CN102435038A - Pesticide degradation subassembly for refrigerator and refrigerator with same - Google Patents

Pesticide degradation subassembly for refrigerator and refrigerator with same Download PDF

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Publication number
CN102435038A
CN102435038A CN2011102692183A CN201110269218A CN102435038A CN 102435038 A CN102435038 A CN 102435038A CN 2011102692183 A CN2011102692183 A CN 2011102692183A CN 201110269218 A CN201110269218 A CN 201110269218A CN 102435038 A CN102435038 A CN 102435038A
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China
Prior art keywords
refrigerator
fruit
degradation
pesticide
vegetable box
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CN2011102692183A
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Chinese (zh)
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CN102435038B (en
Inventor
涂瑞丽
潘巨忠
潘舒伟
吕正光
江敏
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Hefei Hualing Co Ltd
Hefei Midea Refrigerator Co Ltd
Original Assignee
Hefei Hualing Co Ltd
Hefei Midea Rongshida Refrigerator Co Ltd
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Priority to CN2011102692183A priority Critical patent/CN102435038B/en
Publication of CN102435038A publication Critical patent/CN102435038A/en
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Abstract

The invention discloses a refrigerator and a pesticide degradation subassembly for the refrigerator. The pesticide degradation subassembly comprises an atomizing device. The atomizing device is arranged in a refrigerating chamber and comprises a water tank, a cover body, a piezoelectric ceramic oscillator, a water absorber and the pesticide degradation subassembly, wherein a containing space for containing water is defined inside the water tank, and the top of the water tank is opened; the cover body is detachably arranged at the top of the water tank; the piezoelectric ceramic oscillator is arranged on the cover body; the water absorber abuts against the piezoelectric ceramic oscillator through a spring and is used for absorbing water in the water tank until the water is in contact with the piezoelectric ceramic oscillator; and the pesticide degradation subassembly is arranged in the refrigerating chamber of the refrigerator. According to the pesticide degradation subassembly in the embodiment of the invention, the pesticide degradation efficiency is high and no secondary pollution exists, thereby improving the use security of foods. In addition, the storage humidity can be improved to prolong refreshing time and improve a refreshment effect. Furthermore, by arranging the pesticide degradation subassembly in the refrigerator, the functions of refrigerating and refreshing of the refrigerator are combined with the technology of removing pesticides in a degradation manner so that the practical applicability and the convenience are improved.

