CN102485201A

CN102485201A - Hair dye containing one or more food pigments or cosmetic pigments and hair dyeing method thereof

Info

Publication number: CN102485201A
Application number: CN2010105681218A
Authority: CN
Inventors: 庄国昇
Original assignee: Individual
Current assignee: Individual
Priority date: 2010-12-01
Filing date: 2010-12-01
Publication date: 2012-06-06

Abstract

The invention discloses a hair dye produced by mainly using natural pigments (edible and cosmetic purposes), synthetic pigments (edible and cosmetic purposes) or cosmetic pigments and a hair dyeing method thereof. The hair dye is produced according to similar structures of cornifin of skins and hairs and simultaneously can be applied for dyeing on hairs and skins. The hair dye can be produced into hair dyeing pastes, hair dyeing cream, hair dyeing gel, hair dyeing poultice, hair dyeing shampoo, foam-based hair dye, spray hair dye and the like. The hair dye also can be produced into a two-in-one product capable of finishing dyeing and waving at a time after combining with a hair-waving agent. The hair dyeing purpose of the hair dye is realized by permeating the natural pigments (edible and cosmetic purposes), synthetic pigments (edible and cosmetic purposes) or cosmetic pigments into hairs through using different hair dyeing methods, and according to the depth of the pigments in the hairs, the hair dye can be produced into permanent hair dye, semi-permanent hair dye, temporary hair dye and the like.

Description

The hair dye and the hair colouring methods thereof that contain one or more food coloring or cosmetic colors

Technical field

The hair dye that the present invention relates to a kind of use natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors and be main manufacturing with and hair colouring methods.This hair dye also can be applied to the dyeing on hair and the skin simultaneously according to the keratoprotein like configurations of skin and hair; This hair dye can be made into cream rinse, hair dyeing emulsion, hair dyeing frost, hair dyeing gel, hair dyeing paste, hair dyeing shampoo, foam type hair dye, spray-type hair-dyeing agent etc.; Behind agent for permanent hair waving, also can be made into and dye, scald the one step completed two-in-one product that dyes, scalds.This hair dye penetrates into natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors hair and reaches the hair dyeing purpose with different hair colouring methods; And, can be made into Permanent Hair Dyeing Agent, semi-permanent hairdye and temporary hair dye etc. according to the degree of depth that pigment gets into hair construction.

Background technology

Hair dye is divided into temporary hair dye, semi-permanent hairdye, Permanent Hair Dyeing Agent.Temporary hair dye is a kind of need once just can remove hair dye painted on hair with the shampoo washing; Because the granule of these hair dyes can not get into the cortex of hair layer through the hair scale sheet more greatly; Just be deposited on the hair surface, form painted cover layer.Semi-permanent hairdye generally is meant the hair dye that 6～12 shampoo washings of ability are just faded; According to partly forever the dye characteristic of property hair dye can be divided into several types of acidity, alkalescence and decentralized dyestuffs etc.; Wherein acid dye is main with the acid stain of azo (azo) then; Effect by ionic bond makes the calm and colour developing of dyestuff; Can cooperate benzyl alcohol (Benzyl alcohol), N-Methyl pyrrolidone (N-methylpyrrolidone) equal solvent again, and add citric acid and adjust its pH value to promote its hair dyeing effect; Alkaline hair dye is main with basic stain (basic dyestuffs) or nitramino dyestuff (nitro-amino dyes) then; The triethanolamine alkaline agent expansion hair scale sheets such as (Triethanolamine) of can arranging in pairs or groups; Semi-permanent hairdye is applied on the hair; Stop after 20-30 minute, the water flushing can make the hair colouring.Permanent Hair Dyeing Agent is divided into three kinds: metal is permanent, plant is permanent, oxidation is permanent.

(1) metal is permanent: dye with the slaine raw material, its dyeing major sedimentary is on dry surface, and color and luster has dim metal appearance, hair is become fragile, the inefficient of hair-waving.

(2) plant is permanent: present permanent plant hair dye has two types approximately: (I) pigment absorbent-type: utilize vegetable dyes to become fine particle with the cationic surfactant misfit; Cover hair surface; Other method comprises: present different colours after using several plant property dyestuff to mix; Because dye molecule generally ranges temporary pattern or semi-permanent mould hair dye only with suction type and the effect of hair scale sheet.(II) metal ion misfit type: utilize the active ingredient (like hematoxylin or tannic acid) in the plant to form coloured misfit thing with metal ion; Penetrate into hair hair cortex layer; Because dye molecule can get into the hair hair cortex, generally ranges Permanent Hair Dyeing Agent, this type of material is mainly the plant of being rich in polyhydric phenols and being rich in tannic acid; Polyhydric phenols be represented as haematoxylin, tannic acid be represented as Galla Chinensis, Flos Caryophylli, Pericarpium Granati or the like.

(3) permanent oxidized form chemistry hair dye: be main product in the market, first dose of oxidized form chemistry hair dye is Main Ingredients and Appearance with oxidation dye, coupling agent and alkaline agent all, and second dose is then used the hydrogen peroxide of high concentration to be Main Ingredients and Appearance.The hair dyeing principle of oxidized form chemistry hair dye is after with first dose alkaline agent hair hair scale sheet being opened; Make oxidation dye and coupling agent get into the cortical layer of hair smoothly; Then carry out Oxidation with second dose of oxidation dye and the coupling agent that will get into the cortex of hair layer that contains hydrogen peroxide; And then formed high molecular dye directly is deposited in the cortex of hair layer after impelling oxidation, and reaches the purpose of permanent hair dyeing.But many up-to-date research reports are pointed out; Most oxidation dye and coupling agent all have very high toxicity and carcinogenic danger are arranged; Using for a long time or overusing all to impel skin to produce slightly to severe anaphylactic reaction gradually; In addition, first dose of employed alkaline agent is except having stink, and its strong basicity (pH＞9.5) is understood the major injury hair quality; Use for a long time or overuse and all can damage the property sent out and the chafe of hair; And the toxic and side effects and the safety issue of relevant oxidized form chemistry hair dye more and more cause people's attention, therefore in advanced country, pay much attention to and study the carcinogenecity that this type of oxidized form chemistry hair dye is brought already.Present many documents confirm (as shown in table 1), and many oxidation dye and coupling agents all have genotoxicity in the oxidized form chemistry hair dye, wherein " m-diaminobenzene. " (MPD; M-Phenylenediamine) classified as the doubtful carcinogen of animal by World Health Organization (WHO); And cause anaphylaxis, European Union forbids recently, and is domestic then according to the U.S., Japan; Do not forbid as yet, but content must not surpass 5% of product.

The mutagenicity of main component in the table 1. oxidized form chemistry hair dye

Composition	Salmonella reversion test	Additive method	List of references
				P-Nitraniline.	+	+	[3]
P-phenylenediamine	+	+	[3]
					+		[2]
		+	[7]
				Ortho-phenylene diamine	+	+	[3]
	+		[1]
				2-nitro-p-phenylenediamine	+	+	[3]
	+		[4，5]
				3-nitro-ortho-phenylene diamine	+	+	[3]
	+		[5]
				4-nitre α base-ortho-phenylene diamine	+	+	[3]
	+		[4，5]
				2,4 diamino anisoles	+		[1，2，9]
2,5 diamino anisoles	+		[1，10]
				2,4 diaminourea methyl ethers	+		[1]
	+		[2]
					+	+	[9]
		+	[10]
				Between-phenylenediamine	+	+	[1，9，10]
	+		[2]
				2,5 diaminourea methyl ethers	+		[1，2]
4-nitro-ortho-phenylene diamine	+		[1，3]
						+	[9]
2-amino-4-nitre phenol	+		[1，10]
						+	[9]
2-amino-5-nitrophenols			[1，10]
						+	[9]

Right-hydroxyl--phenylenediamine	+		[13]
				Right-methoxyl group--phenylenediamine	+		[13]
4-amino-3-nitro-6-aminoanisole	+		[14]
				2,4-diaminourea-ethoxybenzene	+		[10，11]
2,4-diaminourea-positive propoxy benzene	+		[10，11]
				2,4-diaminourea-ethylbenzene	+	+	[10]
	+		[11]
				2,4-diaminourea-isopropoxy benzene	+		[10，11]
		+	[9]
				3-nitro-4-N-beta-hydroxyethyl aminoanisole	+		[10]
4-amino-3-nitro-phenyl phenol	+		[10]
				4-nitro-2-amino-6-monomethylaniline.	+		[12]
Amino-6 beta-hydroxyethyl aniline of 4-nitro-2-	+		[12]
				4-nitro-2-amino-6 β-hydroxypropyl aniline	+		[12]
4-nitro-2-amino-6 β-isopropyl aniline	+		[12]
				2-nitro-6-methyl	+		[12]
2-nitro-6 beta-hydroxyethyls-p-phenylenediamine	+		[12]
				4-amino-3-nitro-5-monomethylaniline.	+		[14]
4-amino-3-nitro-5-beta-hydroxy propyl group aniline	+		[14]
				4-amino-3-nitro-5-isopropyl-aniline	+		[14]
4-amino-3-nitro-5, the 6-dimethylaniline	+		[14]
				4-amino-2, the 5-dimethylaniline	+		[14]

List of references: J Environ Occup Med.2008,25.1, p100. [mutagenesis of hair dye, carcinogenic and malicious generation dynamic (dynamical) progress]

List of references in the table 1:

1.AMES，BN.，KAMMEN，HO.，YAMASAKI，E.Hair?dyes?are?mutagenic：Identification?of?avariety?of?mutagenic?ingredients.Proc?Nat?Acad?Sci?USA.1975，72(6)，2423-2427.

2.HANLON，J.Tint?of?suspicion.New?Scientist.1978，78，352-357.

3.CHUNG，K.T.，MURDOCU，C.A.，ZHOU，Y.G.Effects?of?the?nitro-group?on?th?emutagenicity?and?toxicity?of?some?benzamines.Environ?and?Mol?Mutagen.1996，27(1)，67-74.

4.CHUNG，K.T.，HUGHES，T.J.，CLAXTON，L.D.Comparison?ofthe?mutagenic?specificity?induced?by?four?nitro-group-containing?aromatic?amines?in?Salmonella?typhimurium?his?genes.Mutat?Res.2000，465(2)，165-171.

5.CHENS，S.U.，CHING，T.Y.，CHUNG，K.T.Base-pair?mutation?caused?by?four?nitro-group-containing?aromatic?amines?in?Salmonella?typhimurium?TA?100，TA?104，TA4001?and?TA4006.Mutat?Res.1997，395(3)，223-227.

6.SHAHIN，M.M.Structure-activity?re?lationships?within?various?series?of?p-pheny?lenediamine?derivatives.Mutat?R?es.1994，307(1)，83-93.

7 Dai monasticism, Yang Wei, Zhou zygomatic. Oxidative hair dye main ingredient in rat skin keratinocyte DNA Damage Induced by Chinese Journal of Public Health .2000,16 (10) ,905-906.

8.SHAHIN，M.M.，ROUERS，D.，BUGAUT，A.Structure-activity?relationship?with?a?series?of?2，4-diaminoalkoxybenzene?compounds.Mutat?Res.1980，79(3)，289-306.

9.SHAHIN，M.M.，CHOPY，C.，LEGUESNE，N.Comparisons?of?mutation?induction?by?six?monocyclic?aromatic?amines?in?Salmonella?typhimurium?tester?strains?TA97.TA1537.TA1538.Environ?Mutag?en.1985，7(4)，535-546.

10.SHAHIN，M.M.，BUGAUT，A.，KALOPISSIS，G.Mutagenicity?of?aminonitrophenol?compounds?in?Salmonella?typhimurium：a?stuly?of?structure-a?ctivity?relationships.Int?J?Cosmetic?Sci.1982，4(1)，25-35.

11.SHAHIN，M.M.，BUGAUT，A.，KALOPISSIS，G.Structure-activity?relationship?with?a?series?of?m-diaminobenzene?derivatives.Mutat?Res.1980，78(1)，25-31.

12.SHAHIN，M.M.，C?HOPY，C.Studies?on?the?mutagen：city?of?monocyclic?aormatic?amines?in?Salmonella?typhimurium：detoxification?effects?of?liver?S9.Foutrh?Int?Conf?Environ?Mutagens.1985，229.

13.WATANABE，T.，HIRAYAMA，T.，FUKUI，S.Phenarzine?derivatives?as?the?mutagenic?reaction?product?from?o-or?m-phenylenediamine?derivatives?with?hydrogen?peroxide.Mutat?Res.1989，227(3)，135-145.

14.SHAHIN，M.M.Structure-activity?relationships?within?various?series?of?p-phenylenediamine?derivatives.Mutat?Res.1994，307(2)，83-93.

