CN102524256A - Pesticide composition containing flutolanil and chlorothalonil - Google Patents
Pesticide composition containing flutolanil and chlorothalonil Download PDFInfo
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- CN102524256A CN102524256A CN2011104369632A CN201110436963A CN102524256A CN 102524256 A CN102524256 A CN 102524256A CN 2011104369632 A CN2011104369632 A CN 2011104369632A CN 201110436963 A CN201110436963 A CN 201110436963A CN 102524256 A CN102524256 A CN 102524256A
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- flutolanil
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Abstract
The invention relates to a pesticide composition containing flutolanil and chlorothalonil and use thereof. The composition contains flutolanil and chlorothalonil at a weight ratio of (2-40):(3-60). The composition can be applied to control disease and pest in ornamental plants. The composition has a wide application range, a good effect and a low cost, reduces pesticide residues, and is harmless to human beings, livestock and environments.
Description
(1) technical field
The present invention relates to a kind of purposes that has the bactericidal composition of synergistic effect and be used for the ornamental plant disease control, relate in particular to a kind of bactericidal composition that contains flutolanil and tpn.
(2) background technology
Along with people's growth in the living standard, the demand of ornamental plant also progressively improve, and its cultivated area is also increasing, and market prospects are very good.In recent years, be accompanied by the expansion of cultivated area, the extermination of disease and insect pest of ornamental plant has also caused concern, and like powdery mildew, anthracnose, sooty mould, scale insect, aleyrodid etc., the ornamental value and the economic worth of ornamental plant take place all can reduce for it.The product that rarely has the ornamental plant extermination of disease and insect pest in the market, and control efficiency is bad, and using dosage is big, number of times is more, and there is potential safety hazard in human and environment.
Tpn (Chlorothalonil) is a low toxicity broad spectrum protection property bactericide.It through with the fungal cell in the glyceraldehyde 3-phosphate dehydro-genase vigor of destructive enzyme of having an effect, thereby fungal cell's metabolism is damaged and loss of life power.
Flutolanil (Flutolanil) belongs to the anilide bactericide, mechanism of action be in respiratory electron transport chain as the succinate dehydrogenase inhibitor, suppress synthesizing of aspartate and glutamate.The flutolanil activity is high, have the protection and control the malignant boil activity, can be used for the control of diseases such as ornamental plants, paddy rice, cereal, potato, beet, vegetables, peanut, fruit, under the RD to ornamental plants, cereal, paddy rice, vegetables Lay and fruit safety.
The relevant report or the application of no above-mentioned both composite products at present.
(3) summary of the invention
One of the object of the invention is to address the above problem, and provides effective, cost is low, residual low, the safe bactericidal composition that contains flutolanil and tpn.
Two of the object of the invention is above-mentioned composite bactericidal composition is used for the control of ornamental plant disease.
The objective of the invention is to realize like this:
A kind of bactericidal composition that contains flutolanil and tpn, said composition contains flutolanil and tpn, and the weight ratio of said flutolanil and tpn is 2～40: 3～60.
Preferably, the weight ratio of said flutolanil and tpn is 5～30: 8～40.
Said combination dosage form is any one formulation that allows on the agricultural chemicals.
Said combination dosage form is wetting powder, water dispersible granules, suspending agent, aqueous emulsion or missible oil.
When concrete the application, said flutolanil and the tpn mass percent in above-mentioned formulation is 5～90%.
A kind of purposes that contains the bactericidal composition of flutolanil and tpn is used for the control of ornamental plant disease.
The present composition can be used for rose anthracnose, powdery mildew, Moth orchid leaf spot, camellia sooty mould, Chinese rose powdery mildew, Indian fig rot, jasmine southern blight, common primrose basal stem rot, cajuputi pinta, money tree brown spot, closes fruit taro gray mold, red along green pepper blade of grass pinta, gardenia sooty mould, ginkgo basal stem rot, cypress leaf blight, add the control of ornamental plant diseases such as poplar rot, the broken look disease of pansy, the mould eqpidemic disease of scarlet sage.
The present composition is except that being applied to prevent and treat the ornamental plant disease; The disease that also can be used for crops such as cereal crop, various melon and fruit, vegetables; Like the control of crop pests such as paddy rice, wheat, tomato, banana, apple, pears, like rice sheath blight disease, wheat powdery mildew, early blight of tomato, alternaria leaf spot of apple, pear scab etc.
