CN102587218A - Composite wallpaper containing polyvinyl chloride - Google Patents
Composite wallpaper containing polyvinyl chloride Download PDFInfo
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- CN102587218A CN102587218A CN2011104113522A CN201110411352A CN102587218A CN 102587218 A CN102587218 A CN 102587218A CN 2011104113522 A CN2011104113522 A CN 2011104113522A CN 201110411352 A CN201110411352 A CN 201110411352A CN 102587218 A CN102587218 A CN 102587218A
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Abstract
The invention relates to composite wallpaper containing polyvinyl chloride and discloses composite polyvinyl chloride (PVC) wallpaper with a flame retarding polyvinyl chloride (for short flame retarding PVC) coating or film as a surface layer and flame retarding paper as a bottom layer. Components of the flame retarding PVC surface layer, by weight ratio, comprise PVC resin 100, a plasticizer 0-50, a flame retardant 20-80, a stabilizing agent 0.01-1, filler 40-150, a foaming agent 0-1 and a thinning agent 0-10. Paper which is not flame retarding is soaked, flame retarding liquid is sprayed or brush-coated on the paper which is not flame retarding, and then drying is conducted to obtain the flame retarding paper. Compared with a traditional processing method of adopting antimonous oxide as a PVC surface layer flame retardant and adopting ammonium polyphosphate as a paper base layer flame retardant, the flame retarding PVC wallpaper is environment-friendly, low in toxicity and small in smoke density during burning, oxygen index can reach above 32%, and burning performance can reach a GB8624-2006B level.
Description
Technical field
The present invention relates to wallpaper, be specifically related to a kind of compound wallpaper that contains polyvinyl chloride.
Background technology
Wallpaper not only is widely used in public places such as hotels as a kind of inner decoration material in room, and along with the improvement of living standards of the people and dwelling house condition, has stepped into huge numbers of families.Decorative wall paper, though can beautify the room, because the general wallpaper that uses all is inflammable, this is dangerous with regard to potential fire.In case the room breaking out of fire, the wallpaper that just possibly ignite, or flame spreads along wallpaper, and the intensity of a fire is enlarged.From the angle of fire safety, development and use wallpaper that do not fire or fire-retardant are necessary.
The enhancing of Along with people's fire-fighting and environmental consciousness and a series of national standard; Promulgation and enforcement like GB50222-95 " code for fire prevention design of interior decoration of buildings ", GB20286-2006 " public place fire-retardant product and assembly combustibility require and sign ", GB 8624-2006 " construction material and the classification of product burns performance ", GB18585-2001 " limits of harmful substances in the indoor decorating material wallpaper " etc.; The used wallpaper of interior decoration also must environmental protection outside keeping function such as fire-retardant, therefore is badly in need of research and development new environmental-protection flame-retardant wallpaper and relevant art thereof.
The PVC wallpaper is made up of paper substrate and PVC surface layer usually.Chloridely in the PVC molecule reaching 56%, is a kind of self-extinguishing polymer, its limited oxygen index>45%.But in the wallpaper production process,, need in PVC, add the plasticizer of 30%-80% in order to make wallpaper high resilience and flexibility.When PVC is about 30% the time owing to the diluting effect of plasticizer or other additive drops to its total chlorinty, the oxygen index (OI) of goods descends greatly.The content of plasticizer can reach 70 parts (100 parts of PVC) in the PVC surface layer thickener of wallpaper, and the oxygen index (OI) of basic paper is generally 19～20%, and the PVC wallpaper that is composited, its oxygen index (OI) burn about 21% easily.Therefore, the existing clearly regulation of wallpaper that fire department is used plastic wall paper especially skyscraper generally requires its oxygen index (OI) >=27%.
Base paper flame-retarded technology does not really reach a standard in China at present as yet fully.Because basic paper will bear the high temperature about 200 ℃ in its surperficial PVC plasticizing operation, most water-soluble inorganic flame retardant tend to occur the paper color jaundice when being used to flame treatment base paper, and intensity seriously descends; Problems such as fragility increases, and folding resistance is very poor, even more serious is; Fire retardant is prone to crystallization and separates out; Paper is prone to the moisture absorption, and is inter-adhesive, and the storage and the use of wallpaper brought a lot of problems.(application number: 87105201) disclose fire-resisting wallpaper of polyvinyl chloride, wherein the used fire retardant of wallpaper base paper layer is an APP, and the basic paper that adopts this fire retardant to handle promptly above-mentioned problems can occur like Chinese patent.