(PPD p-Phenylenediamine), is an anaphylactogen main in the hair dye to p-phenylenediamine (PPD); It is a kind of chemical analysis (shown in table 2 and table 3) that must use in the dark brown colour system hair dye; Colour is that content is fewer, and its 50% mouse fatal dose (being called LD50) is 80mg/kg, representes that the toxicity of this raw material is quite high; And commercially available hair dye contains the PPD composition more, especially oxidized form chemistry hair dye.Medical circle is also pointed out PPD except being the anaphylactogen, and it also is carcinogenic a kind of, and Germany, France, Sweden all legislation once forbid using in the hair dye PPD (p-phenylenediamine (PPD)); And the PPD concentration of commercially available hair dye from 0.01% to 2% has, though meet 4% of Taiwan regulation, no matter how or few the consumption of PPD; The capital produces situation hypersensitive; In addition, the coupling agent in the oxidized form chemistry hair dye is also had toxicity, resorcinol as shown in table 2 (Resorcinol); Its 50% mouse fatal dose (being called LD50) is 200mg/kg, and toxic side effects and safety that above various data is all said oxidized form chemistry hair dye are to let people's worry really.

Table 2. black oxidation type chemistry hair dye composition toxicity data table

The coffee-like oxidized form chemistry of table 3. hair dye composition toxicity data table

Though and the toxicity of semi-permanent hairdye and temporary hair dye does not have the toxic and side effects of permanent oxidized form chemistry hair dye; But the degree of fading is fast and not washable; The advantage that still can't possess Permanent Hair Dyeing Agent in the use, and no matter the vegetalitas hair dye is absorbent-type or metal misfit type, maximum problem is to use complicated steps and color this binomial factor very little; Though cause it to have the advantage in the safety, but still popularity that can't the substituted chemistry hair dye.

Summary of the invention

The technical problem that the present invention will solve is that present hair dye system all has its shortcoming separately, if can develop human body is had high security and can be washable persistent permanent stain system, will be a big Gospel to needs hair dyeing person.The present invention is exactly as prerequisite and carries out the invention that produced after a large amount of research, and the present invention can further be improved anaphylaxis, safety and the usability problems that hair dye caused for a long time, and novelty hair colouring methods fast again is provided.

Hair dye provided by the invention comprises

(a) stain, this stain are selected from the natural pigment of edible and cosmetic use, the synthetic dyestuff or the cosmetic colors of edible and cosmetic use; And

(b) scared scale is opened agent.

Above-mentioned hair dye is Permanent Hair Dyeing Agent, semi-permanent hairdye or temporary hair dye.

Wherein, when above-mentioned hair dye is Permanent Hair Dyeing Agent, comprise

(a) as the synthetic dyestuff of the edible and cosmetic use of stain;

(b) open inorganic peroxide, organic peroxide, the cystine linkage Reducing agent of agent or float agent as scared scale; And arbitrarily selectively

(c) metal ion and/or alkaline agent.

Preferably above-mentioned edible synthetic dyestuff with cosmetic use be one or more combination in any in No. 106, yellow No. 102, No. 103, orange, red No. 104, No. 105, carmetta and the blueness.

Above-mentioned inorganic peroxide is hydrogen peroxide or hydrogen peroxide.

Above-mentioned cystine linkage Reducing agent is D, one or more combination in any in the derivant of L-NAC or its esters, NAC, mercapto acetic acid or its salt or ester, 2-mercaptopropionic acid or its salt, sulfurous acid or its salt, ascorbic acid or its salt and left-handed vitamin C or its salt.

Above-mentioned metal ion is the cation of magnesium, aluminum, ferrum or zinc.

Above-mentioned alkaline agent is inorganic base or organic base.

Above-mentioned hair dye comprises

(a) as the cosmetic colors of stain;

(b) open inorganic peroxide, the organic peroxide of agent or float agent as scared scale; And arbitrarily selectively

(c) alkaline agent.

Wherein, above-mentioned cosmetic colors is one or more combination in any among blue No. 6 of yellow No. 10 of D&C, No. 3, external D&C orange, FD&C red No. 4 and the D&C.

Above-mentioned inorganic peroxide is hydrogen peroxide or hydrogen peroxide.

Above-mentioned alkaline agent is inorganic base or organic base.

Above-mentioned alkaline agent is a kind of or its combination in MEA and the potassium peroxydisulfate.

Above-mentioned hair dye also comprises hair penetration enhancer and/or hair extender.

When above-mentioned hair dye is semi-permanent hairdye, comprise:

(a) eating and the cosmetic use synthetic dyestuff as stain; And arbitrarily selectively

(b) sour agent or alkaline agent.

Above-mentioned edible synthetic dyestuff with cosmetic use be one or more combination in any in No. 106, yellow No. 102, No. 103, orange, red No. 104, No. 105, carmetta and the blueness.

Above-mentioned sour agent is mineral acid or organic acid, and said alkaline agent is inorganic base or organic base.

Above-mentioned hair dye is temporary hair dye.

Above-mentioned temporary hair dye comprises the synthetic dyestuff as the edible and cosmetic use of stain; And arbitrarily selectively

(a) alkaline agent; Or

(b) hydrogen peroxide or hydrogen peroxide.

Above-mentioned alkaline agent is inorganic base or organic base.

Above-mentioned hair dye is cream rinse, hair dyeing emulsion, hair dyeing frost, hair dyeing gel, hair dyeing paste, hair dyeing shampoo, foam type hair dye, spray-type hair-dyeing agent, hotly joins potion or with the variable color hair dye of pH value variable color with bonded the dying of agent for permanent hair waving.

Above-mentioned hair dye comprises for to hotly join potion with bonded the dying of agent for permanent hair waving:

(a) cystine linkage Reducing agent;

(b) eating and the cosmetic use synthetic dyestuff as stain; And

(c) cystine linkage oxidant.

Above-mentioned cystine linkage oxidant is peroxide or hydrogen peroxide.

Above-mentioned hair dye is the variable color hair dye with the pH value variable color, comprises:

(a) as the natural pigment of the edible and cosmetic use of stain; And

(b) buffer agent of change pH value.

Above-mentionedly edible be uva skin pigment, carmine pigment, kermes citraurin, anthocyanidin, carminic acid, Radix Betae red pigment, vulgaxanthin, santalin, bixin or fall annatto, or contain in the above-mentioned pigment one or more plant pigment or its extract with the cosmetic use natural pigment.

The buffer agent of above-mentioned change pH value is the solution of acid, alkali or its salt of pH value between 2.0 to 10.0.

The amount of above-mentioned stain accounts for 1 to 10% of said hair dye gross weight, and said scared scale is opened agent and accounted for 1 to 12% of said hair dye gross weight.

The amount of above-mentioned metal ion, sour agent or alkaline agent accounts for 1 to 10% of this hair dye gross weight.

The amount of above-mentioned cystine linkage oxidant accounts for 1 to 10% of said hair dye gross weight.

The amount of the buffer agent of above-mentioned change pH value accounts for 1 to 10% of said hair dye gross weight.

Above-mentioned hair dye also is used for human body beard, eyebrow, skin, lip and fingernail.

The present invention provides a kind of oxygen type hair colouring methods, uses above-mentioned semi-permanent hairdye and hotly joins potion with bonded the dying of agent for permanent hair waving.It uses inorganic peroxide or organic peroxide to produce oxygen.Preferred use be weak base state and weight percent concentration between 3 to 12% dioxygen breast to produce oxygen.Wherein, the weak base state is meant pH 7.5-8.5.

The present invention provides a kind of cystine linkage reduced form hair colouring methods, semi-permanent hairdye and hotly join potion with bonded the dying of agent for permanent hair waving in the use.

The present invention provides a kind of metal mordant dyeing type hair colouring methods, uses semi-permanent hairdye and hotly joins potion with bonded the dying of agent for permanent hair waving.Its metal ion that uses is the cation of magnesium, aluminum, ferrum or zinc.

The present invention provides a kind of ion of bonding hair colouring methods, uses above-mentioned semi-permanent hairdye and hotly joins potion with bonded the dying of agent for permanent hair waving.

The present invention provides a kind of absorbent-type hair colouring methods, uses above-mentioned temporary hair dye.

Said method also can be applied to human body beard, eyebrow, skin, lip, fingernail.

The present invention is to use natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors to be the hair dye of main manufacturing and to use its hair dyeing method.This hair dye also can be applied to the dyeing on hair and the skin simultaneously according to the keratoprotein like configurations of skin and hair; This hair dye can be made into cream rinse, hair dyeing emulsion, hair dyeing frost, hair dyeing gel, hair dyeing paste, hair dyeing shampoo, foam type hair dye, spray-type hair-dyeing agent etc.; Behind agent for permanent hair waving, also can be made into dye, scald once accomplish dye, scald two-in-one product.This hair dye penetrates into natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors hair and reaches the hair dyeing purpose with different hair colouring methods; And the degree of depth that gets into hair construction according to pigment; Can be made into Permanent Hair Dyeing Agent, semi-permanent hairdye and temporary hair dye etc., hair colouring methods comprises metal mordant dyeing, cystine linkage reducing process, oxygen method, ionic bond method and absorption method.

The pigment of indication of the present invention comprises natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors, and its detailed bill is shown in table 4, table 5, table 6.Natural pigment and food coloring are owing to belong to edible pigment; Unquestionable aspect safety; Though cosmetic colors is edible not; But because it is applied to the color additives of cosmetic product, therefore be used in the dyeing of skin and hair, aspect safety, also be superior to being applied at present the organic dyestuff in the hair dye.The pigment of indication has almost possessed main color among the present invention; Comprise red, yellow, blue, pink, green, orange, Fructus Citri tangerinae, purple, black, white (shown in table 4, table 5, the table 6) etc.; Can use single its hair colouring methods of pigment collocation to carry out during hair dyeing, after single pigment that can also be different mixed via different proportion, its hair colouring methods of arranging in pairs or groups was again had hair dyed; Can also primary colors red, Huang, blue mix via different proportion after, resulting any color its hair colouring methods of arranging in pairs or groups is again had hair dyed; But and the method that produces dye colour can be the blended principle of similar pigment, before hair dyeing, mixes with dyes in different colors and get, also when the hair dye product of the arbitrary color of production, mixes and gets with pre-designed different pigment ratios.Therefore, the hair dye color of indication comprises all colors among the present invention, and can before hair dyeing, modulate and get, and also can when producing hair dye, prepare, and has no restriction.

Table 4. edible natural pigment table

Table 5. edible synthesized coloring matter table

Table 6. cosmetic colors table

The hair colouring methods of indication of the present invention comprises metal mordant dyeing, cystine linkage reducing process, oxygen method method, ionic bond method and absorption method, and according to definition, attribute separately is as shown in table 7.

Table 7. hair dye attribute of the present invention

The metal mordant dyeing is to utilize the middle coupling agent of the metal ion of high price as hair cortical layer protein and hair dye pigment; Produce the active force (Sandwich interacton) of sandwich type whereby; Therefore; Can be in the hair cortical layer and reach the hair dyeing purpose with chromatopexis, the pigment that this hair colouring methods can be suitable for comprises the hair dye product of natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors manufacturing.Wherein the metal ion of indication comprises metallic salts such as magnesium, aluminum, ferrum, zinc; Wherein the active force of indication comprises covalent bond and ionic bond active force.

The cystine linkage reducing process is to utilize the Reducing agent that interrupts the hair proteins cystine linkage as the mode of opening hair hair scale sheet; Make pigment molecular penetrate into the method that the hair cortical layer reaches the hair dyeing purpose; While also can add the hair penetration enhancer and the hair extender improves painted usefulness, and the pigment that this hair colouring methods can be suitable for comprises the hair dye product of natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors manufacturing.

The oxygen method is to utilize the correct blackout of the hydrogen peroxide oxygen that (pH=7.5-8.5) produced under weak base state pigment to carry out decolourization; Weak base also can be opened the hair scale sheet and make pigment molecular get into the hair cortical layer simultaneously, makes pigementation reached the method for hair dyeing purpose at cortical layer with the mode that this works along both lines, safety is not hindered hair quality.The operational approach of the method and permanent oxidized form chemistry hair dye is similar; But principle is very not identical, and the hydrogen peroxide function in the chemical hair dye is except moving back hair melanin, and another kind of function is that the oxidation chemistry dyestuff intermediate makes it to form dye molecule; Hydrogen peroxide only produces oxygen and impels and take off the melanic function of hair in this method; Therefore this method only needs the hydrogen peroxide of low concentration to carry out, and need not use the high concentration hydrogen peroxide, and this can reduce the infringement of hair quality; Moreover; The present invention uses weak base (pH=7.5-8.5) to impel hydrogen peroxide to produce oxygen and opens hair hair scale sheet gets into the hair cortex layer in order to pigment molecular mode; Can not damage hair quality; But do not decrease its dyeing function, open hair scale sheet and the oxygenous purpose of catalysis hydrogen peroxide, can know under strong alkali environment and chemical hair dye must use highly basic (pH＞9.5) just can reach; The amino acid of many hair proteins can produce chemical reaction thereby degeneration with highly basic; Therefore, highly basic (pH＞9.5) is very serious for the infringement of hair, and the pigment that this hair colouring methods can be suitable among the present invention comprises the hair dye product of natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors manufacturing.Wherein the employed reagent of oxygen method of indication can be oxygenous chemical compound; Comprise inorganic peroxide (Inorganic peroxide), organic peroxide (Organic peroxide) and can oxygenous reagent, wherein the alkaline agent of indication comprises organic base and inorganic base.

