CN102604546A - High-transparent EVA (ethylene-vinyl acetate) laminated film - Google Patents

High-transparent EVA (ethylene-vinyl acetate) laminated film Download PDF

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Publication number
CN102604546A
CN102604546A CN2012100405899A CN201210040589A CN102604546A CN 102604546 A CN102604546 A CN 102604546A CN 2012100405899 A CN2012100405899 A CN 2012100405899A CN 201210040589 A CN201210040589 A CN 201210040589A CN 102604546 A CN102604546 A CN 102604546A
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CN
China
Prior art keywords
eva
laminated film
transparent eva
ethylene
sebate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2012100405899A
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Chinese (zh)
Inventor
郑建华
李晓羽
章文明
陈武杰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHEJIANG YANGMING PHOTOVOLTAIC MATERIAL CO Ltd
Original Assignee
ZHEJIANG YANGMING PHOTOVOLTAIC MATERIAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ZHEJIANG YANGMING PHOTOVOLTAIC MATERIAL CO Ltd filed Critical ZHEJIANG YANGMING PHOTOVOLTAIC MATERIAL CO Ltd
Priority to CN2012100405899A priority Critical patent/CN102604546A/en
Publication of CN102604546A publication Critical patent/CN102604546A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a high-transparent EVA (ethylene-vinyl acetate) laminated film which is prepared by mixing 90-99% of EVA (MA-10), 0.2-5% of 1,1-di-tert-butyl peroxide-3,3,5-trimethyl cyclohexane, 0.05-4% of methacryloxy functional-group alkyl silane, 0.1-1% of bis (2,2,6,6-tetramethyl-4-piperidyl) sebate, 0.1-2% of dioctadecyl pentaerythritol diphosphite ester and 0.2-1% of triethylene glycol bi beta (3-tertiary butyl-4-hydroxy-5-methyl phenyl) propionic ester. The high-transparent EVA laminated film can be well adhered to the glass, has high transmittance, low turbidity and simple production process, is easy to control and can be widely applied to the field of the automobile, aviation, construction and financial industries.

Description

A kind of high transparent EVA interlayer film
Technical field
The present invention relates to the EVA film, particularly a kind of high transparent EVA interlayer film.
Background technology
Laminated glass is a kind of ambetti of decorating with security that integrates, and has a extensive future.It not only can protect the person and property safety, but also keeps the attractive in appearance, transparent of glass, can select the pattern of decorating film simultaneously according to hobby, has application surface very widely.
At present; The widely used middle layer of China's laminated glass industry adhesives is polyvinyl butyral film (a PVB film); The PVB film can bonding effectively unorganic glass in very wide TR; But low with the bonding strength of polycarbonate (PC) plate, PET plate etc., transparency is not high, and phenomenon such as easy embrittlement of PVB film and delamination at low temperatures; Simultaneously compound thermal expansivity differs bigger inorganic---organic materials.
Summary of the invention
In order to overcome the above-mentioned weak point that exists in the prior art, the object of the present invention is to provide a kind of high transparent EVA interlayer film.
In order to reach above-mentioned purpose, the present invention adopts following concrete technical scheme: a kind of high transparent EVA interlayer film is characterized in that: contain EVA (MA-10), 1; 1;-di-tert-butyl peroxide-3,3,5-trimethylammonium cyclohexane, methacryloxy functional groups alkyl silane, two (2; 2; 6,6-tetramethyl--4-piperidyl) sebate, two octadecyl season amylalcohol bis-phosphite and the two β of triglycol-(3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionic ester, it is following that each organizes the quality ratio range:
EVA?(MA-10) 90%~99%
1,1 ,-di-tert-butyl peroxide-3,3,5-trimethylammonium cyclohexane 0.2%~5%
Methacryloxy functional groups alkyl silane 0.05%~4%
Two (2,2,6,6-tetramethyl--4-piperidyl) sebate 0.1%~1%
Two octadecyl season amylalcohol bis-phosphite 0.1%~2%
Two β (3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionic esters 0.2%~1% of triglycol.
Compared with prior art; The present invention has following outstanding advantage and effect: the high transparent EVA film through the present invention obtains, glass is had good bounding force, and transmittance is high; Turbidity is low; And production technique is simple, and control can be widely used in industry fields such as automobile, aviation, building, finance easily.
Embodiment
Mode through embodiment further specifies the present invention below, therefore the present invention is not limit
Among described scope of embodiments.
Embodiment 1
Get mass percent 91%EVA (MA-10), 4%1; 1 ,-di-tert-butyl peroxide-3,3; 5-trimethylammonium cyclohexane, 3% methacryloxy functional groups alkyl silane, 0.7% pair (2; 2,6,6-tetramethyl--4-piperidyl) sebate, 1% pair octadecyl season amylalcohol bis-phosphite and the 0.3% triglycol a kind of high transparent EVA interlayer film that two β-(3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionic ester is mixed with after mixing.
Embodiment 2
Get mass percent 97%EVA (MA-10), 1%1; 1 ,-di-tert-butyl peroxide-3,3; 5-trimethylammonium cyclohexane, 0.5% methacryloxy functional groups alkyl silane, 0.5% pair (2; 2,6,6-tetramethyl--4-piperidyl) sebate, 0.5% pair octadecyl season amylalcohol bis-phosphite and the 0.5% triglycol a kind of high transparent EVA interlayer film that two β-(3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionic ester is mixed with after mixing.

