CN102585617A - Fluorocarbon modified styrene-acrylic coating, and preparation method thereof - Google Patents
Fluorocarbon modified styrene-acrylic coating, and preparation method thereof Download PDFInfo
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- CN102585617A CN102585617A CN2012100050764A CN201210005076A CN102585617A CN 102585617 A CN102585617 A CN 102585617A CN 2012100050764 A CN2012100050764 A CN 2012100050764A CN 201210005076 A CN201210005076 A CN 201210005076A CN 102585617 A CN102585617 A CN 102585617A
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Abstract
The invention discloses a fluorocarbon modified styrene-acrylic coating. The fluorocarbon modified styrene-acrylic coating consists of the following components in percentage by mass: 34 to 42.5 percent of GHT-1 styrene-acrylic emulsion, 5.2 to 6.5 percent of GHSF-25 fluorocarbon emulsion, 0.4 to 0.5 percent of gamma-aminopropyltriethoxysilan, 0.4 to 0.5 percent of polyethylene glycol phenyl ether, 18 to 22 percent of rutile type titanium dioxide, 8 to 10 percent of talcpowder, 8 to 10 percent of mica powder, 8 to 11 percent of calcite in powder, 0.1 to 0.15 percent of hydroxy silicone oil modified polyacrylate, 0.01 to 0.02 percent of polyether modified polysiloxane, 0.01 to 0.02 percent of kazon and the balance of water. A preparation method comprises the following steps of: modifying the styrene-acrylic emulsion by using the fluorocarbon emulsion, the gamma-aminopropyltriethoxysilan, and the polyethylene glycol phenyl ether at the temperature of between 76 and 80 DEG C, and preparing by using the modified fluorocarbon modified styrene-acrylic emulsion to obtain the fluorocarbon modified styrene-acrylic coating. The preparation process is simple, and low in investment and cost; and a product has the advantages of high weather fastness, chemical resistance, and water resistance, scrubbing resistance, and artificial aging resistance.
Description
Technical field
The invention belongs to the trade sales coating technical field, relate to a kind of coating, specifically, relate to a kind of fluorine-carbon modified phenylpropyl alcohol coating and preparation method thereof, be mainly used in the building external paint field.
Background technology
In recent years, the research of phenylpropyl alcohol coating is obtained certain achievement, but still had many problems to be solved.Remain in shortcoming such as high-weatherability, high resistance to chemicals corrodibility, water tolerance, scrub resistance and artificial ageing resistance property be relatively poor relatively like the phenylpropyl alcohol building external paint.Adopt the fluorine carbon emulsion modifying cinepazid emulsion to develop fluorine-carbon modified phenylpropyl alcohol coating and can overcome existing shortcoming, satisfy the technical performance index requirement.Because fluoro-containing coating has advantages such as high-weatherability, high resistance to chemicals corrodibility, water tolerance, scrub resistance and artificial ageing resistance property.Can solve the problems such as weathering resistance, chemical resistance, water tolerance, scrub resistance and artificial ageing resistance property of phenylpropyl alcohol coating.
Adopt the fluorine carbon emulsion modifying cinepazid emulsion, can improve weathering resistance, chemical resistance, scrub resistance and the artificial ageing resistance property over-all properties of emulsion; Add γ-An Bingjisanyiyangjiguiwan simultaneously and can further improve sticking power and weather resistance and paint film water tolerance again, improve wettability and the dispersiveness of filler in polymkeric substance.Adopt the prepared emulsion of the present invention to have high-weatherability, high resistance to chemicals corrodibility, water tolerance, scrub resistance and characteristics such as artificial ageing resistance property, alkali resistance, have excellent popularization and be worth and development space.
Summary of the invention
The objective of the invention is problem to above-mentioned prior art existence; Through adopting fluorine carbon emulsion, γ-An Bingjisanyiyangjiguiwan, polyoxyethylene octyl phenyl ether modifying cinepazid emulsion at a certain temperature, prepare a kind of novel fluorine-carbon modified phenylpropyl alcohol building external paint with the fluorine-carbon modified benzene emulsion after the modification then.For this reason, a kind of fluorine-carbon modified phenylpropyl alcohol coating and preparation method thereof is provided.
