CN102585749A - Unsaturated polyester resin adhesive - Google Patents
Unsaturated polyester resin adhesive Download PDFInfo
- Publication number
- CN102585749A CN102585749A CN2011104497077A CN201110449707A CN102585749A CN 102585749 A CN102585749 A CN 102585749A CN 2011104497077 A CN2011104497077 A CN 2011104497077A CN 201110449707 A CN201110449707 A CN 201110449707A CN 102585749 A CN102585749 A CN 102585749A
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- China
- Prior art keywords
- polyester resin
- unsaturated polyester
- powder
- parts
- tackiness agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- Compositions Of Macromolecular Compounds (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention provides an unsaturated polyester resin adhesive adopting a novel rheological agent. The unsaturated polyester resin adhesive consists of the following raw materials in part by weight: 100 parts of unsaturated polyester resin, 50 to 600 parts of organic filler, 1 to 50 parts of silicon micro powder, and 0 to 300 parts of diluent. The adhesive is prepared by using industrial waste residue silicon micro powder which replaces silica (white carbon black) produced by a gas phase method as the rheological agent, and the obtained adhesive is low in cost, good in rheological property, and long in retention period. Meanwhile, new application is found for the industrial residues, and the unsaturated polyester resin adhesive contributes to environment friendliness.
Description
Technical field
The present invention relates to adhesive area, be specifically related to a kind of unsaturated polyester resin glue that adopts the new rheology agent.
Background technology
The tackiness agent of producing with the unsaturated polyester resin fillers such as stone flour different with thickness at present is one type of purposes architecture adhesion agent very widely.Because fillers such as stone flour are different with the proportion of unsaturated polyester resin, fillers such as stone flour are easy in tackiness agent, sink, and cause the tackiness agent layering to use.Original terms of settlement is in tackiness agent, to add the thixotropy that the WHITE CARBON BLACK high speed dispersion is obtained resin, prevents the tackiness agent layering.The price of WHITE CARBON BLACK is very high to have limited its a large amount of uses in tackiness agent or coating, and because it needs high speed dispersion just can play one's part to the full, in practical application, often causes thixotropy not good owing to disperse not reach requirement.
Summary of the invention
The purpose of this invention is to provide a kind of unsaturated polyester resin glue or coating that adopts the new rheology agent, adopt silicon powder to improve the thixotropy of unsaturated polyester resin, prevent unsaturated polyester resin tackiness agent or coating layering.
Technical scheme of the present invention is following:
A kind of unsaturated polyester resin tackiness agent is characterized in that: the weight part of its constitutive material is:
Described unsaturated polyester resin tackiness agent is characterized in that: described mineral filler is selected from one or more in limestone powder, marble flour, silica powder, ground dolomite, porcelain powder and yellow ground, small-particle grouan, talcum powder, the dry powder; Described thinner is divalent alcohol, polyethers LV thinner.Described silicon powder is the silicon powder that stack gas is collected in ferroalloy works' production process, and the technical indicator of silicon powder is:
Median size: 0.1～0.15 μ m, less than accounting for more than 80% of 1 μ m
Specific surface area: 250000～350000C m
2/ g
Dioxide-containing silica >=91%
Loss on ignition≤4%
Moisture content≤2%.
Working method: the starting material of will filling a prescription get final product through simple stirring after mixing.
The advantage of the present invention of comparing with the tackiness agent that common employing WHITE CARBON BLACK is produced as rheological agent is following:
1, cost of material is cheap, wide material sources
The present invention adopts the silicon powder that stack gas is collected in ferroalloy works' production process to replace WHITE CARBON BLACK of the prior art as rheological agent; This silicon powder belongs to industrial residue, and is cheap, reduced material cost; Also reduce industrial residue simultaneously, reduced the pollution of environment;
2, technology is simple
When routine adopts WHITE CARBON BLACK as rheological agent; Must adopt high speed dispersor to carry out high speed dispersion when adding WHITE CARBON BLACK and just can obtain certain thixotropy; Two the present invention do not need high speed dispersion can obtain good thixotropy as long as adopt the volume that strengthens silicon powder, and technology is simple;
3, long preservative period
The tackiness agent that tackiness agent of the present invention and WHITE CARBON BLACK make as rheological agent, under identical preservation condition sizing agent of the present invention keep 1 year not stratified, and three months be layering with the tackiness agent that WHITE CARBON BLACK is produced.
Embodiment
A kind of unsaturated polyester resin tackiness agent, the part by weight of its feed composition is:
Unsaturated polyester resin: 100
Mineral filler: 300
Silicon powder: 10
Thinner: 10.