Description

Be used for the degradation of pesticide assembly of refrigerator and have its refrigerator
Technical field
The present invention relates to art of refrigeration units, especially relate to a kind of refrigerator that is used for the degradation of pesticide assembly of refrigerator and has it.
Background technology
Traditional degrading pesticide technology majority for the fruits and vegetables article is the method that adopts soak with ozone solution to clean.Ozone has strong oxidizing property, can the oxidation Decomposition agricultural chemicals, though can decomposing agricultural chemicals, strong oxidizing property simultaneously fruits and vegetables tissue and nutritional labeling are also had certain influence.
In the life, refrigerator be the food first being processed store operation at last together, if the effect of agricultural chemicals can integratedly be fallen in refrigerator on original fresh-keeping basis, still all significant for refrigerator enterprise for the user.
Summary of the invention
The present invention is intended to solve at least one of technical problem that exists in the prior art.
For this reason, one object of the present invention is to propose a kind of degradation of pesticide assembly that is used for refrigerator, and the degradation of pesticide rate of said degradation of pesticide assembly is high.
Another object of the present invention is to propose a kind of refrigerator with above-mentioned degradation of pesticide assembly.
A kind of degradation of pesticide assembly that is used for refrigerator according to first aspect present invention embodiment; Comprise: atomising device; Said atomising device be located in the refrigerating chamber of said refrigerator and the postnotum setting of contiguous said refrigerator be suitable for in the fruit and vegetable box that is sent to refrigerator behind the water ultrasonic atomization so that the agricultural chemicals on the fruits and vegetables article in the said fruit and vegetable box is separated out; Said atomising device comprises: water tank, limit the spatial accommodation that holds water in the said water tank, and the open-top of said water tank; Lid, said lid removably is located at the top of said water tank; Piezoelectric ceramic vibrator, said piezoelectric ceramic vibrator are installed on the said lid; And absorbent member, said absorbent member offsets with said piezoelectric ceramic vibrator through spring and the water in the said water tank is absorbed to contacting with said piezoelectric ceramic vibrator; And the degradation of pesticide device, said degradation of pesticide device is located in the refrigerating chamber of said refrigerator so that the agricultural chemicals on the fruit in the said fruit and vegetable box is degraded.
The degradation of pesticide assembly that is used for refrigerator according to the embodiment of the invention; Respectively the agricultural chemicals on the fruits and vegetables article in the fruit and vegetable box is separated out and degrade through adopting atomising device and degradation of pesticide device; Residues of pesticides have been reduced greatly; The degradation of pesticide rate is high, and non-secondary pollution, thereby has improved the safety in utilization of food.In addition, can improve storage humidity after the atomizing in the fruit and vegetable box, prolong storage period, and anion and free radical that atomizing produces can play bactericidal action, the raising fresh-keeping effect simultaneously.Further; Through the degradation of pesticide assembly is set in refrigerator, the technology of refrigeration, fresh-keeping function and the degraded of refrigerator being removed agricultural chemicals combines, in other words; Both had deepfreeze and prolonged fresh keeping time; Can remove agricultural chemicals again, improve effect of food preservation and edible safety, thereby improving life practicality and convenience.
In addition, degradation of pesticide assembly according to the present invention also has following additional technical feature:
Said absorbent member is a sponge strip.
Said degradation of pesticide device comprises: adsorption layer, contain the catalyst catalyst that is useful on degrading pesticide on the said adsorption layer, and said adsorption layer is suitable for removably being located on the diapire in the said fruit and vegetable box; With the uviol lamp group, the below that said uviol lamp group is suitable for being located at said fruit and vegetable box is to shine said adsorption layer.
According to the degradation of pesticide assembly of the embodiment of the invention, through adopting the irradiation of uviol lamp group the catalyst catalyst is degraded to agricultural chemicals, efficiency far is higher than the degradation effect of the method for traditional soak with ozone solution cleaning.In addition, adsorption layer removably on the diapire in the fruit and vegetable box, brings back to life so that can take out to clean, and prolonging and to keep the catalyst catalyst activity, thereby can prolong the service life of adsorption layer and provides cost savings.
Alternatively, said uviol lamp group comprises a plurality of uviol lamps, and said a plurality of uviol lamps are arranged with the capable M row of N, wherein, and N >=1, M >=1.
Perhaps alternatively, said uviol lamp group comprises a plurality of uviol lamps, and said a plurality of uviol lamps are configured to circular arrangement.
Said ultraviolet wavelength is approximately 250nm.
Refrigerator according to second aspect present invention embodiment comprises: refrigerating chamber, and the front side of said refrigerating chamber is opened wide; Be used to open and close the chamber door of said refrigerating chamber; Fruit and vegetable box, said fruit and vegetable box is placed in the said refrigerating chamber, and recess is formed at the bottom of the rear wall of said fruit and vegetable box; According to the described degradation of pesticide assembly that is used for refrigerator of first aspect present invention embodiment, said atomising device is located between the recess of postnotum and said fruit and vegetable box of said refrigerating chamber; Be formed with fog inlet on the roof of wherein said recess, said fog inlet is corresponding to the piezoelectric ceramic vibrator in the said atomising device.
Said atomising device removably is located in the refrigerating chamber of said refrigerator, thereby can dismantle easily to add water, cleaning or maintenance.
The bottom of said fruit and vegetable box is processed by transparent electromagnetic wave transparent material.
Refrigerator according to the embodiment of the invention; Through adopting the degradation of pesticide assembly, i.e. atomising device and degradation of pesticide device, the refrigeration effect that both can bring into play refrigerator thus prolongs storage period; Can the agricultural chemicals on the fruits and vegetables article be shifted and special degraded again; Thereby improved foodsafety, broken through the limitation and the unicity of original degradation technique effectively, aspect practicality, improved a lot.
Additional aspect of the present invention and advantage part in the following description provide, and part will become obviously from the following description, or recognize through practice of the present invention.
Description of drawings
