CN102585769A - Plastic-carrier-free antistatic agent functional master batches - Google Patents
Plastic-carrier-free antistatic agent functional master batches Download PDFInfo
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- CN102585769A CN102585769A CN2011100042392A CN201110004239A CN102585769A CN 102585769 A CN102585769 A CN 102585769A CN 2011100042392 A CN2011100042392 A CN 2011100042392A CN 201110004239 A CN201110004239 A CN 201110004239A CN 102585769 A CN102585769 A CN 102585769A
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- antistatic agent
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Abstract
An antistatic agent found by studies comprises the composition of alkyl sulfonic acid, alkyl sulfonate, derivatives of alkyl sulfonate, straight chain paraffin, multifunctional fatty acid, wax, alkaline metal sulfate, alkaline metal halide, alkaline metal chlorate, metal soap, graphite carbon atom crystals and the like; plastic-carrier-free antistatic agent functional master batches with excellent performances can be prepared through the manufacturing processes of melting and stirring, banburying and kneading, forming by grain cutting through a die head or granulating forming by dripping through a fabric, vacuum cooling, and inert gas filling for cooling; and the prepared plastic-carrier-free antistatic agent functional master batches are dyeable and light-transmitting, the content of the effective antistatic agent in the prepared plastic-carrier-free antistatic agent functional master batches is 95 percent, and the prepared plastic-carrier-free antistatic agent functional master batches have a superior conductive function under the condition of an extremely small additive amount and have a static charge eliminating function when the air relative humidity is lower than 30 percent. The Plastic-carrier-free antistatic agent functional master batches have the advantages of excellent heat resistance, low probability of becoming damp, small additive amount, simplicity and convenience in processing, no talcum powder, no heavy metal and the like, do not change the glossiness, the impact and the chemical performance of resin, can be extensively applied to the manufacturing of various kinds of thermoplastic resin, coatings, printing inks and fabrics, and can effectively eliminate static charges to reduce the surface resistivity to be about 103 to 11 power.
Description
Find a kind of static inhibitor after deliberation: comprise alkylsulphonic acid, AS and verivate thereof, straight-chain paraffin, multifunctional lipid acid; Wax, alkali metal sulfates, alkali metal halide, alkaline metal chlorate; Metallic soap, the compsn of graphite carbon atomic crystal etc. stirs through fusion, and banburying is mediated; The moulding of die head pelletizing moulding or cloth drippage granulating, vacuum cooling, filling rare gas element refrigerative manufacturing process can make the no plastic cement carrier static inhibitor functional agglomerate of excellent performance; The no plastic cement carrier static inhibitor master batch that makes possesses tint permanence, light transmission, and its effective static inhibitor content is 95%; Under the few situation of addition, possess good conducting function,, relative air humidity still has the static charge of elimination function when being lower than 30%.Excellent thermotolerance, moisture-sensitive not, addition is few, processes easyly, does not contain talcum powder, does not contain heavy metal etc., can not change glossiness, impact and the chemical property of resin.Can be widely used in various thermoplastic resins, coating, printing ink, fabric manufacturing.Can effectively eliminate static charge, surface resistivity is dropped to 10
3-11About power.
In people's impression,, very easily fly upward bad homodisperse because the consumption of additives for plastics in plastic cement application processing is few; And fusing point is low, and water absorbability is strong, particularly migration-type plastic cement static inhibitor functional agent; Make people in the processed and applied process, run into many difficult problems; So must process the functional agglomerate that includes thermoplastic resin base material carrier usually, convenient keeping, processing are used, and also feel confused because of the very bad transportation of pulverous plastic cement auxiliary agent and keeping.For this reason, a kind of no plastic cement function vector master batch of I invent multi, this technology has been broken has the maximum effective ingredient of plastic cement function vector master batch functional agent to have only 20% rule; Do not need secondary processing; Can greatly reduce production cost, reduce production energy consumption, low carbon ring is protected.No plastic cement function vector master batch is not because there is the plastic cement carrier, thereby need not add talcum powder and draw oily matter.No plastic cement function vector master batch, its functional agent content purity is 95%, can not change glossiness, impact and the chemical property of resin.No plastic cement function vector master batch processing is very easy, only needs not have plastic cement function vector master batch and gets final product with heating and stirring timing even dissipation.This ME can be used for making carrier free plastic cement antioxygen master batch, carrier free plastic cement fire-retardant master granule; Carrier free plastic cement degradation master batch; Carrier free plastic cement ultraviolet light master batch, carrier free plastic cement static eliminator master batch, carrier free plastic cement dyeing master batch; The carrier free plastic cement lubricates master batch, and carrier free plastic cement static inhibitor master batch or the like plastic cement is used functional agglomerate.
