to the pesticides is not easily generated; and a preparation is enhanced in adhesive force and is resistant to rainwater erosion.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of efficient insecticide composition that contains fourth fluorine mite ester.
Background technology
[0002] fourth fluorine mite ester (Cyflumetofen) molecular formula: C
24H
24F
3NO
4, fourth fluorine mite ester is the novel miticide of benzoyl acetonitrile class, does not have cross resistance with existing insecticide; Fourth fluorine mite ester stops the hatching effect of two spotted spider mite ovum lower; But its each vegetative stage is all had very high activity, and especially the activity to young mite is higher, to ovum, become mite, young mite, phase I if mite, second stage are if mite all has greater activity; Simultaneously each plant species all there is not poisoning, all fool proof to non-target organisms such as mammal and aquatile, beneficial organism, natural enemies.
Azacyclotin (azocyclotin) chemical name: 1-(three cyclohexyl stannyls)-1-hydrogen-1,2,4-triazole, molecular formula C
20H
35N
3Sn, azacyclotin are the stronger broad spectrum activity miticide of action of contace poison, can kill if mite, one-tenth mite and summer egg are invalid to winter egg; Light and rainwater are had stability preferably, and the longevity of residure is longer; Under typical concentrations to crop safety.
Bifenazate (bifenazate) chemical name: isopropyl-3-(4-methoxyl biphenyl-3-yl) hydrazinecarboxylate, molecular formula C
17H
20N
2O
3, Bifenazate is that a kind of new selective foliar spray is used miticide, and is effective to each life stage of mite.Have ovicidal activity and knock down activity rapidly what become mite, minimum to the predacious mite influence, be very suitable for the comprehensive regulation of insect, plant is not poisoned.
Fenbutatin oxide (fenbutatin oxide) chemical name: two [three 2-methyl-phenyl propyl) tin] oxide, molecular formula: C
60H
78OSn
2, fenbutatin oxide is a kind of non-internal-absorting miticide, has the harmful mite of resistance that it is not produced cross resistance to organic phosphor and organochlorine.Is main to the evil mite to tag, and initial virulence is slow behind the spray medicine, and activity begins to increase after 3 days, peaks by 14 days.This medicine longevity of residure is grow in the miticide a kind of; Can reach 2-5 month; To young mite with become, if the lethality of mite is stronger, but little to the lethality of ovum, use all very safe each vegetative period crop; Use above effectively killing mite concentration and all do not see have poisoning to take place for one times, very little to evil mite natural enemy as preying on influences such as mite, wooden dipper first and Chrysopa.When temperature active reduction the below 22 ℃, it is lower to be lower than 15 ℃ of drug effects, should not use winter.Fenpropathrin (fenpropathrin) chemical name: alpha-cyano-3-phenoxy benzyl-2,2,3,3-tetramethyl-ring propane carbonyl acid ester, chemical formula: C
22H
23NO
3, fenpropathrin is a kind of pyrethroid insecticides, and insecticidal spectrum is wide, and the longevity of residure is long, and it is its maximum characteristics that multiple tetranychid is had good result, but these article are not inhaled in having, fumigation action.
In the real process of agricultural production, the problem that pest control is easy to generate most is drug-fast generation.The different cultivars composition carries out composite, is the very common method of control resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals all is an additive effect, and the seldom composite of synergistic effect really arranged, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Test discovery in a large number through the inventor, after fourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, fenpropathrin were composite, synergistic effect was remarkable, and Environmental compatibility is fabulous, has greatly reduced the agricultural chemicals dosage.
Summary of the invention
Summary of the invention [0003]Fourth fluorine mite ester, azacyclotin, Bifenazate, fenbutatin oxide, the long-term use of fenpropathrin list agent possibly bring degradation problem under resistance generation, the drug effect; The Pesticidal combination that the present invention proposes contains active components A, active component B, and an amount of surfactant and carrier.
A kind of efficient insecticide composition that contains fourth fluorine mite ester; Contain active components A and active component B; It is characterized in that: active components A and active component B weight ratio are 1 ︰, 70 ~ 70 ︰ 1; Described active components A is selected from fourth fluorine mite ester, and active component B is selected from a kind of in azacyclotin, Bifenazate, fenbutatin oxide, the fenpropathrin, and active components A and the preferred weight ratio of active component B are 1 ︰, 45 ~ 45 ︰ 1; More preferably the weight ratio of fourth fluorine mite ester and azacyclotin is 1 ︰, 30 ~ 20 ︰ 1; Fourth fluorine mite ester and Bifenazate weight ratio are 1 ︰, 30 ~ 20 ︰ 1; The weight ratio of fourth fluorine mite ester and fenbutatin oxide is 1 ︰, 30 ~ 20 ︰ 1, and the weight ratio of fourth fluorine mite ester and fenpropathrin is 1 ︰, 10 ~ 10 ︰ 1.
The described formulation that contains the Pesticidal combination of fourth fluorine mite ester is wetting powder or water dispersible granules or suspending agent or suspension emulsion or aqueous emulsion or microemulsion or microcapsule suspending agent or microcapsules suspension-suspending agent.
The purposes that the described Pesticidal combination that contains fourth fluorine mite ester is used to prevent and treat insect on wheat, cotton, fruit tree, vegetables, the tea tree.
Described purposes; It is characterized in that described insect comprises: tetranychid, Tetranychus urticae, tetranychus viennensis, Panonychus citri, wheat leaf pawl mite, phyllocoptruta oleivora, yellow tea mite, Tetranychus cinnabarinus, beginning tetranychid, two spotted spider mite, yellow spider, rust mite, blister mite, pear sucker, oystershell scale.
The weight ratio of active components A, active component B is 1 ︰, 70 ~ 70 ︰ 1.Usually the weight percentage of active component is 0.5%～90% of a gross weight in the composition, and preferable is 5%～80%.According to different preparation types, the active component content scope is different.Usually, liquid preparation contains 0.5%～70% active substance by weight, preferably is 5%～50%; Solid pharmaceutical preparation contains 5%～80% active substance by weight, preferably is 10%～80%.
At least contain a kind of surfactant in the Pesticidal combination of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 5%～30% of a total formulation weight amount, and surplus is solid or liquid diluent.
The surfactant that Pesticidal combination of the present invention is selected for use is known in those skilled in the art: can be selected from dispersant, wetting agent, binding agent or the antifoaming agent one or more.According to different dosage form, can also contain disintegrant known in those skilled in the art, antifreeze etc. in the preparation.
Composition of the present invention can be by the user before use through dilution or directly use.Its preparation can be by common processing method preparation known in those skilled in the art; Be about to active substance and after liquid flux or solid carrier mix, add in surfactant such as dispersant, stabilizing agent, wetting agent, binding agent, the antifoaming agent etc. one or more again.
Pesticidal combination of the present invention; Can be processed into acceptable forms on any agricultural chemicals on demand, wherein more excellent formulation is: wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsules suspension-suspending agent.
When processing wetting powder, composition comprises following constituent content: active components A 1% ~ 70%, active component B 1% ~ 70%, dispersant 2% ~ 10%, wetting agent 2% ~ 10%, filler surplus.
When processing water dispersible granules, composition comprises following constituent content: active components A 1% ~ 70%, active component B 1% ~ 70%, dispersant 3% ~ 12%, wetting agent 1% ~ 8%, disintegrant 1% ~ 10%, binding agent 0% ~ 4%, filler surplus.
Comprise following constituent content when composition is processed suspending agent: active components A 1% ~ 50%, active component B 1% ~ 50%, dispersant 2% ~ 10%, wetting agent 2% ~ 10%, antifoaming agent 0.1% ~ 1%, thickener 0.05% ~ 2%, antifreeze 0 ~ 8%, deionized water add to 100%.
Comprise following constituent content when composition is processed suspension emulsion: active components A 0.5% ~ 50%, active component B 0.5% ~ 50%, dispersant 2% ~ 10%, antifoaming agent 0.1% ~ 2%, solvent 0% ~ 15%, thickener 0.05% ~ 2%, emulsifier 2% ~ 12%, antifreeze 0% ~ 8%, stabilizing agent 0% ~ 3%, deionized water add to 100%.
Comprise following constituent content when composition is processed aqueous emulsion: active components A 0.5% ~ 50%, active component B 0.5% ~ 50%, solvent 0% ~ 30%, emulsifier 1% ~ 15%, antifreeze 0% ~ 8%, thickener 0.05% ~ 2%, antifoaming agent 0.1% ~ 2%, deionized water are supplied surplus.