Above-mentioned and/or additional aspect of the present invention and advantage obviously with are easily understood becoming the description of embodiment from combining figs, wherein:
Fig. 1 is the side sectional view according to the refrigerator of the embodiment of the invention;
Fig. 2 is the enlarged drawing of A portion among Fig. 1;
Fig. 3 is the sketch map according to the atomising device of the degradation of pesticide assembly that is used for refrigerator of the embodiment of the invention; With
Fig. 4 is the sketch map of the fruit and vegetable box in the refrigerator shown in Fig. 1.
The specific embodiment
Describe embodiments of the invention below in detail, the example of said embodiment is shown in the drawings, and wherein identical from start to finish or similar label is represented identical or similar elements or the element with identical or similar functions.Be exemplary through the embodiment that is described with reference to the drawings below, only be used to explain the present invention, and can not be interpreted as limitation of the present invention.
In description of the invention; It will be appreciated that; Term " on ", the orientation of indications such as D score, " preceding ", " back ", " left side ", " right side ", " vertically ", " level ", " top ", " end ", " interior ", " outward " or position relation be for based on orientation shown in the drawings or position relation; Only be to describe with simplifying for the ease of describing the present invention; Rather than the device or the element of indication or hint indication must have specific orientation, with specific azimuth configuration and operation, therefore can not be interpreted as limitation of the present invention.In addition, term " first ", " second " only are used to describe purpose, and can not be interpreted as indication or hint relative importance.
In description of the invention, need to prove that only if clear and definite regulation and qualification are arranged in addition, term " links to each other ", " connection " should be done broad understanding, for example, can be to be fixedly connected, also can be to removably connect, or connect integratedly; Can be mechanical connection, also can be to be electrically connected; Can be directly to link to each other, also can link to each other indirectly through intermediary, can be the connection of two element internals.For those of ordinary skill in the art, can concrete condition understand above-mentioned term concrete implication in the present invention.In addition, in description of the invention, except as otherwise noted, the implication of " a plurality of " is two or more.
Following with reference to a kind of degradation of pesticide assembly that be used for refrigerator of figure 1-Fig. 4 description according to first aspect present invention embodiment, the agricultural chemicals on the fruits and vegetables article that this degradation of pesticide assembly can be used for 400 inside of the fruit and vegetable box in the cold compartment of refrigerator 300 are held is separated out and is degraded.
Degradation of pesticide assembly according to the embodiment of the invention; Comprise atomising device 100 and degradation of pesticide device 200; As depicted in figs. 1 and 2; Atomising device 100 be located in the refrigerating chamber 300 of refrigerator and the postnotum setting of contiguous refrigerators be suitable for in the fruit and vegetable box 400 that is sent to refrigerator behind the water ultrasonic atomization the agricultural chemicals on the fruits and vegetables article in the fruit and vegetable box 400 being separated out and the part degraded, it is interior so that the agricultural chemicals on the fruits and vegetables article in the fruit and vegetable box 400 is further degraded that degradation of pesticide device 200 is located at the refrigerating chamber 300 of refrigerator.
As shown in Figure 3, atomising device 100 comprises water tank 110, lid 120, piezoelectric ceramic vibrator 130 and absorbent member 140, limits the spatial accommodation that holds water and the open-top of water tank 110 in the water tank 110.Lid 120 removably is located at the top of water tank 110, and for example lid 120 is connected through bolt with the top of water tank 110 or buckle connects (as shown in Figure 3), so that to being filled with water in the water tank 110 and cleaning.Piezoelectric ceramic vibrator 130 is installed on the lid 120.Absorbent member 140 offsets with piezoelectric ceramic vibrator 130 through spring 150 and the water in the water tank 110 is absorbed to contact with piezoelectric ceramic vibrator 130, and the water after being beneficial to water tank 110 interior water are carried out ultrasonic atomization and make atomizing is injected in the fruit and vegetable box 400.Alternatively, in example description of the present invention, absorbent member 140 is a sponge strip.Certainly, the present invention is not limited to this, and absorbent member 140 can also be the absorbent material of other types.
When holding water in the water tank 110; The absorbent member 140 that is immersed in the water tank 110 suctions moisture; Thereby absorbent member 140 contacts with piezoelectric ceramic vibrator 130 through spring 150 water is contacted with piezoelectric ceramic vibrator 130; And utilize piezoelectric ceramic vibrator 130 intrinsic supersonic oscillations characteristics, produce resonance through certain oscillating circuit means and piezoelectric ceramic vibrator 130 intrinsic frequencies of oscillation, thereby directly will change into the molecule of 1--3 μ m with the water smoke that piezoelectric ceramic vibrator 130 contacts.Particularly; Behind the Push switch, piezoelectric ceramic vibrator 130 can produce axial mechanical resonance to be changed, and this mechanical resonance variation is transferred to the water surface (being absorbent member 140 upper ends) that is in contact with it again; Make the water surface produce protuberance; And cavitation takes place around the water surface of protuberance, the strong shock wave that cavitation produces and microjet will make the capillary wave of water surface generation finite amplitude with the vibration frequency of piezoelectric ceramic vibrator 130 constantly repeatedly.The wave head of this tensile wave disperses, thereby the countless little droplets of the aerosolizable one-tenth of water are dispersed in the fruit and vegetable box through the fog inlet on the fruit and vegetable box (scheming not shown), shown in the direction of arrow among Fig. 2.
Wherein above-mentioned ultrasonic wave is countless cavitation bubbles because of cavitation produces; These cavitation bubbles produce localized hyperthermia's high pressure and extreme environments such as strong shock wave and microjet in vibration, growth, compression and process of collapse, caused the separating out with portion of hot of organic agricultural chemicals on the fruits and vegetables article in the fruit and vegetable box to be decomposed.In addition; The free radical that localized hyperthermia's high pressure causes hydrone to be cracked into having strong oxidizing property; And the supercritical water with low-k, high diffusibility and high-transmission ability that forms of the hydrone of cavitation bubble superficial layer, all work in coordination with and promoted separating out and degrading of agricultural chemicals.
