CN102618024A - 一种尼龙基纳米复合材料及其制备方法 - Google Patents
一种尼龙基纳米复合材料及其制备方法 Download PDFInfo
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- CN102618024A CN102618024A CN2012100895258A CN201210089525A CN102618024A CN 102618024 A CN102618024 A CN 102618024A CN 2012100895258 A CN2012100895258 A CN 2012100895258A CN 201210089525 A CN201210089525 A CN 201210089525A CN 102618024 A CN102618024 A CN 102618024A
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- composite material
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- based nano
- barrier
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- 239000000463 material Substances 0.000 title claims abstract description 63
- 239000004677 Nylon Substances 0.000 title claims abstract description 39
- 229920001778 nylon Polymers 0.000 title claims abstract description 39
- 239000002114 nanocomposite Substances 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000000945 filler Substances 0.000 claims abstract description 20
- 229920006122 polyamide resin Polymers 0.000 claims abstract description 13
- 239000012745 toughening agent Substances 0.000 claims abstract description 6
- 230000004888 barrier function Effects 0.000 claims description 51
- 229920000642 polymer Polymers 0.000 claims description 19
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 17
- 239000012752 auxiliary agent Substances 0.000 claims description 15
- 239000000314 lubricant Substances 0.000 claims description 13
- 239000003921 oil Substances 0.000 claims description 13
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 239000003112 inhibitor Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 229920002292 Nylon 6 Polymers 0.000 claims description 8
- 238000006136 alcoholysis reaction Methods 0.000 claims description 8
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 7
- UFRKOOWSQGXVKV-UHFFFAOYSA-N ethene;ethenol Chemical compound C=C.OC=C UFRKOOWSQGXVKV-UHFFFAOYSA-N 0.000 claims description 7
- 239000004715 ethylene vinyl alcohol Substances 0.000 claims description 7
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 6
- 239000003963 antioxidant agent Substances 0.000 claims description 6
- 230000003078 antioxidant effect Effects 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 6
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 6
- -1 polyethylene terephthalate Polymers 0.000 claims description 4
- 239000001993 wax Substances 0.000 claims description 4
- 229920002943 EPDM rubber Polymers 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 3
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 239000005749 Copper compound Substances 0.000 claims description 2
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 claims description 2
- 229920000299 Nylon 12 Polymers 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 2
- 239000008116 calcium stearate Substances 0.000 claims description 2
- 235000013539 calcium stearate Nutrition 0.000 claims description 2
- 150000001880 copper compounds Chemical class 0.000 claims description 2
- 229920001971 elastomer Polymers 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- ZJOLCKGSXLIVAA-UHFFFAOYSA-N ethene;octadecanamide Chemical compound C=C.CCCCCCCCCCCCCCCCCC(N)=O.CCCCCCCCCCCCCCCCCC(N)=O ZJOLCKGSXLIVAA-UHFFFAOYSA-N 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 150000002989 phenols Chemical class 0.000 claims description 2
- 150000008301 phosphite esters Chemical class 0.000 claims description 2
- 229920006124 polyolefin elastomer Polymers 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 239000005060 rubber Substances 0.000 claims description 2
- 239000000344 soap Substances 0.000 claims description 2
- 239000007858 starting material Substances 0.000 claims description 2
- 229920001897 terpolymer Polymers 0.000 claims description 2
- 238000005303 weighing Methods 0.000 claims description 2
- 239000002828 fuel tank Substances 0.000 abstract description 28
- 239000000295 fuel oil Substances 0.000 abstract description 8
- 239000000126 substance Substances 0.000 abstract description 6
- 238000012856 packing Methods 0.000 abstract description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000446 fuel Substances 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 2
- 238000000071 blow moulding Methods 0.000 abstract description 2
- 239000001301 oxygen Substances 0.000 abstract description 2
- 229910052760 oxygen Inorganic materials 0.000 abstract description 2
- 230000000903 blocking effect Effects 0.000 abstract 4
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 238000001746 injection moulding Methods 0.000 abstract 1
- 239000010687 lubricating oil Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 13
- 229920001903 high density polyethylene Polymers 0.000 description 11