Comprise following constituent content when composition is processed microemulsion: active components A 0.5% ~ 50%, active component B 0.5% ~ 50%, solvent 0% ~ 30%, emulsifier 3% ~ 20%, antifreeze 0% ~ 8%, thickener 0.05% ~ 2%, antifoaming agent 0.1% ~ 2%, stabilizing agent 0% ~ 4%, deionized water is supplied surplus.
Comprise following constituent content when composition is processed microcapsule suspending agent: active components A 0.5% ~ 50%, active component B 0.5% ~ 50%, macromolecule cyst material 2% ~ 10%, dispersant 1% ~ 10%, organic solvent 0% ~ 10%, emulsifier 1% ~ 7%, pH regulator agent 1% ~ 5%, deionized water add to 100%.
Composition comprises following constituent content when processing microcapsule suspension-suspending agent: active components A 0.5% ~ 50%, active component B 0.5% ~ 50%, macromolecule cyst material 2% ~ 12%, surfactant 3% ~ 15%, organic solvent 1% ~ 5%, emulsifier 1% ~ 6%, antifoaming agent 0.1% ~ 2%, thickener 0.05% ~ 2%, pH regulator agent 1% ~ 5%, deionized water add to 100%.
Wetting powder the key technical indexes of the present invention:
| Technical indicator | Dispersed | Suspensibility | The moistening time | Fineness (through 45 μ m testing sieves) | Water content |
| All instances of the present invention | ≥90% | ≥90% | <=90 seconds | ≥98% | ≤2% |
| The Pesticidal products specification requirement | ≥80% | ≥80% | <=120 seconds | ≥95% | ≤3% |
Water dispersible granules the key technical indexes of the present invention:
| Technical indicator | Dispersed | Suspensibility | The moistening time | Fineness (through 55 μ m testing sieves) | Water content |
| All instances of the present invention | ≥90% | ≥90% | <=80 seconds | ≥99% | ≤1.5% |
| The Pesticidal products specification requirement | ≥80% | ≥80% | <=120 seconds | ≥95% | ≤3% |
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
| Technical indicator | Suspensibility | Lasting foaming characteristic (after 1 minute) | Topple over the back residue | Heat storage (50 ℃) stability (active ingredient resolution ratio) | Low temperature (0 ℃) stability (educt volume) |
| All instances of the present invention | ≥95% | ≤20ml | ≤3% | ≤3% | ≤0.1ml |
| The Pesticidal products specification requirement | ≥80% | ≤25ml | ≤5% | ≤5% | ≤0.3ml |
Aqueous emulsion the key technical indexes of the present invention:
| Technical indicator | Lasting foaming characteristic (after 1 minute) | Stability of emulsion | Topple over the back residue | Heat storage (50 ℃) stability (active ingredient resolution ratio) | Low temperature (0 ℃) stability (educt volume) |
| All instances of the present invention | ≤20ml | Well | ≤1% | ≤3% | ≤0.1ml |
| The Pesticidal products specification requirement | ≤25ml | Qualified | ≤3% | ≤5% | ≤0.3ml |
Microemulsion the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension of the present invention-suspending agent the key technical indexes:
The invention has the advantages that:
(1) fourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, fenpropathrin composite after, have tangible synergy and lasting effect;
(2) tetranychid on wheat, cotton, fruit tree, vegetables, the tea tree, Tetranychus urticae, tetranychus viennensis, Panonychus citri, wheat leaf pawl mite, phyllocoptruta oleivora, yellow tea mite, Tetranychus cinnabarinus, beginning tetranychid, two spotted spider mite, yellow spider, rust mite, blister mite, pear sucker, oystershell scale etc. all there is greater activity;
(3) and reduced the agricultural chemicals dosage, reduce the residual quantity of agricultural chemicals on crop, alleviated environmental pollution;
(4) to the person poultry safety, Environmental compatibility is good, and the evil mite is difficult for developing immunity to drugs; And the preparation adhesion strength strengthens, resistance of rainwater washing against.
Embodiment
The present invention is explained further that the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
Application implementation example one
Instance 160% fourth fluorine mite ester azacyclotin wetting powder
Fourth fluorine mite ester 15%, azacyclotin 45%, alkylnaphthalene sulfonate 3%, lauryl sodium sulfate 3.5%, kaolin add to 100%, and mixture carries out comminution by gas stream, make 60% fourth fluorine mite ester azacyclotin wetting powder.
Instance 275% fourth fluorine mite ester azacyclotin wetting powder
Fourth fluorine mite ester 30%, azacyclotin 45%, naphthalene sulfonic acid-formaldehyde condensation product 3.5%, spaonin powder 3.5%, diatomite add to 100%, and mixture carries out comminution by gas stream, make 75% fourth fluorine mite ester azacyclotin wetting powder.
Instance 362% fourth fluorine mite ester azacyclotin wetting powder
Fourth fluorine mite ester 2%, azacyclotin 60%, polycarboxylate 3.5%, sldium lauryl sulfate 3%, bentonite add to 100%, and mixture carries out comminution by gas stream, make 62% fourth fluorine mite ester azacyclotin wetting powder.
Instance 480% fourth fluorine mite ester azocyclotin water dispersible granule
Fourth fluorine mite ester 20%, azacyclotin 60%, lignosulfonates 3%, tea are withered 4%, sodium bicarbonate 2%, attapulgite add to 100%, make 80% fourth fluorine mite ester azocyclotin water dispersible granule.
Instance 563% fourth fluorine mite ester azocyclotin water dispersible granule
Fourth fluorine mite ester 60%, azacyclotin 3%, alkyl benzene sulfonate calcium salt 3.5%, silkworm excrement 3%, sodium carbonate 2.5%, white carbon add to 100%, make 63% fourth fluorine mite ester azocyclotin water dispersible granule.
Instance 650% fourth fluorine mite ester azocyclotin water dispersible granule
Fourth fluorine mite ester 40%, azacyclotin 10%, aliphatic amine polyoxyethylene are phonetic 4%, soapberry powder 3.5%, urea 2.5%, melon glue 1%, starch add to 100%, make 50% fourth fluorine mite ester azocyclotin water dispersible granule.
Instance 745% fourth fluorine mite ester azacyclotin suspending agent
Fourth fluorine mite ester 15%, azacyclotin 30%, polyoxyethylene carboxylate 3%, neopelex 3%, silicone 0.1%, CMC 0.05%, glycerine 1%, deionized water add to 100%, make 45% fourth fluorine mite ester azacyclotin suspending agent.
Instance 823% fourth fluorine mite ester azacyclotin suspending agent
Fourth fluorine mite ester 22.5%, azacyclotin 0.5%, lignosulfonates 3.5%, Nekal BX 3%, C
8 ~ 10Aliphatic alcohols 0.15%, Magnesiumaluminumsilicate 0.08%, ethylene glycol 0.5%, deionized water add to 100%, make 23% fourth fluorine mite ester azacyclotin suspending agent.
Instance 932% fourth fluorine mite ester azacyclotin suspending agent
Fourth fluorine mite ester 24%, azacyclotin 8%, naphthalene sulfonic acid-formaldehyde condensation product 4%, wetting and penetrating agent F 3.5%, C
10 ~ 20Saturated fat acids 0.1%, gum Arabic 0.1%, propane diols 0.8 %, deionized water add to 100%, make 32% fourth fluorine mite ester azacyclotin suspending agent.
Instance 1050% fourth fluorine mite ester azacyclotin suspension emulsion
Fourth fluorine mite ester 20%, azacyclotin 30%, alkylaryl APEO 3%, silicone 3%, 3-methyl cyclohexanol ketenes 8%, PAA 0.05%, alkyl biphenyl ether disulfonic acid magnesium salts 3.5%, glycerine 1%, triphenyl phosphite 0.1%, deionized water add to 100%, make 50% fourth fluorine mite ester azacyclotin suspension emulsion.
Instance 1133% fourth fluorine mite ester azacyclotin suspension emulsion
Phonetic 3.5%, the C of fourth fluorine mite ester 30%, azacyclotin 3%, ester polyoxyethylene
8 ~ 10Aliphatic alcohols 3.5%, cyclohexanone 8%, xanthans 0.08%, triethanolamine salt 4%, propane diols 0.5%, epoxychloropropane 0.15%, deionized water add to 100%, make 33% fourth fluorine mite ester azacyclotin suspension emulsion.
