CN102492220A - Biological-based flowerpot capable of releasing negative ions and preparation method thereof - Google Patents
Biological-based flowerpot capable of releasing negative ions and preparation method thereof Download PDFInfo
- Publication number
- CN102492220A CN102492220A CN2011103949753A CN201110394975A CN102492220A CN 102492220 A CN102492220 A CN 102492220A CN 2011103949753 A CN2011103949753 A CN 2011103949753A CN 201110394975 A CN201110394975 A CN 201110394975A CN 102492220 A CN102492220 A CN 102492220A
- Authority
- CN
- China
- Prior art keywords
- starch
- negative ion
- bio
- flowerpot capable
- releasing negative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
Abstract
The invention relates to a biological-based flowerpot capable of releasing negative ions and a preparation method thereof. The biological-based flowerpot capable of releasing the negative ions comprises, by mass, polypropylene 40-70%, starch 15-45%, plasticizer 5-10%, tourmaline powder 5-10% and masterbatch 0.5-2%. The preparation method comprises the steps of producing the polypropylene, the starch, the plasticizer and the tourmaline powder into required granular materials by specific production technology, and adding the masterbatch to perform secondary processing to obtain the biological-based flowerpot capable of releasing the negative ions. The plasticizer is used for enabling the starch to have thermo-plasticity so as to improve starch processibility and compatibility of the starch and a polypropylene base body. The starch with the thermo-plasticity is filled with the polypropylene so that the starch is evenly dispersed in the polypropylene base body. The tourmaline powder body has self-polarizing effect so that the biological-based flowerpot can produce the negative ions continuously in the absence of sources to purify harmful gas in the living environment efficiently and keep fresh and healthy living environment.
Description
Technical field
The present invention relates to a kind of bio-based flowerpot capable of releasing negative ion and preparation method thereof, belong to technical field of polymer materials.
Background technology
According to relevant bibliographical information, the geographic negative ion concentrations of recuperating such as beach, forest, waterfall can reach 10000/cm
3, suburb, wilderness negative ion concentration is 700～1000/cm
3, street greening band negative ion concentration is 100～200/cm
3, residential area, city air-anion concentration is about 40～50/cm
3, air-anion concentration was 0～25/cm after room conditioning worked long hours
3, and the anion number of keeping HUMAN HEALTH is 1000～2000/cm
3, live in for a long time under the low negative ion concentration environment, be prone to symptoms such as weak, nauseating.Therefore the obnoxious flavour of the purification living environment of high-efficient and lasting keeps the environment of pure and fresh health to become the target that people pursue.
Tourmalinite has another name called Tourmaline, is a kind of silicate minerals, and its chemical general formula is: NaRAl
6(Si
6O
18) (BO
3)
3(OH, F)
4, R represents metallic cation in the formula, when R is Mg
2+, Fe
2+Or (Li
+Add Al
+) time, constitute dravite, schorl and elbaite respectively.The staple of tourmalinite has more than 10 kind of trace elements favourable to human body such as magnesium, aluminium, iron, boron, has unique different level symplex structure, its (Si
6O
8) six silicon-oxy tetrahedrons of six-ring, same direction is pointed on the top, angle, is interpreted as the reason that permanent self power generation polarity exists, and its typical case shows as pyroelectricity and piezoelectricity.The self poling effect of tourmalinite makes tourmalinite have some environmental functional attributes, as under passive condition, producing negative ion, has far-infrared transmitting function; Electro-magnetic screen function; The pH value of regulating water is to neutral; Activated water molecules etc., these environmental functional attributes make tourmalinite have widely and use.
Summary of the invention
In view of this, the object of the present invention is to provide a kind of bio-based flowerpot capable of releasing negative ion and preparation method thereof, reduced the problem that the plastics flowerpot causes white pollution when discharging anion fine-purification air function to a certain extent having.
In order to achieve the above object, the invention provides a kind of bio-based flowerpot capable of releasing negative ion, said each component of bio-based flowerpot capable of releasing negative ion according to the proportioning of mass fraction meter is:
Vestolen PP 7052 40～70%;
Starch 15～45%;
Softening agent 5～10%;
Tourmaline powder 5～10%;
Masterbatch 0.5～2%.
Preferably, wherein said Vestolen PP 7052 is the injection grade Vestolen PP 7052, and its molten how is between 3～16g/10min.
Preferably, wherein said starch is one or more in W-Gum, tapioca(flour), yam starch, wheat starch or the pea starch.
Preferably, wherein said softening agent is one or more in terepthaloyl moietie, Ucar 35, USP Kosher, Xylitol, N.F,USP MANNITOL, methane amide or the thanomin.