It is to add antimony oxide (Sb2O3) that the PVC surface layer is carried out the most frequently used method of flame treatment; Like Chinese patent (application number: 87105201) disclose fire-resisting wallpaper of polyvinyl chloride; Wherein the used fire retardant of polyvinyl chloride film is Sb2O3; Yet standard GB 18585-2001 " limits of harmful substances in the indoor decorating material wallpaper " is to content of beary metal in the wallpaper; Like the content of antimony strict restriction is arranged, requires its content in wallpaper to be no more than 20 milligrams every kilogram, this prescribed limits Sb2O3 as the application of fire retardant in wallpaper.Therefore be badly in need of the new flame-retarded technology of exploitation, replace the use of Sb2O3 in the PVC flame wallpaper.
Summary of the invention
Poor in order to overcome in the prior art wallpaper flame retardant effect, shortcomings such as not environmental protection, the present invention provides a kind of environmental protection flame retardant low-smoke low-toxicity compound PVC wallpaper.
It is flame-proof polyvinyl chloride coating or film that one aspect of the present invention provides a kind of surface layer; Bottom is the compound wallpaper of fire retardant papers, and its said surface layer is made up of following components in weight percentage: 100 parts of polyvinyl chloride resins, 0～50 part in plasticizer, 20～80 parts of fire retardants, 0.01～1 part of stabilizing agent, 40～95 parts of fillers, 0～1 part of blowing agent, 3～10 parts of diluents; Wherein said fire retardant is one or more in Firebrake ZB, aluminium hydroxide, triethyl phosphate, magnesium hydroxide, phosphoric acid hexichol 2-Octyl Nitrite, chlorinated paraffin wax, APP, tributyl phosphate, tricresyl phosphate (2-chloroethyl) ester; Said plasticizer is one or more of dibutyl phthalate, o-phthalic acid dibutyl ester, diisobutyl phthalate, dioctyl adipate, di-n-octyl sebacate; Said stabilizing agent is a kind of of calcium zinc stabilizer or dimercapto 2-ethyl hexyl ethanoate dioctyltin stabilizing agent; Said filler is a kind of of talcum powder, calcium carbonate, titanium white powder; Said blowing agent is Celogen Az or azodiisobutyronitrile; Said diluent is toluene or xylene.
The surface layer of above-mentioned compound wallpaper is preferably by the component of following weight proportion to be formed: 100 parts of polyvinyl chloride resins, 10 parts of APPs, 40 parts of tributyl phosphates, 10 parts of chlorinated paraffin waxs, 0.3 part of dimercapto 2-ethyl hexyl ethanoate dioctyltin stabilizing agent, 60 parts of titanium white powders, 10 parts of xylene.
The surface layer of above-mentioned compound wallpaper is preferably again by the component of following weight proportion to be formed: 100 parts of polyvinyl chloride resins, 25 parts of dibutyl phthalates, 5 parts of Firebrake ZBs, 5 parts in aluminium hydroxide, 10 parts of triethyl phosphates, 0.01 part of G-618CZ type calcium zinc stabilizer, 40 parts of talcum powder, 1 part of Celogen Az, 10 parts of toluene.
The surface layer of above-mentioned compound wallpaper also is preferably by the component of following weight proportion to be formed: 100 parts of polyvinyl chloride resins, 50 parts of diisobutyl phthalates, 20 parts of magnesium hydroxides, 30 parts of phosphoric acid hexichol 2-Octyl Nitrites, 30 parts of chlorinated paraffin waxs, 1 part of G-618CZ type calcium zinc stabilizer, 150 parts in calcium carbonate, 3 parts of toluene.
The surface layer of above-mentioned compound wallpaper also is preferably by the component of following weight proportion to be formed: 100 parts of polyvinyl chloride resins, 25 parts of o-phthalic acid dibutyl esters, 10 parts of magnesium hydroxides, 40 parts of tricresyl phosphate (2-chloroethyl) esters, 0.5 part of dimercapto 2-ethyl hexyl ethanoate dioctyltin stabilizing agent, 95 parts of titanium white powders, 0.5 part of azodiisobutyronitrile, 5 parts of diluent xylene.