Instance 1245% fourth fluorine mite ester azacyclotin aqueous emulsion
Fourth fluorine mite ester 30%, azacyclotin 15%, toluene 12%, benzyl dimethyl phenol polyoxy ethyl ether 3%, glycerine 1%, PAA 0.05%, silicone 0.1%, deionized water add to 100%, make 45% fourth fluorine mite ester azacyclotin aqueous emulsion.
Instance 1344% fourth fluorine mite ester azacyclotin aqueous emulsion
Fourth fluorine mite ester 4%, azacyclotin 40%, butyl ether 14%, castor oil polyoxyethylene ether 3.5%, diethylene glycol (DEG) 1.5%, polyvinylpyrrolidone 0.08%, C
8 ~ 10Aliphatic alcohols 0.15%, deionized water add to 100%, make 44% fourth fluorine mite ester azacyclotin aqueous emulsion.
Instance 1440% fourth fluorine mite ester azacyclotin microemulsion
Fourth fluorine mite ester 20%, azacyclotin 20%, vegetable oil 12%, phenethyl fluosite polyoxy ethyl ether 3%, hydroxyethylcellulose 0.05%, silicone 0.1%, BHT 1%, deionized water add to 100%, make 40% fourth fluorine mite ester azacyclotin microemulsion.
Instance 1532% fourth fluorine mite ester azacyclotin microemulsion
Fourth fluorine mite ester 2%, azacyclotin 30%, EGME 16%, castor oil polyoxyethylene ether 3.5%, propane diols 0.1%, C
8 ~ 10Aliphatic alcohols 0.15%, triphenyl phosphite 1.5%, deionized water add to 100%, make 32% fourth fluorine mite ester azacyclotin microemulsion.
Instance 1635.5% fourth fluorine mite ester azacyclotin microcapsule suspending agent
Fourth fluorine mite ester 0.5%, azacyclotin 35%, formaldehyde 2%, alkylnaphthalene sulfonate 3%, propyl alcohol 6%, NPE 3.5%, pH regulator agent sodium hydroxide and citric acid amount to 2.5%, deionized water adds to 100%, make 35.5% fourth fluorine mite ester azacyclotin microcapsule suspending agent.
Instance 1740% fourth fluorine mite ester azacyclotin microcapsule suspending agent
Fourth fluorine mite ester 16%, azacyclotin 24%, PIC 3%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 3.5%, vegetable oil 8%, phenethyl fluosite polyoxy ethyl ether 4%, pH regulator agent sodium hydroxide and hydrochloric acid amount to 3%, deionized water adds to 100%, make 40% fourth fluorine mite ester azacyclotin microcapsule suspending agent.
Instance 1846% fourth fluorine mite ester azacyclotin microcapsule suspension-suspending agent
Fourth fluorine mite ester 1%, azacyclotin 45%, PIC 3.5%, vegetable oil 5%, alkyl biphenyl ether disulfonic acid magnesium salts 3%, silicone 0.2%, polyvinylpyrrolidone 0.06%, pH regulator agent sodium hydroxide and sorbic acid amount to 2.5%, deionized water adds to 100%, make 46% fourth fluorine mite ester azacyclotin microcapsule suspension-suspending agent.
Instance 1942.6% fourth fluorine mite ester azacyclotin microcapsule suspension-suspending agent
Fourth fluorine mite ester 42%, azacyclotin 0.6%, distortion milk protein 4%, ethyl acetate 5%, triethanolamine salt 3.5%, C
8 ~ 10Aliphatic alcohols 0.25%, sodium phosphate trimer 0.08%, pH regulator agent sodium hydroxide and citric acid amount to 3%, deionized water adds to 100%, make 42.6% fourth fluorine mite ester azacyclotin microcapsule suspension-suspending agent.
Azacyclotin among the instance 1-19 is replaced with Bifenazate, fenbutatin oxide, fenpropathrin can make novel formulation equally.
Instance 2050% fourth fluorine mite ester Bifenazate wetting powder
Fourth fluorine mite ester 20%, Bifenazate 30%, two (alkyl) naphthalenesulfonate formaldehyde condensation compound 3.5%, neopelex 3%, diatomite add to 100%, and mixture carries out comminution by gas stream, make 50% fourth fluorine mite ester Bifenazate wetting powder.
Instance 2163% fourth fluorine mite ester Bifenazate wetting powder
Fourth fluorine mite ester 60%, Bifenazate 3%, aryl phenol polyoxyethylene succinate sulfonate 3%, Nekal BX 3.5%, bentonite add to 100%, and mixture carries out comminution by gas stream, make 63% fourth fluorine mite ester Bifenazate wetting powder.
Instance 2275% fourth fluorine mite ester Bifenazate wetting powder
Fourth fluorine mite ester 60%, Bifenazate 15%, octylphenol polyethylene oxyethylene group ether sulfate 4%, wetting and penetrating agent F 3%, attapulgite add to 100%, and mixture carries out comminution by gas stream, make 75% fourth fluorine mite ester Bifenazate wetting powder.
Instance 2375% fourth fluorine mite ester Bifenazate water dispersible granules
Fourth fluorine mite ester 45%, Bifenazate 30%, polycarboxylate 3.6%, spaonin powder 4.2%, sodium carbonate 2.5%, white carbon add to 100%, make 75% fourth fluorine mite ester Bifenazate water dispersible granules.
Instance 2446% fourth fluorine mite ester Bifenazate water dispersible granules
Fourth fluorine mite ester 45%, Bifenazate 1%, aliphatic alcohol polyethenoxy base ether 3.5%, sldium lauryl sulfate 3.2%, bentonite 2%, starch add to 100%, make 46% fourth fluorine mite ester Bifenazate water dispersible granules.
Instance 2580% fourth fluorine mite ester Bifenazate water dispersible granules
The phonetic formaldehyde condensation products sulphate of fourth fluorine mite ester 60%, Bifenazate 20%, alkylphenol-polyethenoxy 4%, tea are withered 3%, ammonium sulfate 2%, starch add to 100%, make 80% fourth fluorine mite ester Bifenazate water dispersible granules.
Instance 2625% fourth fluorine mite ester Bifenazate suspending agent
Fourth fluorine mite ester 5%, Bifenazate 20%, alkyl benzene sulfonate calcium salt 3.2%, Nekal BX 3.5%, C
8 ~ 10Aliphatic alcohols 0.2%, Magnesiumaluminumsilicate 0.06%, ethylene glycol 0.8%, deionized water add to 100%, make 25% fourth fluorine mite ester Bifenazate suspending agent.
Instance 2745% fourth fluorine mite ester Bifenazate suspending agent
Fourth fluorine mite ester 30%, Bifenazate 15%, polyoxyethylene carboxylate 3.6%, wetting and penetrating agent F 3.2%, C
10 ~ 20Saturated fat acids 0.16%, gelatin 0.06%, glycerine 0.6%, deionized water add to 100%, make 45% fourth fluorine mite ester Bifenazate suspending agent.
Instance 2831% fourth fluorine mite ester Bifenazate suspending agent
Fourth fluorine mite ester 1%, Bifenazate 30%, ester polyoxyethylene are phonetic 3.8%, spaonin powder 3%, silicone oil 0.15%, melon glue 0.13%, triethylene glycol 0.6 %, deionized water add to 100%, make 31% fourth fluorine mite ester Bifenazate suspending agent.
Instance 2945% fourth fluorine mite ester Bifenazate suspension emulsion
Fourth fluorine mite ester 30%, Bifenazate 15%, alkylnaphthalene sulfonate 3.2%, C
8 ~ 10Aliphatic alcohols 3.5%, N, dinethylformamide 10%, sodium alginate 0.08%, castor oil polyoxyethylene ether 4.5%, ethylene glycol 1.5%, triethanolamine 0.1%, deionized water add to 100%, make 45% fourth fluorine mite ester Bifenazate suspension emulsion.
Instance 3033% fourth fluorine mite ester Bifenazate suspension emulsion
Fourth fluorine mite ester 3%, Bifenazate 30%, aryl phenol polyoxyethylene succinate sulfonate 4.5%, silicone defoaming agent 2.5%, vegetable oil 10%, polyvinylpyrrolidone 0.06%, phenethyl fluosite polyoxy ethyl ether 3%, polyethylene glycol 0.6%, surface-active substance 0.18%, deionized water add to 100%, make 33% fourth fluorine mite ester Bifenazate suspension emulsion.