Preferably, the granularity of wherein said tourmaline powder is 3000 orders.
Preferably, the color of wherein said Masterbatch is a kind of in black, green or the white.
The preparation method of said bio-based flowerpot capable of releasing negative ion may further comprise the steps:
1) raw materials mix is even: as according to aforementioned proportion Vestolen PP 7052, starch, softening agent and tourmaline powder once to be joined in the high-speed mixer, and under the condition of normal temperature, make it to mix;
2) reaction in twin screw extruder: the mixture that step 1) is obtained adds in the twin screw extruder, and under 90～210 ℃ condition, carries out extruding pelletization;
3) with step 2) pellet that obtains cooperates 0.5～2% Masterbatch can obtain said bio-based flowerpot capable of releasing negative ion through injection molding again.
Compared with prior art, the present invention has following beneficial effect:
1) tourmaline powder that the present invention adopted has the self poling effect, can under passive condition, produce negative ion, thus have function such as far infrared emission, thereby but high-efficient and lasting ground purifies the obnoxious flavour of living environment, and keep the environment of pure and fresh health;
2) softening agent that the present invention adopted makes starch have thermoplasticity, thus improved starch workability and with the consistency of polypropylene matrix;
3) the present invention adopts the thermoplastic starch filled polypropylene, and thermoplastic starch is evenly dispersed in the polypropylene matrix;
4) employed twin screw extruder in the production engineering of the present invention, cooling water circulation utilization does not produce waste water, waste gas and waste residue, and can accomplish scale production.
Embodiment
Below will combine specific embodiment that the present invention is done further detailed description.
Embodiment 1:
With 40 mass parts Vestolen PP 7052 (injection grade Vestolen PP 7052) (trade mark PPB-M-075; The molten MI:4.2 that refers to), 45 mass parts W-Gums, 5 mass parts USP Kosher and 9.5 mass parts tourmaline powders (3000 order) once join in the high-speed mixer, and under the condition of normal temperature, make it to mix; Then that the mixture that obtains is mixing in twin screw extruder, wherein each section of twin screw extruder temperature is set at T
1=90 ℃, T
2=165 ℃, T
3=190 ℃, T
4=180 ℃, T
5=170 ℃, T
6=165 ℃, the twin screw rotating speed is r=300rmin
-1, extrude afterwards, cooling, granulation; Cooperate the black agglomerate of 0.5 mass parts can obtain said bio-based flowerpot capable of releasing negative ion the pellet that obtains again through injection molding.According to the People's Republic of China's said method of building material industry standard JC/T1016-2006 the flowerpot anion-generating capacity is tested, flowerpot discharges negative ion and has reached 1120/cm
3, satisfy the basic demand of keeping the HUMAN HEALTH anion number.
Embodiment 2:
With 70 mass parts Vestolen PP 7052 (injection grade the Vestolen PP 7052) (trade mark: PPB-M-012; The molten MI:3.1 that refers to), the tourmaline powder (3000 order) of 15 mass parts W-Gums, 8 mass parts methane amides and 5 mass parts once joins in the high-speed mixer, and under the condition of normal temperature, makes it to mix; Then that the mixture that obtains is mixing in twin screw extruder, wherein each section of twin screw extruder temperature is set at T
1=100 ℃, T
2=175 ℃, T
3=200 ℃, T
4=190 ℃, T
5=180 ℃, T
6=175 ℃, the twin screw rotating speed is r=300rmin
-1, extrude afterwards, cooling, granulation; Cooperate the green master batch of 2 mass parts can obtain said bio-based flowerpot capable of releasing negative ion the pellet that obtains again through injection molding.According to the People's Republic of China's said method of building material industry standard JC/T1016-2006 the flowerpot anion-generating capacity is tested, flowerpot discharges negative ion and has reached 2360/cm
3, satisfy the basic demand of keeping the HUMAN HEALTH anion number.
Embodiment 3:
With 60 mass parts Vestolen PP 7052 (injection grade the Vestolen PP 7052) (trade mark: PPB-MP-105; The molten MI:11.2 that refers to), 19 mass parts tapioca(flour)s, 10 mass parts terepthaloyl moietie and 10 mass parts tourmaline powders (3000 order) once join in the high-speed mixer, and under the condition of normal temperature, make it to mix; Then that the mixture that obtains is mixing in twin screw extruder, wherein each section of twin screw extruder temperature is set at T
1=90 ℃, T
2=165 ℃, T
3=190 ℃, T
4=180 ℃, T
5=170 ℃, T
6=165 ℃, the twin screw rotating speed is r=300rmin
-1, extrude afterwards, cooling, granulation; Cooperate the green master batch of 1 mass parts can obtain said bio-based flowerpot capable of releasing negative ion the pellet that obtains again through injection molding.According to the People's Republic of China's said method of building material industry standard JC/T1016-2006 the flowerpot anion-generating capacity is tested, flowerpot discharges negative ion and has reached 1270/cm
3, satisfy the basic demand of keeping the HUMAN HEALTH anion number.
