CN102431255A - Composite material having solar cell and production method thereof - Google Patents
Composite material having solar cell and production method thereof Download PDFInfo
- Publication number
- CN102431255A CN102431255A CN2011102791687A CN201110279168A CN102431255A CN 102431255 A CN102431255 A CN 102431255A CN 2011102791687 A CN2011102791687 A CN 2011102791687A CN 201110279168 A CN201110279168 A CN 201110279168A CN 102431255 A CN102431255 A CN 102431255A
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- Prior art keywords
- resin glue
- solar cell
- transparent resin
- layer
- high transparent
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002131 composite material Substances 0.000 title claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 5
- 229920005989 resin Polymers 0.000 claims abstract description 74
- 239000011347 resin Substances 0.000 claims abstract description 74
- 239000010410 layer Substances 0.000 claims abstract description 48
- 239000004744 fabric Substances 0.000 claims abstract description 46
- 239000003292 glue Substances 0.000 claims abstract description 44
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 35
- 239000004917 carbon fiber Substances 0.000 claims abstract description 34
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000000853 adhesive Substances 0.000 claims abstract description 7
- 230000001070 adhesive effect Effects 0.000 claims abstract description 7
- 239000000565 sealant Substances 0.000 claims abstract description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 8
- 239000011229 interlayer Substances 0.000 claims description 8
- 239000007921 spray Substances 0.000 claims description 8
- 239000002344 surface layer Substances 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 7
- 238000012545 processing Methods 0.000 claims description 6
- 239000003822 epoxy resin Substances 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- 229920001567 vinyl ester resin Polymers 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000002390 adhesive tape Substances 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 239000013078 crystal Substances 0.000 claims description 4
- 230000002093 peripheral effect Effects 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims description 3
- 238000013461 design Methods 0.000 claims description 3
- 238000013459 approach Methods 0.000 claims description 2
- 230000001815 facial effect Effects 0.000 claims description 2
- 229920005749 polyurethane resin Polymers 0.000 claims description 2
- 238000002834 transmittance Methods 0.000 claims description 2
- 239000012790 adhesive layer Substances 0.000 abstract 2
- 238000005507 spraying Methods 0.000 abstract 2
- 238000000465 moulding Methods 0.000 abstract 1
- 238000005086 pumping Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- 230000002950 deficient Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000005336 safety glass Substances 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Body Structure For Vehicles (AREA)
- Laminated Bodies (AREA)
Abstract
The invention relates to a composite material having a solar cell for producing automobile components and a production method thereof. The composite material comprises a plurality of layers which are laminated layer upon layer and connected with each other, wherein, the layers successively comprise a high transparent resin adhesive layer and an enhancement layer from top to bottom, the solar cell is buried in the high transparent resin adhesive layer or embedded in the bottom surface. The composite material has the advantages of light weight, high strength, and low cost. The method for producing the composite material effectively and rapidly comprises the following steps: spraying a layer of glue on the surface of a die by using a high transparent resin adhesive; putting the solar cell in the die; spraying a layer of the adhesive on the superficial layer of the die again; paving carbon fibers or carbon fabrics in the die; pasting an adhesive sealant on the periphery and inner side of the die; successively paving a demolding cloth, a flow conducting cloth, and a vacuum bag film on the surface of the carbon fiber layer, and arranging a flow conducting pipe; carrying out vacuum pumping on the die, and detecting the degree of vacuum by using a leak detector; absorbing a common resin adhesive; after infiltrating the carbon fibers by the common resin adhesive and solidifying, molding a product.
Description
Technical field
The present invention relates to a kind of be used to make automobile component have composite of solar cell and preparation method thereof.
Background technology
Because global energy crisis and environmental problem is increasingly serious, people are more and more urgent to the demand of new forms of energy and pollution-free regenerative resource, and solar energy power generating is rising in a new and renewable sources of energy technical field.Solar energy is used for automobile, also is that people seek assiduously as energy source of car.Yet solar cell is easy to suffer breakage or destruction under the unshielded situation in the external world; Cause its disabler, so solar cell on the one hand must there be strong protective device, adopts the protective layer of safety glass usually as solar cell; Cost is higher, and on the other hand, solar energy is as automobile power or its part source; It is enough big to necessarily require solar energy to convert the energy of automobile into, and vehicle weight is enough light, could satisfy the whole need for electricity of automobile like this.It is heavy that existing above-mentioned phenomenon has caused the practical application of solar cell often to hinder, and attends to one thing and lose sight of another, and can't obtain two effects of benefiting mutually.