Instance 3140% fourth fluorine mite ester Bifenazate aqueous emulsion
Fourth fluorine mite ester 20%, Bifenazate 20%, toluene 10%, benzyl dimethyl phenol polyoxy ethyl ether 3%, glycerine 1%, PAA 0.05%, silicone 0.1%, deionized water add to 100%, make 40% fourth fluorine mite ester Bifenazate aqueous emulsion.
Instance 3248% fourth fluorine mite ester Bifenazate aqueous emulsion
Fourth fluorine mite ester 3%, Bifenazate 45%, N; Dinethylformamide 15%, benzyl dimethyl phenol polyoxy ethyl ether 4%, glycerine 1.3%, hydroxyethylcellulose 0.1%, silicone oil 0.15%, deionized water add to 100%, make 48% fourth fluorine mite ester Bifenazate aqueous emulsion.
Instance 3330% fourth fluorine mite ester Bifenazate microemulsion
Fourth fluorine mite ester 12%, Bifenazate 18%, vegetable oil 14%, phenethyl fluosite polyoxy ethyl ether 3.2%, propane diols 1.2%, silicone defoaming agent 0.1%, triphenyl phosphite 1.2%, deionized water add to 100%, make 30% fourth fluorine mite ester Bifenazate microemulsion.
Instance 3444% fourth fluorine mite ester Bifenazate microemulsion
Fourth fluorine mite ester 40%, Bifenazate 4%, cyclohexanone 12%, NPE phosphate 3%, glycerine 1.3%, xanthans 0.05%, silicone 0.16%, BHT 1.5%, deionized water add to 100%, make 44% fourth fluorine mite ester Bifenazate microemulsion.
Instance 3536.8% fourth fluorine mite ester Bifenazate microcapsule suspending agent
Fourth fluorine mite ester 0.8%, Bifenazate 36%, modified starch 2.5%, lignosulfonates 3.5%, butyl ether 8%, triethanolamine salt 3%, pH regulator agent sodium hydroxide and hydrochloric acid amount to 2.8%, deionized water adds to 100%, make 36.8% fourth fluorine mite ester Bifenazate microcapsule suspending agent.
Instance 3635.5% fourth fluorine mite ester Bifenazate microcapsule suspending agent
Fourth fluorine mite ester 35%, Bifenazate 0.5%, maltose 3.5%, polycarboxylate 4%, N-pyrrolidones 8%, alkylphenol-formaldehyde resin polyoxy ethyl ether 4.2%, pH regulator agent sodium hydroxide and citric acid amount to 3%, deionized water adds to 100%, make 35.5% fourth fluorine mite ester Bifenazate microcapsule suspending agent.
Instance 3742.6% fourth fluorine mite ester Bifenazate microcapsule suspension-suspending agent
Fourth fluorine mite ester 0.6%, Bifenazate 42%, polyfunctional group acyl halide dihydroxylic alcohols 4.5%, acetonitrile 3%, sorbitan monostearate 3.2%, C
8 ~ 10Aliphatic alcohols 0.15%, methylcellulose 0.06%, pH regulator agent sodium hydroxide and sorbic acid amount to 2.6%, deionized water adds to 100%, make 42.6% fourth fluorine mite ester Bifenazate microcapsule suspension-suspending agent.
Instance 3845% fourth fluorine mite ester Bifenazate microcapsule suspension-suspending agent
Fourth fluorine mite ester 30%, Bifenazate 15%, calcium chloride 4.5%, EGME 5%, sorbitan fatty acid ester APEO 3%, silicone defoaming agent 0.23%, polyvinylpyrrolidone 0.1%, pH regulator agent sodium hydroxide and citric acid amount to 3%, deionized water adds to 100%, make 45% fourth fluorine mite ester Bifenazate microcapsule suspension-suspending agent.
Bifenazate among the instance 20-38 is replaced with azacyclotin, fenbutatin oxide, fenpropathrin can make novel formulation equally.
Instance 3960% fourth fluorine mite ester fenbutatin oxide wetting powder
Fourth fluorine mite ester 30%, fenbutatin oxide 30%, ester polyoxyethylene are phonetic 3.2%, wetting and penetrating agent F 3.5%, bentonite add to 100%, and mixture carries out comminution by gas stream, makes 60% fourth fluorine mite ester fenbutatin oxide wetting powder.
Instance 4055% fourth fluorine mite ester fenbutatin oxide wetting powder
Fourth fluorine mite ester 5%, fenbutatin oxide 50%, polycarboxylate 3.8%, spaonin powder 3%, attapulgite add to 100%, and mixture carries out comminution by gas stream, make 55% fourth fluorine mite ester fenbutatin oxide wetting powder.
Instance 4175% fourth fluorine mite ester fenbutatin oxide water dispersible granule
Fourth fluorine mite ester 30%, fenbutatin oxide 45%, alkylnaphthalene sulfonate 3.5%, lauryl sodium sulfate 4.2%, sodium bicarbonate 2.6%, starch add to 100%, make 75% fourth fluorine mite ester fenbutatin oxide water dispersible granule.
Instance 4271% fourth fluorine mite ester fenbutatin oxide water dispersible granule
Fourth fluorine mite ester 1%, fenbutatin oxide 70%, lignosulfonates 3 %, Nekal BX 3.2%, urea 2.5%, precipitated calcium carbonate add to 100%, make 71% fourth fluorine mite ester fenbutatin oxide water dispersible granule.
Instance 4345% fourth fluorine mite ester fenbutatin oxide suspending agent
Fourth fluorine mite ester 15%, fenbutatin oxide 30%, alkylphenol-polyethenoxy are phonetic 3.2%, neopelex 3.6%, silicone 0.05%, CMC 0.08%, polyethylene glycol 1%, deionized water add to 100%, make 45% fourth fluorine mite ester fenbutatin oxide suspending agent.
Instance 4422% fourth fluorine mite ester fenbutatin oxide suspending agent
Fourth fluorine mite ester 20%, fenbutatin oxide 2%, alkylphenol-polyethenoxy are phonetic 3.6%, spaonin powder 3.2%, C
8 ~ 10Aliphatic alcohols 0.16%, sodium alginate 0.08%, ethylene glycol 0.8%, deionized water add to 100%, make 22% fourth fluorine mite ester fenbutatin oxide suspending agent.
Instance 4548% fourth fluorine mite ester fenbutatin oxide suspension emulsion
Fourth fluorine mite ester 32%, fenbutatin oxide 16%, ester polyoxyethylene are phonetic 4.5%, silicone 0.5%, ethyl acetate 8%, PVPP 0.08%, NPE 3.5%, glycerine 0.6%, tributyl phosphate 0.16%, deionized water add to 100%, make 48% fourth fluorine mite ester fenbutatin oxide suspension emulsion.
Instance 4640% fourth fluorine mite ester fenbutatin oxide aqueous emulsion
Fourth fluorine mite ester 30%, fenbutatin oxide 10%, N, dinethylformamide 12%, alkylaryl polyoxyethylene polyoxypropylene ether 3.2%, diethylene glycol (DEG) 0.8%, gum Arabic 0.06%, C
8 ~ 10Aliphatic alcohols 0.15%, deionized water add to 100%, make 40% fourth fluorine mite ester fenbutatin oxide aqueous emulsion.
Instance 4746% fourth fluorine mite ester fenbutatin oxide microemulsion
Fourth fluorine mite ester 1%, fenbutatin oxide 45%, vegetable oil 13%, benzyl dimethyl phenol polyoxy ethyl ether 3.8%, ethylene glycol 0.6%, white dextrin 0.08%, silicone defoaming agent 0.18%, tributyl phosphate 1.8%, deionized water add to 100%, make 46% fourth fluorine mite ester fenbutatin oxide microemulsion.
Instance 4840% fourth fluorine mite ester fenbutatin oxide microcapsule suspending agent
Fourth fluorine mite ester 16%, fenbutatin oxide 24%, beta-schardinger dextrin-3%, aliphatic amine polyoxyethylene are phonetic 3.5%, vegetable oil 9%, AEO 3.2%, pH regulator agent sodium hydroxide and sorbic acid amount to 2.5%, deionized water adds to 100%, make 40% fourth fluorine mite ester fenbutatin oxide microcapsule suspending agent.
