CN102593420A - Electrode production apparatus and electrode production method - Google Patents
Electrode production apparatus and electrode production method Download PDFInfo
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- CN102593420A CN102593420A CN2012100103545A CN201210010354A CN102593420A CN 102593420 A CN102593420 A CN 102593420A CN 2012100103545 A CN2012100103545 A CN 2012100103545A CN 201210010354 A CN201210010354 A CN 201210010354A CN 102593420 A CN102593420 A CN 102593420A
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 58
- 239000011149 active material Substances 0.000 claims abstract description 164
- 238000001035 drying Methods 0.000 claims abstract description 74
- 239000000463 material Substances 0.000 claims abstract description 48
- 238000000576 coating method Methods 0.000 claims abstract description 43
- 239000011248 coating agent Substances 0.000 claims abstract description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 238000011144 upstream manufacturing Methods 0.000 claims description 28
- 239000002904 solvent Substances 0.000 claims description 27
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 20
- 239000003990 capacitor Substances 0.000 claims description 20
- 229910001416 lithium ion Inorganic materials 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 11
- 230000005855 radiation Effects 0.000 claims description 7
- 239000000758 substrate Substances 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 abstract description 116
- 239000002184 metal Substances 0.000 abstract description 116
- 239000011888 foil Substances 0.000 abstract 5
- 239000004606 Fillers/Extenders Substances 0.000 abstract 2
- 238000004804 winding Methods 0.000 abstract 2
- 238000009835 boiling Methods 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 230000000875 corresponding effect Effects 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000009795 derivation Methods 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 238000002835 absorbance Methods 0.000 description 2
- 239000006230 acetylene black Substances 0.000 description 2
- 230000002596 correlated effect Effects 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000003522 acrylic cement Substances 0.000 description 1
- 239000005030 aluminium foil Substances 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 230000010165 autogamy Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000007774 positive electrode material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G13/00—Apparatus specially adapted for manufacturing capacitors; Processes specially adapted for manufacturing capacitors not provided for in groups H01G4/00 - H01G11/00
- H01G13/04—Drying; Impregnating
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/04—Hybrid capacitors
- H01G11/06—Hybrid capacitors with one of the electrodes allowing ions to be reversibly doped thereinto, e.g. lithium ion capacitors [LIC]
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
- H01G11/34—Carbon-based characterised by carbonisation or activation of carbon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
- H01G11/86—Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G13/00—Apparatus specially adapted for manufacturing capacitors; Processes specially adapted for manufacturing capacitors not provided for in groups H01G4/00 - H01G11/00
- H01G13/02—Machines for winding capacitors
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Fixed Capacitors And Capacitor Manufacturing Machines (AREA)
Abstract
The invention provides an electrode production apparatus, wherein an active material layer is formed adaptly on the surface of local belt type base material when an electrode is produced. The electrode production device includes the components as following: unwinding roller (10) for unwinding belt type metal foil (M); a coating portion (11) for coating active material extender on both surfaces of the metal foil (M); a drying portion (12) for drying the active material on the metal foil (M) to form active material layers; and winding roller (13) for winding metal foil (M). The drying portion (12) possesses a plurality of LEDs (30) which emit infrared and are arranged at the long edge direction of the metal foil (M). The drying portion (12) is divided into a plurality of areas (Ta, Tb, Tc). The peak of LED (30) in one area (Ta, Tb, Tc) is the infrared length wherein the active extender is not boiled, the luminent wavelength is set as the biggest length when the absorptance of the infarared of water reaches the maximum value.
Description
Technical field
The present invention relates to form active material layer to make the electrode manufacturing apparatus and the electrode manufacturing method of electrode on the two sides of the base material of band shape.
Background technology
In recent years; Utilize the characteristic that small-sized, light weight and energy density are high and can repeat to discharge and recharge, the needs of the electrochemical element of lithium-ion capacitor (LIC:Lithium Ion Capacitor), electric double layer capacitor (EDLC:Electric Double Lay Capacitor) and lithium ion battery (LIB:Lithium Ion Battery) etc. are expansion fast.
Lithium ion battery is because energy density is bigger, so be used in fields such as mobile phone, subnotebook PC.In addition, electric double layer capacitor is because can fast charging and discharging, so be utilized as the memory backup Miniature Power Unit of PC etc.And electric double layer capacitor is also had the application as the large-scale power supply of used for electric vehicle by expectation.In addition, the lithium-ion capacitor of the advantage of the advantage of combination lithium ion battery and electric double layer capacitor is paid close attention to because of energy density, output density are all high.
The electrode of such electrochemical element, for example with after containing the active material intermixture of active material and/or solvent (solvent) in the surface applied as the metal forming of the collector body of base material, the mode that dry this active material intermixture forms active material layer is made.In the manufacturing of relevant electrode, for example use the electrode manufacturing apparatus that between let off roll and takers-in, disposes applying device and drying machine.Applying device has the coating head, and this coating capitiform becomes to be useful on the coating mouth that applies the active material intermixture.In addition, drying machine has a plurality of heaters with the predetermined distance configuration.And, in the banded metal forming of conveyance above approximately vertical on one side between let off roll and the takers-in,, the surface of metal forming is carried out the coating and the drying (patent documentation 1) of active material intermixture respectively on one side through applying device and drying machine.
The prior art document
Patent documentation 1: TOHKEMY 2010-186782 communique
Summary of the invention
The problem that invention will solve
At this, when the active material intermixture that makes the surface that is applied to metal forming is dry,, then might produce convection current and/or bubble in the internal solvent boiling of active material intermixture if carry out rapid drying.Under this kind situation, the surface of the active material layer on metal forming forms concavo-convex, and can not suitably form active material layer.In addition, also might peel off in the generation of the border of metal forming and active material layer.