The ionic bond method is anion or cation and the hair proteins generation ionic bond active force that utilizes in the pigment, cooperates hair extender, penetration enhancer etc. to make pigmentation reach the method for hair dyeing purpose in the hair cortex or the zone line of hair scale sheet and hair cortex again.Moreover anion-containing pigment can add acid to be waited and adjusts its pH value and promote hair dyeing effect whereby; The pigment of cation then can add alkali to be waited and adjusts its pH value and promote hair dyeing effect whereby.The pigment that this hair colouring methods can be suitable among the present invention comprises the hair dye product with anion or cationic natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors manufacturing.Wherein the acid of indication can be organic acid and mineral acid, and wherein the alkali of indication can be organic base and inorganic base.

Absorption method is to utilize the simple absorption affinity between pigment molecular and hair proteins that pigment is covered on the hair surface, forms the method that painted cover layer reaches the hair dyeing purpose.The pigment that this hair colouring methods can be suitable among the present invention comprises the hair dye product of natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors manufacturing.

The present invention disclose a kind of with natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors be main manufacturing hair dye with and hair colouring methods; Especially avirulent natural pigment of successful use and food coloring are as after the hair dyeing raw material; The insurmountable genotoxicity of hair dye, carcinogenecity and hypersensitive problem have for many years been solved; Make the development of hair dye get into a brand-new epoch; But whether the hair dyeing raw material of innovation and technology can replace use habit and advantage for many years; Therefore the present invention is except the safety of paying attention to dyestuff; Another important work be must be breakthrough the technology that natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors is penetrated into hair; Expectation can be reached the natural pigment of high security (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors are carried out permanent, semipermanent, temporary painted target to hair; For this reason, the present invention is directed to the technology that pigment penetrates into the hair different depth and further investigate, developed five kinds of hair dyeing technology altogether and reached this target; These five technology comprise metal mordant dyeing, cystine linkage reducing process, oxygen method, ionic bond method and absorption method, and this target of experience great deal of research results demonstration is reached fully.Ensuing problem is the demand whether hair dye color category of the present invention can meet market; The present invention is with primary colors red, Huang, indigo plant and deceive, white stain is the main colour mixture of carrying out, and the mode of colour mixture comprises utilizes monochromatic stain product directly with after the predetermined ratio mixing, has hair dyed with predetermined hair colouring methods again; The hybrid mode of the similar drawing pigment of this method; The hair dye product that perhaps when producing special color hair dye, mixes with special ratios and produce is then had hair dyed the mode of these two kinds of chromogenesis dye colours with predetermined hair colouring methods again; Add five kinds of red, yellow, blue, black, antholeucins; Even add hybrid mode such as other kinds color element, can create various market and go up required color, this kind colour mixture mode than chemical hair dye more progressive with possess convenience; Obvious, this advantage has surmounted chemical hair dye.

Ensuing problem is whether the persistency of hair dye can reach market standard; Each item hair dye type among the present invention is all passed through harsh hair washing test; And judge that according to the standard (persistency and fastness to washing standard) of table 7 it belongs to permanent, semipermanent, temporary hair dye; Show among the result that hair dye attribute of the present invention is relevant with its hair colouring methods and dye formulation; The hair dyeing experiment of wherein using absorption method to carry out all belongs to temporary hair dye; Because faint absorption affinity is only arranged between pigment and hair, all natural pigment among the present invention (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors are all applicable to the category of this type of hair dye.

The experiment if use ionic bond method is had hair dyed; Because the hair extender, penetration enhancer and the acid that add in the prescription, alkali etc.; Heating promotes it to penetrate into the speed and the degree of depth of hair to heat steam also capable of using to hair simultaneously; To make the pigment part calm in hair cortex or hair scale panel region; Use the stain of this kind prescription all to belong to semi-permanent hairdye,, have anion or cationic natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors among the present invention all applicable to the category of this type of hair dye because institute's tool has plenty of stronger ionic bond active force between pigment and hair.

If the hair dyeing experiment of using the cystine linkage reducing process to carry out; Because of containing the Reducing agent that interrupts the hair proteins cystine linkage in the dye formulation; And utilize weak base or with heat steam the physics of hair heating is opened the mode of hair hair scale sheet; Therefore pigment molecular is able to penetrate into and is deposited in the hair cortical layer; Use the stain and the hair colouring methods of this kind prescription all to belong to Permanent Hair Dyeing Agent, because pigmentation is in the hair cortical layer, all natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors is all applicable to the category of this type of hair dye among the present invention.

The experiment if use oxygen method is had hair dyed; Because of hair colouring methods is to have hair dyed with hydrogen peroxide, weak base and mixed mastic of pigment stain while; Under this situation; When the correct blackout of the oxygen in mastic pigment carries out decolourization; Pigment in can't the oxidation stain, the weak base environment also can be opened the hair scale sheet and impel pigment molecular to get into and be deposited in the hair cortical layer in addition, uses the stain of this kind prescription and hair colouring methods all to belong to Permanent Hair Dyeing Agent; Because pigmentation is in the hair cortical layer, all natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors is all applicable to the category of this type of hair dye among the present invention.

The experiment if use metal mordant dyeing is had hair dyed; Because of being is media and covalent bond and the ionic bond of utilizing itself and pigment molecular to be produced with hypotoxic high volence metal ion; Reach pigment molecular and fix and be deposited on the purpose in the hair cortical layer; Use the stain and the hair colouring methods of this kind prescription all to belong to Permanent Hair Dyeing Agent, because pigmentation is in the hair cortical layer, all have anion, cation, NH among the present invention ₂The natural pigment at base, basic, the SH basigamy seat of OH (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors are all applicable to the category of this type of hair dye.

Last problem that must solve is the rapidity that the required hair dyeing time of the hair dye among the present invention whether possesses chemical hair dye; Hair dye among the present invention is except being that master's hair dye is when costing 40 minutes with the metal mordant dyeing; Other hair colouring methods only need can accomplish hair dyeing in 20-30 minute, and this obvious part is suitable with chemical hair dye.

According to above-mentioned emphasis, the advantage that hair dye possessed that the present invention developed is as follows:

(1) natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or the cosmetic colors with high security is substituted with genotoxicity, carcinogenecity, hypersensitive chemical hair dye, and reaches the Permanent Hair Dyeing Agent standard that is same as chemical hair dye.

(2) natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or the cosmetic colors with high security replaces the semipermanent of use in the market and the dyestuff of temporary hair dye, and reaches identical hair dye standard.

(3) the hair dye color can utilize similar pigment hybrid mode to allocate, and must take office and close required hair dye tone, has hair dyed with predetermined hair colouring methods again, possesses convenience with creative.

(4) all hair colouring methods and employed pigment among the present invention, all with human safety and hair quality for mainly considering, safe and do not hinder hair quality.

(5) the hair dyeing time was accomplished (when costing except that the metal mordant dyeing 40 minutes) in 20-30 minute, according to the selection of employed kind of pigment, stain prescription, hair colouring methods, all can reach the target of permanent, semipermanent, temporary hair dye easily.

(6) according to the dosage form demand, natural pigment of the present invention (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors all can be made into cream rinse, hair dyeing emulsion, hair dyeing frost, hair dyeing gel, hair dyeing paste, hair dyeing shampoo, foam type hair dye, spray-type hair-dyeing agent, dye and scald products such as two-in-one.

The specific embodiment

Below in conjunction with specific embodiment the present invention is described further so that those skilled in the art can better understand the present invention and implementing, but the embodiment that lifts not conduct to qualification of the present invention.

It is main dyestuff by natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors that the present invention discloses a kind of; And combine different hair colouring methods to reach the hair dye of hair dyeing purpose; This hair dye can be applied to the dyeing of hair and skin simultaneously; This hair dye can be made into cream rinse, hair dyeing emulsion, hair dyeing frost, hair dyeing gel, hair dyeing paste, hair dyeing shampoo, foam type hair dye, spray-type hair-dyeing agent etc.; Behind agent for permanent hair waving, also can be made into dye, scald once accomplish dye, scald two-in-one product.And can be made into Permanent Hair Dyeing Agent, semi-permanent hairdye and temporary hair dye etc. respectively according to employed hair colouring methods, pigment type, prescription content, will distinguish that details are as follows.

One, the detailed description of natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors kind

Natural pigment involved in the present invention (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) and cosmetic colors; Comprise edible natural pigment, edible synthetic dyestuff and cosmetic colors; The useful instance of edible natural pigment is as shown in table 4; The useful instance of edible synthesized coloring matter is as shown in table 5; The useful instance of cosmetic colors is as shown in table 6, because the pigment title of various countries has a little difference with standard to food coloring and cosmetic colors, so the Colour Index (C.I.Number that habitually practises with the world of the present invention; Color Index Number),, or directly is referred to as expression with its pigment name if the pigment of not compiling in Colour Index will be with CAS Number as the expression mode as unified expression mode.

Two, the hair colouring methods of natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors

Detail

(1) oxygen method

The hair dyeing mode of the similar chemical hair dye of hair colouring methods of oxygen method among the present invention, containing respectively in the product with the pigment is first dose of main stain mastic, is master's second dose of mastic with hydrogen peroxide or peroxide, is the 3rd dose of the mastic led with the alkaline agent; Alkaline agent also can be contained in the pigment mastic, and its hair dyeing step is as follows.

1. stir subsequent use after colouring substance mastic, hydrogen peroxide or peroxide mastic, alkaline agent being mixed with predetermined ratio.

With Hair-dyeing brush with every hair evenly be coated with spread blended stain after, stop after 20～30 minutes, earlier with the Warm Wash stain on sending out of decaptitating, promptly accomplish hair dyeing after re-using shampoo and cleaning.

The pigment that this hair colouring methods can be suitable among the present invention comprises all natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) and cosmetic colors, and the hair dye type belongs to Permanent Hair Dyeing Agent.Wherein the peroxide of indication can be oxygenous chemical compound; Comprise inorganic peroxide (Inorganic peroxide), organic peroxide (Organic peroxide) and can oxygenous reagent; Inorganic peroxide wherein is meant inorganic matter, mineral acid and its esters that contains peroxy-O-O-, like hydrogen peroxide (hydrogen peroxide), sodium peroxide, potassium peroxide, calper calcium peroxide, Magnesium dioxide, potassium hydrogen peroxymonosulfate, permonosulphuric acid, peroxy-disulfuric acid, pernitric acid, mistake one phosphoric acid, perphosphoric acid, SODIUM PERCARBONATE or Dexol and its esters etc.Organic peroxide (Organic peroxide) is meant and contains the peroxide bond base (organic compound O-O-), general formula are R-O-O-R '.Like peracid, perester and peroxidating ether ether peroxide, oxolane peroxide, glycol dimethyl ether peroxide, benzoyl peroxide, methyl ethyl ketone peroxide, three peroxidating tri acetylacetonates, acetylperoxide nitrate or bisoxirane class etc., wherein the example of peracids comprises peroxyformic acid, peracetic acid, peroxy trifluoroacetic acid, Perpropionic Acid, Perbutyric Acid, peroxide isovaleric acid, long-chain peroxide fatty acid, benzoyl hydroperoxide, metachloroperbenzoic acid, nitro benzoyl hydroperoxide or monoperphthalic acid etc.Other oxygenous reagent can be ozone or other analog.Which refers to an organic base include alkali agent and inorganic bases and useful examples include alkanolamines, such as monoethanolamine, diethanolamine, triethanolamine, monopropanolamine, dipropanolamine, tripropanolamine 2 - amino - 2 - methyl-1,3 - propanediol, 2 - amino -2 - methyl-1 - propanol and 2, - amino -2 - (hydroxymethyl) -1,3 - propanediol; inorganic salts such as sodium , sodium carbonate, sodium bicarbonate, calcium carbonate and calcium bicarbonate; and guanidinium salts, such as guanidine hydrochloride, guanidine sulfate, guanidine nitrate, guanidine phosphate, guanidine phosphate, sulfur, boric acid guanidine, guanidine sulfamate, and organic acids of the guanidine salt, the above peroxide and alkaline agent known in the art are included.

(2) cystine linkage reducing process

The hair colouring methods of first kind of cystine linkage reducing process among the present invention; Containing respectively with the pigment in the product is first dose of main stain mastic; With the cystine linkage Reducing agent is master's second dose of mastic; Can add or not add alkaline agent in this agent, decide according to the character of cystine linkage Reducing agent fully, its hair dyeing step is as follows.

With Hair-dyeing brush with every hair evenly be coated with spread cystine linkage Reducing agent mastic after; Directly stopped 10 minutes; In retention period hair-dryer also capable of using or steam engine hair is heated, then, also can clean and directly carry out next step with Warm Wash this mastic on sending out of decaptitating.

2. after with Hair-dyeing brush every hair evenly being smeared the colouring substance mastic; Directly stopped 20 minutes; In retention period hair-dryer also capable of using or steam engine hair is heated, then decaptitate behind this mastic on sending out, promptly accomplish hair dyeing after re-using shampoo and cleaning with Warm Wash.