Instance 4942.6% fourth fluorine mite ester fenbutatin oxide microcapsule suspension-suspending agent
Fourth fluorine mite ester 0.6%, fenbutatin oxide 42%, methylcellulose 4.8%, EGME 3.5%, castor oil polyoxyethylene ether 3.6%, C
10 ~ 20Saturated fat acids 0.18%, PVPP 0.1%, pH regulator agent sodium hydroxide and citric acid amount to 2.8%, deionized water adds to 100%, make 42.6% fourth fluorine mite ester fenbutatin oxide microcapsule suspension-suspending agent.
Fenbutatin oxide among the instance 39-49 is replaced with azacyclotin, Bifenazate, fenpropathrin can make novel formulation equally.
Instance 5071% fourth fluorine mite ester fenpropathrin wetting powder
Fourth fluorine mite ester 70%, fenpropathrin 1%, lignosulfonates 3.6%, lauryl sodium sulfate 3.8%, white carbon add to 100%, and mixture carries out comminution by gas stream, make 71% fourth fluorine mite ester fenpropathrin wetting powder.
Instance 5171% fourth fluorine mite ester fenpropathrin water dispersible granules
Fourth fluorine mite ester 1%, fenpropathrin 70%, aliphatic amine polyoxyethylene are phonetic 3.5%, spaonin powder 4.3%, ammonium sulfate 2.8%, precipitated calcium carbonate add to 100%, make 71% fourth fluorine mite ester fenpropathrin tin water dispersible granules.
Instance 5246% fourth fluorine mite ester fenpropathrin suspending agent
The phonetic formaldehyde condensation products sulphate of fourth fluorine mite ester 1%, fenpropathrin 45%, alkylphenol-polyethenoxy 3.3%, tea are withered 3.5%, silicone oil 0.06%, polyvinyl alcohol 0.07%, glycerine 1.2%, deionized water add to 100%, make 46% fourth fluorine mite ester fenpropathrin suspending agent.
Instance 5340% fourth fluorine mite ester fenpropathrin suspension emulsion
Fourth fluorine mite ester 20%, fenpropathrin 20%, polycarboxylate 4.2%, C
8 ~ 10Aliphatic alcohols 0.2%, acetonitrile 9%, PVPP 0.08%, NPE 3.5%, glycerine 0.6%, gum Arabic 0.17%, deionized water add to 100%, make 40% fourth fluorine mite ester fenpropathrin suspension emulsion.
Instance 5445% fourth fluorine mite ester fenpropathrin suspension emulsion
Fourth fluorine mite ester 30%, fenpropathrin 15%, octylphenol polyethylene oxyethylene group ether sulfate 4.3%, C
10 ~ 20Saturated fat acids 0.5%, butanols 10%, sodium phosphate trimer 0.1%, alkyl biphenyl ether disulfonic acid magnesium salts 3.4%, propane diols 0.8%, triethanolamine 0.18%, deionized water add to 100%, make 45% fourth fluorine mite ester fenpropathrin suspension emulsion.
Instance 5530% fourth fluorine mite ester fenpropathrin suspension emulsion
Fourth fluorine mite ester 10%, fenpropathrin 20%, alkylnaphthalene sulfonate 4%, silicone defoaming agent 0.1%, cyclohexanone 11%, methylcellulose 0.05%, alkyl biphenyl ether disulfonic acid magnesium salts 3.4%, diethylene glycol (DEG) 0.8%, diethanol amine 0.17%, deionized water add to 100%, make 30% fourth fluorine mite ester fenpropathrin suspension emulsion.
Instance 5625% fourth fluorine mite ester fenpropathrin suspension emulsion
Fourth fluorine mite ester 10%, fenpropathrin 15%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 3.5%, C
8 ~ 10Aliphatic alcohols 0.5%, vegetable oil 12%, xanthans 0.06%, ethylene oxide-propylene oxide block copolymer 3.9%, polyethylene glycol 0.7%, organic acid 0.16%, deionized water add to 100%, make 25% fourth fluorine mite ester fenpropathrin suspension emulsion.
Instance 5744% fourth fluorine mite ester fenpropathrin aqueous emulsion
Fourth fluorine mite ester 4%, fenpropathrin 40%, 3-methyl cyclohexanol ketenes 13%, triethanolamine salt 3.5%, ethylene glycol 1%, polyvinylpyrrolidone 0.06%, silicone defoaming agent 0.1%, deionized water add to 100%, make 44% fourth fluorine mite ester fenpropathrin aqueous emulsion.
Instance 5833% fourth fluorine mite ester fenpropathrin microemulsion
Fourth fluorine mite ester 30%, fenpropathrin 3%, ethanol 13%, ethylene oxide-propylene oxide block copolymer 3.6%, polyethylene glycol 0.7%, sodium alginate 0.09%, silicone oil 0.17%, triethanolamine 2%, deionized water add to 100%, make 33% fourth fluorine mite ester fenpropathrin microemulsion.
Instance 5946% fourth fluorine mite ester fenpropathrin microcapsule suspending agent
Fourth fluorine mite ester 45%, fenpropathrin 1%, sodium alginate 3.5%, lignosulfonates 3.7%, ethyl acetate 10%, alkyl biphenyl ether disulfonic acid magnesium salts 3.3%, pH regulator agent sodium hydroxide and hydrochloric acid amount to 2.6%, deionized water adds to 100%, make 46% fourth fluorine mite ester fenpropathrin microcapsule suspending agent.
Instance 6048% fourth fluorine mite ester fenpropathrin microcapsule suspension-suspending agent
Fourth fluorine mite ester 45%, fenpropathrin 3%, polyfunctional group acyl halide dihydroxylic alcohols 4.6%, vegetable oil 3.8%, castor oil polyoxyethylene ether 3.8%, silicone 0.17%, PVPP 0.2%, pH regulator agent sodium hydroxide and citric acid amount to 2.9%, deionized water adds to 100%, make 48% fourth fluorine mite ester fenpropathrin microcapsule suspension-suspending agent.
Fenpropathrin among the instance 50-60 is replaced with azacyclotin, Bifenazate, fenbutatin oxide can make novel formulation equally.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.Pass through Toxicity Determination earlier, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80≤CTC≤120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field trial again.
Test method: respectively the mother liquor of each mixed agent is diluted to five series concentration during test, places beaker subsequent use respectively.Adopt and to soak the method that connects worm behind the leaf earlier, the blade of the same size that does not contact any medicament is soaked taking-up behind the 5s, dries naturally in the soup that configures, put into insect box; Connect then and supply the examination larva, under 25 ℃ of conditions, raise, every processing repeats for 3 times; Every to repeat used examination borer population be 50, establishes blank simultaneously, checks dead borer population in 72h; Calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50Value.If the contrast lethality then is regarded as invalid test greater than 10%.Computing formula is following:
Borer population alive behind borer population-medicine alive before the medicine
Lethality (%)=------------* 100
Borer population alive before the medicine
Processed group lethality-control group lethality
Corrected mortality (%)=---------------* 100
100-control group lethality
The insect corrected mortality is converted into probit value (y), and concentration of treatment (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates the value of every kind of medicament thus.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula is (with fourth fluorine mite ester is the standard medicament, and its toxicity index is 100) as follows:
The LC of fourth fluorine mite ester
50
Toxicity index (TI)=------------* 100 of effective active composition B
The LC of effective active composition B
50
The LC of fourth fluorine mite ester
50
The toxicity index of M (ATI)=---------* 100
The LC of M
50
TI * the P of the theoretical toxicity index (TTI) of M=fourth fluorine mite ester
Fourth fluorine mite esterTI * P of+effective active composition B
Effective active composition B
The ATI of M
Co-toxicity coefficient (CTC)=------* 100
The TTI of M
In the formula: M is the mixture of different proportionings
P
Effective active composition BBe effective active composition B shared ratio in composition
P
Fourth fluorine mite esterBe fourth fluorine mite ester shared ratio in composition
A is selected from fourth fluorine mite ester;
B is selected from following any one compound: a kind of in azacyclotin, Bifenazate, fenbutatin oxide, the fenpropathrin.
Application implementation example two:
Supply the examination insect: cotton red spider
Experimental scheme: effective lethal concentration scope of confirming fourth fluorine mite ester, the former medicine of azacyclotin and the two different proportioning mixture through preliminary experiment.