But, in the drying machine of patent documentation 1 record, only dispose a plurality of heaters, the countermeasure of the rapid drying of considering to be used to avoid above-mentioned with predetermined distance.Therefore, can not on the surface of metal forming, suitably form active material layer.
On the other hand, also considering has: dispose a plurality of above-mentioned heaters, guarantee sufficient drying time, with dried active material intermixture little by little.But under this kind situation, the length of drying machine is elongated, can not make the active material intermixture dry efficiently.
The present invention accomplishes in view of above-mentioned relevant point, and its purpose is: when making electrode, suitably and efficiently the substrate surface in band shape forms active material layer.
Be used to solve the method for problem
In order to reach above-mentioned purpose, the present invention is a kind of electrode manufacturing apparatus, and its two sides at the base material of band shape forms active material layer to make electrode, and this electrode manufacturing apparatus is characterised in that, comprising: the portion that unreels that unreels base material; Reeling end, it batches above-mentioned and unreels the base material that portion is unreeled; Coating portion, it is arranged on above-mentioned unreeling between portion and the above-mentioned reeling end, applies the active material intermixture that is mixed with active material and solvent on the two sides of base material; And drying section; It is arranged between above-mentioned coating portion and the above-mentioned reeling end; Make in the above-mentioned coated above-mentioned active material intermixture drying of coating portion and form active material layer; Above-mentioned drying section has in the long side direction alignment arrangements of substrate and sends ultrared a plurality of LED (Light Emitting Diode: light-emitting diode); Above-mentioned drying section is split into the different a plurality of zones of emission wavelength that luminous intensity reaches maximum LED, and the emission wavelength of the above-mentioned LED in above-mentioned zone is the thickness for the above-mentioned solvent on the base material in this zone; The ultrared wavelength of the scope that above-mentioned active material intermixture does not seethe with excitement, the ultrared absorptivity that is set to above-mentioned solvent reaches maximum wavelength.In addition, in the present invention, the active material intermixture does not seethe with excitement and is meant that the solvent in this active material intermixture does not seethe with excitement.
Adopt the present invention; Drying section is split into a plurality of zones; The emission wavelength of the LED in a zone is set to the wavelength of the scope that the active material intermixture do not seethe with excitement; The surface that therefore can not form the active material layer of ground on base material as prior art forms concavo-convex, can have the active material layer on level and smooth surface with the thickness formation of equalization.In addition, also can not peel off in the generation of the border of base material and active material layer.And the ultrared absorptivity that the emission wavelength of the LED in zone is set to solvent reaches maximum wavelength, therefore can heat the active material intermixture efficiently and make its drying.And carry out in each zone that is set in of the emission wavelength of such LED, therefore compared with prior art can shorten the drying time of active material intermixture, also can shorten the length of drying section.According to the present invention, can suitably and efficiently form active material layer as stated on the surface of base material.
Above-mentioned solvent can be a water.
Above-mentioned drying section; Unreel 3 zones that portion's side is split into upstream region, zone, middle reaches and downstream area from above-mentioned; The emission wavelength that is configured in the LED of above-mentioned upstream region can be 6 μ m; The emission wavelength that is configured in the LED of above-mentioned downstream area can be 3 μ m, can dispose the LED less than the emission wavelength of 6 μ m greater than 3 μ m in zone, above-mentioned middle reaches.
Above-mentioned drying section; Unreel 3 zones that portion's side is split into upstream region, zone, middle reaches and downstream area from above-mentioned; The emission wavelength that is disposed at the LED of above-mentioned upstream region can be 6 μ m; The emission wavelength that is disposed at the LED of above-mentioned downstream area can be 3 μ m, can dispose the LED of above-mentioned upstream region and the LED of above-mentioned downstream area in zone, above-mentioned middle reaches with mixing.
Above-mentioned drying section can have air fed gas supply mechanism between above-mentioned a plurality of LED and base material.
Above-mentionedly unreel portion and above-mentioned reeling end can be configured to: with the long side direction of base material be the short side direction of horizontal direction and base material be vertical direction towards the conveyance base material.
Above-mentioned electrode can be the electrode that in lithium-ion capacitor, electric double layer capacitor or lithium ion battery, uses.
The present invention according to other viewpoints is; One side is the banded base material of conveyance between portion of unreeling and reeling end; Make the electrode manufacturing method of electrode on one side at the two sides of this base material formation active material layer; It is characterized in that, comprising: working procedure of coating, the active material intermixture that will be mixed with active material and solvent in coating portion is coated in the two sides of base material; After this drying process; At drying section; Make the above-mentioned active material intermixture drying that applies at above-mentioned working procedure of coating and form active material layer, above-mentioned drying section has in the long side direction alignment arrangements of substrate and sends ultrared a plurality of LED, and above-mentioned drying section is split into the different a plurality of zones of emission wavelength that luminous intensity reaches the LED of maximum; The emission wavelength of above-mentioned LED in above-mentioned zone; Be thickness for the above-mentioned solvent on the base material in this zone, the ultrared wavelength of the scope that above-mentioned active material intermixture does not seethe with excitement, the ultrared absorptivity that is set to above-mentioned solvent reaches maximum wavelength.
Above-mentioned solvent can be water.
Above-mentioned drying section; Unreel 3 zones that portion's side is split into upstream region, zone, middle reaches and downstream area from above-mentioned; The emission wavelength that is configured in the LED of above-mentioned upstream region can be 6 μ m; The emission wavelength that is configured in the LED of above-mentioned downstream area can be 3 μ m, can dispose the LED less than the emission wavelength of 6 μ m greater than 3 μ m in zone, above-mentioned middle reaches.