Embodiment 4:
With 50 mass parts Vestolen PP 7052 (injection grade the Vestolen PP 7052) (trade mark: PPB-MP-105; The molten MI:11.2 that refers to), 35 mass parts pea starches, 5 mass parts thanomins and 9.5 mass parts tourmaline powders (3000 order) once join in the high-speed mixer, and under the condition of normal temperature, make it to mix; Then that the mixture that obtains is mixing in twin screw extruder, wherein each section of twin screw extruder temperature is set at T
1=105 ℃, T
2=175 ℃, T
3=205 ℃, T
4=190 ℃, T
5=185 ℃, T
6=180 ℃, the twin screw rotating speed is r=300rmin
-1, extrude afterwards, cooling, granulation; Cooperate the white master batch of 0.5 mass parts can obtain said bio-based flowerpot capable of releasing negative ion the pellet that obtains again through injection molding.According to the People's Republic of China's said method of building material industry standard JC/T1016-2006 the flowerpot anion-generating capacity is tested, flowerpot discharges negative ion and has reached 2610/cm
3, satisfy the basic demand of keeping the HUMAN HEALTH anion number.
Embodiment 5:
With 65 mass parts Vestolen PP 7052 (injection grade the Vestolen PP 7052) (trade mark: PPB-MP-225; The molten MI:15 that refers to), 20 mass parts pea starches, 7.5 mass parts USP Kosher and 5.5 mass parts tourmaline powders (3000 order) once join in the high-speed mixer, and under the condition of normal temperature, make it to mix; Then that the mixture that obtains is mixing in twin screw extruder, wherein each section of twin screw extruder temperature is set at T
1=95 ℃, T
2=170 ℃, T
3=195 ℃, T
4=185 ℃, T
5=175 ℃, T
6=170 ℃, the twin screw rotating speed is r=300rmin
-1, extrude afterwards, cooling, granulation; Cooperate the white master batch of 2 mass parts can obtain said bio-based flowerpot capable of releasing negative ion the pellet that obtains again through injection molding.According to the People's Republic of China's said method of building material industry standard JC/T1016-2006 the flowerpot anion-generating capacity is tested, flowerpot discharges negative ion and has reached 1630/cm
3, satisfy the basic demand of keeping the HUMAN HEALTH anion number.
Embodiment 6:
With 55 mass parts Vestolen PP 7052 (injection grade the Vestolen PP 7052) (trade mark: PPB-MP-075; The molten MI:4.2 that refers to), 30 mass parts tapioca(flour)s, 7 mass parts terepthaloyl moietie and 7 mass parts tourmaline powders (3000 order) once join in the high-speed mixer, and under the condition of normal temperature, make it to mix; Then that the mixture that obtains is mixing in twin screw extruder, wherein each section of twin screw extruder temperature is set at T
1=90 ℃, T
2=165 ℃, T
3=190 ℃, T
4=180 ℃, T
5=170 ℃, T
6=165 ℃, the twin screw rotating speed is r=300rmin
-1, extrude afterwards, cooling, granulation; Cooperate the green master batch of 1 mass parts can obtain said bio-based flowerpot capable of releasing negative ion the pellet that obtains again through injection molding.According to the People's Republic of China's said method of building material industry standard JC/T1016-2006 the flowerpot anion-generating capacity is tested, flowerpot discharges negative ion and has reached 1750/cm
3, satisfy the basic demand of keeping the HUMAN HEALTH anion number.
The above is merely preferred embodiment of the present invention, and protection scope of the present invention is not constituted any limitation, and scope of patent protection of the present invention is as the criterion with the content of claims.
Claims (7)
1. a bio-based flowerpot capable of releasing negative ion is characterized in that, the proportioning that each components in mass portion of said bio-based flowerpot capable of releasing negative ion is counted meter is:
Vestolen PP 7052 40～70%;
Starch 15～45%;
Softening agent 5～10%;
Tourmaline powder 5～10%;
Masterbatch 0.5～2%.