No plastic cement carrier antistatic master granule, physical condition: soybean particle shape thing, fusing point 100-230 degree centigrade; Be very easy to stir and dissipate, and blanking is smooth, only need during use to stir no plastic cement carrier antistatic master granule through specified temp; Regularly mix and be dissipated in the resin; Again with the antistatic resin that mixes, if thermoplastic resin again through banburying mediate alternately disperse to connect after, can make the function moulded work; The moulded work that makes possesses good conducting function, when relative air humidity is lower than 30%, still has the static charge of elimination function.Excellent thermotolerance, moisture-sensitive not, addition is few, processes easyly, does not contain talcum powder, does not contain heavy metal etc., can not change glossiness, impact and the chemical property of resin.
Require following material process for formulating to carry out patent protection for above invention, material compatibility component comprises: a kind of static inhibitor: comprise alkylsulphonic acid, AS and verivate thereof; Straight-chain paraffin, multifunctional lipid acid, wax; Alkali metal sulfates, alkali metal halide, alkaline metal chlorate; Metallic soap, the compsn of graphite carbon atomic crystal.No plastic cement carrier antistatic master granule ME: fusion is stirred, and banburying is mediated, vacuum cooling, and the cooling of filling rare gas element, die head pelletizing or cloth drip granulated available manufacturing process.
Claims (1)
1. require following material process for formulating to carry out patent protection, material compatibility component comprises: a kind of static inhibitor: comprise alkylsulphonic acid, AS and verivate thereof; Straight-chain paraffin, multifunctional lipid acid, wax; Alkali metal sulfates, alkali metal halide, alkaline metal chlorate; Metallic soap, the compsn of graphite carbon atomic crystal.No plastic cement carrier antistatic master granule ME: fusion is stirred, and banburying is mediated, vacuum cooling, and the cooling of filling rare gas element, die head pelletizing or cloth drip granulated available manufacturing process.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100042392A CN102585769A (en) | 2011-01-04 | 2011-01-04 | Plastic-carrier-free antistatic agent functional master batches |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100042392A CN102585769A (en) | 2011-01-04 | 2011-01-04 | Plastic-carrier-free antistatic agent functional master batches |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102585769A true CN102585769A (en) | 2012-07-18 |
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ID=46475015
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011100042392A Pending CN102585769A (en) | 2011-01-04 | 2011-01-04 | Plastic-carrier-free antistatic agent functional master batches |
Country Status (1)
| Country | Link |
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| CN (1) | CN102585769A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104844820A (en) * | 2015-04-24 | 2015-08-19 | 暨南大学 | Carbon nanotube conductive masterbatch, preparation method and application thereof |
| CN105018031A (en) * | 2015-07-20 | 2015-11-04 | 上海市安全生产科学研究所 | Static elimination organogel for electrostatic protection zone and preparation method thereof |
| CN105143143A (en) * | 2013-03-14 | 2015-12-09 | 达普产品公司 | Antistatic additives in sandable repair products |
-
2011
- 2011-01-04 CN CN2011100042392A patent/CN102585769A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105143143A (en) * | 2013-03-14 | 2015-12-09 | 达普产品公司 | Antistatic additives in sandable repair products |
| CN104844820A (en) * | 2015-04-24 | 2015-08-19 | 暨南大学 | Carbon nanotube conductive masterbatch, preparation method and application thereof |
| CN105018031A (en) * | 2015-07-20 | 2015-11-04 | 上海市安全生产科学研究所 | Static elimination organogel for electrostatic protection zone and preparation method thereof |
| CN105018031B (en) * | 2015-07-20 | 2017-06-20 | 上海市安全生产科学研究所 | Static elimination organogel for electrostatic protection region and preparation method thereof |
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| C53 | Correction of patent for invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 430000, Wuhan, Hongshan District, Hubei Province, South Lake Avenue, Zhongnan University of Economics and Law apartment around the lake 6 underground Applicant after: Chi Huahua Address before: 523000 Sima, No. two, No. 215, Sima village, Changping Town, Dongguan, Guangdong Applicant before: Chi Huahua |
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| DD01 | Delivery of document by public notice |
Addressee: Chi Huaying Document name: Notification of Passing Examination on Formalities |
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| DD01 | Delivery of document by public notice |
Addressee: Chi Huahua Document name: Decision of Rejection |
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| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20120718 |