The hair colouring methods of second kind of cystine linkage reducing process among the present invention; Can the pigment of a dosage form and the mixing paste of cystine linkage Reducing agent in the product; Can also be indivedual mastic (as being first dose of main stain mastic, being master's second dose of mastic with the cystine linkage Reducing agent with the pigment) of two dosage forms, the mastic of two dosage forms needs before hair dyeing after the directly mixing subsequent use; Can add or not add alkaline agent in the mastic; Decide according to the character of cystine linkage Reducing agent fully, the mastic of a dosage form then directly uses and gets final product, and its hair dyeing step is as follows.

1. after with Hair-dyeing brush every hair evenly being coated with the mastic of spreading this hair dye, directly stopped 20-30 minute, hair is heated in retention period hair-dryer also capable of using or steam engine;

2. then with Warm Wash this mastic on sending out of decaptitating, promptly accomplish hair dyeing after re-using shampoo and cleaning.

The pigment that this hair colouring methods can be suitable among the present invention comprises all natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors, and the hair dye type belongs to Permanent Hair Dyeing Agent.Wherein the cystine linkage Reducing agent of indication can be D; The derivant of L-NAC and its esters, NAC (N-acetyl group-D; The L-NAC), mercapto acetic acid or its esters and esters, 2-mercaptopropionic acid and its esters, sulfurous acid and its esters, ascorbic acid and its esters, left-handed vitamin C and its esters, also comprise the above compound compositions.In the compositions described above; Also the hair penetration enhancer can be added again and the hair extender improves painted usefulness; Wherein the extender of indication, penetration enhancer can be benzyl alcohol (Benzyl alcohol), isopropyl alcohol (Isopropanol), N-methyl 2-pyridine alkane ketone (N-methyl-2-pyrolidone), propylene carbonate (Propylene carbonate), anhydrous sodium sulfate (sodium sulphate anhydrous), benzoic acid (Benzoic Acid), formic acid (Formic acid), carbamide (Urea), urea hydrochloride (Guanidine), sodium lauryl sulphate (Sodium dodecyl sulfate), sarcosyl (Sodium lauryl sarcosinate), Triton X-100 (Triton X-100), laurocapram (1-Dodecylazacycloheptan-2-one) etc., above-described reagent be the present technique field known all be included in.

(3) metal mordant dyeing

The hair colouring methods of metal mordant dyeing among the present invention; Product can be divided into three dosage forms and two dosage forms, and first dose of three dosage form products is cystine linkage Reducing agent mastic, and the effect of this agent is to interrupt cystine linkage makes the hair scale sheet open the pigment molecular entering hair cortex layer in order to following potion; If but the hair of preparing hair dyeing is hair color or other dark hairs; Then this agent can change the general so-called agent (hair melanin decolourant) of floating, and the purpose of floating agent is that the melanin of hair is desalinated yellowly earlier to coffee-like color development, and another effect of floating agent is to interrupt cystine linkage the hair scale sheet is opened; This two effect can help down the potion metal ion to get into cortical layer smoothly; And second dose be hypotoxic metal ion mastic, and the 3rd dose is pigment stain mastic, and first dose, second dose, the 3rd dose mastic is according to using in order during hair dyeing.First dose of two dosage form products is the mixing paste of metal ion and cystine linkage Reducing agent; Metal ion can be the mastic that separates with the cystine linkage Reducing agent; And use after just directly mixing these two doses of mastic before use; Alkaline agent will be looked the type of cystine linkage Reducing agent and add, and first dose, second dose mastic is according to using in order during hair dyeing, and its hair dyeing step is as follows.

(I) the hair dyeing step of three component hair dyes

1. after with Hair-dyeing brush every hair evenly being coated first dose (cystine linkage Reducing agent mastic) earlier; Directly stopped 10 minutes; In retention period hair-dryer also capable of using or steam engine hair is heated, then, also can clean and directly carry out next step with Warm Wash this mastic on sending out of decaptitating.If the hair that will have hair dyed is hair color or dark hair, then this agent changes 6% dioxygen breast into and adds and float agent (hair melanin stripping agent), and floating that agent stops is 30 minutes, must wash away with clear water after the end and float agent.

2. after with Hair-dyeing brush every hair evenly being coated second dose (metal ion mastic), directly stopped 15 minutes, hair is heated, then with Warm Wash this mastic on sending out of decaptitating in retention period hair-dryer also capable of using or steam engine.

3. after with Hair-dyeing brush every hair being coated the 3rd dose (pigment stain mastic); Directly stopped 15 minutes; In retention period hair-dryer also capable of using or steam engine hair is heated,, promptly accomplish hair dyeing after re-using shampoo and cleaning then with Warm Wash this mastic on sending out of decaptitating.

(II) the hair dyeing step of two component hair dyes

1. after with Hair-dyeing brush every hair evenly being coated first dose (metal ion mastic), directly stopped 15 minutes, hair is heated, then with Warm Wash this mastic on sending out of decaptitating in retention period hair-dryer also capable of using or steam engine.

2. after with Hair-dyeing brush every hair being coated second dose (pigment stain mastic); Directly stopped 15 minutes; In retention period hair-dryer also capable of using or steam engine hair is heated,, promptly accomplish hair dyeing after re-using shampoo and cleaning then with Warm Wash this mastic on sending out of decaptitating.

The pigment that this hair colouring methods can be suitable among the present invention comprise have anion, cation, NH ₂The natural pigment at base, basic, the SH basigamy seat of OH (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors, the hair dye type belongs to Permanent Hair Dyeing Agent, and result is as shown in table 8 in its hair dyeing.。Wherein the cystine linkage Reducing agent of indication is identical with the instance of above-mentioned cystine linkage reducing process.Wherein the metal ion of indication comprises metallic salts such as hypotoxic magnesium, aluminum, ferrum, zinc, above-described reagent be the present technique field known all be included in.

The hair dyeing of table 8. metal mordant dyeing is table as a result

(4) ionic bond method

The hair colouring methods of intermediate ion key method of the present invention; Product has only a dosage form, and it consists of anion or cation pigment is main stain mastic, can add the effect that hair extender, penetration enhancer promote hair dyeing in the mastic; Moreover; Anion-containing pigment can add sour agent and promote hair dyeing effect, and the pigment of cation then can add alkaline agent and promote hair dyeing effect, and hair-dryer also capable of using or steam engine promote hair dyeing effect to the physics mode of hair heating; This method is identical with the hair dyeing mode of semi-permanent hairdye on the market, and its hair dyeing step is as follows.

With Hair-dyeing brush with every hair evenly be coated with spread the stain mastic after, directly stopped 20-30 minute, in retention period hair-dryer also capable of using or steam engine hair is heated;

2. then with the Warm Wash mastic on sending out of decaptitating, promptly accomplish hair dyeing after re-using shampoo and cleaning.

The pigment that this hair colouring methods can be suitable among the present invention comprises have anion or cationic natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors, and the hair dye type belongs to semi-permanent hairdye.Wherein the acid of indication can be organic acid and mineral acid; Wherein the alkali of indication can be organic base and inorganic base; The instance of sending out method with above-mentioned oxygen is identical; Wherein the extender of indication, penetration enhancer be with identical with the instance of above-mentioned cystine linkage reducing process, the above reagent be the present technique field known all be included in.

(5) absorbent-type method

It is main stain mastic that the hair colouring methods of absorbent-type method among the present invention, product have only a dosage form pigment, and this method is identical with the hair dyeing mode of on the market temporary hair dye, and its step of having hair dyed is as follows.

With Hair-dyeing brush with every hair evenly be coated with spread the stain mastic after;

Promptly to accomplish hair dyeing behind the drier hair.

The pigment that this hair colouring methods can be suitable among the present invention comprises all natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors, and the hair dye type belongs to temporary hair dye.

Three, dying of natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors scalded two-in-one product detailed description

General traditional hair-waving program is two dose of two step procedure; First dose is Main Ingredients and Appearance (like employed cystine linkage Reducing agent in the cystine linkage reducing process) with mercapto acetic acid or its esters and these two types of cystine linkage Reducing agents such as esters or secondary cystine, and second dose is Main Ingredients and Appearance with these two types of cystine linkage oxidants such as bromic acid salt or hydrogen peroxide then.The hair-waving principle on basis is to cut off the cystine linkage formation-SH base between hair proteins with first dose of cystine linkage Reducing agent, then builds up new cystine linkage with second dose of cystine linkage oxidant general-SH basic weight again, reaches the purpose of hair plastotype whereby.Known present hair-waving program is separated with the hair dyeing program and is carried out; The necessary therebetween above time in a week at interval; And program out of the ordinary all needs could accomplish more than one hour; Therefore if can combine these two kinds of programs once to accomplish, the time that can save individual and hairdresser with numerous and diverse dye, boiling hot program.

As previously discussed, main purpose of the present invention be with dye, the hair-waving program combines, therefore, in design, must the part raw material that dyes, perms be mixed, and its function that can not interact.According to the hair-waving principle; First dose the main function of cystine linkage Reducing agent is the cystine linkage that cuts off hair proteins; Simultaneously also will impel hair hair scale sheet to open; This is identical with the hair dyeing principle of cystine linkage reducing process among the present invention, and first kind of method for designing of therefore dying, scalding two-in-one product is to reach according to the cystine linkage reducing process in the above-mentioned hair dye, and first dose of two-in-one product dyed, scalds in the hair dye mastic conduct of use cystine linkage reducing process; The effect of this agent can be simultaneously cut off the hair cystine linkage and promote pigment molecular to get into hair hair cortex layer and deposit; Then again with the cystine linkage oxidant as second dose that dyes, scalds two-in-one product, the effect of this agent can be rebuild new cystine linkage makes hair reach the purpose of plastotype, the while also can not carried out the oxidative bleaching effect to the pigment that is positioned at cortical layer; Therefore just can reach and dye, scald two-in-one purpose, this series products belongs to two dosage forms and dyes, scalds two-in-one product.

Second kind of method for designing of dying, scalding two-in-one product is to reach according to the oxygen method in the above-mentioned hair dye; The cystine linkage that the cystine linkage Reducing agent that same use is first dose cuts off hair proteins; Also can hair hair scale sheet be opened simultaneously; Then with the mixing paste of the pigment mastic of above-mentioned oxygen method hair colouring methods and hydrogen peroxide or peroxide mastic (being the cystine linkage oxidant) as second dose; Make hair reach the purpose of plastotype by hydrogen peroxide or the new cystine linkage of peroxide oxidation reconstruction; And promote pigment molecular to get into hair hair cortex layer simultaneously and deposit that dye, scald two-in-one purpose and reach, this series products belongs to two dosage forms and dyes, scalds two-in-one product.The third method for designing of dying, scalding two-in-one product is with not hybrid pigment mastic and hydrogen peroxide or peroxide mastic (being the cystine linkage oxidant); And dye, perm with division step; The cystine linkage that the cystine linkage Reducing agent that same earlier use is first dose cuts off hair proteins; Then have hair dyed as second dose with the pigment mastic; Final step uses the cystine linkage oxidant as the 3rd dose, rebuilds new cystine linkage and makes hair reach the purpose of plastotype, and this series products belongs to three dosage forms and dyes, scalds two-in-one product.The 4th kind of method for designing of dying, scalding two-in-one product is that cystine linkage Reducing agent and pigment are designed in same mastic as first dose; Cut off the cystine linkage of hair proteins; Also can hair hair scale sheet be opened simultaneously; The oxygen that is then produced with air or oxygen generator is rebuild new cystine linkage by dioxygen oxidation and is made hair reach the purpose of plastotype as second dose (cystine linkage oxidant), and promotes pigment molecular to get into hair hair cortex layer simultaneously and deposit; Dye, scald two-in-one purpose and reach, this series products belongs to two dosage forms and dyes, scalds two-in-one product.

The method of hair-waving has three kinds of thermoplastic method, powder stick method, cold wave methods etc., below will the operating procedure of dying, scalding two-in-one product be detailed according to these three kinds of method for permanent waving hair.

1. thermoplastic method: two-in-one product operation step is scalded in dying of two dosage forms

Step 1: hair washing (under the wet state); Step 2: last first dose (stopping 20 minutes); Step 3: bath; Step 4: go up steamed roll; Step 5: add thermoplastic and do (absolutely dry); Step 6: last second dose (stopping 20 minutes); Step 7: unreel; Step 8: flushing.

2. powder stick method: two-in-one product operation step is scalded in dying of two dosage forms

Step 1: hair washing (under the wet state); Step 2: last first dose (stopping 20 minutes); Step 3: go up steamed roll; Step 4: add thermoplastic and do (absolutely dry); Step 5: last second dose (stopping 20 minutes); Step 6: unreel; Step 7: flushing.

3. cold wave method: two-in-one product operation step is scalded in dying of two dosage forms

Step 1: hair washing (under the wet state); Step 2: last first dose (stopping 20 minutes); Step 3: bath; Step 4: go up steamed roll; Step 5: last second dose (stopping 20 minutes); Step 6: unreel; Step 7: flushing.