Claims (1)

1. one kind high transparent EVA interlayer film is characterized in that: contain EVA (MA-10), 1,1;-di-tert-butyl peroxide-3,3,5-trimethylammonium cyclohexane, methacryloxy functional groups alkyl silane, two (2; 2; 6,6-tetramethyl--4-piperidyl) sebate, two octadecyl season amylalcohol bis-phosphite and the two β of triglycol-(3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionic ester, it is following that each organizes the quality ratio range:
EVA?(MA-10) 90%~99%
1,1 ,-di-tert-butyl peroxide-3,3,5-trimethylammonium cyclohexane 0.2%~5%
Methacryloxy functional groups alkyl silane 0.05%~4%
Two (2,2,6,6-tetramethyl--4-piperidyl) sebate 0.1%~1%
Two octadecyl season amylalcohol bis-phosphite 0.1%~2%
Two β (3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionic esters 0.2%~1% of triglycol.
CN2012100405899A 2012-02-22 2012-02-22 High-transparent EVA (ethylene-vinyl acetate) laminated film Pending CN102604546A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2012100405899A CN102604546A (en) 2012-02-22 2012-02-22 High-transparent EVA (ethylene-vinyl acetate) laminated film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2012100405899A CN102604546A (en) 2012-02-22 2012-02-22 High-transparent EVA (ethylene-vinyl acetate) laminated film

Publications (1)

Publication Number Publication Date
CN102604546A true CN102604546A (en) 2012-07-25

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN2012100405899A Pending CN102604546A (en) 2012-02-22 2012-02-22 High-transparent EVA (ethylene-vinyl acetate) laminated film

Country Status (1)

Country Link
CN (1) CN102604546A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153958A (en) * 2011-01-11 2011-08-17 广州市宝力达电气材料有限公司 EVA (ethylene-vinyl acetate) adhesive film for heat-resistant solar battery, and preparation method and application thereof
CN102304331A (en) * 2011-08-25 2012-01-04 詹显光 Aging resistant EVA adhesive film capable of ultraviolet ray transmitting, and preparation method thereof
CN102304332A (en) * 2011-08-25 2012-01-04 詹显光 Ultraviolet-ray-blocking and anti-aging ethylene-vinyl acetate (EVA) adhesive film and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153958A (en) * 2011-01-11 2011-08-17 广州市宝力达电气材料有限公司 EVA (ethylene-vinyl acetate) adhesive film for heat-resistant solar battery, and preparation method and application thereof
CN102304331A (en) * 2011-08-25 2012-01-04 詹显光 Aging resistant EVA adhesive film capable of ultraviolet ray transmitting, and preparation method thereof
CN102304332A (en) * 2011-08-25 2012-01-04 詹显光 Ultraviolet-ray-blocking and anti-aging ethylene-vinyl acetate (EVA) adhesive film and preparation method thereof

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Application publication date: 20120725