Above-mentioned drying section; Unreel 3 zones that portion's side is split into upstream region, zone, middle reaches and downstream area from above-mentioned; The emission wavelength that is disposed at the LED of above-mentioned upstream region can be 6 μ m; The emission wavelength that is disposed at the LED of above-mentioned downstream area can be 3 μ m, can dispose the LED of above-mentioned upstream region and the LED of above-mentioned downstream area in zone, above-mentioned middle reaches with mixing.
Above-mentioned drying section can have air fed gas supply mechanism between above-mentioned a plurality of LED and base material; In above-mentioned drying process; Can make above-mentioned active material intermixture dry through radiation heating that produces by infrared ray and the Convective Heating that produces by the air of supplying with from above-mentioned gas supply mechanism from above-mentioned a plurality of LED.
The short side direction that can be horizontal direction and base material with the long side direction of base material be vertical direction towards, the base material in the conveyance is carried out above-mentioned working procedure of coating and above-mentioned drying process.
Above-mentioned electrode is the electrode that in lithium-ion capacitor, electric double layer capacitor or lithium ion battery, uses.
The effect of invention
According to the present invention, when making electrode, can suitably and efficiently form active material layer on the surface of the base material of band shape
Description of drawings
Fig. 1 is the schematic side view of summary of the structure of the expression electrode manufacturing apparatus that relates to this execution mode.
Fig. 2 is the plane graph of structure that expression relates to the electrode manufacturing apparatus of this execution mode.
Fig. 3 is the end view by the electrode of electrode manufacturing apparatus manufacturing.
Fig. 4 is the plane graph by the electrode of electrode manufacturing apparatus manufacturing.
Fig. 5 is the stereogram of the summary of the expression structure that applies head.
Fig. 6 is the end view of summary of the structure of expression drying section.
Fig. 7 is the plane graph of summary of the structure of expression drying section.
Fig. 8 is the flow chart of the operation of the expression peak value emission wavelength of setting LED.
Fig. 9 figure relevant that be expression ultrared wavelength that LED sent with first of the infrared ray absorbing rate of water.
Figure 10 figure relevant that be expression ultrared wavelength that LED sent with second of the luminous intensity of LED.
Figure 11 is the figure of third phase pass of the luminous intensity of the LED of the boiling of thickness and the active material intermixture of the water in the expression active material intermixture when beginning.
Figure 12 is the plane graph of summary of the structure of the expression coating portion that relates to other execution modes.
Figure 13 is the simple plane graph of summary of the structure of the expression electrode manufacturing apparatus that relates to other execution modes.
Figure 14 is the end view of summary of the structure of the expression electrode manufacturing apparatus that relates to other execution mode.
Symbol description
1 electrode manufacturing apparatus
10 let off roll
11 coating portions
12 drying sections
13 takers-ins
30LED
30a upper reaches LED
30b middle reaches LED
30c downstream LED
40 reflecting plates
41 air supply openings
42 air supply pipes
43 air supply sources
50 control parts
The D arid region
The E electrode
The F active material layer
The M metal forming
S active material intermixture
The Ta upstream region
Zone, Tb middle reaches
The Tc downstream area
Embodiment
Below, execution mode of the present invention is described.Fig. 1 is the schematic side view of summary of the structure of the expression electrode manufacturing apparatus 1 that relates to this execution mode.Fig. 2 is the plane graph of summary of the structure of expression electrode manufacturing apparatus 1.In addition, in the electrode manufacturing apparatus 1 of this execution mode, make the electrode of lithium-ion capacitor.
In electrode manufacturing apparatus 1, be manufactured on the electrode E that is formed with active material layer F as the two sides of the metal forming M of the base material of band shape like Fig. 3 and shown in Figure 4.The active material layer F on the two sides of metal forming M relatively forms.In addition, active material layer F is formed on the central portion of the short side direction (the Z direction among Fig. 3) of metal forming M, and is formed with a plurality of at the long side direction (the Y direction among Fig. 3 and Fig. 4) of metal forming M.
Metal forming M is the collector body of porous matter for example.When making positive pole, for example use aluminium foil as electrode E as metal forming M.On the other hand, when making negative pole, for example use Copper Foil as metal forming M.
In addition, in order to form active material layer F, be covered with slimy active material intermixture in the surfaces coated of metal forming M like the back saidly.Positive active material intermixture when making positive pole; For example through mixing the conductive carbon powders of the acetylene black that helps material as the active carbon of active material, as the acrylic adhesive of sticker, as the carboxymethyl cellulose of dispersant with as conduction etc.; And add water as solvent to it, mediate and generate.On the other hand; Negative electrode active material intermixture when making negative pole; But for example through mixing as occlusion, emit the amorphous carbon of the active material of lithium ion, helping the conductive carbon raw material of the acetylene black etc. of material as the Kynoar of sticker with as conduction; And add water as solvent to it, mediate and generate.
Positive pole and negative pole, though material is different as stated, the width of metal forming M and active material layer F, thickness etc. do not have too big difference.Therefore, electrode manufacturing apparatus 1 positive pole that not only can make lithium-ion capacitor also can be made negative pole.Below, anodal and negative pole is called electrode E and describes with these.
Let off roll 10 be configured to its direction of principal axis be vertical direction (the Z direction among Fig. 1) towards.In let off roll 10, be wound with untreated metal forming M, it can be the center rotation with vertical axle that let off roll 10 constitutes.And metal forming M is along with being stretched at its long side direction and unreeling from let off roll 10.