Summary of the invention
Primary and foremost purpose of the present invention provides a kind of composite that has solar cell simple in structure, and under the prerequisite that guarantees the solar cell operate as normal, to guarantee that its weight is light, intensity is high, and cost is low.
For realizing above-mentioned purpose; The present invention has adopted following technical scheme: a kind of composite that has solar cell; Constitute by a plurality of mutually range upon range of and layers that connect; Said each layer from top to bottom is followed successively by: the high transparent resin glue-line, be used to increase the enhancement layer of high transparent resin glue-line intensity, said solar cell is embedded in the high transparent resin glue-line or to be embedded at its bottom facial.
Major advantage of the present invention is: because high transparent resin itself has the splendid characteristics of the machine-shaping of being easy to, lighter weight and light transmission; Have insulating properties, high-impact performance simultaneously; Can be used as good solar cell overcoat uses; And the lower defective of easy deformation of itself and intensity can overcome according to the enhancement layer that is attached to its back side, makes finally that the present invention has in light weight, high strength, high-modulus, anti-creep, self lubricity is good, wearability is good, shaping shrinkage rate is little, is prone to aspect advantages such as machine-shaping and cost are low.
Another object of the present invention provides a kind of preparation method that has the composite of solar cell, can effectively reach and produce the composite that has solar cell of the present invention fast.
For realizing above-mentioned purpose, the present invention has adopted following technical scheme:
This technical scheme may further comprise the steps:
An automobile component mould is provided, uses high transparent resin glue at its die surface spray one deck glue, as the first high transparent resin glue-line;
Solar cell is placed on request the upper surface layer of the first high transparent resin glue-line of mould;
Re-use high transparent resin glue at above-mentioned upper surface layer spray one deck glue, make its whole formation high transparent resin glue-line;
Carbon fiber or carbon fibre fabric are laid the high transparent resin Jiao Shangbiaomiancengchu in the mould, according to requirement of products design carbon fiber thickness or the carbon fibre fabric number of plies and laying formation carbon fiber layer;
At the peripheral sealant tape that pastes of mould, the inboard double faced adhesive tape that pastes, under go on foot operation and get ready;
Lay release cloth on the carbon fiber layer surface and it is carried out the integral body covering, on release cloth, lay again and the whole flow-guiding cloth that covers, after laying finishes, its redundance is cut out according to the product size;
Integral coating vacuum bag film outside the flow-guiding cloth top layer is provided for the mozzle of water conservancy diversion ordinary resin glue in the mould periphery, said mozzle is communicated with the interlayer between external equipment and carbon fiber layer surface and the release cloth;
Mould is vacuumized processing and checks vacuum with leak detector, and this moment, vacuum bag film integral body was attached at the flow-guiding cloth top layer;
Ordinary resin glue is inhaled in the interlayer between carbon fiber layer surface and the release cloth;
Treat that ordinary resin glue soaks into carbon fiber and curing fully, peel off the vacuum bag film, remove release cloth and flow-guiding cloth, derive product, the product global formation.
Major advantage of the present invention is: the preparation method according to above-mentioned composite can effectively and efficiently produce the composite that has solar cell of the present invention.
Description of drawings
Fig. 1 is a cross-sectional view of the present invention;
Fig. 2 is the plan view of user mode of the present invention;
Fig. 3-11 is for being that the present invention makes flow chart.
The specific embodiment
A kind of composite that has solar cell; Constitute by a plurality of mutually range upon range of and layers that connect; Said each layer from top to bottom is followed successively by: high transparent resin glue-line 10, be used to increase the enhancement layer 20 of high transparent resin glue-line 10 intensity; Said solar cell 30 is embedded in the high transparent resin glue-line 10 or is embedded at its bottom face, shown in Fig. 1-2.