Compared with prior art, the invention has the beneficial effects as follows:
(1) present composition synergistic effect of in certain ratio range, doing well, the bactericidal effect of composition have had than single agent and have significantly improved, and have reduced agricultural chemicals using dosage, access times and cost simultaneously, to human and environment safety;
(2) mechanism of action of two kinds of active components is different among the present invention, and the application of composition can delay or overcome the resistance of pathogen, prolongs the service life of product;
(3) effect of present composition control ornamental plant disease is good, and is especially, especially effective when control rose anthracnose; In addition, the present composition also can be used for the control of multiple kinds of crops disease.
(4) embodiment
In order to make the object of the invention, technical scheme and advantage clearer, the present invention describes with following instantiation, but the present invention is not limited to these examples.
The present composition is an active ingredient with flutolanil and tpn, finds through the indoor bioassay test, and antagonistic drug venereal disease evil had obvious role in synergism after both were composite, specifically explained with following biologicall test instance.
The instance 1 of measuring in kind: flutolanil and chlorothalonil compound are to the toxicity test of rose anthracnose
1, subjects: rose anthracnose (Collectotrichum sp.), this disease is a plant disease common on the rose, influences the sight of rose, thereby influences its selling in market.
2, test method:, adopt the pastille medium therapy with reference to " pesticide bioassay test rule NY/T1156.14-2006 ".
3, data statistic analysis: analyze with the SAS6.12 statistical software.Calculate mycelial growth inhibition rate (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50And co-toxicity coefficient.
4, evaluation method: with reference to " pesticide bioassay test rule "; Estimate the synergistic effect of pharmacy mix according to the co-toxicity coefficient method (CTC) of Sun&Johnson (1960); Be that CTC≤80 are antagonism, 80＜CTC＜120 are summation action, and CTC>=120 are synergistic effect.
5, result and analysis
The toxicity test result who makes up rose anthracnose that is mixed of flutolanil and tpn and the two different proportion thereof sees table 1, and " fluorine: hundred " is writing a Chinese character in simplified form of " flutolanil: tpn " in the table 1.
Table 1 flutolanil and tpn are mixed to the toxicity test result of rose anthracnose
Indoor biometrics is the result show: flutolanil and tpn with 1: 1,1: 3,1: 6,1: 9,1: 12,, 3: 1,6: 1 and 9: 1 ratios be mixed; It shows addition or synergistic effect to the rose anthrax bacteria, and is wherein the most obvious with the ratio mixed synergies of 1: 1,1: 6,1: 9 and 9: 1.
The instance 2 of measuring in kind: flutolanil and chlorothalonil compound are to the toxicity test of Moth orchid leaf spot
1, subjects: Moth orchid leaf spot (Fusarium latertium f.celosia), this disease is a plant disease common on the Moth orchid, influences the sight of Moth orchid, thereby influences its selling in market.
2, test method:, adopt the pastille medium therapy with reference to " pesticide bioassay test rule ".
3, data statistic analysis: analyze with the SAS6.12 statistical software.Calculate mycelial growth inhibition rate (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50And co-toxicity coefficient.
4, evaluation method: with reference to " pesticide bioassay test rule "; Estimate the synergistic effect of pharmacy mix according to the co-toxicity coefficient method (CTC) of Sun&Johnson (1960); Be that CTC≤80 are antagonism, 80＜CTC＜120 are summation action, and CTC>=120 are synergistic effect.
5, result and analysis
The toxicity test result who makes up the Moth orchid leaf spot that is mixed of flutolanil and tpn and the two different proportion thereof sees table 2, and " fluorine: hundred " is writing a Chinese character in simplified form of " flutolanil: tpn " in the table 2.
Table 2 flutolanil and tpn are mixed to the toxicity test result of Moth orchid leaf spot
Indoor biometrics is the result show: flutolanil and tpn are mixed with 1: 1,1: 2,1: 3,1: 8,2: 1,4: 1,8: 1 ratios; It shows addition or synergistic effect to the Moth orchid leaf spot fungi, and is wherein the most obvious with the ratio mixed synergies of 1: 1,2: 1,4: 1 and 1: 4.
The instance 3 of measuring in kind: flutolanil and chlorothalonil compound are to the toxicity test of camellia sooty mould
1, subjects: camellia sooty mould (Fumago sp.), this disease is a plant disease common on the camellia, influences the sight of camellia, thereby influences its selling in market.