In order to achieve the above object, the present invention realizes that the technical scheme that purpose is taked is:
A kind of fluorine-carbon modified phenylpropyl alcohol coating, by the quality percentage composition by component: the GHT-1 benzene emulsion is 34～42.5%, and the GHSF-25 fluorine carbon emulsion is 5.20～6.50%; γ-An Bingjisanyiyangjiguiwan is 0.4～0.5%, and polyoxyethylene octyl phenyl ether is 0.4～0.5%, and Rutile type Titanium Dioxide is 18～22%; Talcum powder is 8%～10%, and mica powder is 8%～10%, and calcite in powder is 8%～11%; Hydroxyl silicon oil modified polyacrylate is 0.1～0.15%; Polyether-modified ZGK 5 is 0.01～0.02%, and the card pine is 0.01～0.02, and water is 4.81～11.81% compositions.
In order to achieve the above object, the present invention realizes that another technical scheme that purpose is taked is:
The preparation method of above-mentioned described a kind of fluorine-carbon modified phenylpropyl alcohol coating comprises the following steps:
1. the GHT-1 benzene emulsion is added in the four-hole bottle; Stirring is warming up to 73 ℃-76 ℃ and is added dropwise to the GHSF-25 fluorine carbon emulsion slowly; Simultaneously be added dropwise to γ-An Bingjisanyiyangjiguiwan slowly, after waiting to add γ-An Bingjisanyiyangjiguiwan, add polyoxyethylene octyl phenyl ether, hydroxyl silicon oil modified polyacrylate, polyether-modified ZGK 5, card pine more respectively; Temperature be controlled at 76 ℃-80 ℃ the reaction half a hour after cooling discharge, obtain fluorine-carbon modified benzene emulsion.
2. water is added and stir in the filling, start whisking appliance, add Rutile type Titanium Dioxide and stir; Add again after fluorine-carbon modified benzene emulsion after step 1 modification stirs, add talcum powder, mica powder, calcite in powder respectively and stir; Promptly obtain fluorine-carbon modified phenylpropyl alcohol coating.
3. the fluorine-carbon modified phenylpropyl alcohol coating that step 2 is obtained gets into sand mill and grinds the both sides filtration, the discharging packing.
The present invention compared with prior art, the advantage and the beneficial effect that have mainly are:
Product of the present invention has advantages such as high-weatherability, high resistance to chemicals corrodibility, water tolerance, scrub resistance and artificial ageing resistance property.The relative prior art of its performance index is doubled many, has overcome the deficiency of phenylpropyl alcohol coating.Preparation technology of the present invention is simple, and less investment, low, the excellent property of cost have good economic benefit and using value.
Specific embodiments
Embodiment 1
One, by quality percentage composition prescription
Two, preparation method
Step 1, the GHT-1 benzene emulsion is added in the four-hole bottle; Stirring is warming up to 73 ℃ and is added dropwise to the GHSF-25 fluorine carbon emulsion slowly; Simultaneously be added dropwise to γ-An Bingjisanyiyangjiguiwan slowly, after waiting to add γ-An Bingjisanyiyangjiguiwan, add polyoxyethylene octyl phenyl ether, hydroxyl silicon oil modified polyacrylate, polyether-modified ZGK 5, card pine more respectively; Temperature be controlled at 76 ℃ the reaction half a hour after cooling discharge, obtain fluorine-carbon modified benzene emulsion.
Step 2, water add to stir irritated, start whisking appliance, add Rutile type Titanium Dioxide and stir; Add again after fluorine-carbon modified benzene emulsion after step 1 modification stirs, add talcum powder, mica powder, calcite in powder respectively and stir; Promptly obtain fluorine-carbon modified phenylpropyl alcohol coating.
Step 3, the fluorine-carbon modified phenylpropyl alcohol coating that step 2 is obtained get into sand mill grinding both sides filtration, discharging packing.
Three, the advantage of present embodiment and beneficial effect (seeing table 1)
The performance comparison of table 1 phenylpropyl alcohol coating and fluorine-carbon modified phenylpropyl alcohol coating
Embodiment 2
One, by quality percentage composition prescription
Two, preparation method
Step 1, the GHT-1 benzene emulsion is added in the four-hole bottle; Stirring is warming up to 74 ℃ and is added dropwise to the GHSF-25 fluorine carbon emulsion slowly; Simultaneously be added dropwise to γ-An Bingjisanyiyangjiguiwan slowly, after waiting to add γ-An Bingjisanyiyangjiguiwan, add polyoxyethylene octyl phenyl ether, hydroxyl silicon oil modified polyacrylate, polyether-modified ZGK 5, card pine more respectively; Temperature be controlled at 77 ℃ the reaction half a hour after cooling discharge, obtain fluorine-carbon modified benzene emulsion.