4. thermoplastic method: two-in-one product operation step is scalded in dying of three dosage forms

Step 1: hair washing (under the wet state); Step 2: last first dose (stopping 10 minutes); Step 3: last second dose (stopping 20 minutes); Step 4: bath; Step 5: go up steamed roll; Step 6: add thermoplastic and do (absolutely dry); Step 7: last the 3rd dose (stopping 10 minutes); Step 8: unreel; Step 9: flushing.

5. powder stick method: two-in-one product operation step is scalded in dying of three dosage forms

Step 1: hair washing (under the wet state); Step 2: last first dose (stopping 10 minutes); Step 3: last second dose (stopping 20 minutes); Step 4: go up steamed roll; Step 5: add thermoplastic and do (absolutely dry); Step 6: last second dose (stopping 10 minutes); Step 7: unreel; Step 8: flushing.

6. cold wave method: two-in-one product operation step is scalded in dying of three dosage forms

Step 1: hair washing (under the wet state); Step 2: last first dose (stopping 10 minutes); Step 3: last second dose (stopping 20 minutes); Step 4: bath; Step 5: go up steamed roll; Step 6: last second dose (stopping 10 minutes); Step 7: unreel; Step 8: flushing.

Thisly among the present invention dye, scald the pigment source that two-in-one product can be suitable for and comprise natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors; The weight percent content of pigment is 1% to 10%, and suitable content is 2% to 5%.Wherein the cystine linkage Reducing agent of indication is identical with the instance of above-mentioned cystine linkage reducing process; The weight percent content of cystine linkage Reducing agent is 1% to 10%; Suitable content is 3% to 8%, and the pH value of cystine linkage Reducing agent is then adjusted with alkaline agent if must adjust; It is main between the 7.5-9.5 that the use amount of alkaline agent is adjusted to the pH value with the product mastic; Actual use amount is looked the character of alkaline agent and is decided, and wherein the alkaline agent of indication can be organic base and inorganic base, and is identical with the instance of above-mentioned cystine linkage reducing process.Wherein the cystine linkage of indication also oxidant can be the hair-waving second dose of raw material, like hydrogen peroxide and bromic acid salt; Can also be organic peroxide and inorganic peroxide, or can oxygenous reagent or cover group, identical with the instance of above-mentioned oxygen method; Its weight percent content is 3% to 12%, and suitable content is 3% to 8%, and the pH value of cystine linkage oxidant is if must adjust; Then adjust with sour agent; It is main between the 2.5-4.5 that the use amount of acid agent is adjusted to the pH value with the product mastic, and actual use amount is looked the character of sour agent and decided, and wherein the sour agent of indication can be organic acid and mineral acid.If need its pH value of adjustment, can add organic acid, mineral acid, organic base, inorganic base etc. and adjust in the pigment mastic, above-described reagent is in present technique field institute well known all is included in.Dosage form of the present invention can be modulated into the preparation pattern of water preparation, emulsion, emulsifiable paste, cream, gel, paste, foam type, aerosol type.

Four, modulate the color and the hair colouring methods detailed description thereof of hair dye with pigment stain colour mixture

Related pigment stain has various main colors among the present invention; Comprise red, yellow, blue, pink, green, orange, Fructus Citri tangerinae, purple, black, white or the like; Required any stain color can utilize the colour mixture principle of drawing pigment to modulate; The present invention has utilized the food coloring stain of 5 kinds of solid colors; Comprise that TaiWan, China edible yellow No. five (FD&C Yellow No.6), TaiWan, China edible yellow No. four (FD&C Yellow No.5), TaiWan, China edible red No. six (Acid Red 18), TaiWan, China edible red No. seven (FD&C Red No.3), TaiWan, China edible blue No. (FD&C Blue No.1) etc. are as embodiment; Modulate the stain of 106 kinds of colors altogether and carried out the most harsh oxygen method hair dyeing experiment; Further confirm the Color on dark hair; Experimental result confirms all can to dye on dark hair by the successful pigment with modulating with the modulation system of dyestuff colour mixture, and confirms to belong to Permanent Hair Dyeing Agent through the fastness to washing of 30 shampoos and the harsh test back of persistence, and the result of stain hybrid modulation is as shown in table 9.

Table 9. stain is through the result of part by weight hybrid modulation

New numbering	Y4	Y5	R6	R7	B1	The Panton number
							1	0.8	0.2	0.0	0.0	0.0	1235c
2	0.6	0.4	0.0	0.0	0.0	1375c
							3	0.4	0.6	0.0	0.0	0.0	1375c
4	0.2	0.8	0.0	0.0	0.0	1375c
							5	0.2	0.6	0.2	0.0	0.0	1585c
6	0.4	0.4	0.2	0.0	0.0	1585c
							7	0.0	0.8	0.2	0.0	0.0	1505c
8	0.6	0.2	0.2	0.0	0.0	1505c
							9	0.8	0.0	0.2	0.0	0.0	1505c
10	0.2	0.4	0.0	0.4	0.0	1787c
							11	0.4	0.0	0.4	0.2	0.0	1787c
12	0.2	0.2	0.4	0.2	0.0	1787c
							13	0.0	0.6	0.0	0.4	0.0	1789c
14	0.6	0.0	0.4	0.0	0.0	1788c
							15	0.4	0.4	0.0	0.2	0.0	1787c
16	0.4	0.2	0.2	0.2	0.0	1787c
							17	0.0	0.4	0.6	0.0	0.0	1787c
18	0.0	0.6	0.4	0.0	0.0	1787c
							19	0.2	0.2	0.6	0.0	0.0	1787c
20	0.2	0.4	0.4	0.0	0.0	1787c
							21	0.8	0.0	0.0	0.2	0.0	1787c
22	0.2	0.6	0.0	0.2	0.0	1787c
							23	0.2	0.0	0.8	0.0	0.0	1787c
24	0.4	0.2	0.4	0.0	0.0	1787c
							25	0.4	0.0	0.6	0.0	0.0	1787c
26	0.2	0.4	0.2	0.2	0.0	1787c
							27	0.6	0.0	0.2	0.2	0.0	1787c
28	0.2	0.2	0.2	0.4	0.0	1787c
							29	0.6	0.2	0.0	0.2	0.0	1787c
30	0.0	0.6	0.2	0.2	0.0	Redc
							31	0.0	0.8	0.0	0.2	0.0	Redc
32	0.4	0.0	0.0	0.6	0.0	Red032c
							33	0.6	0.0	0.0	0.4	0.0	Red032c
34	0.0	0.2	0.2	0.6	0.0	Red032c
							35	0.4	0.2	0.0	0.4	0.0	Red032c
36	0.0	0.4	0.2	0.4	0.0	185c
							37	0.0	0.2	0.6	0.2	0.0	185c
38	0.0	0.2	0.4	0.4	0.0	185c
							39	0.0	0.0	0.8	0.2	0.0	185c
40	0.0	0.2	0.8	0.0	0.0	185c

41	0.0	0.4	0.4	0.2	0.0	1925c
							42	0.0	0.0	0.6	0.4	0.0	1925c
43	0.0	0.4	0.0	0.6	0.0	1925c
							44	0.0	0.2	0.0	0.8	0.0	1925c
45	0.2	0.2	0.0	0.6	0.0	219c
							46	0.0	0.0	0.4	0.6	0.0	219c
47	0.2	0.0	0.0	0.8	0.0	219c
							48	0.0	0.0	0.2	0.8	0.0	219c
49	0.0	0.4	0.0	0.0	0.6	3308c
							50	0.2	0.4	0.0	0.0	0.4	343c
51	0.4	0.2	0.0	0.0	0.4	348c
							52	0.4	0.0	0.0	0.0	0.6	348c
53	0.2	0.2	0.0	0.0	0.6	349c
							54	0.0	0.6	0.0	0.0	0.4	349c
55	0.6	0.2	0.0	0.0	0.2	349c
							56	0.4	0.4	0.0	0.0	0.2	349c
57	0.8	0.0	0.0	0.0	0.2	355c
							58	0.6	0.0	0.0	0.0	0.4	356c
59	0.0	0.8	0.0	0.0	0.2	371c
							60	0.2	0.6	0.0	0.0	0.2	378c
61	0.2	0.0	0.0	0.0	0.8	569c
							62	0.0	0.2	0.0	0.0	0.8	7473c
63	0.0	0.2	0.2	0.0	0.6	432c
							64	0.0	0.0	0.4	0.0	0.6	7463c
65	0.0	0.0	0.2	0.0	0.8	7546c
							66	0.0	0.0	0.0	0.2	0.8	526c
67	0.0	0.0	0.0	0.4	0.6	525c
							68	0.0	0.0	0.2	0.2	0.6	5185c
69	0.0	0.2	0.0	0.2	0.6	515c
							70	0.0	0.0	0.8	0.0	0.2	5125c
71	0.0	0.0	0.6	0.0	0.4	438c
							72	0.0	0.0	0.4	0.2	0.4	262c
73	0.0	0.2	0.0	0.4	0.4	262c
							74	0.2	0.2	0.0	0.2	0.4	261c
75	0.0	0.0	0.2	0.4	0.4	261c
							76	0.0	0.0	0.0	0.6	0.4	229c
77	0.0	0.2	0.0	0.6	0.2	229c
							78	0.0	0.6	0.0	0.2	0.2	229c
79	0.0	0.4	0.0	0.2	0.4	228c
							80	0.0	0.0	0.6	0.2	0.2	228c
81	0.6	0.0	0.0	0.2	0.2	228c
							82	0.0	0.0	0.0	0.8	0.2	227c

83	0.0	0.0	0.2	0.6	0.2	227c
							84	0.4	0.0	0.0	0.4	0.2	227c
85	0.0	0.0	0.4	0.4	0.2	227c
							86	0.4	0.0	0.2	0.2	0.2	222c
87	0.2	0.2	0.0	0.4	0.2	221c
							88	0.4	0.2	0.0	0.2	0.2	215c
89	0.0	0.4	0.0	0.4	0.2	215c
							90	0.2	0.4	0.0	0.2	0.2	215c
91	0.2	0.2	0.4	0.0	0.2	440c
							92	0.2	0.4	0.2	0.0	0.2	450c
93	0.0	0.6	0.2	0.0	0.2	449c
							94	0.0	0.4	0.4	0.0	0.2	491c
95	0.0	0.2	0.6	0.0	0.2	492c
							96	0.4	0.0	0.4	0.0	0.2	498c
97	0.0	0.2	0.4	0.0	0.4	5195c
							98	0.0	0.4	0.2	0.0	0.4	532c
99	0.2	0.2	0.2	0.0	0.4	5467c
							100	0.6	0.0	0.2	0.0	0.2	553c
101	0.4	0.2	0.2	0.0	0.2	5605c
							102	1	0	0	0	0	Yellow?C
103	0	1	0	0	0	Orange?21C
							104	0	0	1	0	0	Red?32
105	0	0	0	1	0	Rhodamine?Red?C
							106	0	0	0	0	1	Blue?072C

Five, the pigment hair dye with the pH value variable color details

In the disclosed pigment hair dye; There is one type of natural food colour to change the pigment composition of pigmentary colours, as contains the natural pigment that anthocyanidin is main pigment composition, the color changeable effect with similar pH indicator of anthocyanidin because of having to change with pH value; Its color can change with the variation of pH; When pH brought up to 13 gradually by 1, its color can change into yellow at last by redness, bluish red color, purple, blueness, green; Therefore can utilize the hair dye of this feature development changeable colour, with the natural pigment inventory of the rough expression changeable colour of table 10.The aforesaid various hair dyeing mode of arranging in pairs or groups; Like metal mordant dyeing, cystine linkage reducing process, oxygen method method, ionic bond method and absorption method etc.; Natural pigment in the table 10 different hair colouring methods all capable of using and demand penetrate into the target site (hair scale sheet or hair cortex) of hair with natural pigment, and produce permanent, semipermanent, temporary hair dye.Can comprising anthocyanidin (Anthocyanin), carminic acid (Carminic acid), Radix Betae red pigment (Betanin), vulgaxanthin (Vulgaxanthin), santalin (Santalin), bixin (Bixin), fall annatto (Norbixin) etc. of indication of the present invention wherein, and plant pigment and extract with this pigment molecular with the natural pigment molecule monomer that pH value changes its color.Wherein the changeable colour hair dye of indication can be to be made up of single pigment stain; Also can mix the stain color that is produced via the pigment of any ratio; During hair dyeing, after carrying out according to different hair colouring methods, be sprayed on the buffer solution of different pH value on the hair after; Can accomplish the hair variable color with the drier hair again; More than the NM natural pigment that possesses with the pH value variable color be the category that the present invention comprises, the pigment weight percent content is 1% to 10% in the pigment mastic, suitable content is 2% to 5%.

Wherein the pH value buffer agent of indication is sour agent, alkaline agent, salt and compositions thereof or buffer solution, and sour agent can be organic acid and mineral acid and its esters.Alkaline agent can be organic base and inorganic base and its esters, and buffer solution can be in this field institute well known all is included between the pH value 2.0-10.0.Hair dye of the present invention can be modulated into the dosage form of water preparation, emulsion, emulsifiable paste, cream, gel, paste, foam type, aerosol type, shampoo.