Takers-in 13 also be configured to its direction of principal axis be vertical direction towards.It can be the center rotation with vertical axle that takers-in 13 constitutes.And the metal forming M that is formed with active material layer F batches takers-in 13.
These let off roll 10 are configured in identical height with takers-in 13.And let off roll 10 is configured to takers-in 13: the long side direction of metal forming M be the short side direction of horizontal direction (the Y direction among Fig. 1 and Fig. 2) and metal forming M be vertical direction (the Z direction among Fig. 1) towards, conveyance metal forming M.
Apply 20, as shown in Figure 5 have an about rectangular shape that extends in vertical direction (the Z direction among Fig. 5).Apply 20 for example form longer than the short side direction of metal forming M.At a face relative that applies 20, be formed with the coating mouth 21 of the slit-shaped of ejection active material intermixture with metal forming M.Coating mouth 21 forms in vertical direction (the Z direction among Fig. 5) and extends.In addition, apply mouthfuls 21 and be formed on position from the active material intermixture to the central portion of the short side direction of metal forming M that to supply with.In addition, apply a supply pipe 23 that 20 connections are communicated with active material intermixture supply source 22.Inner product at active material intermixture supply source 22 has the active material intermixture, and can be from active material intermixture supply source 22 to applying 20 a supply active material intermixture.
Drying section 12 is as being split into a plurality of for example 3 regional Ta, Tb, Tc on Fig. 1, Fig. 2 and the long side direction at metal forming M shown in Figure 6 (the Y direction among Fig. 1, Fig. 2 and Fig. 6).Below, promptly begin from let off roll 10 sides at the upstream side of the conveyance direction of metal forming M, these 3 regional Ta, Tb, Tc are called " upstream region Ta ", " zone, middle reaches Tb ", " downstream area Tc " respectively.In addition, the different zone of peak value emission wavelength of each LED30 that states after these 3 regional Ta, Tb, Tc are segmented in.
In addition, drying section 12, as shown in Figure 7 have send ultrared a plurality of LED (Light Emitting Doide: light-emitting diode) 30.LED30 goes up alignment arrangements at the long side direction (the Y direction among Fig. 7) of metal forming M.These LED30 are configured in the both sides of the metal forming M in the conveyance between let off roll 10 and the takers-in 13.In addition, LED30 is provided with longlyer than the length of the short side direction of metal forming M on vertical direction.That is, LED30 can send infrared ray to the short side direction integral body of metal forming M.
In addition, as stated, drying section 12 is split into different 3 regional Ta, Tb, the Tc of emission wavelength (below, be also referred to as " peak value emission wavelength ") that luminous intensity reaches the emission wavelength LED30 of maximum LED30.So for ease; Like Fig. 1, Fig. 2 and shown in Figure 6; Also the LED30 that is disposed at upstream region Ta among a plurality of LED30 is called " upper reaches LED30a "; The LED30 that is disposed at zone, middle reaches Tb is called " middle reaches LED30b ", the LED30 that is disposed at downstream area Tc is called " downstream LED30c ".In addition, the method about the peak value emission wavelength of setting these upper reaches LED30a, middle reaches LED30b, downstream LED30c is elaborated following.
In addition, drying section 12 is as shown in Figure 7 to have reflecting plate 40, and its surface that clips LED30 and metal forming M relatively disposes, and makes infrared reflection from LED30 to metal forming M side.Reflecting plate 40 extends in vertical direction with the mode that covers LED30, and extends at the long side direction (the Y direction among Fig. 7) of metal forming M with the mode that covers a plurality of LED30.And the infrared ray from LED30 is radiated the opposition side of metal forming M reflects and radiation direction metal forming M at reflecting plate 40.In addition, this reflecting plate 40 is configured in the both sides of the metal forming M in the conveyance between let off roll 10 and the takers-in 13.
Be formed with a plurality of air supply openings 41 at reflecting plate 40, it is to the arid region D air supply that is formed between this reflecting plate 40 and the metal forming M.Be provided with separately at each air supply opening 41 and be used for to this air supply opening 41 air fed supply pipes 42.Supply pipe 42 is communicated with air supply source 43.Inner product at air supply source 43 has for example dry air etc. of air.And from the air that air supply opening 41 is supplied with to arid region D, after the surface current of metal forming M, discharge the end of D from the arid region.In addition, these air supply openings 41, supply pipe 42 and air supply source 43 constitute gas supply mechanism of the present invention.
In above electrode manufacturing apparatus 1, the control part 50 that is provided with as shown in Figure 1.Control part 50 for example is a computer, has program storage part (not shown).In program storage part, store the program of processing that is used to make electrode E of control electrode manufacturing installation 1.In addition, said procedure for example is recorded among the storage medium H that in computer, can read of hard disk (HD), floppy disk (FD), CD (CD), magneto optical disk (MO), storage card etc. of embodied on computer readable, also can be installed to control part 50 from this storage medium H.
Then, the method to the peak value emission wavelength of setting above-mentioned upper reaches LED30a, middle reaches LED30b, downstream LED30c describes.
At first, the method to the peak value emission wavelength of setting upper reaches LED30a describes.Fig. 8 representes to set the flow process of the peak value emission wavelength of upper reaches LED30a.The peak value emission wavelength of upper reaches LED30a; Be to be the thickness of water with respect to the solvent in the active material intermixture that is dried at upstream region Ta; Do not make the ultrared wavelength of the scope of this active material intermixture boiling, the ultrared absorptivity that is set to water reaches maximum wavelength.In addition, the active material intermixture does not seethe with excitement and is meant that the water in this active material intermixture does not seethe with excitement.