Toxicity test result one
The different proportionings with azacyclotin of table 1 fourth fluorine mite ester are to the toxicity test of cotton red spider
Can know by table 1; Fourth fluorine mite ester and the composite control cotton red spider of azacyclotin fit over 70:1 to 1:70 the time; Co-toxicity coefficient is all greater than 120; Explaining that both are mixed in 70:1 to 1:70 scope all shows synergistic effect; Especially when the proportioning of fourth fluorine mite ester and azacyclotin during at 20:1 to 1:30; Synergistic effect is more obviously outstanding; Wherein co-toxicity coefficient is maximum when fourth fluorine mite ester and azacyclotin weight ratio are 2:3, and synergistic effect is the most obvious, finds simultaneously; Fourth fluorine mite ester and azacyclotin proportioning are composite when 20:1,10:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:11,1:12,1:13,1:14,1:15,1:16,1:17,1:18,1:19,1:20,1:30 also to have synergistic effect preferably to insects such as tetranychid, Tetranychus urticae, tetranychus viennensis, Panonychus citri, wheat leaf pawl mite, phyllocoptruta oleivora, yellow tea mite, Tetranychus cinnabarinus, beginning tetranychid, two spotted spider mite, yellow spider, rust mite, blister mite, pear sucker, oystershell scales, and co-toxicity coefficient is all greater than 180.
Application implementation example three: supply the examination insect: the peach Tetranychus urticae
Experimental scheme: effective lethal concentration scope of confirming fourth fluorine mite ester, the former medicine of Bifenazate and the two different proportioning mixture through preliminary experiment.
Toxicity test result two
The different proportionings with Bifenazate of table 2 fourth fluorine mite ester are to the toxicity test of peach Tetranychus urticae
Can know by table 2; The composite control of fourth fluorine mite ester and Bifenazate peach Tetranychus urticae fit over 70:1 to 1:70 the time; Co-toxicity coefficient is all greater than 120; Explaining that both are mixed in 70:1 to 1:70 scope all shows synergistic effect; Especially when the proportioning of fourth fluorine mite ester and Bifenazate during at 20:1 to 1:30; Synergistic effect is more obviously outstanding; Wherein co-toxicity coefficient is maximum when fourth fluorine mite ester and Bifenazate weight ratio are 2:3, and synergistic effect is the most obvious, finds simultaneously; Fourth fluorine mite ester and Bifenazate proportioning are composite when 20:1,10:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:11,1:12,1:13,1:14,1:15,1:16,1:17,1:18,1:19,1:20,1:30 also to have synergistic effect preferably to insects such as tetranychid, Tetranychus urticae, tetranychus viennensis, Panonychus citri, wheat leaf pawl mite, phyllocoptruta oleivora, yellow tea mite, Tetranychus cinnabarinus, beginning tetranychid, two spotted spider mite, yellow spider, rust mite, blister mite, pear sucker, oystershell scales, and co-toxicity coefficient is all greater than 180.
Application implementation example four: supply the examination insect: panonychus citri
Experimental scheme: effective lethal concentration scope of confirming fourth fluorine mite ester, the former medicine of fenbutatin oxide and the two different proportioning mixture through preliminary experiment.
Toxicity test result three
The different proportionings with fenbutatin oxide of table 3 fourth fluorine mite ester are to the toxicity test of panonychus citri
Can know by table 3; Fourth fluorine mite ester and the composite control panonychus citri of fenbutatin oxide fit over 70:1 to 1:70 the time; Co-toxicity coefficient is all greater than 120; Explaining that both are mixed in 70:1 to 1:70 scope all shows synergistic effect; Especially when the proportioning of fourth fluorine mite ester and fenbutatin oxide during at 20:1 to 1:30; Synergistic effect is more obviously outstanding; Wherein co-toxicity coefficient is maximum when fourth fluorine mite ester and fenbutatin oxide weight ratio are 2:3, and synergistic effect is the most obvious, finds simultaneously; Fourth fluorine mite ester and fenbutatin oxide proportioning are composite when 20:1,10:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:11,1:12,1:13,1:14,1:15,1:16,1:17,1:18,1:19,1:20,1:30 also to have synergistic effect preferably to insects such as tetranychid, Tetranychus urticae, tetranychus viennensis, Panonychus citri, wheat leaf pawl mite, phyllocoptruta oleivora, yellow tea mite, Tetranychus cinnabarinus, beginning tetranychid, two spotted spider mite, yellow spider, rust mite, blister mite, pear sucker, oystershell scales, and co-toxicity coefficient is all greater than 180.
Application implementation example five: supply the examination insect: the oranges and tangerines blister mite
Experimental scheme: effective lethal concentration scope of confirming fourth fluorine mite ester, the former medicine of fenpropathrin and the two different proportioning mixture through preliminary experiment.
Toxicity test result four
The different proportionings with fenpropathrin of table 4 fourth fluorine mite ester are to the toxicity test of oranges and tangerines blister mite
Can know by table 4; Fourth fluorine mite ester and the composite control oranges and tangerines of fenpropathrin blister mite fit over 70:1 to 1:70 the time; Co-toxicity coefficient is all greater than 120; Explaining that both are mixed in 70:1 to 1:70 scope all shows synergistic effect; Especially when the proportioning of fourth fluorine mite ester and fenpropathrin during at 10:1 to 1:10, synergistic effect is more obviously outstanding, wherein co-toxicity coefficient maximum when fourth fluorine mite ester and fenpropathrin weight ratio are 1:1; Synergistic effect is the most obvious; Find that simultaneously fourth fluorine mite ester and fenpropathrin proportioning are composite when 10:1,9:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10 also to have synergistic effect preferably to insects such as tetranychid, Tetranychus urticae, tetranychus viennensis, Panonychus citri, wheat leaf pawl mite, phyllocoptruta oleivora, yellow tea mite, Tetranychus cinnabarinus, beginning tetranychid, two spotted spider mite, yellow spider, rust mite, blister mite, pear sucker, oystershell scales, co-toxicity coefficient is all greater than 180.
Application implementation example sixFourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, the tetranychid test of pesticide effectiveness of composite control citrus beginning of fenpropathrin
This test arrangement is Hanzhong City in Shaanxi Province; Test medicine is researched and developed, is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 20% fourth fluorine mite ester suspending agent (autogamy), 25% azacyclotin suspending agent (commercial), 43% Bifenazate suspending agent (commercial), 50% fenbutatin oxide wetting powder (commercial), 20% fenpropathrin milk oil (commercial).
Test and adopt conventional spray-on process, investigation citrus beginning tetranychid insect pest index before the medicine in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 45 days after the dispenser and is calculated preventive effect.Experimental result is as follows:
Table 5 fourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, the tetranychid test of pesticide effectiveness of composite control citrus beginning of fenpropathrin
| Handle medicament | The preparation dosage | 10 days preventive effects (%) behind the medicine | 30 days preventive effects (%) behind the medicine | 45 days preventive effects (%) behind the medicine |
| Instance 1 | 15 gram/mus | 98.00 | 98.43 | 97.17 |
| Instance 7 | 20 gram/mus | 98.43 | 99.79 | 98.21 |
| Instance 18 | 20 gram/mus | 97.99 | 98.35 | 97.02 |
| Instance 20 | 18 gram/mus | 97.32 | 99.80 | 98.49 |
| Instance 29 | 18 gram/mus | 98.92 | 98.43 | 98.30 |
| Instance 35 | 30 gram/mus | 98.21 | 99.13 | 98.13 |
| Instance 39 | 15 gram/mus | 98.14 | 98.45 | 98.26 |
| Instance 46 | 20 gram/mus | 97.89 | 99.01 | 97.79 |
| Instance 50 | 10 gram/mus | 98.56 | 99.24 | 98.89 |
| Instance 53 | 15 gram/mus | 97.28 | 98.45 | 98.15 |
| 20% fourth fluorine mite ester suspending agent | 45 gram/mus | 64.78 | 68.26 | 63.17 |
| 25% azacyclotin suspending agent | 50 gram/mus | 65.09 | 69.02 | 65.12 |
| 43% Bifenazate suspending agent | 30 gram/mus | 64.12 | 68.45 | 64.18 |
| 50% fenbutatin oxide wetting powder | 25 gram/mus | 65.49 | 68.43 | 65.12 |
| 20% fenpropathrin milk oil | 45 gram/mus | 64.38 | 67.19 | 63.11 |
Can be found out that by table 5 fourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, fenpropathrin is composite can effectively prevent and treat citrus beginning tetranychid, control efficiency all is superior to the preventive effect of single agent, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
Application implementation example sevenFourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, the composite control of the fenpropathrin cotton rust mite test of pesticide effectiveness
This test arrangement is in the Xianyang, Shanxi province city; Test medicine is researched and developed, is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 20% fourth fluorine mite ester suspending agent (autogamy), 25% azacyclotin suspending agent (commercial), 43% Bifenazate suspending agent (commercial), 50% fenbutatin oxide wetting powder (commercial), 20% fenpropathrin milk oil (commercial).