The present invention also provides a kind of preparation method of bottom fire retardant papers of compound wallpaper, specifically is prepared from following method: will be not at first dipping or spraying in fire resistant fluid of fire retardant papers, brush fire resistant fluid, and then process through the method for super-dry; Wherein said fire resistant fluid is the aqueous solution or emulsion, the fire retardant in the fire resistant fluid be a) contain nitrogen combustion inhibitor one or more, b) one or more or c in the phosphonium flame retardant) in the aluminium hydroxide, magnesium hydroxide, boric acid, Firebrake ZB, zinc one or more.
It is 10～35% that the described aqueous solution of preparation method of the bottom fire retardant papers of above-mentioned a kind of compound wallpaper or the concentration expressed in percentage by weight of emulsion are preferably.
Fire retardant described in the preparation method of the bottom fire retardant papers of above-mentioned a kind of compound wallpaper in the fire resistant fluid is preferably by following components in weight percentage content to be formed: dicyandiamide 5%, APP 10%, Firebrake ZB 5%.
Fire retardant described in the preparation method of the bottom fire retardant papers of above-mentioned a kind of compound wallpaper in the fire resistant fluid also is preferably by following components in weight percentage content to be formed: melamine 3%, APP 4%, boric acid 3%.
Fire retardant described in the preparation method of the bottom fire retardant papers of above-mentioned a kind of compound wallpaper in the fire resistant fluid also is preferably by following components in weight percentage content to be formed: melamine 5%, APP 10%, Guanidine Sulfamate 99 20%.
Fire retardant described in the preparation method of the bottom fire retardant papers of above-mentioned a kind of compound wallpaper in the fire resistant fluid also is preferably by following components in weight percentage content to be formed: dicyandiamide 5%, phosphoric acid 5%, Guanidine Sulfamate 99 12%.
Compound PVC wallpaper of the present invention compared with prior art has the following advantages:
1) do not contain the poisonous fire retardant of heavy metal in the wallpaper surface layer, like Sb
2O
3, compliance with environmental protection requirements;
2) the wallpaper bottom adopts compound flame retardant, and the wallpaper bottom after the flame treatment does not have jaundice, embrittlement phenomenon in follow-up high-temperature process, and fire retardant is difficult for crystallization and separates out in storing process, and the moisture absorption and adhesion do not take place paper;
3) adopt the PVC wallpaper that the present invention produced to adopt standard GB 8624-2006 to detect, can reach the B level, toxicity is low, smoke density is little, and oxygen index (OI) can reach more than 32%, has improved its fire protecting performance.
The specific embodiment
Below in conjunction with specific embodiment the present invention is described further, but this explanation does not limit protection scope of the present invention.
The compound PVC wallpaper of environmental-protection flame-retardant low-smoke low-toxicity of the present invention is a surface layer with flame-proof PVC coating or film, and fire retardant papers is a bottom.
Embodiment 1
According to patent (application number: 87105201); With the flame-proof PVC film is surface layer; Fire retardant papers is the compound PVC wallpaper of bottom, and the weight ratio of flame-proof PVC surface layer component is: 100 parts of polyvinyl chloride resins, 52 parts of dioctyl phthalates (DOP), 2 parts of liquid Ba-Cd-Zn, 1 part of three salt lead stearate, 1 part of lead stearate, 0.2 part of stearic acid, CaCO
35 parts of 80 parts, antimony oxide; Fire retardant papers is the aqueous solution that the dipping of fire retardant papers is not contained APP 30% (the white component of weight), and oven dry forms then.The flame-proof PVC wallpaper that adopts this method to process is pressed the GB5454-1997 test, and oxygen index (OI) is 27%; According to GB5455-1997 test, char length>200mm, glow the time 5s, after flame time>5s.In addition, the wallpaper bottom after the flame treatment has jaundice, embrittlement phenomenon in follow-up high-temperature process, and the paper generation moisture absorption and adhesion are separated out in the easy crystallization of fire retardant in storing process.