Specifically; As shown in Figure 9; Derive the first relevant of relation that the expression ultrared wavelength (transverse axis among Fig. 9) that LED30 sent and the ultrared absorptivity (longitudinal axis among Fig. 9) of water are arranged in advance, the thickness derivation (the operation A1 of Fig. 8) that first is correlated with presses the water in the active material intermixture.In addition, the thickness of the thickness of water and active material intermixture self is roughly the same.In addition, in embodiment illustrated, the thickness of water has two kinds of 10 μ m and 2 μ m, but in fact also derive in advance the first relevant of other thickness is arranged.
In addition, shown in figure 10, derive second relevant (the operation A1 of Fig. 8) that the expression ultrared wavelength (transverse axis among Figure 10) that LED30 sent and the relation of the luminous intensity (longitudinal axis among Figure 10) of LED30 are arranged in advance.In addition, in embodiment illustrated, it is the LED of 2.84 μ m~4.45 μ m that expression has ultrared wavelength, is correlated with but in fact also derive in advance to have with respect to second of other wavelength.
And shown in figure 11, the third phase of the relation of the luminous intensity (longitudinal axis among Figure 11) of the LED30 when derivation in advance has the thickness (transverse axis among Figure 11) of the water in the expression active material intermixture to come to life with the active material intermixture closes (the operation A1 of Fig. 8).In addition, in Figure 11, third phase close above be that the luminous intensity of LED30 is higher than under the situation of the luminous intensity that third phase closes the boiling of active material intermixture.On the other hand, in Figure 11, third phase close below be that the luminous intensity of LED30 is lower than under the situation of the luminous intensity that third phase closes, the active material intermixture does not seethe with excitement.
And, infer the thickness (the operation A2 of Fig. 8) of the water in the active material intermixture that upstream region Ta is dried.In this execution mode, the thickness of this water for example is estimated to be 10 μ m.
Then, be based on the thickness of the water that operation A2 infers, use the first relevant ultrared wavelength corresponding (below, be also referred to as " peak wavelength ") (the operation A3 of Fig. 8) of deriving with the ultrared maximum absorbance of water.In this execution mode, be 3 μ m with the corresponding peak wavelength of thickness 10 μ m of water.
Then, be based on the peak wavelength that operation A3 infers, use the maximum emission intensity (the operation A4 of Fig. 8) of the second relevant upper reaches LED30a of derivation.In this execution mode, the maximum emission intensity of the upper reaches LED30a corresponding with peak wavelength 3 μ m is 1.0.
Then, be based on the maximum emission intensity of thickness with the upper reaches LED30a that derives at operation A4 of the water that operation A2 infers, use third phase to close to judge active material intermixture whether seethe with excitement (the operation A5 of Fig. 8).
Then, when active material intermixture in operation A5 is judged as when not seething with excitement, the peak value emission wavelength of upper reaches LED30a is set to the peak wavelength (the operation A6 of Fig. 8) of in operation A4, deriving.That is, in the LED30a of the upper reaches, use the peak wavelength of in operation A4, deriving LED as emission wavelength.On the other hand, when active material intermixture in operation A5 is judged as boiling, be back to above-mentioned operation A3, carry out operation A3~operation A5.Then, until active material intermixture in operation A5 be judged as do not seethe with excitement till, repeat these operations A3~operation A5.
In this execution mode, in operation A5, the thickness 10 μ m of relative water, the luminous intensity that third phase closes is 0.6.To this, the maximum emission intensity of the upper reaches LED30a that in operation A4, derives is 1.0.Therefore, active material intermixture boiling.
Like this, in this execution mode, the active material intermixture is judged as boiling in operation A5, therefore, is back to operation A3.In operation A3, use the first relevant derivation peak wavelength corresponding with the absorptivity that is only second to maximum absorbance.In this execution mode, peak wavelength is 6 μ m.Then, in operation A4, use the second relevant maximum emission intensity 0.5 that derives the upper reaches LED30a corresponding with peak wavelength 6 μ m.Then, in operation A5, use third phase to close and judge whether the active material intermixture seethes with excitement.In this execution mode, the maximum emission intensity of upper reaches LED30a is 0.5, and the active material intermixture does not seethe with excitement.
Like this, when active material intermixture in operation A5 is judged as when not seething with excitement, the peak value emission wavelength of upper reaches LED30a is set at the peak wavelength (the operation A6 of Fig. 8) of in operation A4, deriving.In this execution mode, the peak value emission wavelength of upper reaches LED30a is set at 6 μ m.That is, LED30a use peak value emission wavelength is the LED of 6 μ m at the upper reaches.
For the peak value emission wavelength of middle reaches LED30b and downstream LED30c, carry out above-mentioned operation A1~A6 too and set.Then, in this execution mode, the peak value emission wavelength of downstream LED30c is set at 3 μ m.In addition, the peak value emission wavelength of middle reaches LED30b is greater than the peak value emission wavelength of 3 μ m less thaies, 6 μ m, for example is set at 4.5 μ m.
The electrode manufacturing apparatus 1 that relates to this execution mode is made up of above mode.The processing of then, being used to of being carried out by this electrode manufacturing apparatus 1 being made electrode E describes.
Metal forming M unreels from let off roll 10, and is arrived coating portion 11 by conveyance.In coating portion 11,, apply from a slimy active material intermixture S who applies 20 to the surface of the metal forming M in the conveyance.At this moment, through supplying with active material intermixture S from the coating of the both sides that are configured in metal forming M 20,20, the thickness on the two sides of metal forming M with equalization applies active material intermixture S simultaneously.In addition, will be coated in the central portion of the short side direction of metal forming M from the active material intermixture S of coating 20 supply.And through supplying with active material intermixture S intermittently from applying 20, a plurality of zones on the long side direction of metal forming M apply active material intermixture S.