Table 10. can be with the natural pigment kind of pH value variable color

Six, the optimal conditions of hair dye

(1) optimal conditions of oxygen method Permanent Hair Dyeing Agent product

This hair dye can be divided into three dosage forms and two dosage form products, is respectively first dose of pigment stain mastic in the three dosage form products, second agent hydrogen peroxide or peroxide mastic, the 3rd dose of alkaline agent mastic or powder; First dose of two dosage form product integrate pigment and alkaline agent, and second dose is still hydrogen peroxide or peroxide mastic, can use after during use all mastic being mixed.Pigment source comprises natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors; The pigment weight percent content is 1% to 10% in the pigment mastic, and suitable content is 2% to 5%.Hydrogen peroxide, peroxide, or the paste composition weight percentage of 3-12%, suitable amount of 3-6%; alkali agent paste or powder is used in an amount to adjust the pH of the paste product to mainly between 7.5-8.5, depending on the actual use of the nature of the alkaline agent, wherein the alkali agent may be referred to the organic bases and inorganic bases, organic bases useful in the Examples include alkanolamines, such as monoethanolamine, diethanolamine , triethanolamine, monopropanolamine, dipropanolamine, tripropanolamine 2 - amino -2 - methyl-1,3 - propanediol, 2 - amino -2 - methyl-1 - propanol and 2 - amino -2 - (hydroxymethyl) -1,3 - propanediol; inorganic salts such as sodium hydroxide, sodium carbonate, sodium bicarbonate, calcium carbonate and calcium bicarbonate; and guanidinium salts, such as guanidine hydrochloride, guanidine sulfate, guanidine nitrate, guanidine phosphate, guanidine phosphate, sulfur, boric acid guanidine, guanidine sulfamate, and the guanidine salts of organic acids.Hair dye of the present invention can be modulated into the preparation pattern of water preparation, emulsion, emulsifiable paste, cream, gel, paste, foam type, aerosol type, shampoo.

(2) optimal conditions of cystine linkage reducing process Permanent Hair Dyeing Agent product

This hair dye can be divided into two dosage forms and a dosage form product; First dose of two dosage form products is cystine linkage Reducing agent mastic, and second dose is pigment stain mastic, during hair dyeing first dose with second dose of mastic according to using in order; Or use after directly mixing these two doses of mastic; If need to add alkaline agent, then alkaline agent will integrate with cystine linkage Reducing agent mastic, directly use during use to get final product.One dosage form product then is that to contain cystine linkage Reducing agent, pigment, alkaline agent be the mastic of one, directly uses during use to get final product.Pigment source comprises natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors; The pigment weight percent content is 1% to 10% in the pigment mastic, and suitable content is 2% to 5%; The weight percent content of cystine linkage Reducing agent is 1% to 10% in the cystine linkage Reducing agent mastic; Suitable content is 3% to 8%; Wherein the cystine linkage Reducing agent of indication can be D; The derivant of L-NAC and its esters, NAC (N-acetyl group-D; The L-NAC), mercapto acetic acid or its esters and esters, 2-mercaptopropionic acid and its esters, sulfurous acid and its esters, ascorbic acid and its esters, left-handed vitamin C and its esters, also comprise the above compound compositions, above-described reagent be the present technique field known all be included in.It is main between the 8.0-9.0 that the use amount of alkaline agent is adjusted to the pH value with the product mastic, and actual use amount is looked the character of alkaline agent and decided, and wherein the alkaline agent of indication is same as described above.Hair dye of the present invention can be modulated into the preparation pattern of water preparation, emulsion, emulsifiable paste, cream, gel, paste, foam type, aerosol type, shampoo.

(3) optimal conditions of metal mordant dyeing Permanent Hair Dyeing Agent product

This hair dye can be divided into three dosage forms and two dosage form products; First dose of three dosage form products is cystine linkage Reducing agent mastic; The effect of this agent is to interrupt cystine linkage makes the hair scale sheet open the pigment molecular entering hair cortex layer in order to following potion, if but the hair of preparing to have hair dyed is hair color or other dark hairs, then this agent can change the general so-called agent (hair melanin stripping agent) of floating; The purpose of floating agent is that the melanin of hair is desalinated yellowly earlier to coffee-like color development; Another effect of floating agent is to interrupt cystine linkage the hair scale sheet is opened, and this two effect can help down the potion metal ion to get into cortical layer smoothly, and second dose be hypotoxic metal ion mastic; The 3rd dose is pigment stain mastic, and first dose, second dose, the 3rd dose mastic is according to using in order during hair dyeing.First dose of two dosage form products is the mixing paste of metal ion and cystine linkage Reducing agent; Metal ion can be the mastic that separates with the cystine linkage Reducing agent; And use after just directly mixing these two doses of mastic before use; Alkaline agent will be looked the type of cystine linkage Reducing agent and add, and second dose is pigment stain mastic, and first dose, second dose mastic is according to using in order during hair dyeing.Pigment source comprises natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors; The pigment weight percent content is 1% to 10% in the pigment mastic, and suitable content is 2% to 5%.Wherein the metal ion of indication comprises metallic salts such as hypotoxic magnesium, aluminum, ferrum, zinc, and in this field institute well known all was included in, the weight percent content of metal ion was 1% to 10%, and suitable content is 2% to 5%.The weight percent content of cystine linkage Reducing agent is 1% to 10% in the cystine linkage Reducing agent mastic, and suitable content is 3% to 8%, wherein the cystine linkage Reducing agent of indication with above-mentioned shown in the person identical, wherein the alkaline agent of indication with above-mentioned shown in the person identical.Hair dye of the present invention can be modulated into the preparation pattern of water preparation, emulsion, emulsifiable paste, cream, gel, paste, foam type, aerosol type, shampoo.

(4) optimal conditions of ionic bond method semi-permanent hairdye product

This hair dye has only a dosage form product; Mainly contain anion or cation pigment, also contain hair extender, penetration enhancer in addition in the mastic, moreover; Anion-containing pigment can add sour agent and promote hair dyeing effect; The pigment of cation then can add alkaline agent and promote hair dyeing effect, and hair-dryer also capable of using or steam engine promote hair dyeing effect to the physics mode of hair heating, directly uses during hair dyeing to get final product.Pigment source comprises have anion or cationic natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors; The pigment weight percent content is 1% to 10% in the pigment mastic, and suitable content is 2% to 5%.Wherein the acid of indication can be organic acid and mineral acid; Its use amount is looked acid the matter of use and is decided; But to being main between the 2.0-6.0, instance example hydrochloric acid, tartaric acid, citric acid, phosphoric acid are in present technique field institute well known all is included in target with the pH value of adjustment mastic.Wherein the alkali of indication can be organic base and inorganic base, the type of alkaline agent with aforementioned shown in the person identical.Its use amount is looked alkaline agent character and is decided, but target with the pH value of adjustment mastic to being main between the 8.0-10.0.Wherein the extender of indication, penetration enhancer with aforementioned shown in the person identical, its weight percent content is 3% to 20%, suitable content is 5% to 15%, above-described reagent is in present technique field institute well known all is included in.Hair dye of the present invention can be modulated into the preparation pattern of water preparation, emulsion, emulsifiable paste, cream, gel, paste, foam type, aerosol type, shampoo.

(5) optimal conditions of the temporary hair dye product of absorption method

This hair dye has only a dosage form product, mainly is the mastic that contains pigment, directly uses during hair dyeing to get final product.Pigment source comprises natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors; The pigment weight percent content is 1% to 10% in the pigment mastic, and suitable content is 2% to 5%.Hair dye of the present invention can be modulated into the preparation pattern of water preparation, emulsion, emulsifiable paste, cream, gel, paste, foam type, aerosol type, shampoo.

Except above-mentioned; Corresponding its prescription demand; In the scope of not damaging effect of the present invention; Can use in the hair dye general employed other composition, so composition can be enumerated like water soluble polymer such as plant extract, cationic, anionic property, nonionics such as cation interfacial active agent, teepol, non-ionic surfactant, both sexes interfacial agent, lanolin derivative, protein derivatives, oils, fat, wax, hydrocarbon, polyhydric alcohol, ester, amide, wetting agent composition, Chinese medicine and polymer, viscosity/gelling thickener, low-carbon alcohols solvent, vitamin, amino acid, metal ion and block agent, antiseptic, antibacterial, pH adjustment agent, penetrant, UV absorbent, antioxidant, coloring agent, spice etc.

The hair dye that the present invention developed has used natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or the cosmetic colors of high security; Purpose be replace genotoxicity is arranged at present, carcinogenecity, hypersensitive chemical hair dye; Make human body when using hair dye, needn't worry toxicity and anaphylaxis problem again; Therefore hair and all relieved this type of hair dye of use of skin, in addition human body such as beard, eyebrow, skin, lip, fingernail etc. all in the scope of application.Various hair colouring methods among the present invention also make natural pigment (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or the hair dye of cosmetic colors made can reach standard in the market; Comprise washability, persistency, convenience, rapidity etc., some in addition surmount present use standard.Natural pigment among the present invention (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors be according to the selection of employed kind of pigment, stain prescription, hair colouring methods, all can reach the target of permanent, semipermanent, temporary hair dye easily.And, also can be made into products such as cream rinse, hair dyeing emulsion, hair dyeing frost, hair dyeing gel, hair dyeing paste, hair dyeing shampoo, foam type hair dye, spray-type hair-dyeing agent according to the dosage form demand.In the specialities aspect, the natural pigment among the present invention (edible and cosmetic use), synthetic dyestuff (edible and cosmetic use) or cosmetic colors can be made into to dye scalds two-in-one and with the hair dye of pH value variable color.The hair dye color of being developed among the present invention can utilize the hybrid mode of drawing pigment to allocate; For example utilize five kinds of red, yellow, blue, black, antholeucins; Even the pigment that can add more kinds of other colors carries out hybrid modulation, can create the required shades of colour hair dye in market, and then has hair dyed with predetermined hair colouring methods; More employed various hair dyes more possess advantage, simplicity, convenience and creativeness than in the market in this measure; Obvious, this advantage has surmounted present hair dye basis, makes hair dye will march toward new milestone.

Following examples will specify the present invention, but the invention is not restricted to these embodiment.

One, the embodiment of oxygen method Permanent Hair Dyeing Agent product

(1) hair dye is formed

First dose of composition: food coloring mastic; Second dose of composition: 6% dioxygen breast; The 3rd dose of composition: MEA and potassium peroxydisulfate.

(2) stain mastic:

Five kinds of yellow No. 102 (FD&C Yellow No.5), orange No. 103 (FD&C Yellow No.6), red No. 104 (Acid Red 18), carmetta No. 105 (FD&C Red No.3), blue No. 106 (FD&C Blue No.1) etc.

(3) hair colouring methods and step

Hair colouring methods and step (I): stir subsequent use with the 3rd dose with the predetermined ratio back that is mixed with second dose.With Hair-dyeing brush every hair is evenly smeared above-mentioned blended stain, stop after 20 minutes, the stain so that Warm Wash is decaptitated and sent out then evenly is coated with every hair with Hair-dyeing brush and spreads first dose, stops after 20 minutes, and i.e. completion is had hair dyed after re-using shampoo and cleaning.

Hair colouring methods and step (II): stir subsequent use with the predetermined ratio back that is mixed with first dose, second dose, the 3rd dose.With Hair-dyeing brush with every hair evenly be coated with spread blended stain after, stop after 20～30 minutes, earlier with the Warm Wash stain on sending out of decaptitating, promptly accomplish hair dyeing after re-using shampoo and cleaning.

Hair colouring methods and step (III): stir subsequent use with the 3rd dose with the predetermined ratio back that is mixed with second dose.With Hair-dyeing brush every hair is evenly smeared above-mentioned blended stain, stop after 10 minutes, do not clean, directly every hair evenly is coated with and spreads first dose, stop after 20 minutes, promptly accomplish hair dyeing after re-using shampoo and cleaning with Hair-dyeing brush.

(4) test hair: poliosis and hair color

(5) hair dye mastic prescription: as shown in table 11.

Have hair dyed according to hair colouring methods and the step of I, II, III with above-mentioned 5 kinds of target pigment mastic; The hair of test is divided into white hair and black hair, accomplish hair dyeing after, with the above-mentioned topknot of commercial shampoo repeated washing 30 times; Again with the drier hair; And according to dying afterwards color, stainability, the color anelasticity of following standard with this topknot of visual means evaluation, assessment method is as shown in table 12, and final assessment result is as shown in table 13.