Embodiment 2
With the flame-proof PVC coating is surface layer; Fire retardant papers is the compound PVC wallpaper of bottom, and the weight ratio of flame-proof PVC surface layer component is: 100 parts of polyvinyl chloride resins, 25 parts of dibutyl phthalates (DBP), 5 parts of Firebrake ZBs, 5 parts in aluminium hydroxide, 10 parts of triethyl phosphates, 0.01 part of G-618CZ type calcium zinc stabilizer (Xiamen City is with Allianz auspicious chemical industry Co., Ltd), 40 parts of talcum powder, 1 part of Celogen Az, 10 parts of toluene; Fire retardant papers is the fire resistant fluid that fire retardant papers is not at first contained dicyandiamide 5% (percentage by weight), APP 10% (percentage by weight), Firebrake ZB 5% (percentage by weight) through dipping, and then processes through the method for super-dry.This fire-retardant compound PVC wallpaper is pressed the GB5454-1997 test, and oxygen index (OI) is 32%; According to GB5455-1997 test, char length 120mm, the time 1s that glows, after flame time 1s; Press the GB8624-2006 test, combustibility reaches B-s2, d0, t1 level.Wallpaper bottom after the flame treatment does not have jaundice, embrittlement phenomenon in follow-up high-temperature process, fire retardant does not have crystallization and separates out in storing process, and paper does not have the moisture absorption and adhesion phenomenon.
Embodiment 3
With the flame-proof PVC film is surface layer; Fire retardant papers is the compound PVC wallpaper of bottom, and the weight ratio of flame-proof PVC surface layer component is: 100 parts of polyvinyl chloride resins, 50 parts of diisobutyl phthalates, 20 parts of magnesium hydroxides, 30 parts of phosphoric acid hexichol 2-Octyl Nitrites, 30 parts of chlorinated paraffin waxs, 1 part of G-618CZ type calcium zinc stabilizer, 150 parts in calcium carbonate, 3 parts of toluene; Fire retardant papers is the fire resistant fluid that fire retardant papers is not at first contained melamine 3% (percentage by weight), APP 4% (percentage by weight), boric acid 3% (percentage by weight) through dipping, and then processes through the method for super-dry.This fire-retardant compound PVC wallpaper is pressed the GB5454-1997 test, and oxygen index (OI) is 33%; According to the GB5455-1997 test, char length 100mm glows the time 0, after flame time 1s; Press the GB8624-2006 test, combustibility reaches B-s2, d0, t1 level.Wallpaper bottom after the flame treatment does not have jaundice, embrittlement phenomenon in follow-up high-temperature process, fire retardant does not have crystallization and separates out in storing process, and paper does not have the moisture absorption and adhesion phenomenon.
Embodiment 4
With the flame-proof PVC film is surface layer; Fire retardant papers is the compound PVC wallpaper of bottom, and the weight ratio of flame-proof PVC surface layer component is: 100 parts of polyvinyl chloride resins, 10 parts of APPs, 40 parts of tributyl phosphates, 10 parts of chlorinated paraffin waxs, 0.3 part of dimercapto 2-ethyl hexyl ethanoate dioctyltin stabilizing agent, 60 parts of titanium white powders, 10 parts of xylene; Fire retardant papers is the fire resistant fluid that fire retardant papers is not at first contained melamine 5% (percentage by weight), APP 10% (percentage by weight), Guanidine Sulfamate 99 20% (percentage by weight) through dipping, and then processes through the method for super-dry.This fire-retardant compound PVC wallpaper is pressed the GB5454-1997 test, and oxygen index (OI) is 33.4%; According to the GB5455-1997 test, char length 80mm glows the time 0, after flame time 0; Press the GB8624-2006 test, combustibility reaches B-s2, d0, t1 level.Wallpaper bottom after the flame treatment does not have jaundice, embrittlement phenomenon in follow-up high-temperature process, fire retardant does not have crystallization and separates out in storing process, and paper does not have the moisture absorption and adhesion phenomenon.
Embodiment 5
With the flame-proof PVC film is surface layer; Fire retardant papers is the compound PVC wallpaper of bottom, and the weight ratio of flame-proof PVC surface layer component is: 100 parts of polyvinyl chloride resins, 25 parts of o-phthalic acid dibutyl esters (DOP), 10 parts of magnesium hydroxides, 40 parts of tricresyl phosphate (2-chloroethyl) esters, 0.5 part of dimercapto 2-ethyl hexyl ethanoate dioctyltin stabilizing agent, 95 parts of titanium white powders, 0.5 part of azodiisobutyronitrile, 5 parts of xylene; Fire retardant papers is the fire resistant fluid that fire retardant papers is not at first contained dicyandiamide 5% (percentage by weight), phosphoric acid 5% (percentage by weight), Guanidine Sulfamate 99 12% (percentage by weight) through dipping, and then processes through the method for super-dry.This fire-retardant compound PVC wallpaper is pressed the GB5454-1997 test, and oxygen index (OI) is 32.6%; According to GB5455-1997 test, char length 95mm, the time 1s that glows, after flame time 0; Press the GB8624-2006 test, combustibility reaches B-s2, d0, t1 level.Wallpaper bottom after the flame treatment does not have jaundice, embrittlement phenomenon in follow-up high-temperature process, fire retardant does not have crystallization and separates out in storing process, and paper does not have the moisture absorption and adhesion phenomenon.