Then, the metal forming M that is coated with active material intermixture S is arrived drying section 12 by conveyance.At drying section 12, the radiation heating that places the infrared ray of a plurality of LED30 and a plurality of reflecting plate 40 of the both sides of metal forming M to produce through the origin autogamy makes the active material intermixture S on two sides of metal forming M dry.At this moment, the peak value emission wavelength of upper reaches LED30a is 6 μ m as stated, and the peak value emission wavelength of middle reaches LED30b is 4.5 μ m, and the peak value emission wavelength of downstream LED30c is 3 μ m.And, the active material intermixture S ground that do not seethe with excitement, active material intermixture S absorbs infrared ray to greatest extent, and active material intermixture S is dried in above-mentioned LED30 successively.
In addition, at drying section 12,, make the active material intermixture S drying on the two sides of metal forming M through the Convective Heating that the air of being supplied with by the arid region D that forms to the both sides at metal forming M from air supply opening 41, D produces.And, through in the D of arid region, produce from the air-flow of air supply opening 41 to the end of arid region D, flow smoothly to arid region D from the water of active material intermixture S evaporation, and the water of this evaporation is not removed with can not being attached to metal forming M again.The active material intermixture S on the two sides of metal forming M is dried in this wise, forms the active material layer F of the thickness of regulation on the two sides of this metal forming M.
After this, form the metal forming M of active material layer F, arrived takers-in 13, and batch at this takers-in 13 by conveyance.The a series of processing of electrode manufacturing apparatus 1 finishes in this wise, and electrode E is made.
Adopt above mode; Drying section 12 is split into 3 regional Ta, Tb, Tc; And the peak value emission wavelength of the LED30 of regional Ta, Tb, Tc is set at the wavelength of the scope that does not make active material intermixture S boiling; Therefore can be as prior art the surface of the active material layer of ground on metal forming form concavo-convexly, can have the active material layer F on level and smooth surface with the thickness formation of equalization.In addition, also do not peel off in the generation of the border of metal forming M and active material layer F.And the peak value emission wavelength of the LED30 of regional Ta, Tb, Tc is set at the ultrared absorptivity that makes water and reaches maximum wavelength, therefore can heat active material intermixture S efficiently and make its drying.And be set in each regional Ta, Tb, Tc of the emission wavelength of such LED30 carry out, and therefore compared with prior art can shorten the drying time of active material intermixture S more, also can shorten the length of drying section 12.As stated according to this execution mode, can suitably and efficiently form active material layer F on the surface of the metal forming M of band shape.
In addition, at drying section 12,, make the active material intermixture S on the metal forming M dry through radiation heating that produces by infrared ray and the Convective Heating that produces by the air of in the D of arid region, supplying with from air supply opening 41 from a plurality of LED30 and reflecting plate 40.Because use radiation heating that produces by infrared ray and the such 2 kinds of drying means of Convective Heating that produce by air in this wise, can suitably make this active material intermixture S dry.And, under the situation of having used the radiation heating that produces by infrared ray, do not exist with ... the ultrared radiant heat of distance ground conduction between LED30 and reflecting plate 40 and the metal forming M.Therefore, can suitably do not heated active material intermixture S by the bending of metal forming M and obliquity effects ground.
In addition, at drying section 12, can make in the D of arid region to produce from the air-flow of air supply opening 41 to the end of arid region D.Through this air-flow, when active material intermixture S on making metal film M was dry, discharged the end of the water of evaporation D from the arid region, water that therefore should evaporation can be not again attached to the surface of metal forming M.Therefore, can more suitably make the active material intermixture S on the metal forming M dry.
In addition, reflecting plate 40 clips the surface configuration relatively of LED30 and metal forming M, therefore is radiated the infrared ray of the opposition side of metal forming M from LED30, is radiated metal forming M in reflecting plate 40 reflections.Therefore, can utilize whole infrared rays, can make the active material intermixture S on the metal forming M dry efficiently.
In addition, in coating portion 11, the long side direction of metal forming M be horizontal direction towards conveyance metal forming M, therefore can not flow to the upstream side or the downstream of the conveyance direction of this metal forming M at the active material intermixture S of the surface applied of metal forming M.And, the short side direction of metal forming M be vertical direction towards conveyance metal forming M, therefore can apply active material intermixture S equably on the two sides of metal forming M.Active material intermixture S can be suitably applied in coating portion 11 like this, therefore active material layer F can be on metal forming M, suitably formed.
In addition, between let off roll 10 and takers-in 13, long side direction be horizontal direction towards conveyance metal forming M, therefore can metal forming M be reduced to certain height, make the maintenance of electrode manufacturing apparatus 1 become easy.Therefore, can form active material layer F on the surface of metal forming M effectively.
In above execution mode; The peak value emission wavelength of the middle reaches LED30b of zone, middle reaches Tb is set at 4.5 μ m; But in the Tb of middle reaches zones, also can mixed configuration have the upper reaches LED30a and downstream LED30c of the peak value emission wavelength of 6 μ m with peak value emission wavelength of 3 μ m.Under this kind situation, the upper reaches LED30a of zone, middle reaches Tb and downstream LED30c can configurations arbitrarily in the scope that does not make active material intermixture S boiling.Particularly; In order not make the adjustment of active material intermixture S boiling; For example can change the adjustment of ratio of the radical of upper reaches LED30a and downstream LED30c, perhaps for example also can change the adjustment at the interval of configuration upper reaches LED30a and downstream LED30c.No matter any situation does not make active material intermixture S boiling, therefore can suitably dry this active material intermixture S.Therefore, can suitably form active material layer F on the surface of metal forming M.