Conventional spray-on process is adopted in test, and investigation cotton rust mite insect pest index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 45 days after the dispenser and calculated preventive effect before the medicine.Experimental result is as follows:
Table 6 fourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, the composite control of the fenpropathrin cotton rust mite test of pesticide effectiveness
| Handle medicament | The preparation dosage | 10 days preventive effects (%) behind the medicine | 30 days preventive effects (%) behind the medicine | 45 days preventive effects (%) behind the medicine |
| Instance 2 | 10 gram/mus | 98.45 | 99.47 | 98.15 |
| Instance 10 | 18 gram/mus | 98.53 | 99.21 | 98.49 |
| Instance 12 | 18 gram/mus | 97.89 | 98.85 | 97.72 |
| Instance 21 | 11 gram/mus | 98.37 | 99.82 | 98.79 |
| Instance 30 | 30 gram/mus | 97.94 | 98.73 | 98.32 |
| Instance 36 | 20 gram/mus | 98.47 | 99.23 | 98.42 |
| Instance 40 | 18 gram/mus | 97.94 | 98.95 | 98.21 |
| Instance 45 | 15 gram/mus | 98.87 | 99.41 | 97.89 |
| Instance 51 | 10 gram/mus | 98.75 | 99.04 | 98.89 |
| Instance 54 | 15 gram/mus | 98.29 | 99.43 | 98.35 |
| 20% fourth fluorine mite ester suspending agent | 45 gram/mus | 64.78 | 68.26 | 63.17 |
| 25% azacyclotin suspending agent | 50 gram/mus | 65.09 | 69.02 | 65.12 |
| 43% Bifenazate suspending agent | 30 gram/mus | 64.12 | 68.45 | 64.18 |
| 50% fenbutatin oxide wetting powder | 25 gram/mus | 65.49 | 68.43 | 65.12 |
| 20% fenpropathrin milk oil | 45 gram/mus | 64.38 | 67.19 | 63.11 |
Can be found out that by table 6 fourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, fenpropathrin is composite can effectively prevent and treat the cotton rust mite, control efficiency all is superior to the preventive effect of single agent, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
Application implementation example eightFourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, the composite control wheat of the fenpropathrin wheat leaf pawl mite test of pesticide effectiveness
This test arrangement is in the Xianyang, Shanxi province city; Test medicine is researched and developed, is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 20% fourth fluorine mite ester suspending agent (autogamy), 25% azacyclotin suspending agent (commercial), 43% Bifenazate suspending agent (commercial), 50% fenbutatin oxide wetting powder (commercial), 20% fenpropathrin milk oil (commercial).
Test and adopt conventional spray-on process, investigation wheat wheat leaf pawl acarid evil index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 45 days after the dispenser and is calculated preventive effect before the medicine.Experimental result is as follows:
Table 7 fourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, the composite control wheat of the fenpropathrin wheat leaf pawl mite test of pesticide effectiveness
| Handle medicament | The preparation dosage | 10 days preventive effects (%) behind the medicine | 30 days preventive effects (%) behind the medicine | 45 days preventive effects (%) behind the medicine |
| Instance 3 | 15 gram/mus | 97.45 | 98.45 | 98.03 |
| Instance 5 | 10 gram/mus | 98.54 | 99.22 | 98.79 |
| Instance 11 | 20 gram/mus | 98.78 | 98.75 | 97.62 |
| Instance 22 | 10 gram/mus | 98.34 | 99.81 | 98.69 |
| Instance 31 | 20 gram/mus | 97.98 | 98.63 | 98.42 |
| Instance 37 | 25 gram/mus | 98.37 | 99.33 | 98.45 |
| Instance 41 | 10 gram/mus | 97.91 | 99.05 | 97.21 |
| Instance 47 | 20 gram/mus | 98.86 | 99.44 | 97.87 |
| Instance 52 | 15 gram/mus | 97.76 | 98.74 | 98.19 |
| Instance 55 | 30 gram/mus | 98.39 | 99.43 | 98.34 |
| 20% fourth fluorine mite ester suspending agent | 45 gram/mus | 64.78 | 68.26 | 63.17 |
| 25% azacyclotin suspending agent | 50 gram/mus | 65.09 | 69.02 | 65.12 |
| 43% Bifenazate suspending agent | 30 gram/mus | 64.12 | 68.45 | 64.18 |
| 50% fenbutatin oxide wetting powder | 25 gram/mus | 65.49 | 68.43 | 65.12 |
| 20% fenpropathrin milk oil | 45 gram/mus | 64.38 | 67.19 | 63.11 |
Can be found out that by table 7 fourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, fenpropathrin is composite can effectively prevent and treat wheat wheat leaf pawl mite, control efficiency all is superior to the preventive effect of single agent, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
Application implementation example nineFourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, the composite control of the fenpropathrin European red mite test of pesticide effectiveness
This test arrangement is the Weinan City Linwei District in Shaanxi Province; Test medicine is researched and developed, is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 20% fourth fluorine mite ester suspending agent (autogamy), 25% azacyclotin suspending agent (commercial), 43% Bifenazate suspending agent (commercial), 50% fenbutatin oxide wetting powder (commercial), 20% fenpropathrin milk oil (commercial).
Conventional spray-on process is adopted in test, and investigation European red mite insect pest index before the medicine in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 60 days after the dispenser and calculated preventive effect.Experimental result is as follows:
Table 8 fourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, the composite control of the fenpropathrin European red mite test of pesticide effectiveness
| Handle medicament | The preparation dosage | 10 days preventive effects (%) behind the medicine | 30 days preventive effects (%) behind the medicine | 60 days preventive effects (%) behind the medicine |
| Instance 4 | 5500 times | 98.12 | 99.40 | 98.23 |
| Instance 8 | 2000 times | 98.44 | 99.42 | 98.78 |
| Instance 13 | 2800 times | 97.98 | 98.85 | 97.62 |
| Instance 24 | 4000 times | 98.32 | 98.82 | 98.59 |
| Instance 32 | 3000 times | 98.68 | 98.73 | 98.32 |
| Instance 38 | 3600 times | 97.36 | 98.32 | 98.45 |
| Instance 42 | 4200 times | 98.91 | 99.15 | 98.23 |
| Instance 48 | 2800 times | 98.85 | 99.54 | 97.97 |
| Instance 56 | 2500 times | 97.66 | 98.64 | 98.29 |
| Instance 59 | 4000 times | 98.79 | 99.33 | 98.52 |
| 20% fourth fluorine mite ester suspending agent | 1500 times | 65.78 | 69.56 | 64.27 |
| 25% azacyclotin suspending agent | 1500 times | 65.09 | 69.02 | 65.12 |
| 43% Bifenazate suspending agent | 2000 times | 64.82 | 68.78 | 64.23 |
| 50% fenbutatin oxide wetting powder | 2500 times | 65.79 | 68.24 | 65.57 |
| 20% fenpropathrin milk oil | 1500 times | 64.42 | 67.39 | 63.22 |
Can be found out that by table 8 fourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, fenpropathrin is composite can effectively prevent and treat European red mite, control efficiency all is superior to the preventive effect of single agent, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
Application implementation example tenFourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, the composite control oranges and tangerines of the fenpropathrin blister mite test of pesticide effectiveness
This test arrangement is Hanzhong City in Shaanxi Province; Test medicine is researched and developed, is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 20% fourth fluorine mite ester suspending agent (autogamy), 25% azacyclotin suspending agent (commercial), 43% Bifenazate suspending agent (commercial), 50% fenbutatin oxide wetting powder (commercial), 20% fenpropathrin milk oil (commercial).