The unsaturated polyester resin sizing agent that the present invention processes sees the following form with the performance comparison that adopts WHITE CARBON BLACK as the unsaturated polyester resin sizing agent of rheological agent:
Claims (2)
1. unsaturated polyester resin tackiness agent, it is characterized in that: the weight part of its constitutive material is:
Unsaturated polyester resin 100
Mineral filler 50-600
Silicon powder 1-50
Alcohol ethers thinner 0-300.
2. unsaturated polyester resin tackiness agent according to claim 1 is characterized in that: described mineral filler is selected from one or more in limestone powder, marble flour, silica powder, ground dolomite, porcelain powder and yellow ground, small-particle grouan, talcum powder, the dry powder; Described thinner is divalent alcohol, polyethers LV thinner; Described silicon powder is the silicon powder that stack gas is collected in ferroalloy works' production process, and the technical indicator of silicon powder is:
Median size: 0.1～0.15 μ m, less than accounting for more than 80% of 1 μ m
Specific surface area: 250000～350000C ㎡/g
Dioxide-containing silica >=91%
Loss on ignition≤4%
Moisture content≤2%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104497077A CN102585749A (en) | 2011-12-29 | 2011-12-29 | Unsaturated polyester resin adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104497077A CN102585749A (en) | 2011-12-29 | 2011-12-29 | Unsaturated polyester resin adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102585749A true CN102585749A (en) | 2012-07-18 |
Family
ID=46474999
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011104497077A Pending CN102585749A (en) | 2011-12-29 | 2011-12-29 | Unsaturated polyester resin adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102585749A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634763A (en) * | 2016-12-06 | 2017-05-10 | 苏州洛特兰新材料科技有限公司 | High-heat-conductivity electric-insulation adhesive material and preparation method thereof |
| CN107674626A (en) * | 2017-09-28 | 2018-02-09 | 武汉市科达云石护理材料有限公司 | A kind of transparent cloud stone glue of high thixotropic and preparation method thereof |
| CN107793985A (en) * | 2017-09-28 | 2018-03-13 | 武汉市科达云石护理材料有限公司 | A kind of coloured cloud stone glue of high thixotropic and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000219804A (en) * | 1999-02-02 | 2000-08-08 | Takata Corp | Clayey photocurable resin composition, sheet, caulking agent and adhesive |
| CN101851483A (en) * | 2010-06-08 | 2010-10-06 | 武汉市科达云石护理材料有限公司 | Stone jointing adhesive |
-
2011
- 2011-12-29 CN CN2011104497077A patent/CN102585749A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000219804A (en) * | 1999-02-02 | 2000-08-08 | Takata Corp | Clayey photocurable resin composition, sheet, caulking agent and adhesive |
| CN101851483A (en) * | 2010-06-08 | 2010-10-06 | 武汉市科达云石护理材料有限公司 | Stone jointing adhesive |
Non-Patent Citations (4)
| Title |
|---|
| 《中山大学学报（自然科学版）》 19990725 刘岚等 "活性稀释剂对不饱和聚酯流变性能的影响" "前言"、"1.1试剂与仪器"、"2.2不同稀释剂的稀释效率"部分 1-2 第38卷, 第4期 * |
| 《贵州工业大学学报（自然科学版）》 20021025 毛健全等 "铁合金烟气治理及硅微粉的回收利用" "2烟气粉尘资源化前景：回收硅微粉"部分 1-2 第31卷, 第5期 * |
| 刘岚等: ""活性稀释剂对不饱和聚酯流变性能的影响"", 《中山大学学报（自然科学版）》 * |
| 毛健全等: ""铁合金烟气治理及硅微粉的回收利用"", 《贵州工业大学学报（自然科学版）》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106634763A (en) * | 2016-12-06 | 2017-05-10 | 苏州洛特兰新材料科技有限公司 | High-heat-conductivity electric-insulation adhesive material and preparation method thereof |
| CN107674626A (en) * | 2017-09-28 | 2018-02-09 | 武汉市科达云石护理材料有限公司 | A kind of transparent cloud stone glue of high thixotropic and preparation method thereof |
| CN107793985A (en) * | 2017-09-28 | 2018-03-13 | 武汉市科达云石护理材料有限公司 | A kind of coloured cloud stone glue of high thixotropic and preparation method thereof |
| CN107793985B (en) * | 2017-09-28 | 2020-05-22 | 武汉市科达云石护理材料有限公司 | High-thixotropic colored marble adhesive and preparation method thereof |
| CN107674626B (en) * | 2017-09-28 | 2020-08-04 | 武汉市科达云石护理材料有限公司 | High-thixotropic transparent marble adhesive and preparation method thereof |
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Application publication date: 20120718 |