Step 2, water add to stir irritated, start whisking appliance, add Rutile type Titanium Dioxide and stir; Add again after fluorine-carbon modified benzene emulsion after step 1 modification stirs, add talcum powder, mica powder, calcite in powder respectively and stir; Promptly obtain fluorine-carbon modified phenylpropyl alcohol coating.
Step 3, the fluorine-carbon modified phenylpropyl alcohol coating that step 2 is obtained get into sand mill grinding both sides filtration, discharging packing.
Three, the advantage of present embodiment and beneficial effect (seeing table 2)
The performance comparison of table 2 phenylpropyl alcohol coating and fluorine-carbon modified phenylpropyl alcohol coating
Embodiment 3
One, by quality percentage composition prescription
Two, preparation method
Step 1, the GHT-1 benzene emulsion is added in the four-hole bottle; Stirring is warming up to 75 ℃ and is added dropwise to the GHSF-25 fluorine carbon emulsion slowly; Simultaneously be added dropwise to γ-An Bingjisanyiyangjiguiwan slowly, after waiting to add γ-An Bingjisanyiyangjiguiwan, add polyoxyethylene octyl phenyl ether, hydroxyl silicon oil modified polyacrylate, polyether-modified ZGK 5, card pine more respectively; Temperature be controlled at 78 ℃ the reaction half a hour after cooling discharge, obtain fluorine-carbon modified benzene emulsion.
Step 2, water add to stir irritated, start whisking appliance, add Rutile type Titanium Dioxide and stir; Add again after fluorine-carbon modified benzene emulsion after step 1 modification stirs, add talcum powder, mica powder, calcite in powder respectively and stir; Promptly obtain fluorine-carbon modified phenylpropyl alcohol coating.
Step 3, the fluorine-carbon modified phenylpropyl alcohol coating that step 2 is obtained get into sand mill grinding both sides filtration, discharging packing.
Three, the advantage of present embodiment and beneficial effect (seeing table 3)
The performance comparison of table 3 phenylpropyl alcohol coating and fluorine-carbon modified phenylpropyl alcohol coating
Embodiment 4
One, by quality percentage composition prescription
Two, preparation method
Step 1, the GHT-1 benzene emulsion is added in the four-hole bottle; Stirring is warming up to 76 ℃ and is added dropwise to the GHSF-25 fluorine carbon emulsion slowly; Simultaneously be added dropwise to γ-An Bingjisanyiyangjiguiwan slowly, after waiting to add γ-An Bingjisanyiyangjiguiwan, add polyoxyethylene octyl phenyl ether, hydroxyl silicon oil modified polyacrylate, polyether-modified ZGK 5, card pine more respectively; Temperature be controlled at 79 ℃ the reaction half a hour after cooling discharge, obtain fluorine-carbon modified benzene emulsion.
Step 2, water add to stir irritated, start whisking appliance, add Rutile type Titanium Dioxide and stir; Add again after fluorine-carbon modified benzene emulsion after step 1 modification stirs, add talcum powder, mica powder, calcite in powder respectively and stir; Promptly obtain fluorine-carbon modified phenylpropyl alcohol coating.
Step 3, the fluorine-carbon modified phenylpropyl alcohol coating that step 2 is obtained get into sand mill grinding both sides filtration, discharging packing.
Three, the advantage of present embodiment and beneficial effect (seeing table 4)
The performance comparison of table 4 phenylpropyl alcohol coating and fluorine-carbon modified phenylpropyl alcohol coating
Embodiment 5
Two, preparation method
Step 1, the GHT-1 benzene emulsion is added in the four-hole bottle; Stirring is warming up to 75 ℃ and is added dropwise to the GHSF-25 fluorine carbon emulsion slowly; Simultaneously be added dropwise to γ-An Bingjisanyiyangjiguiwan slowly, after waiting to add γ-An Bingjisanyiyangjiguiwan, add polyoxyethylene octyl phenyl ether, hydroxyl silicon oil modified polyacrylate, polyether-modified ZGK 5, card pine more respectively; Temperature be controlled at 80 ℃ the reaction half a hour after cooling discharge, obtain fluorine-carbon modified benzene emulsion.