In addition, in above execution mode, drying section 12 is split into 3 regional Ta, Tb, Tc, but the quantity of cutting apart the zone of drying section 12 is not limited to this execution mode, can at random set.For example can drying section 12 be divided into 2 zones, also can be divided into 4 zones.No matter any situation as long as carry out the peak value emission wavelength that above-mentioned operation A1~A6 sets each regional LED30, just can both not make active material intermixture S boiling ground, suitably make this active material intermixture S dry.
In addition, in above execution mode, be that the situation of water is illustrated to the solvent of active material intermixture S, for example be that the situation of organic solvent also can be applicable to the present invention but the solvent of active material intermixture is other material.Under this kind situation, according to solvent types, first third phase relevant and shown in figure 11 as shown in Figure 9 of deriving operation A1 in advance closes.And, through carrying out operation A2~A6, can suitably set the peak value emission wavelength of the LED30 of drying section 12, can suitably make active material intermixture S dry.
In the electrode manufacturing apparatus 1 of above execution mode, as the portion of unreeling let off roll 10 is set, but the structure that unreels portion is not limited to this execution mode, just can take various structures so long as unreel the structure of metal forming M.Likewise, takers-in 13 is set, but the structure of reeling end is not limited to this execution mode, just can takes various structures so long as batch the structure of metal forming M as reeling end.
In addition, in the coating portion 11 of above execution mode, be provided with and apply 20, the structure of coating portion 11 is not limited to this execution mode, so long as can just can take various structures in the structure of the surface applied active material intermixture S of metal forming M.
For example in above execution mode, apply 20,20 relatively be arranged on metal forming M both sides, but any side's coating 20 also can be configured in the downstream more of the opposing party's coating 20.In addition, apply 20 quantity and be not limited to this execution mode, can dispose a plurality of coatings 20 in the both sides of metal forming M respectively.
For example also can use the surface applied active material intermixture S of ink-jetting style in addition at metal forming M in coating portion 11.
For example shown in figure 12 in addition, coating portion 11 also can have: the cylinder 100 that is coated in the surface of this metal forming M with the surperficial butt of metal forming M and with slimy active material intermixture S; With nozzle 101 from active material intermixture S to cylinder 100 surfaces that supply with.These cylinders 100 and nozzle 101 relatively are configured in the both sides of the metal forming M in the conveyance between let off roll 10 and the takers-in 13.
Under this kind situation, in coating portion 11, from nozzle 101 to the surface of cylinder 100 supply with active material intermixture S on one side, make the surperficial butt of the cylinder 100 that is attached with this active material intermixture S and metal forming M on one side.So, duplicate on the surface of metal forming M attached to the active material intermixture S on the surface of cylinder 100, be covered with active material intermixture S in the surfaces coated of this metal forming M.
According to this execution mode, through at active material intermixture S when cylinder 100 is coated to metal forming M surperficial, adjust the distance on surface of surface and the metal forming M of this cylinder 100 self, can adjust the thickness of active material intermixture S.Therefore, can apply active material intermixture S with impartial more thickness on the surface of metal forming M.
In the electrode manufacturing apparatus 1 of above execution mode; Metal forming M; This long side direction be horizontal direction and this short side direction be vertical direction towards by conveyance, but as Figure 13 and metal forming M shown in Figure 14 can this long side direction be horizontal direction (the Y direction among Figure 13 and Figure 14) and this short side direction be horizontal direction (directions X among Figure 13) towards by conveyance.Under this kind situation, let off roll 10 is configured in equal height with takers-in 13.In addition, let off roll 10 and takers-in 13 be configured in separately its direction of principal axis be horizontal direction (directions X among Figure 13) towards.Even under the situation of the electrode manufacturing apparatus 1 that uses this execution mode, also can play the effect of above-mentioned execution mode.
In above execution mode, active material layer F is formed with a plurality of at the long side direction of metal forming M, but electrode manufacturing apparatus 1 of the present invention also is useful when formation possesses the electrode E of an active material layer F.
In this external above execution mode, electrode manufacturing apparatus 1 forms active material layer F on the two sides of metal forming M, but also can carry out other processing, the for example extruding of metal forming M and cut-out etc. in order to form electrode E.Electrode manufacturing apparatus 1 also can carry out these other processing continuously between let off roll 10 and takers-in 13.
In this external above execution mode; Situation to the electrode E that makes lithium-ion capacitor is illustrated; But be used in manufacturing under the situation of the electrode of electric double layer capacitor and the electrode that is used in lithium ion battery, also can use electrode manufacturing apparatus 1 of the present invention.Under this kind situation, the kind according to the electrode of making can change the material of metal forming M and the material of active material intermixture S etc.
More than, preferred embodiment be illustrated of the present invention with reference to accompanying drawing, but the present invention is not limited to and above relevant example.So long as the one's own profession dealer, various change examples or correction example in the category of the thought in the patent request that the is recorded in scope that just can expect significantly also belong to technical scope of the present invention natch about those.
Claims (14)
1. electrode manufacturing apparatus, its two sides at the base material of band shape forms active material layer and makes electrode, and this electrode manufacturing apparatus is characterised in that, comprising:
Unreel the portion of base material;
Reeling end, it batches above-mentioned and unreels the base material that portion is unreeled;
Coating portion, it is arranged on said unreeling between portion and the said reeling end, applies the active material intermixture that is mixed with active material and solvent on the two sides of base material; With
Drying section, it is arranged between said coating portion and the said reeling end, and make in the said coated said active material intermixture drying of coating portion and form active material layer,
Said drying section has in the long side direction alignment arrangements of substrate and sends ultrared a plurality of LED,
Said drying section is split into the different a plurality of zones of emission wavelength that luminous intensity reaches the LED of maximum,
The emission wavelength of said LED in said zone; It is thickness for the said solvent on the base material in this zone; The ultrared absorptivity that the ultrared wavelength of the scope that said active material intermixture does not seethe with excitement, this emission wavelength are set to said solvent reaches maximum wavelength.