Conventional spray-on process is adopted in test, and investigation oranges and tangerines blister mite insect pest index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 60 days after the dispenser and calculated preventive effect before the medicine.Experimental result is as follows:
Table 8 fourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, the composite control oranges and tangerines of the fenpropathrin blister mite test of pesticide effectiveness
| Handle medicament | The preparation dosage | 10 days preventive effects (%) behind the medicine | 30 days preventive effects (%) behind the medicine | 60 days preventive effects (%) behind the medicine |
| Instance 6 | 4000 times | 98.23 | 99.13 | 98.14 |
| Instance 9 | 2500 times | 98.44 | 99.42 | 98.78 |
| Instance 15 | 2000 times | 97.95 | 98.95 | 97.62 |
| Instance 25 | 6500 times | 98.32 | 98.82 | 98.59 |
| Instance 34 | 3800 times | 98.68 | 98.73 | 98.32 |
| Instance 44 | 2000 times | 97.36 | 98.32 | 98.35 |
| Instance 49 | 6500 times | 98.91 | 99.25 | 98.23 |
| Instance 57 | 4000 times | 98.75 | 99.54 | 97.97 |
| Instance 58 | 3000 times | 97.66 | 98.63 | 98.29 |
| Instance 60 | 4500 times | 98.63 | 99.33 | 98.42 |
| 20% fourth fluorine mite ester suspending agent | 1500 times | 65.78 | 69.56 | 64.27 |
| 25% azacyclotin suspending agent | 1500 times | 65.09 | 69.02 | 65.12 |
| 43% Bifenazate suspending agent | 2000 times | 64.82 | 68.78 | 64.23 |
| 50% fenbutatin oxide wetting powder | 2500 times | 65.79 | 68.24 | 65.57 |
| 20% fenpropathrin milk oil | 1500 times | 64.42 | 67.39 | 63.22 |
Can be found out that by table 8 fourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, fenpropathrin is composite can effectively prevent and treat the oranges and tangerines blister mite, control efficiency all is superior to the preventive effect of single agent, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
Application implementation example tenFourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, the composite control of the fenpropathrin tea tree yellow tea mite test of pesticide effectiveness
This test arrangement is at the Zhejiang Hangzhou Xihu District; Test medicine is researched and developed, is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 20% fourth fluorine mite ester suspending agent (autogamy), 25% azacyclotin suspending agent (commercial), 43% Bifenazate suspending agent (commercial), 50% fenbutatin oxide wetting powder (commercial), 20% fenpropathrin milk oil (commercial).
Conventional spray-on process is adopted in test, and investigation tea tree yellow tea mite insect pest index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 10 days, 30 days, 60 days after the dispenser and calculated preventive effect before the medicine.Experimental result is as follows:
Table 9 fourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, the composite control of the fenpropathrin tea tree yellow tea mite test of pesticide effectiveness
| Handle medicament | The preparation dosage | 10 days preventive effects (%) behind the medicine | 30 days preventive effects (%) behind the medicine | 60 days preventive effects (%) behind the medicine |
| Instance 14 | 3000 times | 98.53 | 99.24 | 98.54 |
| Instance 16 | 2000 times | 97.41 | 98.52 | 97.78 |
| Instance 17 | 2800 times | 98.95 | 99.25 | 98.62 |
| Instance 19 | 3800 times | 98.12 | 99.02 | 98.59 |
| Instance 23 | 5800 times | 98.78 | 99.63 | 98.32 |
| Instance 26 | 1600 times | 97.34 | 98.36 | 98.53 |
| Instance 27 | 3600 times | 98.92 | 99.27 | 98.33 |
| Instance 28 | 2000 times | 97.85 | 98.54 | 97.97 |
| Instance 33 | 2000 times | 97.76 | 98.63 | 98.39 |
| Instance 43 | 3000 times | 98.51 | 99.13 | 98.24 |
| 20% fourth fluorine mite ester suspending agent | 1500 times | 65.78 | 69.56 | 64.27 |
| 25% azacyclotin suspending agent | 1500 times | 65.09 | 69.02 | 65.12 |
| 43% Bifenazate suspending agent | 2000 times | 64.82 | 68.78 | 64.23 |
| 50% fenbutatin oxide wetting powder | 2500 times | 65.79 | 68.24 | 65.57 |
| 20% fenpropathrin milk oil | 1500 times | 64.42 | 67.39 | 63.22 |
Can be found out that by table 9 fourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, fenpropathrin is composite can effectively prevent and treat the tea tree yellow tea mite, control efficiency all is superior to the preventive effect of single agent, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
After draw through not comprovincial test throughout the country; The preventive effect that fourth fluorine mite ester and azacyclotin, Bifenazate, fenbutatin oxide, fenpropathrin be composite processes behind wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, the microcapsule suspension-suspending agent common insects such as tetranychid to all kinds of crops, Tetranychus urticae, tetranychus viennensis, Panonychus citri, wheat leaf pawl mite, phyllocoptruta oleivora, yellow tea mite, Tetranychus cinnabarinus, beginning tetranychid, two spotted spider mite, yellow spider, rust mite, blister mite, pear sucker, oystershell scale is all more than 95%; Be superior to single agent preventive effect, synergistic effect is obvious.
Claims (9)
1. efficient insecticide composition that contains fourth fluorine mite ester; Contain active components A and active component B; It is characterized in that: active components A and active component B weight ratio are 1: 70～70: 1; Described active components A is selected from fourth fluorine mite ester, and active component B is selected from a kind of in azacyclotin, Bifenazate, fenbutatin oxide, the fenpropathrin.
2. the Pesticidal combination that contains fourth fluorine mite ester according to claim 1 is characterized in that: the weight ratio of active components A and active component B is 1: 45～45: 1.
3. the Pesticidal combination that contains fourth fluorine mite ester according to claim 2 is characterized in that: the weight ratio of fourth fluorine mite ester and azacyclotin is 1: 30～20: 1.
4. the Pesticidal combination that contains fourth fluorine mite ester according to claim 2 is characterized in that: fourth fluorine mite ester and Bifenazate weight ratio are 1: 30～20: 1.
5. the Pesticidal combination that contains fourth fluorine mite ester according to claim 2 is characterized in that: the weight ratio of fourth fluorine mite ester and fenbutatin oxide is 1: 30～20: 1.
6. the Pesticidal combination that contains fourth fluorine mite ester according to claim 2 is characterized in that: the weight ratio of fourth fluorine mite ester and fenpropathrin is 1: 10～10: 1.
7. according to each described Pesticidal combination that contains fourth fluorine mite ester in the claim 3 to 6, it is characterized in that: composition is processed wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsules suspension-suspending agent.
8. the purposes that the Pesticidal combination that contains fourth fluorine mite ester according to claim 7 is used to prevent and treat insect on wheat, cotton, fruit tree, vegetables, the tea tree.
9. purposes according to claim 8; It is characterized in that described insect comprises: tetranychid, Tetranychus urticae, tetranychus viennensis, Panonychus citri, wheat leaf pawl mite, phyllocoptruta oleivora, yellow tea mite, Tetranychus cinnabarinus, beginning tetranychid, two spotted spider mite, yellow spider, rust mite, blister mite, pear sucker, oystershell scale.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108041042A (en) * | 2017-12-10 | 2018-05-18 | 广东中迅农科股份有限公司 | A kind of composition pesticide containing cyflumetofen and fluazinam |
| CN111226945A (en) * | 2018-11-29 | 2020-06-05 | 沈阳中化农药化工研发有限公司 | Synergistic insecticidal and acaricidal composition |
| CN112335659A (en) * | 2020-11-16 | 2021-02-09 | 广东省农业科学院农业科研试验示范场 | Pharmaceutical composition for preventing and treating pest mites, pesticide and application |
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| WO2002014263A1 (en) * | 2000-08-11 | 2002-02-21 | Otsuka Chemical Co., Ltd. | Acylacetonitriles, process for preparation thereof and miticides containing the same |
| JP2009209124A (en) * | 2008-02-06 | 2009-09-17 | Nissan Chem Ind Ltd | Insect- or acarian-controlling composition |
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| CN108041042A (en) * | 2017-12-10 | 2018-05-18 | 广东中迅农科股份有限公司 | A kind of composition pesticide containing cyflumetofen and fluazinam |
| CN111226945A (en) * | 2018-11-29 | 2020-06-05 | 沈阳中化农药化工研发有限公司 | Synergistic insecticidal and acaricidal composition |
| CN111226945B (en) * | 2018-11-29 | 2021-11-23 | 沈阳中化农药化工研发有限公司 | Synergistic insecticidal and acaricidal composition |
| CN112335659A (en) * | 2020-11-16 | 2021-02-09 | 广东省农业科学院农业科研试验示范场 | Pharmaceutical composition for preventing and treating pest mites, pesticide and application |
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