As further preferred version of the present invention: as shown in Figure 1, said enhancement layer 20 comprises ordinary resin glue-line 21, is folded with between said ordinary resin glue-line 21 and the high transparent resin glue-line 10 and the range upon range of carbon fiber layer that is connected 22 between the two.Like this, rely on the characteristics of carbon fiber high-strength degree, lightweight to remedy the easy deformation and the lower defective of intensity of high transparent resin, guarantee its unitarily formed lightweight simultaneously, further meet the lightweight demand of vehicle.
Further, shown in Fig. 1-2, said solar cell 30 is crystal silicon cell or hull cell, said solar cell 30 is embedded in the high transparent resin glue-line 10 and the parallel high transparent resin glue-line 10 aspect settings of its battery sensitive surface.
A kind of above-mentioned manufacturing approach that has the composite of solar cell may further comprise the steps:
An automobile component mould 40 is provided, uses high transparent resin glue at its mould 40 surface spray one deck glue, as the first high transparent resin glue-line 11, as shown in Figure 3;
Re-use high transparent resin glue at above-mentioned upper surface layer spray one deck glue, make its whole formation high transparent resin glue-line 10, as shown in Figure 5;
Carbon fiber or carbon fibre fabric are laid the high transparent resin Jiao Shangbiaomiancengchu in the mould 40, according to requirement of products design carbon fiber thickness or the carbon fibre fabric number of plies and laying formation carbon fiber layer 22, as shown in Figure 6;
At the peripheral sealant tapes that paste of mould 40, the inboard double faced adhesive tape that pastes, under go on foot operation and get ready;
Lay release cloth 50 and it is carried out the integral body covering on carbon fiber layer 22 surfaces, on release cloth 50, lay again and the whole flow-guiding cloth 60 that covers, after laying finishes, its redundance is cut out according to the product size, as shown in Figure 7;
Integral coating vacuum bag film 70 outside flow-guiding cloth 60 top layers is provided for the mozzle 80 of water conservancy diversion ordinary resin glue in mould 40 peripheries, the interlayer that said mozzle 80 is communicated with between external equipments and carbon fiber layer 22 surfaces and the release cloth 50 is as shown in Figure 8;
Mould 40 is vacuumized processing and checks vacuum with leak detector, and this moment, vacuum bag film 70 integral body were attached at flow-guiding cloth 60 top layers, and are as shown in Figure 9;
Ordinary resin glue is inhaled in the interlayer between carbon fiber layer 22 surfaces and the release cloth 50, and is shown in figure 10;
Treat that ordinary resin glue soaks into carbon fiber and curing fully, peel off vacuum bag film 70, remove release cloth 50 and flow-guiding cloth 60, derive product, the product global formation, shown in figure 11.
Further, in the step as shown in Figure 9, vacuumize processing and check vacuum requirement >=0.095Mpa with leak detector.
High transparent resin glue and ordinary resin glue being done following specializing here limits: said high transparent resin glue is that light transmittance is higher than 70% and resin glue with insulating properties, high-impact, high strength, high ageing-resistant performance.Said ordinary resin glue is epoxide-resin glue or vinyl ester resin glue or unsaturated-resin glue or polyurethane resin adhesive etc.
Describe a kind of preferred embodiment of the present invention below in conjunction with accompanying drawing 3-11, conduct is not to qualification of the present invention.
Solar cell: crystal silicon cell;
Carbon fiber: 3k twill 200g/m2 carbon fibre fabric;
Resin glue: epoxy resin+curing agent, vinyl ester resin;
Automobile component: covering for roofs.