2, test method:, adopt the pastille medium therapy with reference to " pesticide bioassay test rule NY/T 1156.2-2006 ".
3, data statistic analysis: analyze with the SAS6.12 statistical software.Calculate mycelial growth inhibition rate (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50And co-toxicity coefficient.
4, evaluation method: with reference to " pesticide bioassay test rule "; Estimate the synergistic effect of pharmacy mix according to the co-toxicity coefficient method (CTC) of Sun&Johnson (1960); Be that CTC≤80 are antagonism, 80＜CTC＜120 are summation action, and CTC>=120 are synergistic effect.
5, result and analysis
The toxicity test result who makes up the camellia sooty mould that is mixed of flutolanil and tpn and the two different proportion thereof sees table 3, and " fluorine: hundred " is writing a Chinese character in simplified form of " flutolanil: tpn " in the table 3.
Table 3 flutolanil and tpn are mixed to the toxicity test result of camellia sooty mould bacterium
Indoor biometrics is the result show: flutolanil and tpn are mixed with 1: 1,1: 2,1: 4,1: 6,2: 1,4: 1 and 6: 1 ratios; It shows addition or synergistic effect to camellia sooty mould bacterium, and is wherein the most obvious with the ratio mixed synergies of 1: 1,2: 1,6: 1 and 1: 4.
The instance 4 of measuring in kind: flutolanil and chlorothalonil compound are to the toxicity test of alternaria leaf spot of apple bacterium.
1, subjects: alternaria leaf spot of apple bacterium (Alternaria blotch)
2, test method:, adopt the pastille medium therapy with reference to " pesticide bioassay test rule NY/T 1156.2-2006 ".
3, data statistic analysis: analyze with the SAS6.12 statistical software.Calculate mycelial growth inhibition rate (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50And co-toxicity coefficient.
4, evaluation method: with reference to " pesticide bioassay test rule NY/T 1156.2-2006 "; Estimate the synergistic effect of pharmacy mix according to the co-toxicity coefficient method (CTC) of Sun&Johnson (1960); Be that CTC≤80 are antagonism; 80＜CTC＜120 are summation action, and CTC>=120 are synergistic effect.
5, result and analysis
The toxicity test result who makes up the alternaria leaf spot of apple bacterium that is mixed of flutolanil and tpn different proportion sees table 4, and " fluorine: hundred " is writing a Chinese character in simplified form of " flutolanil: tpn " in the table 4.
Table 4 flutolanil and tpn are mixed to the toxicity test result of alternaria leaf spot of apple bacterium
Indoor biometrics is the result show: tpn and flutolanil are mixed with 1: 1,3: 1,5: 1,7: 1,1: 7,1: 5 and 1: 3 ratio; It shows addition or synergistic effect to alternaria leaf spot of apple, and is wherein the most obvious with the ratio mixed synergies of 1: 1,1: 3,1: 5 and 3: 1.
The application of the present invention's combination is not limited to the foregoing description.
The present composition can be used the preparation of known method to claim to be fit to agricultural and go up any one formulation of using, and wherein reasonable formulation has microemulsion, water dispersible granules, aqueous emulsion, suspending agent and wetting powder, below describes with instantiation.
Embodiment 1:
With flutolanil 3g, tpn 18g, dodecyl sodium sulfate 5g, NPE 3g, dispersing agent NNO (sodium methylene bis-naphthalene sulfonate) 3g, xanthans 0.2g propane diols 5g; After mixing precomminution, mixing; Add suitable quantity of water again through wet grinding, homogenizing, make the present composition 21% suspending agent.
Embodiment 2:
Flutolanil 20g, tpn 20g, dispersing agent NNO 5g, sodium lignin sulfonate 3g, ammonium sulfate 5.0g, xanthans 0.5g, organic silicone 0.2g, kaolin are added to 100g; Elder generation's precomminution mixing; Through comminution by gas stream, granulation, make the present composition 40% water dispersible granules again.
Embodiment 3:
With flutolanil 15g, tpn 25g, dodecyl sodium sulfate 5g, phenethyl phenol polyethenoxy ether 3g, dispersing agent NNO 2g, xanthans 0.2g propane diols 5g, suitable quantity of water; Mix precomminution; Through wet grinding, homogenizing, make the present composition 40% suspending agent again.