Table 11. oxygen method Permanent Hair Dyeing Agent mastic prescription (percentage by weight)

Composition/dosage form	First dose (%)	Second dose (%)	The 3rd dose (%)
				Food coloring	5
Polyoxyethylene laurel ether	6
				Polyoxyethylene (30) lanoline	2
Hexadecanol	1.5
				Propylene glycol	5
Hexadecyltrimethylammonium chloride	1.5
				Oleic acid	10
Water	Surplus
				Hydrogen peroxide (30%)		20
Hexadecanol		1.5
				Polyoxyethylene laurel ether		3
Phosphoric acid		0.1
				Sodium stannate		0.02
Water		Surplus
				MEA (g)			2
Potassium peroxydisulfate (g)			10

The assessment method of table 12. hair dye and explanation

C

Compare with the topknot before the hair washing, can see the phenomenon of fading in a large number

The test result of table 13. oxygen method Permanent Hair Dyeing Agent

Can know by table 13 result; Method I, II, III have hair dyed, and mode is resulting to come to the same thing; All belong to Permanent Hair Dyeing Agent; With poliosis test hair dyeing to dye the back color identical with employed food coloring stain color, if with the dying the back color and can form secondary colour yellow and the stain color of hair color test hair dyeing, this is because 6% dioxygen breast can only fade to yellow or brown to the fading extent of dark hair; Color development behind the therefore after stain can form secondary colour, and this is the normal result that this field person is known.

Two, the embodiment of cystine linkage method reducing process Permanent Hair Dyeing Agent product

(1) hair dye is formed: food coloring mastic, cystine linkage Reducing agent, alkaline agent.

(2) stain: five kinds of yellow No. 102 (FD&C Yellow No.5), orange No. 103 (FD&C Yellow No.6), red No. 104 (Acid Red 18), carmetta No. 105 (FD&C Red No.3), blue No. 106 (FD&C Blue No.1) etc.

(3) hair colouring methods and step: with Hair-dyeing brush with every hair evenly be coated with spread the hair dye mastic after, directly stopped 20 minutes, if the hair that will have hair dyed is hair color or dark hair; Then add with 6% dioxygen breast earlier and float agent; Hair melanin is faded to yellow or brown (float agent stop be 30 minutes), must wash away with clear water after the end and float agent, again with Hair-dyeing brush with every hair evenly be coated with spread the hair dye mastic after; The time of staying is 20 minutes; In retention period hair-dryer also capable of using or steam engine hair is heated, then decaptitate behind this mastic on sending out, promptly accomplish hair dyeing after re-using shampoo and cleaning with Warm Wash.

(4) test hair: poliosis

(5) hair dye mastic prescription: as shown in table 14.

Have hair dyed according to hair colouring methods and step with above-mentioned 5 kinds of target pigment mastic; With the white hair test of having hair dyed; Accomplish the hair dyeing back with the above-mentioned topknot of commercial shampoo repeated washing 30 times,, and dying back color, stainability, color anelasticity with this topknot of visual means evaluation according to following standard again with the drier hair; Assessment method is as shown in table 12, and final assessment result is as shown in Tble 15.

Table 14. cystine linkage method reducing process Permanent Hair Dyeing Agent prescription

Composition	Percentage by weight (%)
		Food coloring	5
NAC	5
		Polyoxyethylene laurel ether	6
Polyoxyethylene (30) lanoline	2
		Hexadecanol	1.5
Propylene glycol	5
		Hexadecyltrimethylammonium chloride	1.5
MEA	4
		Water	Surplus

The test result of table 15. cystine linkage method reducing process Permanent Hair Dyeing Agent

Can know that by table 15 fruit the resulting result that has hair dyed belongs to Permanent Hair Dyeing Agent, afterwards color is identical with employed food coloring stain color to test dying of having hair dyed with poliosis.

Three, the embodiment of metal mordant dyeing Permanent Hair Dyeing Agent product

(1) hair dye is formed

First dose of composition: poliosis this agent of when test is the cystine linkage Reducing agent, and this agent is that 6% dioxygen breast adds and floats agent during the hair color test; Second dose of composition: metal ion mastic, embodiment are iron sulfate, magnesium chloride, iron chloride; The 3rd dose of composition: food coloring mastic.

(3) hair colouring methods and step

1. after with Hair-dyeing brush every hair evenly being coated first dose (cystine linkage Reducing agent mastic) earlier; Directly stopped 10 minutes; If hair color test; In retention period hair-dryer also capable of using or steam engine hair is heated, then, also can clean and directly carry out next step with Warm Wash this mastic on sending out of decaptitating.If the hair that will have hair dyed is hair color or dark hair, then this agent changes 6% dioxygen breast into and adds and float agent, and floating that agent stops is 30 minutes, must wash away with clear water after the end and float agent.

(4) test hair: poliosis and hair color.

(5) hair dye mastic prescription: shown in table 16.

Have hair dyed according to hair colouring methods and step with above-mentioned 5 kinds of target pigment mastic; With the test of having hair dyed of white hair and dark hair; Accomplish the hair dyeing back with the above-mentioned topknot of commercial shampoo repeated washing 30 times,, and dying back color, stainability, color anelasticity with this topknot of visual means evaluation according to following standard again with the drier hair; Assessment method is as shown in table 12, and final assessment result is shown in table 17.

Table 16. metal mordant dyeing Permanent Hair Dyeing Agent prescription

Composition/dosage form	First dose (%)	Second dose (%)	The 3rd dose (%)
				Metal ion	3
Sodium carboxymethyl cellulose	1.2
				Sodium lauryl sulphate	2
Propylene glycol	10
				Triethanolamine	0.2
Water	Surplus
				NAC		5
Polyoxyethylene laurel ether		6
				Polyoxyethylene (30) lanoline		2
Hexadecanol		1.5
				Propylene glycol		5
Hexadecyltrimethylammonium chloride		1.5
				MEA		4
Water		Surplus
				Food coloring			5
Polyoxyethylene laurel ether			6
				Polyoxyethylene (30) lanoline			2
Hexadecanol			1.5
				Propylene glycol			5
Hexadecyltrimethylammonium chloride			1.5
				Oleic acid			10
Water			Surplus

The test result of table 17. metal mordant dyeing Permanent Hair Dyeing Agent

Can know by table 17 result; The hair dyeing of being carried out with three kinds of different metal ions is tested resulting result and is all belonged to Permanent Hair Dyeing Agent; Afterwards color is identical with employed food coloring stain color to test dying of having hair dyed with poliosis; As if the dying secondary colour that the back color can form yellow and stain color with hair color test hair dyeing, it is master's hair dyeing test fruit that The above results occurs in aluminum sulfate and magnesium chloride, and identical with oxygen method result of the test; This is that the color development behind the therefore after stain can form secondary colour because 6% dioxygen breast can only fade to yellow or brown to the fading extent of dark hair; But with iron chloride be main hair dyeing test its dye the back color can be than the former two for dark, this is because the iron chloride intrinsic colour is caused by yellowish-brown, so can deepen the color after hair dyes, this result belongs to normal result.

Four, the embodiment of ionic bond method semi-permanent hairdye product

(1) hair dye is formed: anion food coloring, hair extender, penetration enhancer, sour agent.

(4) test hair: poliosis

(5) hair dye mastic prescription: shown in table 18.

Have hair dyed according to hair colouring methods and step with above-mentioned 5 kinds of target pigment mastic; With the white hair test of having hair dyed; Accomplish the hair dyeing back with the above-mentioned topknot of commercial shampoo repeated washing 15 times,, and dying back color, stainability, color anelasticity with this topknot of visual means evaluation according to following standard again with the drier hair; Assessment method is as shown in table 12, and final assessment result is shown in table 19.

Table 18. ionic bond method semi-permanent hairdye prescription

Composition	Percentage by weight (%)
		Food coloring	5
Isopropyl alcohol	5
		Benzyl alcohol	5
Polyoxyethylene laurel ether	6
		Polyoxyethylene (30) lanoline	2
Propylene glycol	5
		Hexadecyltrimethylammonium chloride	1.5
Citric acid	1
		Water	Surplus

The test result of table 19. ionic bond method semi-permanent hairdye

Can be known that by table 19 result the resulting result that has hair dyed belongs to semi-permanent hairdye, afterwards color is identical with employed food coloring stain color to test dying of having hair dyed with poliosis.

Five, the pigment mastic colour mixture of five primaries modulation embodiment

(1) hair dye is formed: the composition according to oxygen method, cystine linkage reducing process, metal mordant dyeing is modulated.

(2) stain: mix with the reservation ratio according to yellow No. 102 (FD&C Yellow No.5), orange No. 103 (FD&C Yellow No.6), red No. 104 (Acid Red 18), carmetta No. 105 (FD&C Red No.3), blue No. 106 five kinds of basic colors such as (FD&C Blue No.1), shown in table 20.

(3) hair colouring methods and step: the hair dyeing step according to oxygen method, cystine linkage reducing process, metal mordant dyeing is had hair dyed respectively.

(4) test hair: poliosis and hair color.

The stain mastic that utilizes in the table 20 to be modulated is had hair dyed according to the step of oxygen method, cystine linkage reducing process, metal mordant dyeing; With the test of having hair dyed of white hair and dark hair; Accomplish the hair dyeing back with the above-mentioned topknot of commercial shampoo repeated washing 30 times,, and dying back color, stainability, color anelasticity with this topknot of visual means evaluation according to following standard again with the drier hair; Assessment method is as shown in table 12, and final assessment result is shown in table 21.

Table 20. table that mixes colours

The test result of the pigment mastic colour mixture modulation hair dye of table 21. five primaries

Can know that by table 21 result the stain after the modulation colour mixture uses any hair colouring methods all can dye smoothly to poliosis and hair color, dye back color and various hair colouring methods gained and come to the same thing, the indifference opposite sex, and all belong to Permanent Hair Dyeing Agent.

Six, dye, scald the embodiment of two-in-one product

(1) two dosage form is dyed, is scalded two-in-one product and forms

First dose: food coloring mastic, cystine linkage Reducing agent, alkaline agent; Second dose: cystine linkage oxidant (6% dioxygen breast).

(2) stain: No. 105, carmetta (FD&C RedNo.3); Or black stain.

The modulator approach of this black stain is following: yellow No. 102 (FD&C Yellow No.5): No. 103, orange (FD&C Yellow No.6): red No. 104 (Acid Red 18): the ratio of blue No. 106 (FD&C Blue No.1) is 4: 2: 4: 2.

(3) dye, method for permanent waving hair and step: use thermoplastic method, powder stick method, three kinds of methods of cold wave method to test, operating procedure is shown in table 22.

(4) test hair: poliosis and hair color.

(5) mastic prescription: shown in table 23 and 23-1.

(6) test effect: shown in table 23-2 and 23-3.

Table 22. thermoplastic method, powder stick method, cold wave method operating procedure

Method for permanent waving hair/step	The thermoplastic method	The powder stick method	The cold wave method
				Step 1	Hair washing	Hair washing	Hair washing
Step 2	Last first dose	Last first dose	Last first dose
				Step 3	Bath	Last steamed roll	Bath
Step 4	Last steamed roll	Adding thermoplastic does	Last steamed roll
				Step 5	Adding thermoplastic does	Last second dose	Last second dose
Step 6	Last second dose	Unreel	Unreel
				Step 7	Unreel	Flushing	Flushing
Step 8	Flushing

Two-in-one formula for a product (embodiment 12,13,14) is dyed, scalded to table 23. two dosage forms

Two-in-one formula for a product (embodiment 12-1,13-1,14-1) is dyed, scalded to table 23-1. two dosage forms

Table 23-2. uses No. 105 stains of carmetta

Table 23-3. uses synthetic black stain

Seven, the embodiment of foam hair dye

(1) composition of foam hair dye

(I) dosage form: food coloring mastic, foaming agent, alkaline agent.

(II) two dosage forms: first dose: food coloring mastic, foaming agent, alkaline agent.Second dose: 6% dioxygen breast.

(2) operating procedure

(I) a dosage form operating procedure: the stain mastic is poured in the bottle, shaken bottle 30 seconds, putting on one's gloves spreads upon foam on the hair; Foam was directly stopped 30 minutes,, then add with 6% dioxygen breast earlier and float agent if the hair that will have hair dyed is hair color or dark hair; Hair melanin is faded to yellow or brown (floating the agent stop is 30 minutes); Must wash away with clear water after the end and float agent, putting on one's gloves spreads upon the stain foam on the hair, and foam was directly stopped 30 minutes; Then decaptitate behind this mastic on sending out, promptly accomplish hair dyeing after re-using shampoo and cleaning with Warm Wash.

(II) two dosage form operating procedures: the stain mastic of bottle 1 is poured in the bottle 2; Shook bottle 30 seconds, putting on one's gloves spreads upon foam on the hair, and foam was directly stopped 30 minutes; Then decaptitate behind this mastic on sending out, promptly accomplish hair dyeing after re-using shampoo and cleaning with Warm Wash.

(3) mastic prescription: shown in table 24.

Table 24. foam hair dye prescription (embodiment 15)

Hexadecanol	1.5
		Polyoxyethylene laurel ether	3
Phosphoric acid	0.1
		Sodium stannate	0.02
Water	Surplus

Eight, the embodiment of hair dyeing shampoo

(1) composition of hair dyeing shampoo

First dose: food coloring, teepol, antioxidant, alkaline agent.

Second dose: 6% dioxygen breast.