The degradation of pesticide assembly that is used for refrigerator according to the embodiment of the invention; Respectively the agricultural chemicals on the fruits and vegetables article in the fruit and vegetable box 400 is separated out and degrade through adopting atomising device 100 and degradation of pesticide device 200; Residues of pesticides have been reduced greatly; The degradation of pesticide rate is high, and non-secondary pollution, thereby has improved the safety in utilization of food.In addition, can improve storage humidity after the atomizing in the fruit and vegetable box 400, prolong storage period, and anion and free radical that atomizing produces can play bactericidal action, the raising fresh-keeping effect simultaneously.Further; Through the degradation of pesticide assembly is set in refrigerator, the technology of refrigeration, fresh-keeping function and the degraded of refrigerator being removed agricultural chemicals combines, in other words; Both had deepfreeze and prolonged fresh keeping time; Can remove agricultural chemicals again, improve effect of food preservation and edible safety, thereby improving life practicality and convenience.
In some embodiments of the invention; Degradation of pesticide device 200 comprises adsorption layer 210 and uviol lamp group 220; As depicted in figs. 1 and 2, on adsorption layer 210, contain the catalyst catalyst that is useful on degrading pesticide, adsorption layer 210 is suitable for being located on the diapire in the fruit and vegetable box 400.Alternatively, adsorption layer 210 removably on the diapire in the fruit and vegetable box 400, brings back to life so that can take out to clean, and prolonging and to keep the catalyst catalyst activity, thereby can prolong the service life of adsorption layer 210 and provides cost savings.The below that uviol lamp group 220 is suitable for being located at fruit and vegetable box 400 is to shine adsorption layer 210.That is to say that when fruit and vegetable box 400 was placed on the bottom of refrigerating chamber 300, uviol lamp group 220 should be located on the diapire of refrigerating chamber 300.Alternatively, ultraviolet wavelength is approximately 250nm.
Thus, as shown in Figure 2, when forming from atomising device 100 and be injected in the fruit and vegetable box 400, disperses water smoke;, because the space is narrow and small relatively and airtight in the fruit and vegetable box 400, most of water smoke becomes water droplet in the surface condensation of fruits and vegetables article; When water droplet is agglomerated to enough when big; Just flow to fruit and vegetable box 400 bottoms, take away the agricultural chemicals on fruits and vegetables article surfaces simultaneously, the uviol lamp of below of fruit and vegetable box 400 sent ultraviolet ray and passed the bottom of fruit and vegetable box 400 and be mapped on the adsorption layer 210 that contains the catalyst catalyst this moment; Make the catalyst catalyst begin the agricultural chemicals of degrade residual, thereby further improved foodsafety.
According to the degradation of pesticide assembly of the embodiment of the invention, through adopting 220 irradiations of uviol lamp group the catalyst catalyst is degraded to agricultural chemicals, efficiency far is higher than the degradation effect of the method for traditional soak with ozone solution cleaning.
In examples more of the present invention, uviol lamp group 220 comprises a plurality of uviol lamps, and a plurality of uviol lamps are arranged with the capable M row of N, wherein, and N >=1, M >=1.And in other examples of the present invention, uviol lamp group 220 comprises a plurality of uviol lamps, and a plurality of uviol lamps are configured to circular arrangement.Certainly, persons of ordinary skill in the art may appreciate that the present invention is not limited to this, the spread geometry of uviol lamp group 220 can also be for example ellipse or polygons of other types, as long as can be covered with the below, bottom of fruit and vegetable box 400 evenly distributedly.
A kind of refrigerator according to second aspect present invention embodiment comprises: refrigerating chamber 300, chamber door 500, fruit and vegetable box 400 and degradation of pesticide assembly, wherein the degradation of pesticide assembly is according to the degradation of pesticide assembly of describing among the first aspect present invention embodiment.
As shown in Figure 1, the front side of refrigerating chamber 300 is opened wide, and chamber door 500 is used to open and close refrigerating chamber 300.Fruit and vegetable box 400 is placed in the refrigerating chamber 300, and is as shown in Figure 4, and recess 410 is formed at the bottom of the rear wall of fruit and vegetable box 400, and alternatively, the bottom of fruit and vegetable box 400 is transparent electromagnetic wave transparent material.Certainly, the bottom of fruit and vegetable box 400 also can be nontransparent common material, as long as can see through ultraviolet wavelength.Atomising device 100 is located between the recess 410 of postnotum and fruit and vegetable box 400 of refrigerating chamber 300; Wherein be formed with fog inlet (scheming not shown) on the roof of recess 410; Fog inlet is corresponding to the piezoelectric ceramic vibrator in the atomising device 100 130, so that along with piezoelectric ceramic vibrator 130 makes water fogging in the fruit and vegetable box 400.
In some embodiments of the invention, atomising device 100 removably is located in the refrigerating chamber 300 of refrigerator, thereby can dismantle easily to add water, cleaning or maintenance.
Refrigerator according to the embodiment of the invention; Through adopting the degradation of pesticide assembly, i.e. atomising device 100 and degradation of pesticide device 200, the refrigeration effect that both can bring into play refrigerator thus prolongs storage period; Can the agricultural chemicals on the fruits and vegetables article be shifted and special degraded again; Thereby improved foodsafety, broken through the limitation and the unicity of original degradation technique effectively, aspect practicality, improved a lot.
For example constitute refrigerating chamber and control according to other of the refrigerator of the embodiment of the invention and form and wait and operation all is known for those of ordinary skills, be not described in detail here.
In the description of this specification, the description of reference term " embodiment ", " some embodiment ", " illustrative examples ", " example ", " concrete example " or " some examples " etc. means the concrete characteristic, structure, material or the characteristics that combine this embodiment or example to describe and is contained at least one embodiment of the present invention or the example.In this manual, the schematic statement to above-mentioned term not necessarily refers to identical embodiment or example.And concrete characteristic, structure, material or the characteristics of description can combine with suitable manner in any one or more embodiment or example.
Although illustrated and described embodiments of the invention; Those having ordinary skill in the art will appreciate that: under the situation that does not break away from principle of the present invention and aim, can carry out multiple variation, modification, replacement and modification to these embodiment, scope of the present invention is limited claim and equivalent thereof.