Step 2, water add to stir irritated, start whisking appliance, add Rutile type Titanium Dioxide and stir; Add again after fluorine-carbon modified benzene emulsion after step 1 modification stirs, add talcum powder, mica powder, calcite in powder respectively and stir; Promptly obtain fluorine-carbon modified phenylpropyl alcohol coating.
Step 3, the fluorine-carbon modified phenylpropyl alcohol coating that step 2 is obtained get into sand mill grinding both sides filtration, discharging packing.
Three, the advantage of present embodiment and beneficial effect (seeing table 5)
The performance comparison of table 5 phenylpropyl alcohol coating and fluorine-carbon modified phenylpropyl alcohol coating
The said phenylpropyl alcohol coating of table 1 to table 5 among the embodiment 1 to embodiment 5 in sum and the performance comparison of fluorine-carbon modified phenylpropyl alcohol coating can be found out the fluorine-carbon modified phenylpropyl alcohol coating that the present invention prepares; Has film forming properties preferably, enhanced water resistance, acid resistance, alkali resistance, abrasion resistance, artificial ageing resistance property.The major cause that significantly improves performance index is; Fluorine carbon emulsion has been incorporated in the structure of benzene emulsion; Make former emulsion possess the advantage of fluorine carbon emulsion HS, water tolerance, acid resistance, alkali resistance, abrasion resistance, artificial ageing resistance property; The γ-An Bingjisanyiyangjiguiwan that adds has simultaneously further improved the weather resistance and the paint film water tolerance of sticking power again, and has improved wettability and the dispersiveness of filler in polymkeric substance.Prepared fluorine-carbon modified benzene emulsion has the advantage of HS, enhanced water resistance, acid resistance, alkali resistance, abrasion resistance, artificial ageing resistance property, and development and application has good prospects.
Claims (2)
1. a fluorine-carbon modified phenylpropyl alcohol coating is characterized in that, by the quality percentage composition by component: the GHT-1 benzene emulsion is 34～42.5%; The GHSF-25 fluorine carbon emulsion is 5.20～6.50%, and γ-An Bingjisanyiyangjiguiwan is 0.4～0.5%, and polyoxyethylene octyl phenyl ether is 0.4～0.5%; Rutile type Titanium Dioxide is 18～22%, and talcum powder is 8%～10%, and mica powder is 8%～10%; Calcite in powder is 8%～11%, and hydroxyl silicon oil modified polyacrylate is 0.1～0.15%, and polyether-modified ZGK 5 is 0.01～0.02%; The card pine is 0.01～0.02, and water is 4.81～11.81% compositions.
2. the preparation method of a fluorine-carbon modified phenylpropyl alcohol coating as claimed in claim 1 is characterized in that, comprises the following steps:
(1) the GHT-1 benzene emulsion is added in the four-hole bottle; Stirring is warming up to 73 ℃-76 ℃ and is added dropwise to the GHSF-25 fluorine carbon emulsion slowly; Simultaneously be added dropwise to γ-An Bingjisanyiyangjiguiwan slowly, after waiting to add γ-An Bingjisanyiyangjiguiwan, add polyoxyethylene octyl phenyl ether, hydroxyl silicon oil modified polyacrylate, polyether-modified ZGK 5, card pine more respectively; Temperature be controlled at 76 ℃-80 ℃ the reaction half a hour after cooling discharge, obtain fluorine-carbon modified benzene emulsion;
(2) water is added in the stirring filling, start whisking appliance, add Rutile type Titanium Dioxide and stir; Add again after fluorine-carbon modified benzene emulsion after step 1 modification stirs, add talcum powder, mica powder, calcite in powder respectively and stir; Promptly obtain fluorine-carbon modified phenylpropyl alcohol coating;
(3) the fluorine-carbon modified phenylpropyl alcohol coating that step (2) is obtained gets into sand mill and grinds the both sides filtration, the discharging packing.