2. electrode manufacturing apparatus as claimed in claim 1 is characterized in that:
Said solvent is a water.
3. electrode manufacturing apparatus as claimed in claim 2 is characterized in that:
Said drying section unreels 3 zones that portion's side is split into upstream region, zone, middle reaches and downstream area from said,
The emission wavelength that is configured in the LED of said upstream region is 6 μ m,
The emission wavelength that is configured in the LED of said downstream area is 3 μ m,
Area configurations has the LED less than the emission wavelength of 6 μ m greater than 3 μ m in said middle reaches.
4. electrode manufacturing apparatus as claimed in claim 2 is characterized in that:
Said drying section unreels 3 zones that portion's side is split into upstream region, zone, middle reaches and downstream area from said,
The emission wavelength that is disposed at the LED of said upstream region is 6 μ m,
The emission wavelength that is disposed at the LED of said downstream area is 3 μ m,
In zone, said middle reaches, dispose the LED of said upstream region and the LED of said downstream area with mixing.
5. like any described electrode manufacturing apparatus in the claim 1~4, it is characterized in that:
Said drying section has air fed gas supply mechanism between said a plurality of LED and base material.
6. like any described electrode manufacturing apparatus in the claim 1~4, it is characterized in that:
Saidly unreel portion and said reeling end is configured to: with the long side direction of base material be the short side direction of horizontal direction and base material be vertical direction towards the conveyance base material.
7. like any described electrode manufacturing apparatus in the claim 1~4, it is characterized in that:
Said electrode is the electrode that in lithium-ion capacitor, electric double layer capacitor or lithium ion battery, uses.
8. electrode manufacturing method, it is the banded base material of conveyance between portion of unreeling and reeling end on one side, on the two sides of this base material form active material layer and make the electrode manufacturing method of electrode on one side, it is characterized in that, comprising:
Working procedure of coating, the active material intermixture that will be mixed with active material and solvent in coating portion is coated in the two sides of base material; With
After this drying process at drying section, makes the said active material intermixture that applies at said working procedure of coating dry and form active material layer,
Said drying section has in the long side direction alignment arrangements of substrate and sends ultrared a plurality of LED,
Said drying section is split into the different a plurality of zones of emission wavelength that luminous intensity reaches the LED of maximum,
The emission wavelength of said LED in said zone; It is thickness for the said solvent on the base material in this zone; The ultrared absorptivity that the ultrared wavelength of the scope that said active material intermixture does not seethe with excitement, this emission wavelength are set to said solvent reaches maximum wavelength.
9. electrode manufacturing method as claimed in claim 8 is characterized in that:
Said solvent is a water.
10. electrode manufacturing method as claimed in claim 9 is characterized in that:
Said drying section unreels 3 zones that portion's side is split into upstream region, zone, middle reaches and downstream area from said,
The emission wavelength that is configured in the LED of said upstream region is 6 μ m,
The emission wavelength that is configured in the LED of said downstream area is 3 μ m,
Area configurations has the LED less than the emission wavelength of 6 μ m greater than 3 μ m in said middle reaches.
11. electrode manufacturing method as claimed in claim 9 is characterized in that:
Said drying section unreels 3 zones that portion's side is split into upstream region, zone, middle reaches and downstream area from said,
The emission wavelength that is disposed at the LED of said upstream region is 6 μ m,
The emission wavelength that is disposed at the LED of said downstream area is 3 μ m,
In zone, said middle reaches, dispose the LED of said upstream region and the LED of said downstream area with mixing.
12. any described electrode manufacturing method as in the claim 8~11 is characterized in that:
Said drying section has air fed gas supply mechanism between said a plurality of LED and base material,
In said drying process,, make said active material intermixture dry through radiation heating that produces by infrared ray and the Convective Heating that produces by the air of supplying with from said gas supply mechanism from said a plurality of LED.
13. any described electrode manufacturing method as in the claim 8~11 is characterized in that:
With the long side direction of base material be the short side direction of horizontal direction and base material be vertical direction towards, the base material in the conveyance is carried out said working procedure of coating and said drying process.
14. any described electrode manufacturing method as in the claim 8~11 is characterized in that:
Said electrode is the electrode that in lithium-ion capacitor, electric double layer capacitor or lithium ion battery, uses.
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CN105470446A (en) * | 2014-09-29 | 2016-04-06 | Lg化学株式会社 | Method for manufacturing electrode and electrode manufactured by same |
CN109550659A (en) * | 2017-09-25 | 2019-04-02 | 株式会社斯库林集团 | Drying means and drying device |
CN110337750A (en) * | 2017-03-22 | 2019-10-15 | 株式会社石井表记 | Battery manufacture device |
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EP4199164A1 (en) | 2021-06-29 | 2023-06-21 | LG Energy Solution, Ltd. | Secondary battery lamination device using infrared lamps |
KR20230002079A (en) | 2021-06-29 | 2023-01-05 | 주식회사 엘지에너지솔루션 | Lamination apparatus for secondary battery using infrared lamp |
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- 2012-01-12 KR KR1020120003827A patent/KR20120082365A/en not_active Application Discontinuation
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TWI506682B (en) | 2015-11-01 |
JP5271366B2 (en) | 2013-08-21 |
JP2012146850A (en) | 2012-08-02 |
TW201246313A (en) | 2012-11-16 |
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Application publication date: 20120718 |