Claims (9)

1. a degradation of pesticide assembly that is used for refrigerator is characterized in that, comprising:
Atomising device; Said atomising device be located in the refrigerating chamber of said refrigerator and the postnotum setting of contiguous said refrigerator be suitable for in the fruit and vegetable box that is sent to refrigerator behind the water ultrasonic atomization so that the agricultural chemicals on the fruits and vegetables article in the said fruit and vegetable box is separated out, said atomising device comprises:
Water tank limits the spatial accommodation that holds water in the said water tank, and the open-top of said water tank;
Lid, said lid removably is located at the top of said water tank;
Piezoelectric ceramic vibrator, said piezoelectric ceramic vibrator are installed on the said lid; With
Absorbent member, said absorbent member offsets through spring and said piezoelectric ceramic vibrator and the water in the said water tank is inhaled
Receive to contacting with said piezoelectric ceramic vibrator; And
Degradation of pesticide device, said degradation of pesticide device are located in the refrigerating chamber of said refrigerator so that the agricultural chemicals on the fruit in the said fruit and vegetable box is degraded.
2. the degradation of pesticide assembly that is used for refrigerator according to claim 1 is characterized in that said absorbent member is a sponge strip.
3. the degradation of pesticide assembly that is used for refrigerator according to claim 1 is characterized in that, said degradation of pesticide device comprises:
Adsorption layer contains the catalyst catalyst that is useful on degrading pesticide on the said adsorption layer, said adsorption layer is suitable for removably being located on the diapire in the said fruit and vegetable box; With
The below that uviol lamp group, said uviol lamp group are suitable for being located at said fruit and vegetable box is to shine said adsorption layer.
4. the degradation of pesticide assembly that is used for refrigerator according to claim 3 is characterized in that said uviol lamp group comprises a plurality of uviol lamps, and said a plurality of uviol lamps are arranged with the capable M row of N, wherein, and N >=1, M >=1.
5. the degradation of pesticide assembly that is used for refrigerator according to claim 3 is characterized in that said uviol lamp group comprises a plurality of uviol lamps, and said a plurality of uviol lamps are configured to circular arrangement.
6. according to claim 4 or the 5 described degradation of pesticide assemblies that are used for refrigerator, it is characterized in that said ultraviolet wavelength is approximately 250nm.
7. a refrigerator is characterized in that, comprising:
Refrigerating chamber, the front side of said refrigerating chamber is opened wide;
Be used to open and close the chamber door of said refrigerating chamber;
Fruit and vegetable box, said fruit and vegetable box is placed in the said refrigerating chamber, and recess is formed at the bottom of the rear wall of said fruit and vegetable box;
According to each described degradation of pesticide assembly that is used for refrigerator among the claim 1-6, said atomising device is located between the recess of postnotum and said fruit and vegetable box of said refrigerating chamber; Wherein
Be formed with fog inlet on the roof of the female portion, said fog inlet is corresponding to the piezoelectric ceramic vibrator in the said atomising device.
8. refrigerator according to claim 7 is characterized in that said atomising device removably is located in the refrigerating chamber of said refrigerator.
9. refrigerator according to claim 7 is characterized in that the bottom of said fruit and vegetable box is processed by transparent electromagnetic wave transparent material.
CN2011102692183A 2011-09-05 2011-09-05 Pesticide degradation subassembly for refrigerator and refrigerator with same Active CN102435038B (en)