2. according to the said bio-based flowerpot capable of releasing negative ion of claim 1, it is characterized in that said Vestolen PP 7052 is the injection stage Vestolen PP 7052, its molten how is between 3～16g/10min.
3. according to the said bio-based flowerpot capable of releasing negative ion of claim 1, it is characterized in that said starch is one or more in W-Gum, tapioca(flour), yam starch, wheat starch or the pea starch.
4. according to the said bio-based flowerpot capable of releasing negative ion of claim 1, it is characterized in that said softening agent is one or more in terepthaloyl moietie, Ucar 35, USP Kosher, Xylitol, N.F,USP MANNITOL, methane amide or the thanomin.
5. according to the said bio-based flowerpot capable of releasing negative ion of claim 1, it is characterized in that the granularity of said tourmaline powder is 3000 orders.
6. according to the said bio-based flowerpot capable of releasing negative ion of claim 1, it is characterized in that the color of said Masterbatch is a kind of in black, green or the white.
7. according to the said bio-based flowerpot capable of releasing negative ion of claim 1, it is characterized in that, said method comprising the steps of:
1) raw materials mix is even: as according to aforementioned proportion Vestolen PP 7052, starch, softening agent and tourmaline powder once to be joined in the high-speed mixer, and under the condition of normal temperature, make it to mix;
2) at the twin screw extruder internal reaction: the mixture that step 1) is obtained adds in the twin screw extruder, and under 90～210 ℃ condition, carries out extruding pelletization;
3) with step 2) pellet that obtains cooperates 0.5～2% Masterbatch can obtain said bio-based flowerpot capable of releasing negative ion through injection molding again.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103949753A CN102492220A (en) | 2011-12-02 | 2011-12-02 | Biological-based flowerpot capable of releasing negative ions and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103949753A CN102492220A (en) | 2011-12-02 | 2011-12-02 | Biological-based flowerpot capable of releasing negative ions and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102492220A true CN102492220A (en) | 2012-06-13 |
Family
ID=46184084
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011103949753A Pending CN102492220A (en) | 2011-12-02 | 2011-12-02 | Biological-based flowerpot capable of releasing negative ions and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102492220A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103147227A (en) * | 2013-03-04 | 2013-06-12 | 武汉华丽生物材料有限公司 | Bio-based non-woven fabrics and preparation method thereof |
| CN106397940A (en) * | 2016-11-01 | 2017-02-15 | 广州邦士度眼镜有限公司 | Manufacturing method for novel anion material |
| CN109053036A (en) * | 2018-10-08 | 2018-12-21 | 李玉芝 | A kind of ornament materials and preparation method thereof with negative ion-releasing function |
| CN109809767A (en) * | 2019-01-29 | 2019-05-28 | 郑州高聚粉体科技有限公司 | A kind of flowerpot and preparation method thereof of releasable negative oxygen ion |
| CN110733143A (en) * | 2019-10-10 | 2020-01-31 | 四川圣达高环保科技有限公司 | method for preparing air-conditioning grids capable of releasing negative oxygen ions |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1566188A (en) * | 2003-06-18 | 2005-01-19 | 周秋华 | Plastic products containing black tourmalines, preparing process and use thereof |
| CN102229720A (en) * | 2011-05-12 | 2011-11-02 | 中国科学院长春应用化学研究所 | High impact polypropylene composition and preparation method thereof |
-
2011
- 2011-12-02 CN CN2011103949753A patent/CN102492220A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1566188A (en) * | 2003-06-18 | 2005-01-19 | 周秋华 | Plastic products containing black tourmalines, preparing process and use thereof |
| CN102229720A (en) * | 2011-05-12 | 2011-11-02 | 中国科学院长春应用化学研究所 | High impact polypropylene composition and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103147227A (en) * | 2013-03-04 | 2013-06-12 | 武汉华丽生物材料有限公司 | Bio-based non-woven fabrics and preparation method thereof |
| CN106397940A (en) * | 2016-11-01 | 2017-02-15 | 广州邦士度眼镜有限公司 | Manufacturing method for novel anion material |
| CN109053036A (en) * | 2018-10-08 | 2018-12-21 | 李玉芝 | A kind of ornament materials and preparation method thereof with negative ion-releasing function |
| CN109809767A (en) * | 2019-01-29 | 2019-05-28 | 郑州高聚粉体科技有限公司 | A kind of flowerpot and preparation method thereof of releasable negative oxygen ion |
| CN110733143A (en) * | 2019-10-10 | 2020-01-31 | 四川圣达高环保科技有限公司 | method for preparing air-conditioning grids capable of releasing negative oxygen ions |
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Application publication date: 20120613 |