- 239000004700 high-density polyethylene Substances 0.000 description 11
- 229920003023 plastic Polymers 0.000 description 10
- 239000004033 plastic Substances 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 150000003384 small molecules Chemical class 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 238000012216 screening Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
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- 230000008569 process Effects 0.000 description 4
- 239000004567 concrete Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003502 gasoline Substances 0.000 description 3
- 230000008595 infiltration Effects 0.000 description 3
- 238000001764 infiltration Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000004334 fluoridation Methods 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- 229920006659 PA12 Polymers 0.000 description 1
- 239000007977 PBT buffer Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/505—Screws
- B29C48/625—Screws characterised by the ratio of the threaded length of the screw to its outside diameter [L/D ratio]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92885—Screw or gear
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN2012100895258A CN102618024A (zh) | 2012-03-30 | 2012-03-30 | 一种尼龙基纳米复合材料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2012100895258A CN102618024A (zh) | 2012-03-30 | 2012-03-30 | 一种尼龙基纳米复合材料及其制备方法 |
Publications (1)
Publication Number | Publication Date |
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CN102618024A true CN102618024A (zh) | 2012-08-01 |
Family
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Family Applications (1)
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CN2012100895258A Pending CN102618024A (zh) | 2012-03-30 | 2012-03-30 | 一种尼龙基纳米复合材料及其制备方法 |
Country Status (1)
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CN (1) | CN102618024A (zh) |
Cited By (23)
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CN102977598A (zh) * | 2012-08-20 | 2013-03-20 | 安徽凯迪电气有限公司 | 一种pbt改性的尼龙pa66粒子料及其制备方法及在汽车上的应用 |
CN102993701A (zh) * | 2012-10-19 | 2013-03-27 | 芜湖市鑫海橡塑制品有限责任公司 | 一种汽车油管用改性尼龙pa6材料及其制备方法 |
CN102993692A (zh) * | 2012-08-20 | 2013-03-27 | 安徽凯迪电气有限公司 | 一种原料含有改性凹凸棒土的仪表托架的制造工艺 |
CN103613922A (zh) * | 2013-11-29 | 2014-03-05 | 江门市奇德工程塑料科技有限公司 | 一种高阻隔纳米pa6纳米复合材料及其制备方法 |
CN104910617A (zh) * | 2015-05-27 | 2015-09-16 | 苏州博利迈新材料科技有限公司 | 一种防渗透阻燃尼龙复合材料及其制备方法 |
CN104974503A (zh) * | 2015-06-23 | 2015-10-14 | 苏州博利迈新材料科技有限公司 | 隔热型汽车用纳米pa复合材料及其制备方法 |
CN105985624A (zh) * | 2015-02-13 | 2016-10-05 | 常州大学 | 用于油田柔性集输油管传输层的管用材料及其制备方法 |
CN106398203A (zh) * | 2016-08-31 | 2017-02-15 | 合肥邦立电子股份有限公司 | 一种车载usb2.0连接线束外护套材料 |
CN106751764A (zh) * | 2017-01-20 | 2017-05-31 | 叶红燕 | 一种pet‑聚酰胺阻隔材料及其制备方法和应用 |
CN107011652A (zh) * | 2017-05-05 | 2017-08-04 | 江苏龙迪高分子科技有限公司 | 一种适用于生物柴油的汽车燃油箱及其制备方法 |
CN107541033A (zh) * | 2017-08-30 | 2018-01-05 | 华南理工大学 | 一种高气体阻隔性纳米复合材料及其制备方法 |
CN107805388A (zh) * | 2017-09-14 | 2018-03-16 | 杨智航 | 一种塑料合金阻隔母料及其制备方法和应用 |
CN108047712A (zh) * | 2017-12-14 | 2018-05-18 | 广东思汗新材料有限公司 | 阻燃尼龙66复合材料及其制备方法 |
CN109517374A (zh) * | 2018-11-30 | 2019-03-26 | 公安部沈阳消防研究所 | 高阻隔性尼龙复合材料及其制备方法 |
CN109575529A (zh) * | 2018-11-27 | 2019-04-05 | 浙江乐岁新材料有限公司 | 一种用于制作食品盒的片材及其制备方法 |
CN110982259A (zh) * | 2019-12-02 | 2020-04-10 | 东北林业大学 | 一种完全生物降解高阻隔聚酰胺基复合薄膜材料及其制备方法 |
CN111117217A (zh) * | 2019-12-26 | 2020-05-08 | 上海普利特复合材料股份有限公司 | 一种用于注塑成型低渗透燃油箱尼龙材料及其制备方法 |
CN111718578A (zh) * | 2020-06-30 | 2020-09-29 | 重庆科聚孚工程塑料有限责任公司 | 一种乙醇汽油油箱用聚酰胺6复合材料及其制备方法 |
CN112824740A (zh) * | 2019-11-20 | 2021-05-21 | 刘振国 | 一种储氢罐内胆及其制备方法 |
CN113388247A (zh) * | 2021-06-09 | 2021-09-14 | 昆山运融新材料科技有限公司 | 一种用于食品包装材料的高阻隔尼龙母料及其制备方法 |
CN113881221A (zh) * | 2021-11-12 | 2022-01-04 | 惠州市晋裕塑料科技有限公司 | 一种高阻隔尼龙共混材料 |
CN114181524A (zh) * | 2021-12-14 | 2022-03-15 | 上汽大众汽车有限公司 | 燃油分配管和塑料粒子的生产方法 |
CN114621550A (zh) * | 2022-02-28 | 2022-06-14 | 上海金发科技发展有限公司 | 一种软触感低气味低tvoc聚丙烯复合材料及其制备方法和应用 |
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CN101845231A (zh) * | 2010-04-08 | 2010-09-29 | 湖南工业大学 | 一种高阻隔纳米复合材料的制备方法 |
CN101921476A (zh) * | 2010-09-29 | 2010-12-22 | 重庆可倍多塑料有限公司 | 高阻隔性加纤阻燃吹塑尼龙复合材料及其制备方法 |
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CN101659786A (zh) * | 2009-09-22 | 2010-03-03 | 东莞市意普万工程塑料有限公司 | 一种燃油箱用低燃油渗透率尼龙复合材料及其制备方法 |
CN101845231A (zh) * | 2010-04-08 | 2010-09-29 | 湖南工业大学 | 一种高阻隔纳米复合材料的制备方法 |
CN101921476A (zh) * | 2010-09-29 | 2010-12-22 | 重庆可倍多塑料有限公司 | 高阻隔性加纤阻燃吹塑尼龙复合材料及其制备方法 |
CN102382429A (zh) * | 2011-10-24 | 2012-03-21 | 广州市信联智通实业有限公司 | 一种聚对苯二甲酸乙二醇酯阻隔性复合材料及其制备工艺 |
Cited By (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102977598A (zh) * | 2012-08-20 | 2013-03-20 | 安徽凯迪电气有限公司 | 一种pbt改性的尼龙pa66粒子料及其制备方法及在汽车上的应用 |
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