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Cited By (6)

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Publication number Priority date Publication date Assignee Title
CN103604266A (en) * 2013-12-06 2014-02-26 合肥华凌股份有限公司 Refrigerator
CN105276907A (en) * 2014-07-16 2016-01-27 Bsh家用电器有限公司 Household refrigerating appliance with food processing unit and method of operating same
CN110579055A (en) * 2019-09-27 2019-12-17 长虹美菱股份有限公司 Refrigerator with pesticide residue reducing function
CN111811195A (en) * 2019-04-12 2020-10-23 合肥华凌股份有限公司 Drawer assembly and refrigerator
CN111802563A (en) * 2019-04-12 2020-10-23 合肥华凌股份有限公司 Photolysis method, computer storage medium, computer program product and refrigeration device
CN112013622A (en) * 2020-09-27 2020-12-01 惠而浦(中国)股份有限公司 Shelf with pesticide degradation function and refrigerator

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103604266A (en) * 2013-12-06 2014-02-26 合肥华凌股份有限公司 Refrigerator
CN103604266B (en) * 2013-12-06 2015-11-25 合肥华凌股份有限公司 Refrigerator
CN105276907A (en) * 2014-07-16 2016-01-27 Bsh家用电器有限公司 Household refrigerating appliance with food processing unit and method of operating same
CN105276907B (en) * 2014-07-16 2020-04-07 Bsh家用电器有限公司 Domestic refrigeration appliance having a food processing unit and method for operating the same
CN111811195A (en) * 2019-04-12 2020-10-23 合肥华凌股份有限公司 Drawer assembly and refrigerator
CN111802563A (en) * 2019-04-12 2020-10-23 合肥华凌股份有限公司 Photolysis method, computer storage medium, computer program product and refrigeration device
CN110579055A (en) * 2019-09-27 2019-12-17 长虹美菱股份有限公司 Refrigerator with pesticide residue reducing function
CN112013622A (en) * 2020-09-27 2020-12-01 惠而浦(中国)股份有限公司 Shelf with pesticide degradation function and refrigerator

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