The carbon fiber automobile top-cap procedure of processing that has solar cell is following:
An automobile top-cap mould is provided, uses the glue of epoxy resin+curing agent glue, as the first high transparent resin glue-line at automobile top-cap die surface spray one deck 0.5mm left and right thickness;
Crystal silicon cell is placed on request the upper surface layer of the first high transparent resin glue-line of mould;
Re-use use epoxy resin+curing agent glue and spray the glue of one deck 0.3mm left and right thickness above that, make its whole formation high transparent resin glue-line;
With the upper surface layer place that 3k twill 200g/m2 carbon fibre fabric is laid the high transparent resin glue-line in the mould, lay 8 layers altogether to constitute carbon fiber layer;
At the peripheral sealant tape that pastes of mould, the inboard double faced adhesive tape that pastes, under go on foot operation and get ready;
Lay release cloth on the carbon fiber layer surface and it is carried out the integral body covering, on release cloth, lay again and the whole flow-guiding cloth that covers, after laying finishes, its redundance is cut out according to the product size;
Integral coating vacuum bag film outside the flow-guiding cloth top layer is provided for the mozzle of water conservancy diversion ordinary resin glue in the mould periphery, mozzle is communicated with the interlayer between external equipment and carbon fiber layer surface and the release cloth;
Mould is vacuumized processing and checks vacuum with leak detector, vacuum requirement >=0.095Mpa, this moment, vacuum bag film integral body was attached at the flow-guiding cloth top layer;
Open external equipment, vinyl ester resin glue is sucked in the interlayer between carbon fiber layer surface and the release cloth;
Treat that vinyl ester resin glue soaks into carbon fiber and curing fully, peel off the vacuum bag film, remove release cloth and flow-guiding cloth, derive product, the product global formation.
Claims (7)
1. composite that has solar cell; Constitute by a plurality of mutually range upon range of and layers that connect; It is characterized in that: said each layer from top to bottom is followed successively by: high transparent resin glue-line (10), be used to increase the enhancement layer (20) of high transparent resin glue-line (10) intensity, said solar cell (30) is embedded in the high transparent resin glue-line (10) or to be embedded at its bottom facial.
2. the composite that has solar cell according to claim 1; It is characterized in that: said enhancement layer (20) comprises ordinary resin glue-line (21), is folded with between said ordinary resin glue-line (21) and the high transparent resin glue-line (10) and the range upon range of carbon fiber layer that is connected (22) between the two.
3. the composite that has solar cell according to claim 1 and 2; It is characterized in that: said solar cell (30) is crystal silicon cell or hull cell, and said solar cell (30) is embedded in the high transparent resin glue-line (10) and the parallel high transparent resin glue-line of its battery sensitive surface (10) aspect setting.
4. manufacturing approach that has the composite of solar cell according to claim 1 is characterized in that it may further comprise the steps:
An automobile component mould (40) is provided, uses high transparent resin glue at its mould (40) surface spray one deck glue, as the first high transparent resin glue-line (11);
Solar cell (30) is placed on request the upper surface layer of the first high transparent resin glue-line (11) of mould (40);
Re-use high transparent resin glue at above-mentioned upper surface layer spray one deck glue, make its whole formation high transparent resin glue-line (10);
Carbon fiber or carbon fibre fabric are laid the high transparent resin Jiao Shangbiaomiancengchu in the mould (40), according to requirement of products design carbon fiber thickness or the carbon fibre fabric number of plies and laying formation carbon fiber layer (22);
At the peripheral sealant tape that pastes of mould (40), the inboard double faced adhesive tape that pastes, under go on foot operation and get ready;
Lay release cloth (50) on carbon fiber layer (22) surface and it is carried out the integral body covering, upward lay and whole covering flow-guiding cloth (60) at release cloth (50) again, after laying finishes, its redundance is cut out according to the product size;
Integral coating vacuum bag film (70) outside flow-guiding cloth (60) top layer is provided for the mozzle (80) of water conservancy diversion ordinary resin glue in mould (40) periphery, said mozzle (80) be communicated with external equipment with carbon fiber layer (22) interlayer between the surperficial and release cloth (50);
Mould (40) is vacuumized processing and checks vacuum with leak detector, and this moment, vacuum bag film (70) integral body was attached at flow-guiding cloth (60) top layer;
Ordinary resin glue is inhaled in the interlayer between carbon fiber layer (22) surface and the release cloth (50);
Treat that ordinary resin glue soaks into carbon fiber and curing fully, peel off vacuum bag film (70), remove release cloth (50) and flow-guiding cloth (60), derive product, the product global formation.
