CN102500241B - Preparation method for anti-pollution permeable vaporization film - Google Patents
Preparation method for anti-pollution permeable vaporization film Download PDFInfo
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- CN102500241B CN102500241B CN201110375074.XA CN201110375074A CN102500241B CN 102500241 B CN102500241 B CN 102500241B CN 201110375074 A CN201110375074 A CN 201110375074A CN 102500241 B CN102500241 B CN 102500241B
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- preparation
- infiltrating
- pollution
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- polysiloxane
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- 230000008016 vaporization Effects 0.000 title claims abstract description 56
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 238000009834 vaporization Methods 0.000 title claims abstract description 15
- 239000011248 coating agent Substances 0.000 claims abstract description 32
- 238000000576 coating method Methods 0.000 claims abstract description 32
- -1 polysiloxane Polymers 0.000 claims abstract description 19
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 14
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910000077 silane Inorganic materials 0.000 claims abstract description 11
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 9
- 239000011737 fluorine Substances 0.000 claims abstract description 9
- 239000012528 membrane Substances 0.000 claims description 62
- 239000003960 organic solvent Substances 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 9
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 9
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 239000012975 dibutyltin dilaurate Substances 0.000 claims description 5
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 4
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 claims description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 3
- BAAAEEDPKUHLID-UHFFFAOYSA-N decyl(triethoxy)silane Chemical compound CCCCCCCCCC[Si](OCC)(OCC)OCC BAAAEEDPKUHLID-UHFFFAOYSA-N 0.000 claims description 3
- WEUBQNJHVBMUMD-UHFFFAOYSA-N trichloro(3,3,3-trifluoropropyl)silane Chemical compound FC(F)(F)CC[Si](Cl)(Cl)Cl WEUBQNJHVBMUMD-UHFFFAOYSA-N 0.000 claims description 3
- JLGNHOJUQFHYEZ-UHFFFAOYSA-N trimethoxy(3,3,3-trifluoropropyl)silane Chemical group CO[Si](OC)(OC)CCC(F)(F)F JLGNHOJUQFHYEZ-UHFFFAOYSA-N 0.000 claims description 3
- JJLKTTCRRLHVGL-UHFFFAOYSA-L [acetyloxy(dibutyl)stannyl] acetate Chemical group CC([O-])=O.CC([O-])=O.CCCC[Sn+2]CCCC JJLKTTCRRLHVGL-UHFFFAOYSA-L 0.000 claims description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- BRWZYZWZBMGMMG-UHFFFAOYSA-J dodecanoate tin(4+) Chemical class [Sn+4].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O BRWZYZWZBMGMMG-UHFFFAOYSA-J 0.000 claims description 2
- 238000013021 overheating Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 8
- 244000005700 microbiome Species 0.000 abstract description 4
- 238000006243 chemical reaction Methods 0.000 abstract description 3
- 230000004907 flux Effects 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- 239000003344 environmental pollutant Substances 0.000 abstract 1
- 239000007888 film coating Substances 0.000 abstract 1
- 238000009501 film coating Methods 0.000 abstract 1
- 238000002715 modification method Methods 0.000 abstract 1
- 231100000719 pollutant Toxicity 0.000 abstract 1
- 229920002379 silicone rubber Polymers 0.000 description 14
- 230000002209 hydrophobic effect Effects 0.000 description 12
- 239000007788 liquid Substances 0.000 description 12
- 229920002614 Polyether block amide Polymers 0.000 description 11
- 229920001400 block copolymer Polymers 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 239000004945 silicone rubber Substances 0.000 description 8
- 238000000926 separation method Methods 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 230000003373 anti-fouling effect Effects 0.000 description 4
- 238000001764 infiltration Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
- 239000002028 Biomass Substances 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 230000008595 infiltration Effects 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 101001012021 Homo sapiens Mammalian ependymin-related protein 1 Proteins 0.000 description 2
- 102100030031 Mammalian ependymin-related protein 1 Human genes 0.000 description 2
- 229920000459 Nitrile rubber Polymers 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000855 fermentation Methods 0.000 description 2