Embodiment 6
With the flame-proof PVC film is surface layer; Fire retardant papers is the compound PVC wallpaper of bottom, and the weight ratio of flame-proof PVC surface layer component is: 100 parts of polyvinyl chloride resins, 60 parts of dioctyl adipates (DOA), 10 parts of APPs, 40 parts of tributyl phosphates, 10 parts of chlorinated paraffin waxs, 0.3 part of G-618CZ type calcium zinc stabilizer, 60 parts in barium sulfate, 5 parts of triethanolamines; Fire retardant papers is the fire resistant fluid that fire retardant papers is not at first contained melamine 5% (percentage by weight), APP 8% (percentage by weight), Guanidine Sulfamate 99 15% (percentage by weight) through dipping, and then processes through the method for super-dry.This fire-retardant compound PVC wallpaper is pressed the GB5454-1997 test, and oxygen index (OI) is 25%; According to GB5455-1997 test, char length>150mm; Press the GB8624-2006 test, combustibility fails to reach the B level.
Embodiment 7
With the flame-proof PVC coating is surface layer; Fire retardant papers is the compound PVC wallpaper of bottom, and the weight ratio of flame-proof PVC surface layer component is: 100 parts of polyvinyl chloride resins, 50 parts of di-n-octyl sebacate DOS, 10 parts of APPs, 8 parts of chlorinated paraffin waxs, 0.3 part of G-618CZ type calcium zinc stabilizer, 60 parts in potter's clay, 5 parts of xylene; Fire retardant papers is the fire resistant fluid that fire retardant papers is not at first contained melamine 5% (percentage by weight), APP 8% (percentage by weight), Guanidine Sulfamate 99 15% (percentage by weight) through dipping, and then processes through the method for super-dry.This fire-retardant compound PVC wallpaper is pressed the GB5454-1997 test, and oxygen index (OI) is 22%; According to GB5455-1997 test, char length>150mm; Press the GB8624-2006 test, combustibility fails to reach the B level.
Claims (10)
1. compound wallpaper that contains polyvinyl chloride; Its surface layer is pvc coating or film; Bottom is a fire retardant papers, it is characterized in that said surface layer is made up of following components in weight percentage: 100 parts of polyvinyl chloride resins, 0～50 part in plasticizer, 20～80 parts of fire retardants, 0.01～1 part of stabilizing agent, 40～95 parts of fillers, 0～1 part of blowing agent, 3～10 parts of diluents; Wherein said fire retardant is one or more in Firebrake ZB, aluminium hydroxide, triethyl phosphate, magnesium hydroxide, phosphoric acid hexichol 2-Octyl Nitrite, chlorinated paraffin wax, APP, tributyl phosphate, tricresyl phosphate (2-chloroethyl) ester; Said plasticizer is one or more of dibutyl phthalate, o-phthalic acid dibutyl ester, diisobutyl phthalate, dioctyl adipate, di-n-octyl sebacate; Said stabilizing agent is a kind of of calcium zinc stabilizer or dimercapto 2-ethyl hexyl ethanoate dioctyltin stabilizing agent; Said filler is a kind of of talcum powder, calcium carbonate, titanium white powder; Said blowing agent is Celogen Az or azodiisobutyronitrile; Said diluent is toluene or xylene.
2. compound wallpaper according to claim 1 is characterized in that the surface layer of said wallpaper is made up of the component of following weight proportion: 100 parts of polyvinyl chloride resins, 10 parts of APPs, 40 parts of tributyl phosphates, 10 parts of chlorinated paraffin waxs, 0.3 part of dimercapto 2-ethyl hexyl ethanoate dioctyltin stabilizing agent, 60 parts of titanium white powders, 10 parts of xylene.