5. the preparation method that has the composite of solar cell according to claim 4 is characterized in that: said high transparent resin glue is that light transmittance is higher than 70% resin glue.
6. the preparation method that has the composite of solar cell according to claim 4 is characterized in that: said vacuum requirement >=0.095Mpa.
7. the preparation method that has the composite of solar cell according to claim 4 is characterized in that: said ordinary resin glue is epoxide-resin glue or vinyl ester resin glue or unsaturated-resin glue or polyurethane resin adhesive.
Priority Applications (1)
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CN201110279168.7A CN102431255B (en) | 2011-09-20 | 2011-09-20 | Composite material having solar cell and production method thereof |
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CN201110279168.7A CN102431255B (en) | 2011-09-20 | 2011-09-20 | Composite material having solar cell and production method thereof |
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CN102431255A true CN102431255A (en) | 2012-05-02 |
CN102431255B CN102431255B (en) | 2014-12-24 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103387011A (en) * | 2012-05-10 | 2013-11-13 | 王洪举 | Carbon fiber solar panel car roof |
CN105810776A (en) * | 2014-12-31 | 2016-07-27 | 北京汉能创昱科技有限公司 | Preparation method of carbon fiber solar panel and carbon fiber solar panel thereof |
CN107804177A (en) * | 2017-10-26 | 2018-03-16 | 张娜 | A kind of solar electrically propelled vehicle |
CN109830543A (en) * | 2019-01-31 | 2019-05-31 | 光之科技发展(昆山)有限公司 | A kind of photovoltaic building materials and preparation method thereof |
CN110416340A (en) * | 2019-08-02 | 2019-11-05 | 灵翼飞航(天津)科技有限公司 | A kind of packaging technology of solar panel |
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CN1807492A (en) * | 2005-12-29 | 2006-07-26 | 复旦大学 | Method for preparing inorganic semi-conductor/ conducting polymer composite film by photocatalyzed polymerization |
CN1836899A (en) * | 2006-04-29 | 2006-09-27 | 梁晓斌 | Liquid crystal screen protection paste made of titanium oxide film coating by high vacuum optical plating |
WO2010051355A2 (en) * | 2008-10-31 | 2010-05-06 | Dow Corning Corporation | Photovoltaic cell module and method of forming |
CN101719523A (en) * | 2009-11-18 | 2010-06-02 | 常熟阿特斯阳光电力科技有限公司 | Solar energy battery panel for automobile |
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2011
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CN2646870Y (en) * | 2003-08-25 | 2004-10-06 | 无锡尚德太阳能电力有限公司 | Solar battery skylight |
CN1807492A (en) * | 2005-12-29 | 2006-07-26 | 复旦大学 | Method for preparing inorganic semi-conductor/ conducting polymer composite film by photocatalyzed polymerization |
CN1836899A (en) * | 2006-04-29 | 2006-09-27 | 梁晓斌 | Liquid crystal screen protection paste made of titanium oxide film coating by high vacuum optical plating |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103387011A (en) * | 2012-05-10 | 2013-11-13 | 王洪举 | Carbon fiber solar panel car roof |
CN105810776A (en) * | 2014-12-31 | 2016-07-27 | 北京汉能创昱科技有限公司 | Preparation method of carbon fiber solar panel and carbon fiber solar panel thereof |
CN105810776B (en) * | 2014-12-31 | 2018-06-29 | 北京创昱科技有限公司 | A kind of preparation method of carbon fiber solar panels and its carbon fiber solar panels |
CN107804177A (en) * | 2017-10-26 | 2018-03-16 | 张娜 | A kind of solar electrically propelled vehicle |
CN109830543A (en) * | 2019-01-31 | 2019-05-31 | 光之科技发展(昆山)有限公司 | A kind of photovoltaic building materials and preparation method thereof |
CN109830543B (en) * | 2019-01-31 | 2021-08-10 | 光之科技发展(昆山)有限公司 | Photovoltaic building material and preparation method thereof |
CN110416340A (en) * | 2019-08-02 | 2019-11-05 | 灵翼飞航(天津)科技有限公司 | A kind of packaging technology of solar panel |
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