(2) operating procedure: with water hair is drenched earlier, then first dose is poured on hand and mixes with second dose, with the hair washing mode above-mentioned mastic is had one's hair wash on hair, a shampoo of following on decaptitating with Warm Wash is promptly accomplished hair dyeing.

(3) mastic prescription: as shown in Tble 25.

Table 25. hair dyeing shampoo prescription (embodiment 16)

Composition	First dose (%)	Second dose (%)
			Food coloring	5
Methyl sodiosul foaliphatate	5
			Polyoxyethylenated alcohol sodium sulfate	12
Oleum Cocois ethylene glycol amide	2
			Different anti-hematic acid	0.5
Sodium sulfite	0.5
			Triethanolamine	4
Water	Surplus
			Hydrogen peroxide (30%)		20
Hexadecanol		1.5
			Polyoxyethylene laurel ether		3
Hexadecyltrimethylammonium chloride		1.5
			Phosphoric acid		0.1
Sodium stannate		0.02
			Water		Surplus

Nine, can be with the hair dye embodiment of pH value variable color

(2) use pigment: uva skin pigment (color change interval: red), carmine pigment (color change interval: red), kermes citraurin (color change interval: yellow) to orange to orange to purple.

(4) test hair: poliosis.

(5) pH buffer solution: pH=2.0, pH=4.0, pH=7.0, pH=9.0.

Modulate the hair dye mastic with uva skin pigment, carmine pigment, annatto pigment; And have hair dyed according to the step of oxygen method, cystine linkage reducing process, metal mordant dyeing; With the white hair test of having hair dyed, accomplish the hair dyeing back with the above-mentioned topknot of commercial shampoo repeated washing 30 times, again with the drier hair; Then be sprayed on the topknot after the hair dyeing with different pH buffer solution; With the drier hair, with the dying back color of this topknot of visual means evaluation, final assessment result is shown in table 26 again.

Table 26. can be with the test result of the hair dye of pH value variable color

Can know that by table 26 result the color change interval of hair color is identical with the character of pigment molecular, and can repeated multiple times and colour-fast through this variable color character of experiment confirm.

Ten, with the cosmetic colors be the embodiment of master's oxygen method Permanent Hair Dyeing Agent product

(1) hair dye is formed

First dose of composition: cosmetic colors mastic; Second dose of composition: 6% dioxygen breast; The 3rd dose of composition: MEA and potassium peroxydisulfate.

(2) stain mastic: D&C yellow No. 10 (D&C Yellow No.10), external D&C orange No. 3 (Ext.D&C Orange No.3), FD&C red No. 4 (FD&C Red No.4), D&C blue No. 6 (D&C Blue No.6) etc. are four kinds; More than the adding proportion of 4 kinds of cosmetic colors be 1: 1: 1: 2; Resulting color is an aeruginous after the colour mixture, and its Panton color number is 5467C.

(3) hair colouring methods and step

(4) test hair: poliosis and hair color

(5) hair dye mastic prescription: shown in table 27.

Have hair dyed according to hair colouring methods and the step of I, II, III with above-mentioned 5 kinds of target pigment mastic; The hair of test is divided into white hair and black hair, accomplish hair dyeing after, with the above-mentioned topknot of commercial shampoo repeated washing 30 times; Again with the drier hair; And according to dying afterwards color, stainability, the color anelasticity of following standard with this topknot of visual means evaluation, assessment method is shown in table 28, and final assessment result is shown in table 29.

Table 27. oxygen method Permanent Hair Dyeing Agent mastic prescription

Composition/dosage form	First dose (%)	Second dose (%)	The 3rd dose (%)
				Yellow No. 10 of D&C	0.5
No. 3, external D&C orange	0.5
				Red No. 4 of FD&C	0.5
Blue No. 6 of D&C	2
				Polyoxyethylene laurel ether	6
Polyoxyethylene (30) lanoline	2
				Hexadecanol	1.5
Propylene glycol	5
				Hexadecyltrimethylammonium chloride	1.5
Oleic acid	10
				Water	Surplus
Hydrogen peroxide (30%)		20
				Hexadecanol		1.5
Polyoxyethylene laurel ether		3
				Phosphoric acid		0.1
Sodium stannate		0.02
				Water		Surplus
MEA (g)			2
				Potassium peroxydisulfate (g)			10

The assessment method of table 28. hair dye and explanation

The test result of table 29. oxygen method Permanent Hair Dyeing Agent

Can know that by table 29 result method I, II, III have hair dyed, and mode is resulting to come to the same thing, and all belongs to Permanent Hair Dyeing Agent, dying the back color near aeruginous with what the poliosis test was had hair dyed, can approaching darker aeruginous as if color test dying of hair dyeing with hair color after.

The above embodiment is the preferred embodiment that proves absolutely that the present invention lifts, and protection scope of the present invention is not limited thereto.Being equal to that the technical staff in present technique field is done on basis of the present invention substitutes or conversion, all within protection scope of the present invention.Protection scope of the present invention is as the criterion with claims.

Claims

1. a hair dye is characterized in that, comprises

(b) scared scale is opened agent.

2. hair dye as claimed in claim 1 is characterized in that, said hair dye is Permanent Hair Dyeing Agent, semi-permanent hairdye or temporary hair dye.

3. hair dye as claimed in claim 2 is characterized in that, said hair dye is a Permanent Hair Dyeing Agent.

4. hair dye as claimed in claim 3 is characterized in that, comprises

(a) as the synthetic dyestuff of the edible and cosmetic use of stain;

(b) open inorganic peroxide, organic peroxide, the cystine linkage Reducing agent of agent or float agent as scared scale;

And arbitrarily selectively

(c) metal ion and/or alkaline agent.

5. hair dye as claimed in claim 4 is characterized in that, said edible synthetic dyestuff with cosmetic use be one or more combination in any in No. 106, yellow No. 102, No. 103, orange, red No. 104, No. 105, carmetta and the blueness.

6. hair dye as claimed in claim 4 is characterized in that, said inorganic peroxide is hydrogen peroxide or hydrogen peroxide.

7. hair dye as claimed in claim 4; It is characterized in that; Said cystine linkage Reducing agent is D, one or more combination in any in the derivant of L-NAC or its esters, NAC, mercapto acetic acid or its salt or ester, 2-mercaptopropionic acid or its salt, sulfurous acid or its salt, ascorbic acid or its salt and left-handed vitamin C or its salt.

8. hair dye as claimed in claim 4 is characterized in that, said metal ion is the cation of magnesium, aluminum, ferrum or zinc.

9. hair dye as claimed in claim 4 is characterized in that, said alkaline agent is inorganic base or organic base.

10. hair dye as claimed in claim 3 is characterized in that, comprises

(a) as the cosmetic colors of stain;

(c) alkaline agent.

11. hair dye as claimed in claim 10 is characterized in that, said cosmetic colors is one or more combination in any among blue No. 6 of yellow No. 10 of D&C, No. 3, external D&C orange, FD&C red No. 4 and the D&C.

12. hair dye as claimed in claim 10 is characterized in that, said inorganic peroxide is hydrogen peroxide or hydrogen peroxide.

13. hair dye as claimed in claim 10 is characterized in that, said alkaline agent is inorganic base or organic base.

14. hair dye as claimed in claim 13 is characterized in that, said alkaline agent is a kind of or its combination in MEA and the potassium peroxydisulfate.

15., it is characterized in that said hair dye also comprises hair penetration enhancer and/or hair extender like each described hair dye in the claim 3 to 14.

16. hair dye as claimed in claim 2 is characterized in that, said hair dye is a semi-permanent hairdye.

17. hair dye as claimed in claim 16 is characterized in that, comprises:

(b) sour agent or alkaline agent.

18. hair dye as claimed in claim 17 is characterized in that, said edible synthetic dyestuff with cosmetic use be one or more combination in any in No. 106, yellow No. 102, No. 103, orange, red No. 104, No. 105, carmetta and the blueness.

19. hair dye as claimed in claim 17 is characterized in that, said sour agent is mineral acid or organic acid, and said alkaline agent is inorganic base or organic base.

20., it is characterized in that said hair dye also comprises hair penetration enhancer and/or hair extender like each described hair dye in the claim 16 to 19.

21. hair dye as claimed in claim 2 is characterized in that, said hair dye is temporary hair dye.

22. hair dye as claimed in claim 21 is characterized in that, comprises the synthetic dyestuff as the edible and cosmetic use of stain; And arbitrarily selectively

(a) alkaline agent; Or

(b) hydrogen peroxide or hydrogen peroxide.

23. hair dye as claimed in claim 22 is characterized in that, said edible synthetic dyestuff with cosmetic use be one or more combination in any in No. 106, yellow No. 102, No. 103, orange, red No. 104, No. 105, carmetta and the blueness.

24. hair dye as claimed in claim 22 is characterized in that, said alkaline agent is inorganic base or organic base.

25. hair dye as claimed in claim 2; It is characterized in that said hair dye is cream rinse, hair dyeing emulsion, hair dyeing frost, hair dyeing gel, hair dyeing paste, hair dyeing shampoo, foam type hair dye, spray-type hair-dyeing agent, hotly joins potion or with the variable color hair dye of pH value variable color with bonded the dying of agent for permanent hair waving.

26. hair dye as claimed in claim 25 is characterized in that, said hair dye is for to hotly join potion with bonded the dying of agent for permanent hair waving.

27. hair dye as claimed in claim 26 is characterized in that, comprises:

(a) cystine linkage Reducing agent;

(b) eating and the cosmetic use synthetic dyestuff as stain; And

(c) cystine linkage oxidant.

28. hair dye as claimed in claim 26; It is characterized in that; Said cystine linkage Reducing agent is D, one or more combination in any in the derivant of L-NAC or its esters, NAC, mercapto acetic acid or its salt or ester, 2-mercaptopropionic acid or its salt, sulfurous acid or its salt, ascorbic acid or its salt and left-handed vitamin C or its salt.

29. hair dye as claimed in claim 26 is characterized in that, said edible synthetic dyestuff with cosmetic use be one or more combination in any in No. 106, yellow No. 102, No. 103, orange, red No. 104, No. 105, carmetta and the blueness.

30. hair dye as claimed in claim 26 is characterized in that, said cystine linkage oxidant is peroxide or hydrogen peroxide.

31. hair dye as claimed in claim 25 is characterized in that, said hair dye is the variable color hair dye with the pH value variable color.

32. hair dye as claimed in claim 31 is characterized in that, comprises:

(a) as the natural pigment of the edible and cosmetic use of stain; And

(b) buffer agent of change pH value.

33. hair dye as claimed in claim 32; It is characterized in that; Saidly edible be uva skin pigment, carmine pigment, kermes citraurin, anthocyanidin, carminic acid, Radix Betae red pigment, vulgaxanthin, santalin, bixin or fall annatto, or contain in the above-mentioned pigment one or more plant pigment or its extract with the cosmetic use natural pigment.

34. hair dye as claimed in claim 32 is characterized in that, the buffer agent of said change pH value is the solution of acid, alkali or its salt of pH value between 2.0 to 10.0.

35. hair dye as claimed in claim 1 is characterized in that, the amount of said stain accounts for 1 to 10% of said hair dye gross weight, and said scared scale is opened agent and accounted for 1 to 12% of said hair dye gross weight.

36., it is characterized in that the amount of said metal ion, sour agent or alkaline agent accounts for 1 to 10% of this hair dye gross weight like each described hair dye in the claim 4,10 and 17.

37. hair dye as claimed in claim 27 is characterized in that, the amount of said cystine linkage oxidant accounts for 1 to 10% of said hair dye gross weight.

38. hair dye as claimed in claim 32 is characterized in that, the amount of the buffer agent of said change pH value accounts for 1 to 10% of said hair dye gross weight.

39. hair dye as claimed in claim 1 is characterized in that, said hair dye also is used for human body beard, eyebrow, skin, lip and fingernail.

40. an oxygen type hair colouring methods is characterized in that, uses each described hair dye in claim 3 to 15 and the claim 26 to 34.

41. oxygen type hair colouring methods as claimed in claim 40 is characterized in that, uses inorganic peroxide or organic peroxide to produce oxygen.

42. oxygen type hair colouring methods as claimed in claim 41 is characterized in that, use be weak base state and weight percent concentration between 3 to 12% dioxygen breast to produce oxygen.

43. oxygen type hair colouring methods as claimed in claim 42 is characterized in that said weak base state is meant pH 7.5-8.5.

44. a cystine linkage reduced form hair colouring methods is characterized in that, uses like each described hair dye in claim the 3 to 15 and the claim 26 to 34.

45. a metal mordant dyeing type hair colouring methods is characterized in that, uses like each described hair dye in claim the 3 to 15 and the claim 26 to 34.

46. metal mordant dyeing type hair colouring methods as claimed in claim 45 is characterized in that employed metal ion is the cation of magnesium, aluminum, ferrum or zinc.

47. an ion of bonding hair colouring methods is characterized in that, uses like each described hair dye in the claim 16 to 20.

48. an absorbent-type hair colouring methods is characterized in that, uses like each described hair dye in the claim 21 to 24.

49. like claim 40,44,45,47,48 each described methods, it is characterized in that, also be applied to human body beard, eyebrow, skin, lip, fingernail.