3. compound wallpaper according to claim 1 is characterized in that the surface layer of said wallpaper is made up of the component of following weight proportion: 100 parts of polyvinyl chloride resins, 25 parts of dibutyl phthalates, 5 parts of Firebrake ZBs, 5 parts in aluminium hydroxide, 10 parts of triethyl phosphates, 0.01 part of G-618CZ type calcium zinc stabilizer, 40 parts of talcum powder, 1 part of Celogen Az, 10 parts of toluene.
4. compound wallpaper according to claim 1 is characterized in that the surface layer of said wallpaper is made up of the component of following weight proportion: 100 parts of polyvinyl chloride resins, 50 parts of diisobutyl phthalates, 20 parts of magnesium hydroxides, 30 parts of phosphoric acid hexichol 2-Octyl Nitrites, 30 parts of chlorinated paraffin waxs, 1 part of G-618CZ type calcium zinc stabilizer, 150 parts in calcium carbonate, 3 parts of toluene.
5. compound wallpaper according to claim 1 is characterized in that the surface layer of said wallpaper is made up of the component of following weight proportion: 100 parts of polyvinyl chloride resins, 25 parts of o-phthalic acid dibutyl esters, 10 parts of magnesium hydroxides, 40 parts of tricresyl phosphate (2-chloroethyl) esters, 0.5 part of dimercapto 2-ethyl hexyl ethanoate dioctyltin stabilizing agent, 95 parts of titanium white powders, 0.5 part of azodiisobutyronitrile, 5 parts of diluent xylene.
6. according to described any the compound wallpaper of claim 1-5; The bottom fire retardant papers that it is characterized in that said wallpaper is prepared from following method: will be not at first dipping or spraying in fire resistant fluid of fire retardant papers, brush fire resistant fluid, and then process through the method for super-dry; Wherein said fire resistant fluid is the aqueous solution or emulsion, the fire retardant in the fire resistant fluid be a) contain nitrogen combustion inhibitor one or more, b) one or more or c in the phosphonium flame retardant) in the aluminium hydroxide, magnesium hydroxide, boric acid, Firebrake ZB, zinc one or more; The concentration expressed in percentage by weight of the wherein said aqueous solution or emulsion is preferably 10～35%.
7. compound wallpaper according to claim 6 is characterized in that the fire retardant in the said fire resistant fluid is made up of following components in weight percentage content: dicyandiamide 5%, APP 10%, Firebrake ZB 5%.
8. compound wallpaper according to claim 6 is characterized in that the fire retardant in the said fire resistant fluid is made up of following components in weight percentage content: melamine 3%, APP 4%, boric acid 3%.
9. compound wallpaper according to claim 6 is characterized in that the fire retardant in the said fire resistant fluid is made up of following components in weight percentage content: melamine 5%, APP 10%, Guanidine Sulfamate 99 20%.
10. compound wallpaper according to claim 6 is characterized in that the fire retardant in the said fire resistant fluid is made up of following components in weight percentage content: dicyandiamide 5%, phosphoric acid 5%, Guanidine Sulfamate 99 12%.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87105201A (en) * | 1987-07-31 | 1988-03-16 | 北京市建筑塑料制品厂 | Fire-resisting wallpaper of polyvinyl chloride |
| CN1282662A (en) * | 1999-07-29 | 2001-02-07 | 普雷马克Rwp控股公司 | System and method of producing laminated product by using plastic film |
| CN101397377A (en) * | 2007-09-25 | 2009-04-01 | Sk能源株式会社 | Auxiliary plasticizers of PVC and PVC sol composition and products containing the same |
| CN102002200A (en) * | 2001-09-25 | 2011-04-06 | 埃克森美孚化学专利公司 | Plasticised polyvinyl chloride |
-
2011
- 2011-12-12 CN CN201110411352.2A patent/CN102587218B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87105201A (en) * | 1987-07-31 | 1988-03-16 | 北京市建筑塑料制品厂 | Fire-resisting wallpaper of polyvinyl chloride |
| CN1282662A (en) * | 1999-07-29 | 2001-02-07 | 普雷马克Rwp控股公司 | System and method of producing laminated product by using plastic film |
| CN102002200A (en) * | 2001-09-25 | 2011-04-06 | 埃克森美孚化学专利公司 | Plasticised polyvinyl chloride |
| CN101397377A (en) * | 2007-09-25 | 2009-04-01 | Sk能源株式会社 | Auxiliary plasticizers of PVC and PVC sol composition and products containing the same |
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