- 230000004151 fermentation Effects 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- MWWATHDPGQKSAR-UHFFFAOYSA-N propyne Chemical compound CC#C MWWATHDPGQKSAR-UHFFFAOYSA-N 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000001471 micro-filtration Methods 0.000 description 1
- 239000004941 mixed matrix membrane Substances 0.000 description 1
- 230000000051 modifying effect Effects 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 238000001728 nano-filtration Methods 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
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Priority Applications (1)
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CN201110375074.XA CN102500241B (en) | 2011-11-22 | 2011-11-22 | Preparation method for anti-pollution permeable vaporization film |
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CN201110375074.XA CN102500241B (en) | 2011-11-22 | 2011-11-22 | Preparation method for anti-pollution permeable vaporization film |
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CN102500241A CN102500241A (en) | 2012-06-20 |
CN102500241B true CN102500241B (en) | 2014-02-26 |
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CN201110375074.XA Active CN102500241B (en) | 2011-11-22 | 2011-11-22 | Preparation method for anti-pollution permeable vaporization film |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108201792B (en) * | 2016-12-16 | 2022-02-11 | 大连联和环保技术有限公司 | Preparation method of fluorine-containing silicone rubber composite separation membrane |
CN106582314B (en) * | 2017-02-26 | 2019-01-25 | 浙江理工大学 | A kind of small-bore hydrophobic composite membrane preparation method for membrane distillation |
CN108295669A (en) * | 2018-03-05 | 2018-07-20 | 北京清源洁华膜技术有限公司 | A kind of composite membrane and preparation method thereof of separation VOCs |
CN112933983B (en) * | 2021-01-29 | 2022-06-28 | 三明学院 | Graphene silicon dioxide core-shell structure filled PDMS hybrid membrane and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1310749A (en) * | 1998-06-30 | 2001-08-29 | 罗狄亚化学公司 | Crosslinkable silicone composition useful, in particular for producing water-repellent and/or oil-repellent coating and/or impregnation with low surface energy |
CN1331260A (en) * | 2000-06-30 | 2002-01-16 | 中国科学院化工冶金研究所 | Process for preparing anti-pollution film |
CN1724127A (en) * | 2005-06-16 | 2006-01-25 | 南京工业大学 | Organic and inorganic composite hydrophobic film and its preparing process |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007262287A (en) * | 2006-03-29 | 2007-10-11 | Dainippon Ink & Chem Inc | Coating composition |
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- 2011-11-22 CN CN201110375074.XA patent/CN102500241B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1310749A (en) * | 1998-06-30 | 2001-08-29 | 罗狄亚化学公司 | Crosslinkable silicone composition useful, in particular for producing water-repellent and/or oil-repellent coating and/or impregnation with low surface energy |
CN1331260A (en) * | 2000-06-30 | 2002-01-16 | 中国科学院化工冶金研究所 | Process for preparing anti-pollution film |
CN1724127A (en) * | 2005-06-16 | 2006-01-25 | 南京工业大学 | Organic and inorganic composite hydrophobic film and its preparing process |
Non-Patent Citations (1)
Title |
---|
JP特开2007-262287A 2007.10.11 |
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CN102500241A (en) | 2012-06-20 |
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Owner name: NANJING JIUSI HIGH-TECH CO., LTD. Free format text: FORMER OWNER: NANJING UNIVERSITY OF TECHNOLOGY Effective date: 20140718 |
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Free format text: CORRECT: ADDRESS; FROM: 210009 NANJING, JIANGSU PROVINCE TO: 211800 NANJING, JIANGSU PROVINCE |
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Effective date of registration: 20140718 Address after: 211800 Nanjing, Pukou Province Economic Development Zone, Phoenix Road, No. 8, No. Patentee after: Nanjing Jiusi High-Tech Co., Ltd. Address before: 210009 Gulou District, Jiangsu, Nanjing new model road, No. 5 Patentee before: Nanjing University of Technology |
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Effective date of registration: 20201109 Address after: No.1, yanchuang garden, Nanjing area, China (Jiangsu) pilot Free Trade Zone, Nanjing, Jiangsu Province, 211800 Patentee after: Jiangsu jiumo Hi Tech Co., Ltd Address before: 211800 No. 8 Fenghuang Road, Pukou Economic Development Zone, Nanjing, Jiangsu Patentee before: NANJING JIUSI HIGH-TECH Co.,Ltd. |