Embodiment 4:
Flutolanil 45g, tpn 15g, dispersing agent NNO 4.5g, sodium lignin sulfonate 3g, white carbon 5g, kaolin are added to 100g, and the mixing ultra-fine grinding makes the present composition 60% wetting powder.
Embodiment 5:
With flutolanil 16g, tpn 4g, xylol 7g, alkylaryl formaldehyde resin APEO 10g, APES phosphate 1g, ethylene glycol 4g, xanthans 0.1g, organic silicone 0.1g, suitable quantity of water; Mixing precomminution; Prepare oil phase again, the preparation water is under high shear; The even aqueous phase of oil phase is perhaps added water in the oil phase, shear and make the present composition 20% aqueous emulsion.
Embodiment 6:
Flutolanil 10g, tpn 5g, xylol 7g, alkylaryl formaldehyde resin APEO 10g, APES phosphate 1g, ethylene glycol 4g, xanthans 0.1g, organic silicone 0.1g, suitable quantity of water; Mixing precomminution; Prepare oil phase again, the preparation water is under high shear; The even aqueous phase of oil phase is perhaps added water in the oil phase, shear and make the present composition 15% aqueous emulsion.
Application implementation example 1:
The preparation control rose anthracnose test that utilizes the foregoing description to make.
1, test is handled: this test medicine consumption is established three concentration of treatment respectively according to the difference of each composition, and the contrast medicament is respectively commercially available agricultural chemicals 75% tpn wetting powder, 20% flutolanil wetting powder and clear water blank.
2, test method: test and Selection is carried out in the more serious flower planting garden of rose anthracnose over the years, and testing each sub-district is 30m
2, repeat 4 times.Investigation method and evaluating drug effect carry out with reference to GB/T 17980.112-2004.
3, result of the test such as following table:
Annotate: a is illustrated on α=0.05 level significantly, and b is illustrated on α=0.05 level variant, c be illustrated in have on α=0.05 level not remarkable.
Field control effectiveness test shows that tpn and flutolanil bactericidal composition have good preventive effect to rose anthracnose, and control efficiency obviously is superior to single agent kind.
With embodiment 2:
The preparation control Moth orchid leaf spot test that utilizes the foregoing description to make.
1, test is handled: this test medicine consumption is established three concentration of treatment respectively according to the difference of each composition, and the contrast medicament is respectively commercially available agricultural chemicals 75% tpn wetting powder, 20% flutolanil wetting powder and clear water blank.
2, test method: test and Selection is carried out at the more serious floriculture greenhouse of Moth orchid leaf spot over the years, and testing each sub-district is 30m
2, repeat 4 times.Investigation method and evaluating drug effect carry out with reference to GB/T 17980.112-2004.
3, result of the test such as following table:
Annotate: a is illustrated on α=0.05 level significantly, and b is illustrated on α=0.05 level variant, c be illustrated in have on α=0.05 level not remarkable.
Field control effectiveness test shows that tpn and flutolanil bactericidal composition have good preventive effect to rose anthracnose, and control efficiency obviously is superior to single agent kind.
With embodiment 3:
The preparation control camellia sooty mould test that utilizes the foregoing description to make.
1, test is handled: this test medicine consumption is established three concentration of treatment respectively according to the difference of each composition, and the contrast medicament is respectively commercially available agricultural chemicals 40% tpn suspending agent, 20% flutolanil wetting powder and clear water blank.
2, test method: test and Selection is carried out at the more serious floriculture greenhouse of camellia sooty mould over the years, and testing each sub-district is 30m
2, repeat 4 times.Investigation method and evaluating drug effect carry out with reference to GB/T 17980.112-2004.
3, result of the test such as following table:
Annotate: a is illustrated on α=0.05 level significantly, and b is illustrated on α=0.05 level variant, c be illustrated in have on α=0.05 level not remarkable.
Field control effectiveness test shows that tpn and flutolanil bactericidal composition have good preventive effect to rose anthracnose, and control efficiency obviously is superior to single agent kind.
Application implementation example 4: the preparation control alternaria leaf spot of apple test that utilizes the foregoing description to make.
1, test is handled: this test medicine consumption is established three concentration of treatment respectively according to the difference of each composition, and the contrast medicament is respectively commercially available agricultural chemicals 40% tpn suspending agent, 20% wetting powder and clear water blank.
2, test method: test and Selection is carried out in the more serious orchard of alternaria leaf spot of apple over the years, tests hank 2 in year fruit tree of each sub-district, repeats 4 times.Investigation method and evaluating drug effect are undertaken by GB/T17980.124-2004.