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| CN2012100050764A CN102585617B (en) | 2012-01-10 | 2012-01-10 | Fluorocarbon modified styrene-acrylic coating, and preparation method thereof |
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| CN2012100050764A CN102585617B (en) | 2012-01-10 | 2012-01-10 | Fluorocarbon modified styrene-acrylic coating, and preparation method thereof |
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| CN102585617B CN102585617B (en) | 2013-12-04 |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102875735A (en) * | 2012-09-29 | 2013-01-16 | 上海东升新材料有限公司 | Styrene-acrylic emulsion for surface coating paint of coated paper and preparation method thereof |
| CN104327630A (en) * | 2014-10-14 | 2015-02-04 | 马鞍山市恒毅机械制造有限公司 | Glass coating with anti-radiation function, and its preparation method |
| CN104327626A (en) * | 2014-10-14 | 2015-02-04 | 马鞍山市恒毅机械制造有限公司 | Hydrolysis and light resistant aqueous coating for glass doors, and its preparation method |
| CN104341914A (en) * | 2014-10-14 | 2015-02-11 | 凤阳徽亨商贸有限公司 | Dirt-resistant mold-resistant paint for glass doors and preparation method thereof |
| CN104479474A (en) * | 2014-12-03 | 2015-04-01 | 东莞市长安东阳光铝业研发有限公司 | Super-weatherability fluorocarbon coating and preparation method thereof |
| CN104845473A (en) * | 2015-04-29 | 2015-08-19 | 广德嘉宝莉化工有限公司 | High-strength, shock-resistant and abrasion-resistant mechanical paint |
| CN105504904A (en) * | 2016-01-11 | 2016-04-20 | 中国神华能源股份有限公司 | Acid-modified potash water glass-fluorocarbon-modified styrene-acrylic emulsion composite coating and preparation method thereof |
| CN105820703A (en) * | 2016-04-12 | 2016-08-03 | 湖州新奥克化工有限公司 | Water-based transparent weather-resisting paint for thermos cups |
| CN106085024A (en) * | 2016-06-12 | 2016-11-09 | 安徽快来防水防腐有限公司 | A kind of low temperature resistant double-component cinepazid polymer cement-base waterproof coating and preparation method thereof |
| CN106398406A (en) * | 2016-09-14 | 2017-02-15 | 四川力久云智知识产权运营有限公司 | Novel anti-corrosion coating |
| CN106833247A (en) * | 2017-02-28 | 2017-06-13 | 广州聚澜健康产业研究院有限公司 | A kind of environment-friendly type fluorine carbon anticorrosive paint and preparation method thereof |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102875735A (en) * | 2012-09-29 | 2013-01-16 | 上海东升新材料有限公司 | Styrene-acrylic emulsion for surface coating paint of coated paper and preparation method thereof |
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| CN104327630A (en) * | 2014-10-14 | 2015-02-04 | 马鞍山市恒毅机械制造有限公司 | Glass coating with anti-radiation function, and its preparation method |
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| CN104479474A (en) * | 2014-12-03 | 2015-04-01 | 东莞市长安东阳光铝业研发有限公司 | Super-weatherability fluorocarbon coating and preparation method thereof |
| CN104845473A (en) * | 2015-04-29 | 2015-08-19 | 广德嘉宝莉化工有限公司 | High-strength, shock-resistant and abrasion-resistant mechanical paint |
| CN105504904A (en) * | 2016-01-11 | 2016-04-20 | 中国神华能源股份有限公司 | Acid-modified potash water glass-fluorocarbon-modified styrene-acrylic emulsion composite coating and preparation method thereof |
| CN105820703A (en) * | 2016-04-12 | 2016-08-03 | 湖州新奥克化工有限公司 | Water-based transparent weather-resisting paint for thermos cups |
| CN106085024A (en) * | 2016-06-12 | 2016-11-09 | 安徽快来防水防腐有限公司 | A kind of low temperature resistant double-component cinepazid polymer cement-base waterproof coating and preparation method thereof |
| CN106398406A (en) * | 2016-09-14 | 2017-02-15 | 四川力久云智知识产权运营有限公司 | Novel anti-corrosion coating |
| CN106833247A (en) * | 2017-02-28 | 2017-06-13 | 广州聚澜健康产业研究院有限公司 | A kind of environment-friendly type fluorine carbon anticorrosive paint and preparation method thereof |
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| CN102585617B (en) | 2013-12-04 |
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