3, result of the test such as following table:
Annotate: a is illustrated on α=0.05 level significantly, and b is illustrated on α=0.05 level variant, c be illustrated in have on α=0.05 level not remarkable.
Field control effectiveness test shows that the composition pesticide of flutolanil and tpn has good preventive effect to alternaria leaf spot of apple, and control efficiency obviously is superior to single agent kind, and consumption is less than each single agent kind.
The application of the present invention's combination is not limited to the foregoing description.
Claims (8)
1. bactericidal composition that contains flutolanil and tpn, it is characterized in that: said composition contains flutolanil and tpn, and the weight ratio of said flutolanil and tpn is 2～40: 3～60.
2. according to the bactericidal composition of claim 1, it is characterized in that: the weight ratio of said flutolanil and tpn is 5～30: 8～40.
3. according to the arbitrary described bactericidal composition of claim 1, it is characterized in that: said composition is mixed with any one formulation that allows on the agricultural chemicals.
4. according to the bactericidal composition of claim 4, it is characterized in that: said combination dosage form is aqueous emulsion, water dispersible granules, suspending agent, aqueous emulsion or missible oil.
5. according to the bactericidal composition of claim 5, it is characterized in that: the mass percent of said composition in formulation is 5～90%.
6. the arbitrary described bactericidal composition of claim 1-6 is used to prevent and treat the purposes of ornamental plant disease.
7. according to the purposes of claim 7, said ornamental plant disease is rose anthracnose, Moth orchid leaf spot and camellia sooty mould.
8. claim 1 or the 2 described bactericidal compositions purposes that is used to prevent and treat alternaria leaf spot of apple.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2011104369632A CN102524256A (en) | 2011-12-23 | 2011-12-23 | Pesticide composition containing flutolanil and chlorothalonil |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2011104369632A CN102524256A (en) | 2011-12-23 | 2011-12-23 | Pesticide composition containing flutolanil and chlorothalonil |
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| CN102524256A true CN102524256A (en) | 2012-07-04 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106718406A (en) * | 2017-01-11 | 2017-05-31 | 贵州省植物园 | A kind of method for preventing and treating Rose Powdery Mildew |
| CN107950536A (en) * | 2017-12-04 | 2018-04-24 | 刘志伟 | A kind of bactericidal composition containing Bravo |
| CN113973820A (en) * | 2021-11-10 | 2022-01-28 | 江阴苏利化学股份有限公司 | Application of bactericidal composition containing flutolanil and chlorothalonil |
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| US4093743A (en) * | 1976-07-12 | 1978-06-06 | Nihon Nohyaku Co., Ltd. | Novel benzoic anilide derivative and fungicide containing same |
| CN1282214A (en) * | 1997-12-18 | 2001-01-31 | 巴斯福股份公司 | Fungicide mixtures based on pyridine amides and chlorothalonil |
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2011
- 2011-12-23 CN CN2011104369632A patent/CN102524256A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4093743A (en) * | 1976-07-12 | 1978-06-06 | Nihon Nohyaku Co., Ltd. | Novel benzoic anilide derivative and fungicide containing same |
| CN1282214A (en) * | 1997-12-18 | 2001-01-31 | 巴斯福股份公司 | Fungicide mixtures based on pyridine amides and chlorothalonil |
Non-Patent Citations (3)
| Title |
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| HAGAN AK 等: "Comparison of fungicide programs for the control of early leaf spot and southern stem rot on selected peanut cultivars", 《PEANUT SCIENCE》 * |
| HAGAN AK 等: "Effects of application timing and method on control of southern stem rot of peanut with foliar-applied fungicides", 《PEANUT SCIENCE 》 * |
| HAGAN AK 等: "Impact of application rate and treatment interval on the efficacy of pyraclostrobin in fungicide programs for the control of early leaf spot and southern stem rot on peanut", 《PEANUT SCIENCE》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106718406A (en) * | 2017-01-11 | 2017-05-31 | 贵州省植物园 | A kind of method for preventing and treating Rose Powdery Mildew |
| CN107950536A (en) * | 2017-12-04 | 2018-04-24 | 刘志伟 | A kind of bactericidal composition containing Bravo |
| CN113973820A (en) * | 2021-11-10 | 2022-01-28 | 江阴苏利化学股份有限公司 | Application of bactericidal composition containing flutolanil and chlorothalonil |
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